PUBLICATIONS : 1. Additions-1,3 dipolaires du

PUBLICATIONS :
1. Additions-1,3 dipolaires du diazo-2 propane sur le diacétylène et évolution
photochimique des 3H-pyrazoles formés.
M. Franck-Neumann, P. Geoffroy, J.J. Lohmann Tetrahedron Lett. 1983, 1775.
2. Transpositions et réactions intermoléculaires de vinylalcynylcarbènes.
M. Franck-Neumann, P. Geoffroy Tetrahedron Lett. 1983, 1779.
3. Arynic condensation of ketone enolates 18. Efficient access to benzocyclenones and
polycyclic indanone derivatives.
M.C. Carré, B. Jamart-Grégoire, P. Geoffroy, P. Caubère, S. Ianelli, M. Nardelli
Tetrahedron 1988, 44, 127.
4. Arynic condensation of ketone enolates 19. Synthesis of polycyclic
phenylethanolamines.
P. Geoffroy, A. Mouaddib, M.C. Carré, P. Caubère Tetrahedron Lett. 1988, 1385.
5. Structural influence of the ortho-peri-condensed cycloalkane rings on the conformation
of 2-(hydroxyalkyloxy)indanone cyclisation products.
P. Geoffroy, M.C. Carré, B. Jamart-Grégoire, P. Caubère, S. Ianelli, M. Nardelli
Z.Kristallographie 1988, 185, 239.
6. A simple synthesis of a new family of polycyclic oxygen containing heterocycles.
P. Geoffroy, M.C. Carré, P. Caubère, S. Ianelli, M. Nardelli
J. Heterocyclic Chem. 1989, 26, 65.
7. Structural influence of the ortho-peri-condensed cycloalkane rings on the conformation
of 2-(hydroxyalkyloxy)indanone cyclisation products.
P. Geoffroy, M.C. Carré, B. Jamart-Grégoire, P. Caubère, S. Ianelli, M. Nardelli
Acta Cryst. B 45 1989, 2, 178.
8. Arynic condensations of ketone enolates 20. New access to polycyclic
phenylethanolamines.
M.C. Carré, A.A. Aatif, P. Geoffroy, P. Caubère Synthetic Comm. 1989, 19, 2523.
9. New easy access to benzocyclobutenones derivatives.
M.A. Zouaoui, M.C. Carré, B. Jamart-Groigoire, P. Geoffroy, P. Caubère
Tetrahedron 1989, 45, 5485.
10. Arynic condensation of nitrile anions in the presence of the complex base NaNH2CH3CH2(OCH2CH2)2ONa.
M.C. Carré, A.S. Ezzinadi, M.A. Zouaoui, P. Geoffroy, P. Caubère Synth. Comm.
1989, 19, 3323.
11. Cistulynes : proton NMR and single-crystal X-ray evidence for structure and cation
encapsulation in a rigid, molecular channel model system.
A. Nakano, Y. Li, P. Geoffroy, M. Kim, J.L. Atwood, S. Bott, H. Zhang,
L. Echegoyen, G.W. Gokel Tetrahedron Lett. 1989, 30, 5099.
12. Structures of two products of arynic condensation of ketone enolates.
S. Ianelli, M. Nardelli, D. Belletti, P. Geoffroy, M.C. Carré M. Mouaddib,
P. Caubère Acta Crystallogr., sect C. Crystal Struct. Com. 1990,C467, 1348.
13. Synthesis and bronchospasmolytic effects of benzocyclobutenic and benzocyclenic
compounds.
P. Geoffroy, M.C. Carré, B. Jamart-Grégoire, A. Mouaddib, A.A Aatif, M.A. Zouaoui,
P. Caubère, M. Blanc, J.P. Gnassounou, C. Advenier Eur. J. Med. Chem. 1990, 25,
441.
14. Convergent
syntheses
C7-vinylalkynylcarbene.
in
the
sesquicarene
series
using
a
M. Franck-Neumann, P. Geoffroy, M. Miesch, F. Zaragoza Dörwald Tetrahedron Lett.
1990, 31, 4121.
15. Alkynes and poly (ethylene glycol) derivatives as nucleophiles and catalysts in
substitution reactions of 1-chloroanthraquinones.
J. Fang, T. Lu, H. Kim, I. Delgado, P. Geoffroy, J.L. Atwood, G.W. Gokel
J. Org. Chem. 1991, 56, 7059.
16. The aldol condensation reaction of diene (tricarbonyl) iron complexes. From metal
coordinated trimethylsilyl enol ethers to polyols of known configuration.
