Institute for Sanitary Engineering, Water Quality and Solid Waste
Transcription
Institute for Sanitary Engineering, Water Quality and Solid Waste
Universität Stuttgart Universität Stuttgart Universität Stuttgart Institute report 2006-2007 Chair of Sanitary Engineering and Water Quality Management o. Prof. Dr.-Ing. Ulrich Rott Tel.: ++49 (0) 711/685-63711 Water Quality Management and Water Supply | WGW Dipl.-Ing. Ralf Minke Tel.: ++49 (0) 711/685-65423 Industrial Water and Wastewater Technology | IWT Solid Waste | SIA Institute for Sanitary Engineering, Water Quality and Solid Waste Management Dr.-Ing. Klaus Fischer Tel.: ++49 (0) 711/685-65427 Hazardous Waste and Contaminated Sites | SOA Prof. Dr.-Ing. Erwin Thomanetz Tel.: ++49 (0) 711/685-65438 | ALR Measuring in Air Pollution Control | TAL Dr.-Ing. Martin Reiser Tel.: ++49 (0) 711/685-65416 | AWT Dr.-Ing. Uwe Menzel Tel.: ++49 (0) 711/685-65417 o. Prof. Dr.-Ing. Heidrun Steinmetz Tel.: ++49 (0) 711/685-63723 Hydrochemistry | CH o. Prof. Dr. rer. nat. habil. Jörg W. Metzger . Tel.: ++49 (0) 711/685-63721 Biology | BIO Wastewater Technology | AWT Dr.-Ing. Jörg Krampe Tel.: ++49 (0) 711/685-65420 Chair of Waste Management and Emissions Dr.-Ing. Wolf-Rüdiger Müller Tel.: ++49 (0) 711/685-65411 Sewage Treatment Plant for Research and Education | LFKW Dr.-Ing. Manfred Roth Tel.: ++49 (0) 711/685-63724 o. Prof. Dr.-Ing. Martin Kranert Tel.: ++49 (0) 711/685-65500 Administrative Office Biological Air Purification | ALR Dipl.-Ing. Stephan Mollweide Tel.: ++49 (0) 711/685-63713 Prof. Dr. rer. nat. Karl-Heinrich Engesser . Tel.: ++49 (0) 711/685-63734 | BIO Bandtäle 2 70569 Stuttgart Germany Tel.: ++49 (0) 711/685-63711 Fax: ++49 (0) 711/685-63729 www.iswa.uni-stuttgart.de Institute report 2006-2007 Chair of Sanitary Engineering and Waterrecycling Chair of Hydrochemistry and Hydrobiology | CH | IWT | LFKW | SIA | SOA | TAL | WGW Institute report 2006-2007 Institute for Sanitary Engineering, Water Quality and Solid Waste Management | ISWA Bandtäle 2 Content Institute for Sanitary Engineering, Water Quality 5 and Solid Waste Management Chair of Sanitary Engineering and Water Quality Management 11 Chair of Sanitary Engineering and Waterrecycling Water Quality Management and Water Supply | WGW 22 Industrial Water and Wastewater Technology | IWT 30 Wastewater Technology | AWT 44 Chair of Waste Management and Emissions 61 Solid Waste | SIA 70 Hazardous Waste and Contaminated Sites | SOA 86 Measuring in Air Pollution Control | TAL 94 Biological Air Purification | ALR 98 Chair of Hydrochemistry and Hydrobiology 103 Hydrochemistry | CH 108 Biology | BIO 114 Sewage Treatment Plant for Research and Education | LFKW 122 3 4 Institute for Sanitary Engineering, Water Quality and Solid Waste Management ISWA Institute for Sanitary Engineering, Water Quality and Solid Waste Management Bandtäle 2 70569 Stuttgart Germany Tel.: ++49 (0) 711/685-63711 Fax: ++49 (0) 711/685-63729 www.iswa.uni-stuttgart.de 5 Universität Stuttgart The Institute for Sanitary Engineering, Water Quality and Solid Waste Management (ISWA) is a research and training facility of the University of Stuttgart (Universität Stuttgart) within the faculty of “Civil and Environmental Engineering Sciences”. The University’s Sewage Treatment Plant for Research and Teaching, which is situated within the institute, is unique throughout Europe. Experts from various engineering and natural sciences work together at our institute on an interdisciplinary basis. Our principal areas of expertise are the classical engineering tasks in the environmental fields of water, wastewater, solid waste, soil and exhaust air. The continuous development of technical facilities and practical methods in the fields of industrial and municipal supply and disposal are the focus of our interest. Our experience is also incorporated in the monitoring and development of quality assurance measures and management systems. Our institute, which is known today as the Institute for Sanitary Engineering, Water Quality and Solid Waste Management (ISWA), was founded as the “Institute for Sanitary Engineering and Health Technology” in the early 1950s. At that time it was the first educational establishment in Germany for civil engineers in the field of water and solid waste in urban development. In the 1970s the first chair of solid waste management at a German university was created. Today, our institute is one of the largest of its kind in the world. in Sanitary Engineering – represent the broad spectrum of environmental issues that occupy us in two departments and seven sections. Our institute offers numerous courses and internships in