PDF - Pan Stanford Publishing
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PDF - Pan Stanford Publishing
NanotechAndEnergy.indd 1 7/12/12 11:44:20 AM July 25, 2012 19:6 PSP Book - 9in x 6in Published by Pan Stanford Publishing Pte. Ltd. Penthouse Level, Suntec Tower 3 8 Temasek Boulevard Singapore 038988 Email: [email protected] Web: www.panstanford.com British Library Cataloguing-in-Publication Data A catalogue record for this book is available from the British Library. Nanotechnology and Energy: Science, Promises, and Limits c 2013 Pan Stanford Publishing Pte. Ltd. Copyright All rights reserved. This book, or parts thereof, may not be reproduced in any form or by any means, electronic or mechanical, including photocopying, recording or any information storage and retrieval system now known or to be invented, without written permission from the publisher. For photocopying of material in this volume, please pay a copying fee through the Copyright Clearance Center, Inc., 222 Rosewood Drive, Danvers, MA 01923, USA. In this case permission to photocopy is not required from the publisher. ISBN 978-981-4310-81-9 (Hardcover) ISBN 978-981-4364-06-5 (eBook) Printed in the USA 00-Lambauer–prelims July 25, 2012 19:6 PSP Book - 9in x 6in 00-Lambauer–prelims Contents Notes on the Contributors Foreword 1. Challenges in the Energy Sector and Future Role of Nanotechnology Jochen Lambauer, Dr. Ulrich Fahl, and Prof. Dr. Alfred Voß 1.1 The Energy Sector in Germany and Its Future Challenges 1.1.1 Demographic and Economic Development 1.1.2 Development of Prices for Fossil Energy Sources 1.1.3 Primary Energy Consumption 1.1.4 Electricity Generation 1.1.5 Final Energy Consumption 1.1.6 Energy Productivity and Energy Intensity 1.1.7 Emissions 1.2 Nanotechnology and Energy 2. Principles of Nanotechnology 2.1 Definition and Classification Jochen Lambauer, Dr. Ulrich Fahl, and Prof. Dr. Alfred Voß 2.2 Scientific and Technical Background Jochen Lambauer, Dr. Ulrich Fahl, and Prof. Dr. Alfred Voß 2.2.1 Nanomaterials 2.2.1.1 Point-shaped structures 2.2.1.2 Line-shaped structures 2.2.1.3 Layer structures xiii xxi 1 1 2 2 3 6 9 9 12 15 21 21 25 25 25 27 28 July 25, 2012 19:6 PSP Book - 9in x 6in 00-Lambauer–prelims vi Contents 2.2.1.4 Pore structures 2.2.1.5 Complex structures 2.2.2 Top-Down and Bottom-Up Strategy 2.2.3 Tools and Production Processes 2.2.3.1 Vapour deposition 2.2.3.2 Manufacturing from liquid or dissolved raw materials 2.2.3.3 Manufacturing from solid raw materials 2.2.3.4 Lithography 2.2.3.5 Self-organisation 2.2.3.6 Nanoanalytics 2.3 Innovation and Economic Potential Dr. Wolfgang Luther 2.3.1 Nanotechnology as a Cross-Cutting Innovation Field 2.3.2 Economic Relevance of Nanotechnology 2.3.3 Nanotechnology Companies in the Value-Added Chain 2.4 Risk and Safety Issues Niels Boeing 2.4.1 The Image of Nanotechnology: Three Phases 2.4.1.1 Pre-2000: the futuristic phase 2.4.1.2 2000–2006: the nanomarkets phase 2.4.1.3 Since 2006: the sceptical phase 2.4.2 A Systematic Approach to Nanotechnology Risks 2.4.2.1 Primary nanorisks: impacts on health and the environment 2.4.2.2 Secondary nanorisks: impacts on society and the economy 2.4.3 Conclusion 2.5 Public Perception of Nanotechnologies: Challenges and Recommendations for Communication Strategies and Dialogue Concepts Dr. Antje Grobe and Nico Kreinberger 2.5.1 Introduction 2.5.2 Psychological, Social, and Cultural Factors of Risk Perception 29 30 31 33 37 38 38 39 40 40 42 42 47 50 54 54 55 55 56 57 58 63 63 68 68 69 July 25, 2012 19:6 PSP Book - 9in x 6in 00-Lambauer–prelims Contents 2.5.3 Public Perception of Nanotechnologies: an International Comparison 2.5.4 Consumer’s Perception of Nanotechnologies in German Language Areas 2.5.5 Attitudes Towards Nanotechnologies in the Energy Sector 2.5.6 Requirements for Consumer Communication 2.5.7 Conclusions: Recommendations for Communication Strategies and Dialogue Concepts 3. Examples for Nanotechnological Applications in the Energy Sector 3.1 Aerogels: Porous Sol-Gel-Derived Solids for Applications in Energy Technologies Dr. Gudrun Reichenauer 3.1.1 Aerogels–Synthesis and Properties 3.1.1.1 Synthesis 3.1.1.2 Structural properties 3.1.2 Properties Meeting Applications 3.1.2.1 Thermal insulation 3.1.2.2 Components for energy storage 