M. Franck-Neumann, P.J. Colson, P. Geoffroy, K.M. Taba Tetrahedron Lett. 1992, 33,
1903.
17. One-carbon Friedel-Crafts functionalizations of acyclic diene iron tricarbonyl complexes.
M. Franck-Neumann, P. Bissinger, P. Geoffroy Tetrahedron Lett. 1993, 34,4643.
18. Synthesis of dienic α-ketoesters by Friedel-Crafts reaction of ethyl oxalyl chloride with
tricarbonyl iron complexes of E- and Z- substituted acyclic dienes.
M. Franck-Neumann, P. Geoffroy Tetrahedron Lett. 1994, 35, 7027.
19. Tricarbonyl iron complexes bearing a free diazo group.I.Synthesis and cyclocarbonylation
reactions of α-diazodiene complexes.
M. Franck-Neumann, P. Geoffroy, A.Winling Synlett 1995,341.
20. Tricarbonyl Iron complexes bearing a free diazo group. II. Diene and
trimethylenemethane diazoketon complexes as precursors of highly reactive
ketocarbenes and diazonium cations.
M. Franck-Neumann, P. Geoffroy, A. Winling Tetrahedron Lett. 1995, 36, 8213.
21. Aldol condensation reactions of chiral (dienone) tricarbonyliron complexes.
2. Enantioselective synthesis of the dienic polyols streptenols C and D (Metabolites
from Streptomyces Fimbriatus).
M. Franck-Neumann, P. Bissinger, P. Geoffroy Tetrahedron Lett. 1997, 38, 4469.
22. Aldol condensation reactions of chiral (dienone) tricarbonyliron complexes.
3. Enantioselective total synthesis of 3,6-dideoxyhexoses from lactaldehyde.
M. Franck-Neumann, P. Bissinger, P. Geoffroy Tetrahedron Lett. 1997, 38, 4473.
23. Aldol condensation reactions of chiral (dienone) tricarbonyliron complexes.
4. Enantioselective totale synthesis of 3-deoxypensoses from (-)myrtenal.
M. Franck-Neumann, P. Bissinger, P. Geoffroy Tetrahedron Lett. 1997, 38, 4477.
24. Diene tricarbonyl iron complexes bearing a free diazo group. III. Synthesis of pyrazoles
and chiral complexes with α aminoacid or dienylcyclopropane substructures by 1,3dipolar cycloaddition reactions.
M. Franck-Neumann, P. Geoffroy, A. Winling Tetrahedron Lett. 1998, 39, 5643.
25. Cyclization and fluorination of 5-hexenols with boron trifluoride etherate.
Stereoselective synhesis of (optically active) fluorinated cyclohexane derivatives by
cyclization of ω-pentenyl pentadienol tricarbonyl iron complexes.
M. Franck-Neumann, P. Geoffroy, D. Hanss Tetrahedron Lett. 1999, 40, 8487.
26. Aldol condensation reactions of tricarbonyliron complexes. Easy access to
diastereomerically pure 1,2,3-trisubstituted 1,3-diols from α-substituted dienone
complexes.
M. Franck-Neumann, P. Geoffroy, F. Gumery, P. Bissinger
Tetrahedron Lett. 2000, 41, 4213.
27. Aldol condensation reactions of tricarbonyliron complexes. Towards building blocks
for the synthesis of macrolide antibiotics and fluorinated analogs.
M. Franck-Neumann, P. Geoffroy, F. Gumery Tetrahedron Lett. 2000, 41, 4219.
28. A new method for the demetallation of tricarbonyliron diene complexes by total
hydrogenation with Raney Nickel. Application to a very short synthesis of (+)-[6]gingediol
M. Franck-Neumann, P. Bissinger, P. Geoffroy, S. Adelaide
Tetrahedron Lett. 2001, 42, 6401
29.
Highly stereoselective biomimetic polyene cyclizations using chiral pentadienol
tricarbonyliron complexes
M.Franck-Neumann, P.Geoffroy, D.Hanss Tetrahedron Lett. 2002, 43, 2277
30.
Synthesis of mono- and polycyclic tricarbonyliron cyclohexa-2,4-dienone complexes
and phenols from tosylhydrazones of acyclic dienone complexes.
M.Franck-Neumann, P.Geoffroy, D.Gassmann Synlett, 2002,12,2054-58
31.