basic and specialized studies as well as student research projects, dissertations, Bachelor- and Master’s theses for the following courses of study: • Civil Engineering • Environmental Engineering • WAREM (Water Resources Engineering and Management) • WASTE (Air Quality Control, Solid Waste and Waste Water Process Engineering) • Infrastructure Planning • Geography • Technical Biology • real estate technic and -industry • EDUBRAS-MAUI We offer a large variety of study courses For the first time, ISWA introduced a M. Sc. course under German administration at the public university UFBR of Curitiba, Brazil. The project named „Export of German universitary education“ is funded by DAAD. Therewith, courses of ISWA are also offered overseas. The and ring and In addition there are courses for students of process engineering, real estate management, biology and chemistry. We also participate in the international doctoral candidate programme ENWAT (Environment Water) of 6 four chairs at the ISWA – Sanitary Engineering Water Quality Management, Sanitary Engineeand Water Recycling, Solid Waste Management Exhaust Air, Hydrochemistry and Hydrobiology Institute for Sanitary Engineering, Water Quality and Solid Waste Management ISWA the University of Stuttgart (Universität Stuttgart), as well as in programmes for extracurricular training and continuing professional development. Under the auspices of the ISWA, scientific colloquia and congresses on current topics of national significance relating to sanitary engineering and solid waste management have been held since 1957. Our academic employees are represented on numerous national and international boards as well as on technical and standardization committees of various technical-scientific organizations. have a large amount of (online) measuring equipment available for experiments on a laboratory scale, semitechnical scale and technical scale. In particular, this includes equipment for organic trace analysis; in part, these are operated using special coupling techniques for mass spectrometry (GCMS-MS, HPLCMS- MS). We also utilize computer supported prediction methods. With the aid of specially designed computer applications, modelling of processes in water and wastewater treatment is possible; measures in the fields of rainwater management and waste management concepts can be modelled, as well as geochemical simulations being carried out. The continuously improved computer simulations serve process control or decision making at various levels. The ISWA facilities Focal points of teaching and research The institute currently employs around 120 people; five professors and about sixty academic employees, supported by a considerable number of academic and student assistants as well as technical and administrative staff. Our activities under the chairs of sanitary engineering and water quality management and Sanitary Engineering and Water Recycling are concentrated around the minimization of the anthropogenic influence on water bodies and the natural hydrologic cycle during water extraction, and are engaged in the optimized treatment and sustainable use of water resources, as well as effective, environmentally friendly wastewater discharge and treatment. Internationally, water resources management in particular is of increasing importance in the rapidly growing urban areas of the developing and emerging countries in different climatic zones. Scientific collaboration All necessary facilities, from the research treatment plant, laboratories and lecture rooms, to the technical library and computer workstations equipped with specialist applications, are available for university teaching and research. One of the special features of our institute is the sewage treatment plant for research and education, which routinely also cleans the wastewater from the campus in Vaihingen and the district Stuttgart Büsnau. Our laboratories are excellently equipped for extensive investigations in a wide variety of environmental fields (water, wastewater, solid waste/soil, air). We The chair of solid waste management and exhaust air develops solutions ranging from waste avoidance to routes for material recycling and energy exploitation of waste, and their environmentally friendly disposal, including controlling the resulting emissions. Waste management is interdisciplinarily embedded in both a 7 Universität Stuttgart scientific-technical and socio-economic context. Here, too, international cooperation projects are highly valued, but also regional integration, e.g. via the Kompetenzzentrum Umwelttechnik – KURS e.V. (Competence Centre Environmental Engineering). The chair of