3.1.2.3 Catalysts supports 3.1.2.4 Other energy-related fields of application 3.1.3 Problems to be Solved for a Broad Introduction of Aerogels in Energy-Related Applications 3.1.4 Conclusions 3.2 Energy Sources and Conversion 3.2.1 Dye Solar Cells Dr. Claus Lang-Koetz, Dr. Andreas Hinsch, and Dr. Severin Beucker 3.2.1.1 DSC technology and its application 3.2.1.2 Characteristics of DSC modules 3.2.1.3 Manufacturing steps for DSC modules 3.2.1.4 Industrial production for DSC modules 71 76 82 83 85 89 90 90 90 93 94 94 102 106 107 107 109 114 114 115 116 118 119 vii July 25, 2012 19:6 PSP Book - 9in x 6in 00-Lambauer–prelims viii Contents 3.2.1.5 Application scenarios for future DSC products 3.2.1.6 Environmental impact 3.2.1.7 Conclusions and outlook 3.2.2 Nanoscale Thermoelectrics – a Concept for Higher Energy Efficiency? Dr. Harald Böttner and Jan König 3.2.2.1 Introduction 3.2.2.2 Initial concepts of nanoscale thermoelectrics 3.2.2.3 Current concepts of nanoscale thermoelectrics 3.2.2.4 Nanocomposite bulk materials 3.2.2.5 Summary and outlook 3.2.3 Nanostructured Ceramic Membranes for Carbon Capture and Storage Dr. Martin Bram, Dr. Tim van Gestel, Dr. Wilhelm Albert Meulenberg, and Prof. Dr. Detlev Stöver 3.2.3.1 Requirements of membranes for gas separation in post- and pre-combustion power plants 3.2.3.2 Gas separation with microporous ceramic membranes 3.2.3.3 Membrane materials 3.2.3.4 Performance of microporous ceramic membranes 3.2.3.5 Summary and conclusion 3.3 Energy Storage and Distribution 3.3.1 Materials for Energy Storage Dr. Wiebke Lohstroh 3.3.1.1 Materials for hydrogen storage 3.3.1.2 Physiorption materials 3.3.1.3 Chemisorption materials 3.3.1.4 Materials for energy storage in batteries 3.3.1.5 ‘New’ battery materials 3.3.1.6 Conclusions 122 123 125 128 129 130 131 138 142 144 144 147 149 153 159 162 162 165 166 167 176 180 184 July 25, 2012 19:6 PSP Book - 9in x 6in 00-Lambauer–prelims Contents 3.4 Energy Use 3.4.1 Nanotechnology in Construction Dr. Wenzhong Zhu 3.4.1.1 General development 3.4.1.2 Application areas 3.4.1.3 Future prospect 3.4.2 Active Windows for Daylight-Guiding Applications Andreas Jäkel, Qingdang Li, Jörg Clobes, Volker Viereck, and Prof. Dr. Hartmut Hillmer 3.4.2.1 Introduction and basics 3.4.2.2 Complete active window 3.4.2.3 Regulation concepts for active windows 3.4.2.4 Production of micromirror arrays 3.4.3 Energy Efficiency Potential of Nanotechnology in Production Processes Dr. Karl-Heinz Haas 3.4.3.1 Introduction 3.4.3.2 Types and properties of nanoscaled materials 3.4.3.3 Production processes of nanomaterials 3.4.3.4 Nanotechnologies in production processes 3.4.3.5 The vision of molecular manufacturing 3.4.3.6 Conclusion, summary, and outlook 4. Potential Analysis and Assessment of the Impact of Nanotechnology on the Energy Sector Until 2030 4.1 Methodological Approach Jochen Lambauer, Dr. Ulrich Fahl, and Prof. Dr. Alfred Voß 4.2 Environmental Impact and Energy Demand of Nanotechnology Michael Steinfeldt 190 190 190 193 200 203 203 208 211 212 215 215 216 217 220 231 232 241 241 247 ix July 25, 2012 19:6 PSP Book - 9in x 6in 00-Lambauer–prelims x Contents 4.2.1 Environmental Reliefs Potentials of Nanotechnology 4.2.2 Evaluation of Specific Application Contexts: Life Cycle Assessment 4.2.3 Evaluation of Specific Manufactured Nanoparticles 4.3 Potentials of Nanotechnology for Improvements in Energy Efficiency and Emission Reduction Jochen Lambauer, Dr. Ulrich Fahl, and Prof. Dr. Alfred Voß 4.3.1 Energy Sources and Conversion 4.3.1.1 Solar heat and photovoltaics 4.3.1.2 Fuel cells 4.3.1.3 Fuel additives 4.3.1.4 Nanostructured membranes 4.3.1.5 Thermoelectric generators 4.3.2 Energy Storage and Distribution 4.3.3 Energy Use 4.3.3.1 LED and OLED in illumination 4.3.3.2 New display technologies 4.3.3.3 Ultra-high-performance concrete 4.3.3.4 Insulation with vacuum-insulation panels 4.3.3.5 Polycarbonates for automotive glazing 4.3.3.6 Nano-lacquers 4.3.3.7 Nanocatalysts 4.3.3.8 Nanoparticles in synthetic production 4.3.3.9 Nanpoarticles in tyre compounds 4.3.3.10 Nano-based coatings to reduce friction 4.3.4 Theoretical Potentials of Nanotechnology 4.4 Scenario and Sensitivity Analyses for Impacts of Nanotechnological Applications Jochen Lambauer, Dr. Ulrich Fahl, and Prof. Dr. Alfred