Synthesis of tricarbonyliron cyclohexa-2,4-dienone complexes from tosylhydrazones of
acyclic dienone complexes. A novel ansa dicarbonyliron complex by intramolecular
trapping of reaction intermediates of the cyclocarbonylation reaction
M.Franck-Neumann, P.Geoffroy, D.Gassmann, Christophe Cénac J. of Organomet
Chem,2003, 678, 68-71
32.
Inter- and intramolecular carbene reactions of diazoketones tethered to tricarbonyliron
coordinated acyclic dienes. New tricarbonyliron complexes of cyclohexa-2,4-dienone
and cyclopent-2-enone
M.Franck-Neumann, P.Geoffroy, D.Gassmann, Alain Winling Tetrahedron Lett. 2004,
45, 5407.
33.
Different apoptotic mechanisms are involved in the antiproliferative effects of 7betahydroxysitisterol and 7beta-hydroxycholesterol in human colon cancer cells
S.Roussi, A.Winter, F.Gosse, D.Werner, X.Zhang, E.Marchioni, P.Geoffroy, M.Miesch
and F.Raul Cell Death and Differenciation 2005, 12, 128
34.
Gram-scale chromatographic purification of beta-sitosterol. Synthesis and
characterization of beta-sitosterol oxides
X.Zhang, P.Geoffroy, M.Miesch, D.Julien-David, F.Raul, D. Aoudé-Werner,
E.Marchioni Steroids, 2005, 70, 886
35.
Identification and quantitative analysis of beta-sitosterol oxides in vegetable oils by
capillary gas chromatography-mass spectrometry
X.Zhang, D.Julien-David, M.Miesch, P.Geoffroy, F.Raul, S.Roussi, D.Aoudé-Werner,
E.Marchioni Steroids, 2005, 70, 896
36.
Quantitative analysis of beta-sitosterol oxides induced in vegatable oils by natural
sunlight, artificially generated light and irradiation
X.Zhang, D.Julien-David, M.Miesch, F.Raul, P.Geoffroy, D.Aoudé-Werner,
S.Ennahar, E.Marchioni J.Agric. Food Chem 2006, 54, 5410
37.
Perturbation of polyamine metabolism and its relation to cell death in human colon
cancer cells treated by 7 beta-hydroxycholesterol and 7beta-hydroxysitosterol
S.Roussi, F.Gossé, D.Aoudé-Werner, X.Zhang, P.Geoffroy, M.Miesch, E.Marchioni,
F.Raul International Journal of Oncology, 2006, 29, 1549-1554
38.
Mitochondrial perturbation, oxidative stress and lysosomal destabilization are involved
in 7beta-hydroxysitosterol and 7beta-hydroxycholesterol triggered apoptosis in human
colon cancer cells
S.Roussi, F.Gossé, D.Aoudé-Werner, X.Zhang, E.Marchioni, P.Geoffroy, M.Miesch,
F.Raul Apoptosis, 2007, 12, 87-96
39.
Synthesis of highly pure oxyphytosterols and (oxy)phytosterol esters
Part I. Regioselective hydrogenation of stigmasterol: an easy access to oxyphytosterols
P.Geoffroy, D.Julien-David, E.Marchioni, F.Raul, D.Aoudé-Werner, M.Miesch
Steroids, 2008, 73, 702-707
40.
Synthesis of highly pure oxyphytosterols and (oxy)phytosterol esters
Part II. (Oxy)-sitosterol esters derived from oleic acid and from 9,10-dihydroxystearic
acid
D.Julien-David, P.Geoffroy, E.Marchioni, F.Raul, D.Aoudé-Werner, M.Miesch
Steroids, 2008, 73, 1098-1109
41.
Effects of oxidation on the hydrolysis by cholesterol esterase of sitosteryl esters as
compared to a cholesteryl ester
D.Julien-David, S.Ennahar, M.Miesch, P.Geoffroy, F.Raul, D.Aoude-Werner, J.-M.
Lessinger, E.Marchioni Steroids, 2009, 74, 832-836
42.
Synthesis of racemic and enantiomerically pure acetylenic omega-keto esters from 2methyl-1,3-cycloalkanediones and 2-methylcycloalkanones respectively
P.Geoffroy, M.P.Ballet, S.Fink (In part), E.Marchhioni, C.Marcic, M.Miesch
Synthesis, 2010, PSP 175, 0171-0179