Hydrochemistry and Hydrobiology in Sanitary Engineering addresses questions on sanitary engineering and solid waste management using natural scientific methods. In particular, the occurrence and behaviour of environmental chemicals (e.g. eliminatability, accumulation, mobility) in surface waters and groundwater, in water and wastewater treatment, as well as in soil and waste, are investigated. Moreover, analytical quality assurance takes a high priority. The close association of interdisciplinary research, teaching and practice in all areas of our institute is achieved by a constant discourse with external partners and research facilities as well as with clients, public and private facilities. Beside work on research and development projects, we offer external partners numerous services, consulting and expert’s advisory services as well as continuing education programmes. 8 The professors of ISWA together with their collegues from IWS founded the „Wasserforschungszentrum Stuttgart“ - wfz (Water Research Center Stuttgart) end of 2007. The wfz is an international engineering center for water research that supports and interdisciplinarily networks teaching (academic studies), instruction (pHD students), research and practice. Institute for Sanitary Engineering, Water Quality and Solid Waste Management ISWA Institute for Sanitary Engineering, Water Quality and Solid Waste Management Managing Director: o. Prof. Dr.-Ing. Ulrich Rott Board of Management: Full professors — Department Heads Head of Administrativ Office — Manager of the Waste Water Treatment Plant Chair of Sanitary Engineering and Water Quality Management o. Prof. Dr.-Ing. Ulrich Rott Water Quality Management and Water Supply Dipl.-Ing. Ralf Minke Industrial Water and Wastewater Technology Dr.-Ing. Uwe Menzel Chair of Sanitary Engineering and Water Recycling o. Prof. Dr.-Ing. Heidrun Steinmetz Wastewater Technology Dr.-Ing. Jörg Krampe Chair of Waste Management and Emissions o. Prof. Dr.-Ing. Martin Kranert Biological Air Purification Prof. Dr. rer. nat. Karl-Heinrich Engesser Solid Waste Management Dr.-Ing. Klaus Fischer Hazardous Waste and Contaminated Sites Prof. Dr.-Ing. Erwin Thomanetz Measuring and Air Pollution Control Dr.-Ing. Martin Reiser Chair of Hydrochemistry and Hydrobiology o. Prof. Dr. rer. nat. habil Jörg W. Metzger Hydrochemistry o. Prof. Dr. rer. nat. habil Jörg W. Metzger Biology Dr.-Ing. Wolf-Rüdiger Müller Administrative Office ISWA Dipl.-Ing. Stephan Mollweide Research and Teaching Wastewater Treatment Plant; Dr.-Ing. Manfred Roth www.iswa.uni-stuttgart.de 9 10 Chair of Sanitary Engineering and Water Quality Management o. Prof. Dr.-Ing. Ulrich Rott Chair of Sanitary Engineering and Water Recycling o. Prof. Dr.-Ing. Heidrun Steinmetz Water Quality Management and Water Supply Dipl.-Ing. Ralf Minke WGW Industrial Water and Waste Water Technology Dr.-Ing. Uwe Menzel IWT Sewage Technology Dr.-Ing. Jörg Krampe AWT 11 Institute for Sanitary Engineering, Water Quality and Solid Waste Management Chair of Sanitary Engineering and Water Quality Management, Chair of Sanitary Engineering and Water Recycling Research The Chair of Sanitary Engineering and Water Quality Management as well as the Chair of Sanitary Engineering and Water Recycling are engaged in a wide range of activities. These include the fields of pure and applied research, the consulting of governmental, municipal and industrial partners and the completion of research and development contracts on behalf of private, industrial and public sponsors. As activities of the Field of „Wastewater Technology“, stormwater treatment and discharge, concept development for urban drainage, planning of sewage networks and minimisation of infiltration water can be mentioned. Another area of key activities includes the further development of biological and advanced wastewater treatment processes, in particular of anaerobic, membrane and disinfection processes, measurement and control technologies, water-recycling as well as the assessment and survey of planning and process engineering methods. Moreover, topics such as energy optimisation, employment of alternative energy resources in wastewater treatment and recycling of valuable materials and nutrients are encompassed. For a worldwide implementation, concepts and technologies for reutilization of water are tested and dimensioning principles for tropic climates are developed. Finally, neutral evaluation of performance of individual process stages, e.g. oxygen intake measurements, as well as of entire water purification facilities and small sewage plants according to DIN 4262 and EN 12566-3 respectively is conducted. In the