Voß 4.4.1 Energy Sources and Conversion 4.4.1.1 Solar heat and photovoltaics 4.4.1.2 Fuel cells 248 249 255 265 266 266 271 271 272 272 273 274 274 276 279 281 282 282 283 284 284 285 286 296 298 298 302 July 25, 2012 19:6 PSP Book - 9in x 6in 00-Lambauer–prelims Contents 4.4.1.3 Fuel additives 4.4.1.4 Nano-based membranes for carbon capture and storage 4.4.1.5 Thermoelectric generators 4.4.2 Energy Storage and Distribution 4.4.3 Energy Use 4.4.3.1 LED and OLED in illumination 4.4.3.2 New display technologies 4.4.3.3 Ultra-high-performance concrete 4.4.3.4 Insulation with vacuum-insulation panels 4.4.3.5 Polycarbonates for automotive glazing 4.4.3.6 Nano-lacquers 4.4.3.7 Nanocatalysts for styrene manufacturing 4.4.3.8 Nanoparticles in synthetic production 4.4.3.9 Nanoparticles in tyre compounds 4.4.3.10 Nano-based coatings to reduce friction 4.5 Comprehensive Subsumption of Nanotechnology in the Energy Sector Jochen Lambauer, Dr. Ulrich Fahl, and Prof. Dr. Alfred Voß Index 306 307 309 310 311 311 314 316 317 319 320 322 323 324 325 330 341 xi July 25, 2012 19:6 PSP Book - 9in x 6in 00-Lambauer–prelims July 25, 2012 19:6 PSP Book - 9in x 6in Notes on the Contributors Severin Beucker is co-founder of and senior researcher at the Borderstep Institute for Innovation and Sustainability, Berlin. His research focuses on innovation and technology analyses for new technologies. In the project ColorSol, he was responsible for the analysis of market potentials and the development of application scenarios for dye solar cells. Niels Boeing graduated in physics and science theory at Technische Universität Berlin. Since 2002 he has been working as a freelance science writer for major German publications, including Die Zeit and MIT Technology Review (German edition). In 2004 he published the popular-science introduction to nanotechnology Nano?! Die Technik des 21. Jahrhunderts (Rowohlt, Berlin). He lives in Hamburg, Germany. Harald Böttner is head of the Thermoelectric and Integrated Sensor Systems department of the Fraunhofer Institute for Physical Measurement Techniques, Freiburg, Germany. He graduated with a diploma in chemistry from the University of Münster, Germany, in 1974 and received his Ph.D. in 1977 at the same university for his thesis on diffusion and solid state reaction in the quaternary semiconductor II–VI/IV–VI materials system. In 1978 he joined the Fraunhofer Institut für Silicatforschung, Würzburg, Germany, and in 1980 he changed to the present appointment at the Fraunhofer Institute for Physical Measurement Techniques, Freiburg, Germany. From 1980 to 1995 he developed IV–VI infrared semiconductor lasers, while being active in thin film thermoelectrics based on PbTe. He was one of the main inventors of the worldwide first waferscale technology for vertical thermoelectric known under “Micropelt.” He is a board member of the International Thermoelectric Society, of 00-Lambauer–prelims July 25, 2012 19:6 xiv PSP Book - 9in x 6in Notes on the Contributors the European Thermoelectric Society, and co-founder of the German Thermoelectric Society. Martin Bram graduated as a materials scientist from the Friedrich Alexander University of Erlangen-Nürnberg in 1995 and received his Ph.D. from the University of Saarbrücken in 1999. After joining Forschungszentrum Jülich in 1999, the main topic of his research has been materials in energy systems. He is currently head of a research group Powder Metallurgy and Composite Materials. Dr. Bram is continuously looking for new solutions if metals or ceramics or even composites are required with defined functional porosity. His expertise in materials science and technology enables him to fruitfully combine materials synthesis, phase composition, heat treatment, grain growth, and chemical interaction during processing, as well as during operation. Ulrich Fahl studied economics at the University of Freiburg from 1978 to 1983 and received his Ph.D. in 1990 from the University of Stuttgart on a decision support system for energy economy and energy policy. Since 1990 he heads the Energy Economics and Systems Analysis department at the Institute of Energy Economics and the Rational Use of Energy (IER) (staff of 20 researchers). He is responsible for national and international research activities