department Water Quality Management and Water Supply, as the name implies, attention is paid both to water quality management and water supply. In terms of water quality management, major focus is given to the analysis of water body quality and to the investigation of impacts of water saving measures and of rain water management and usage. Attention is also given to the precautionary protection of drinking water resources, e.g. in terms of research on the pesticides’ pathway into surface water bodies or on the interactions of industrial waste water pretreatment/management and the subsequent treatment in public plants. Competence is superabound particularly with regard to modelling and simulation of the transformation of indirectly discharged waste waters in the course of their transport and of their treatment along with municipal 12 waste waters. The development of procedurally, ecologically and economically optimised water recycling concepts for various industries such as textile finishing, leather, paper, milk and beverage industry, is also one the core competences. In terms of water supply, issues regarding subterranean water treatment like denitrification and removal of iron, manganese and arsenic are addressed. Significant focus is also given to membrane applications, advanced oxidation processes and anaerobic biological processes for the allocation of drinking and service waters in industry. Furthermore, the department deals with all issues related to transport, storage and distribution of drinking water, e.g. hygienic problems resulting due to excess retention times in the water distribution network. At the IWT department (Industrial Water and Wastewater Technology), we specialize in redefining plant internal processes and production integrated environmental protection, processing and cleaning wastewater as well as the recirculation and discharge of industrial wastewater. Due to our systematic procedures and many years of experience we are able to represent our customers from the different sectors of the industry with a considerably wide range of economical as well as ecological solutions and potentials. We emphasis mainly in offering our professional advice to clients from the textile finishing industry and paper industry, gastronomy- and food-industry, the cosmetic and pharmaceutical industry, the chemical as well as the metal and automobile industry. Alongside plant internal solutions we also create decentral as well as central solutions by developing extensive purification processes for the treatment of industrial wastewater at communal treatment plants. Therefore a series of aerobic and anaerobic biological degradation tests are carried out in advance. Further emphasis of ours is the treatment of leachate of landfills using biological and chemical-physical processes. For example we are developing adaptable modular processes for the aftercare operations of landfills at reduced leachate levels and toxic concentrations. Therefore the use of carbon adsorption processes and membrane processes play an essential role in our work. Here at the IWT department we also deal with topics such as water and waste recycling as well as saving resources. Exemplary is our expert’s assessment Chair of Sanitary Engineering and Water Quality Management Chair of Sanitary Engineering and Water Recycling of industrial residues as alternative fuel in the cement industry as well as the sludge incineration in cement plants. Further more at the IWT department we specialize in developing international study courses and curriculum exchanges at universities and academies abroad, for example the initiation of the Master of Science program “EDUBRAS-MAUI - Kommunaler und industrieller Umweltschutz” in Curitiba/ Brazil. A further research topic that is being researched here at the IWT department is the complex theme “Wastewater containing mineral oil”. Head of the department Dr. Menzel, was appointed as the expert for this project by the “Deutsches Institut für Bautechnik (DIBt)” in Berlin. As a result of being appointed as part of the expert-committee, the IWT department was then appointed as the official inspection office. The department is responsible for carrying out practical tests at different plants to ensure the reduction of hydrocarbon in wastewater containing mineral oil. Courses and Lectures Chair professors, assistant professors and researchers supervise students in the following courses: ring course. The main course is divided into three specialised areas: “Water Supply and Water Quality Management”, “Wastewater Treatment” and “Industrial Wastewater” along with numerous core and complementary