in the field of energy and electricity demand and supply analysis, energy and electricity modelling, energy and environmental management in industry and commerce, sustainable development of energy systems, energy and transport issues, and energy and climate. Regine Geerk-Hedderich is a physicist. She studied solid state physics at the Central Institute for Solid State Physics and Material Research of the TU Dresden (Dr. rer. nat.) and at the FriedrichSchiller-Universität Jena (Dr. sc.). Between 1980 and 1989 she worked as visiting scientist for several months at the Kapitza Institute at the Academy of Science in Moscow and the High Field Magnet Laboratory in Wroclaw. During 1990–91 Dr. GeerkHedderich held a research position at the high field magnet laboratory in Grenoble. Since 1991 she is employed at the Karlsruhe Institute of Technology (Forschungszentrum Karlsruhe). From 1992 to 1993 she held a guest scientist position at the international 00-Lambauer–prelims July 25, 2012 19:6 PSP Book - 9in x 6in 00-Lambauer–prelims Notes on the Contributors superconducting laboratory in Tokyo. Since 1998 she is director the network NanoMat (supra-regional network for nanomaterials, www.nanomat.de), which has 29 partners from industry and academia. Antje Grobe obtained her M.A. from the University of Stuttgart, Germany, where she gives lectures on dialogue management and leads several national and EU-funded research projects on risk assessment and risk perception with an emphasis on nanotechnologies and climate change issues. Grobe is managing director of DialogBasis, a science-based think-tank and dialogue platform. Since more than 15 years, she has been facilitating stakeholder dialogues and citizen participation exercises in Europe on behalf of governmental bodies, academia, industry, and civil society organizations. She serves as an expert on nanotechnologies for the European Commission and the Swiss Confederation and was with the German government’s NanoKommission from 2006 to 2011. Karl-Heinz Haas studied chemistry and obtained his Ph.D. from the University of Karlsruhe, Germany, in 1983. He joined Fraunhofer ISC (sol-gel, materials, hybrid polymers) and worked for BASF in the central polymer research lab from 1988 to 1995. In 1995 Dr. Haas became head of the hybrid polymer department at ISC. Since 2004 he is managing director of the Fraunhofer Alliance Nanotechnology and is currently also head of the New Business Development department at ISC. Hartmut Hillmer received his Ph.D. in physics from Stuttgart University in 1989, after which he joined the Research Center German Telekom, Darmstadt. In 1991 he became a guest scientist at NTT Optoelectronic Laboratories, Japan. Since 1999 he is professor of technological electronics at the Institute of Nanostructure Technologies and Analytics, University of Kassel, Germany. In 2006 he received the Grand Prix Europeen for Innovation Award for the patent “Micro Mirror Array.” Dr. Hillmer’s research interests include networked sensors and actuators for smart personal environments, micromirror arrays in intelligent windows, non-invasive optical biomarker detection in breath and tissue, semiconductor lasers, and optical filters for telecommunication. xv July 25, 2012 19:6 xvi PSP Book - 9in x 6in Notes on the Contributors Andreas Hinsch is a physicist who has been working as a researcher for many years. He is responsible for the dye solar cell activities of Fraunhofer Institute for Solar Energy Systems (ISE), Freiburg, Germany. For the project ColorSol, he was in charge of technology research and development and the technology transfer to the companies involved. Andreas Jäkel studied physics at the University of Kassel, Germany, from 2001 to 2008. In May 2008 he joined the Department of Technological Electronics, University of Kassel, where he worked on his Ph.D. in micro-optical and electromechanical systems with a focus on micromirror applications. He is one of the project leaders at the Institute of Nanostructure Technologies and Analytics and responsible for the development of micromirror arrays for active windows. Jan D. König is group leader for the Thermoelectric Energy Conversion branch in the Thermoelectric Systems department of the Fraunhofer Institute for Physical Measurement