lectures. • In the Master-Program Infrastructure Planning in English language in the courses “Water Supply and Water Distribution”, “Water Quality Management”, “Wastewater Technology” and “Water Treatment”. • In the Master-Program Water Resources Engineering and Management (WAREM) oriented for foreign students with “Water Quality Management”, “Waste Water Technology”, Biological and Advanced Wastewater Treatment”, “Water Supply and Water Distribution” as well as “Water Treatment” and as optional lectures “Design of Sewer Systems and Stormwater Treatment”, “Treatment of Industrial Wastewater” as well as “Water Quality Measurements on Location”. • In the Master-Program Air Quality Control, Solid Waste and Waste Water Process Engineering (WASTE) oriented for foreign students with core and optional lectures in all fields of domestic and industrial wastewater disposal and treatment as well as of water quality and management. • In the basic course “Sanitary Engineering” and in the specialised courses “Water Quality and Water Supply” and “Wastewater Technology” for German graduands of the civil engineering course. Thereby, the following core lectures are offered: “Water Quality Management”, “Water Treatment”, Design of Water Treatment Plants”, “Construction and Operation of Sewer Systems”, “Highly Efficient Biological Wastewater Treatment”, “Industrial Wastewater”, “Design of Wastewater Treatment Plants” as well as “Sewer Systems and Stormwater Treatment”. Besides, the following complementary courses are offered: “Water Supply in Remote Areas”, “Practical Work on Location for Water Quality and Water Supply”, “Water Supply Networks”, “Control and Simulation of Wastewater Treatment Plants”, Monitoring and Operation of Wastewater Treatment Plants” and “Practical Work on Wastewater Treatment Plants”. • In Curitiba/Brazil, the Master-Program “EDUBRASMAUI” (Meio Ambient Urbano e Rural – Domestic and Industrial Environment Protection” was introduced by the department IWT with German standards and co-ordination. In this new MasterProgram, Brazilian students are qualified in the scope of the German Program “Study Proposals by German Faculties Overseas”, sponsored by the German Academic Exchange Service (DAAD). The title “Master of Science” shall be acknowledged in Brazil and Germany and its accreditation shall be aimed. Furthermore, some lectures are offered for students of process engineering. The proposed lectures are completed by various excursions of one or more days, practical works as well as by the periodic seminar “Wastewater Technology” and “Water Supply and Water Quality Management”. • In the basic courses “Water Management I” and “Sanitary Engineering, Disposal Techniques I” for German graduands of the environmental enginee- By means of seminars and colloquia, a high number of events for continuing education are offered. These are preferably organised in co-operation with DWA, DVGW 13 Institute for Sanitary Engineering, Water Quality and Solid Waste Management and BWK. Other events to be emphasised are the periodic colloquia for Wastewater Treatment and Potable Water, the course for Water Sampling by order of The Ministry for Environment of Baden-Württemberg as well as the lectures in the scope of the correspondence course “Water and Environment” at the Bauhaus Universität Weimar. The chair’s international activities continuously increase in importance. Apart from the Master-Programm “EDUBRAS-MAUI”, the department IWT offers other courses internationally. In the scope of the Program “Export of German Study Proposals” of the model project “Study Proposals on Environmental Engineering in Brazil – Summer School” by DAAD, classes are offered during three weeks in different Federal States of Brazil. Last but not least, the supervision of study seminars, independent studies, master theses and design works is an important aspect for the formation of junior researchers. Excursion with international students to decentralized stormwater discharge and infiltration facilities; here open channel in a housing area 14 Chair of Sanitary Engineering and Water Quality Management Chair of Sanitary Engineering and Water Recycling Dissertations Aufbereitung von Spülwässern bei der hydraulischen In-situ-Sanierung Integrated Ressource Planning to Meet Future Demand in Jeddah - Saudi Arabia Birgit Memminger (2006) Supervisor: Prof. Dr.-Ing. U. Rott, Prof. Dr.-Ing. H. Hasse Hassan Shawly (2007) Development of a Knowledge Based Decicion Support System for Private Sector Participation in Water and Sanitation Utilities Carla Conçalves Pinheiro Böhl (2007) Supervisor: Prof. Dr.-Ing. U. Rott, Prof. Dr. rer. nat. Dr.