Techniques (IPM), Freiburg, Germany. He is project manager in different projects regarding thermoelectric materials research, measurement systems, and thermoelectric generator development. Some of his remarkable projects include the design and fabrication of a fully automated material measurement setup, standardization of thermoelectric metrology, and the development of a smallscale production of thermoelectric generator for high-temperature application. König’s current activities cover nanoscale bulk and thinfilm research on Bi2 Te3 , PbTe, and silicide-based materials as well as the development of a high-temperature generator for automotive applications. Since 2009 he is executive board member of the German Thermoelectric Society. Nico Kreinberger has a B.A. from University of Stuttgart, Germany, where he studied politics, sociology, and empirical social research. In the EU-FP 7–funded NanoCode project he conducted an international survey and several conferences on the responsible research of nanotechnologies. At the Switzerland-based Risk Dialogue Foundation he works in the fields of nanotechnologies, microsystem technologies, and climate change in several stakeholder dialogues. 00-Lambauer–prelims July 25, 2012 19:6 PSP Book - 9in x 6in 00-Lambauer–prelims Notes on the Contributors Jochen Lambauer has studied environmental engineering (Dipl.Ing., B.Sc.) at the University of Stuttgart, Germany, and the University of Iceland (Háskolı́ Islands, Reykjavı́k), Iceland. Since 2005 he is a research associate at the Institute for Energy Economics and the Rational Use of Energy (IER) at the University of Stuttgart. Lambauer is responsible for research activities in the fields of rational use of energy, energy efficiency, virtual power plants, demand response, and energy impacts of innovations (e.g., nanotechnology). In addition, he is managing director and scientific coordinator of the Graduate and Research School, Efficient Use of Energy, Stuttgart (GREES). Claus Lang-Koetz is an environmental engineer. He obtained his doctorate degree from the University of Stuttgart. He was the manager of the group “Innovative Technologies” at the Fraunhofer Institute for Industrial Engineering IAO, Stuttgart, Germany, and coordinator of the research project ColorSol. He is now working in the machine and plant manufacturing industry as an innovation manager. Qingdang Li studied electronics engineering at the Wuhan University of Technology, China, from 1993 to 1997, economics at the Harbin Institute of Technology, China, from 2000 to 2002, and mechanical engineering at the University of Paderborn from 2003 to 2005. In August 2006 Li joined the Department of Technological Electronics, University of Kassel, Germany, where he worked on his Ph.D. in micro-optical and electromechanical systems with a focus on micromirror applications. Wiebke Lohstroh received her doctorate in physics in 1999 at the Georg-August Universität, Göttingen, Germany. During her stay as postdoctoral fellow at Oxford University (UK) and at Vrije Universiteit, Amsterdam (the Netherlands), she investigated structural and optical properties of thin films during hydrogen uptake. From 2005 to 2011 she worked at the Institute of Nanotechnology, Karlsruhe Institute of Technology (KIT), Germany. In 2011, she joined the Forschungsneutronenquelle Heinz MaierLeibnitz (FRM II), TU München, Germany. Her work focuses on xvii July 25, 2012 19:6 PSP Book - 9in x 6in xviii Notes on the Contributors materials development for energy storage, i.e., solid state hydrogen storage systems and electrode materials for secondary batteries. Wolfgang Luther works as a consultant and project manager at the VDI Technologiezentrum GmbH in Duesseldorf, Germany, since 1999. He holds a degree in chemistry, a degree in economics, and a Ph.D. in analytical chemistry. Dr. Luther’s specific field of competence is the socioeconomic assessment of emerging technologies, in particular nanotechnology. His current main field of activity is the coordination of innovation accompanying measures for nanotechnology within the funding programme of the Federal Ministry of Research and Education. Gudrun Reichenauer works in the field of materials science and physics, with a particular focus on the synthesis and characterization of aerogels and xerogels since more than 20 years. During 1999–2000 she was a research assistant in the group of Prof. G. W. Scherer at Princeton University and the Princeton Materials Institute, NJ, USA. On her return to Germany she became the head of the Nanomaterials group of the Bavarian Center for Applied Energy Research (Division: Functional Materials for Energy Technology). Her current research is focussed on the synthesis and characterization of nanoporous materials in general, with special emphasis on sol-gel-derived materials and nanofibres synthesized by chemical vapour deposition. Application-directed activities concern, in particular, thermal insulations, electrodes in electrochemical devices, IR opacifiers, and materials for gas separation and gas storage. Michael Steinfeldt, a diploma’d engineer, is senior scientist at the Faculty of Production Engineering, University of Bremen, Germany, since 2005. His main focus of research is environmental valuation and methods of technology assessment and life cycle assessment. Current research themes are green and sustainable nanotechnology. After some years as a process engineer in an industrial enterprise he worked as senior researcher and project manager at the Institute for Ecological Economy Research (IÖW) gGmbH, Berlin, in the field corporate environmental management (1992–2004). Volker Viereck studied physics at the Humboldt University, Berlin, and at the University of Kassel, Germany, from 1997 to 2004. He 00-Lambauer–prelims July 25, 2012 19:6 PSP Book - 9in x 6in 00-Lambauer–prelims Notes on the Contributors worked out his diploma thesis at the Volkswagen Konzernforschung, Wolfsburg, on nanoparticle measurement in 2003. In June 2004 he joined the Department of Technological Electronics, University of Kassel, where he worked on his Ph.D. in micro-optical and electromechanical systems with a focus on micromirror applications. He is now leader of the Optical MEMS Technologies group there. Alfred Voß received his Dipl.-Ing. degree in energy engineering from the Technical University of Aachen in 1970 and a Ph.D. (Dr.-Ing.) in 1973. In 1990 the University of Stuttgart appointed him director of the Institute of Energy Economics and the Rational Use of Energy. His areas of expertise are new energy technologies, including renewable energy; energy systems and energy modeling; rational use of energy; and energy and sustainability. Wenzhong Zhu is lecturer at and manager of the Scottish Centre of Nanotechnology in Construction Materials, School of Engineering, University of the West of Scotland. His main interests and expertise are in technology and properties of self-compacting concrete and special concretes, nanotechnology in construction, and particularly nano- and micromechanical characterization of materials. xix July 25, 2012 19:6 PSP Book - 9in x 6in 00-Lambauer–prelims July 25, 2012 19:6 PSP Book - 9in x 6in Foreword Heat, light, and mobility are essential for our modern lifestyle. However, some of these resources, such as oil and therefore gas and diesel, are not indefinitely available. Experts on energy expect a further increase in the worldwide energy demand in the next few years. For instance, we can expect the actual numbers to double by 2050. At the same time it seems as if global oil production has already reached its maximum capacity. In order to counter the growing energy shortage, research on energy is being fostered the world over. Nanomaterials play an important role in that matter, as many of the macroscopic properties of energy materials derive from the nanoscale. Compared with the big technological revolutions in the past, it is the small but creative ideas that nowadays spur important innovations. Knowledge gained in and through the world of nanotechnology allows us to ameliorate many existing technologies and to make them more reliable, efficient, and resource friendly. Nanotechnology will break into many different sectors, and the energy industry will see new materials with better properties come up or notice a decrease in the need of materials: high-efficiency accumulators, photovoltaics, compact fuel cells, surface coating. In the car industry we will find light-weight construction, tires with optimal adherence, self-healing varnishes, LEDs, and electromobility. The construction industry and process technology are two sectors that will also profit from the benefits of nanotechnology. This book provides an interdisciplinary approach to the presentation of research results in various energy applications of nanomaterials. We look at individual technologies in their global context and deal with the resulting scientific and technological questions, commercial implementation, and ecological, ethical, and 00-Lambauer–prelims July 25, 2012 19:6 xxii PSP Book - 9in x 6in Foreword social aspects. Not only are physical-chemical basics examined, but subjects and questions concerning communication risks, protection of the environment, health, regulation or science requirements, as well as economic and social implementing are also addressed. Storing electricity in huge quantities is one of the future challenges we will face, especially with the massive expansion of renewable energies. To get a more precise idea of these quantities, we take a hypothetical look at the year 2030. Supposing that until then, 30% of Germany’s entire electricity will be provided by wind, a storage or buffer capacity of about 3000 GWh will be necessary to make up for the energy lost during an almost wind-free week. This is more than 70 times the capacity of our actual pump storage capacity of 40 GWh. A similar problem arises in the face of a temporary energy excess. Along with pump storage plants and air pressure storages, developments in stationary storing solutions are necessary in order to store energy intelligently and to be able to feed the network when needed. Electro-chemical storage options are described in the chapter 3.3.1, “Materials for Energy Storage.” Chapter 3.4.1, “Nanotechnology in Construction,” provides an overview on nanotechnology applications within the construction sector. All over the world, scientists look for new processes in order to enhance energy and ecological assets in the cement production. CO2 emissions in cement production are three to four times higher than, for instance, the entire air traffic’s discharges. Scientists at the Karlsruhe Institute of Technology (KIT) fabricated a new adhesive agent with Celitement, which is comparable to the adhesive in Portland cement (OPC), based on the still unidentified hydraulically active calcium hydro-silicates. Compared with the standard fabrication of Portland cement, 50% of energy and CO2 emissions can be saved during its production. How to use lost heat efficiently with the help of the thermoelectric effect and adequate materials is the subject dealt with in chapter 3.2.2, “Nanoscale Thermoelectrics”. Nanoscalic thermoelectric materials with high Seebeck coefficients show excellent characteristics for technical use — for instance, in the car industry. 00-Lambauer–prelims July 25, 2012 19:6 PSP Book - 9in x 6in 00-Lambauer–prelims Foreword xxiii Light is an elemental aspect of work quality and influences our well-being. Approximately 10% of power requirements are used for lighting appliances, half of which are employed by trade and craft businesses while 25% are used by the industry and another 25% by private households. Energy-saving lighting facilities not only aim to reduce electricity costs but set important ecological accents, a subject that is described in detail in the chapter 3.4.2, “Active Windows for Daylight Guiding Applications.” The further development of coal power plants is focused on the elimination of CO2 by storage below the ground or below the sea level. Chapter 3.2.3, dealing with nanostructured ceramic membranes for carbon capture and storage (CCS), describes an option for technological enhancement of CO2 elimination in power plants. Chapter 4, on the potential analysis and assessment of the impacts of nanotechnology on the energy sector until 2030, does not only cover very interesting subjects, but completes the other chapters. All subjects treated in this book are very important for us today, as the prevailing ecological and societal problems concern all of us. With help of new technologies and common efforts, we can create more awareness and encourage our future generations. Dr. Regine Geerk-Hedderich Managing Director, NanoMat July 25, 2012 19:6 PSP Book - 9in x 6in 00-Lambauer–prelims