-Ing. habil. András Bárdossy Supervisor: Prof. Dr.-Ing. U. Rott, Prof. Dr. rer. nat. Dr.-Ing. habil. András Bárdossy Multi-objective and Risk-based Modelling Methodology for Planning, Design and Operation of Water Supply Systems Aleksandar Trifkovic (2007) Supervisor: Prof. Dr.-Ing. U. Rott, Prof. Dr. rer. nat. Dr.-Ing. habil. András Bárdossy Verfahrenstechnische Möglichkeiten zur Entfernung von organischen Spurenstoffen aus kommunalem Abwasser Corinna Schrader (2007) Supervisor: Prof. Dr.-Ing. U. Rott, Prof. Dr.-Ing. J. Pinnekamp Publications Antakyalı, D., Krampe, J., Steinmetz H., Hafner G., Kranert M.: “Turizm bölgelerinde atıksu arıtımı, katı atık yönetimi ve enerji kazanımına bütünleyici bakış: MODULAARE”. TMMOB Çevre Mühendisleri Odası, 7. Ulusal Çevre Mühendisliği Kongresi, 24-27 Ekim 2007, İzmir, Türkiye English title: “An integrated approach on the wastewater treatment, solid waste disposal and energy recovery in tourist resorts: MODULAARE” Kauffmann, H., et al.: In-situ treatment of arsenic contaminated groundwater in West Bengal / India. Poster, As 2006, Natural Arsenic in Groundwaters of Latin America, Mexico City, 20. – 23.06.2006 Kauffmann, H., et al.: Groundwater use in irrigation in the Mature Delta of West Bengal. Poster, European Groundwater Conference, Vienna, 22. - 23.06.2006 Gasse, J.: Keimbelastung in Fließgewässern - Quellen und Ansätze zur Bilanzierung. Kleines Institutstreffen, 14./15. Februar 2006, Stuttgart Kauffmann, H., et al.: Arsenic Removal from Groundwater in West-Bengal / India by Means of In-situ Treatment. Poster, European Groundwater Conference, Vienna, 22. - 23. June 2006 Gasse, J., Krampe, J.: Keimbelastung in Fließgewässern – Untersuchungen im Einzugsgebiet des Bodensees. Dienstbesprechung Kommunales Abwasser und Gewässerschutz, Umweltministerium Baden-Württemberg, 11./12. Juli 2006, Pfedelbach Krampe, J.: Vergleich verschiedener Druckbelüftungssysteme unter Betriebsbedingungen in kommunalen Kläranlagen, in: Stuttgarter Berichte zur Siedlungswasserwirtschaft, Band 186, S. 59 – 77, Oldenbourg Verlag, München, 2006 Gasse, J., Krampe, J.: Auswirkungen von Abwassereinleitungen auf die hygienische Gewässerqualität. DWA Landesverbandstagung Baden-Württemberg, 18./19. Oktober 2007, Pforzheim Krampe, J., Kaebert, S.: Stand der Belüftungstechnik in Baden-Württemberg. Jahresbesprechung der Lehrer des DWA-Landesverbandes Baden-Württemberg, 30. März 2006, Stuttgart 15 Institute for Sanitary Engineering, Water Quality and Solid Waste Management Krampe, J., Schrader, C.: Technische Möglichkeiten zur Elimination organischer Spurenstoffe bei der Abwasserbeseitigung. Kongress des Umweltministeriums Baden-Württemberg: Arzneimittel – Spurenschadstoffe im Wasserkreislauf und Boden, 17. Mai 2006, Stuttgart Krampe, J., Laufer, R.: Abwasserreinigung mit Membrantechnologie - Die Kläranlage Schramberg-Waldmössingen. Dienstbesprechung kommunales Abwasser und Gewässerschutz des Umweltministeriums BadenWürttemberg, 11. Juli 2006, Pfedelbach Krampe, J., Waizenegger, K.: Membran-Scheibentauchkörper für den dezentralen Einsatz. 9. VDMA-Wasserund Abwassertagung, 30. November 2006, Frankfurt Krampe, J., Weidelener, A.: Umgang mit Fremdwasserproblemen - Erfahrungen in Baden-Württemberg, Auswirkungen auf Kanal, Kläranlage und Gewässer. DWA Fortbildungsveranstaltung „Umgang mit Fremdwasserproblemen“, 14. Juni 2007, Freudenstadt Krampe, J., Weidelener, A.: Phosphorrückgewinnung auf Kläranlagen. Dienstbesprechung kommunales Abwasser und Gewässerschutz des Umweltministeriums Baden-Württemberg, 20. Juni 2007, Rastatt Menzel, U.: Wirtschaftlich und ökologisch verantwortlicher Umgang mit Wasser in der Textilindustrie. Vortrag bei der Veranstaltung „effiziente Wassernutzung in der Industrie im Rahmen des KFW-Programms „Industrial pollution abatement project (IPAP)“ in Kooperation mit der türkischen Entwicklungsbank TSKB, 02.05.2006, Istanbul, Türkei Menzel, U.: Produktionsintegrierter Umweltschutz in der Industrie. Vortrag im Rahmen des KFW-Programms „Industrial pollution abatement project (IPAP) in Kooperation mit der türkischen Entwicklungsbank TSKB, 03.05.2006, Adana, Türkei Menzel, U.: Weitergehende Textilabwasserreinigung am Beispiel des AFF-Verfahrens der Kläranlage Albstadt. Vortrag im großen Sitzungssaal der Stadt Albstadt im Rahmen des Programms „Projekt- und Umweltmanagement, Umwelttechnik anlässlich eines Studienaufenthaltes von Umweltexperten aus Brasilien. Veranstalter: Wirtschaftsministerium BW, Landestiftung BW und Entwicklungs GmbH (Inwent), 17.05.2006, Albstadt Krampe, J., Pressinotti, F.: Evaluation of Wastewater Treatment in Trickling Filters under High Temperatures. H2O Vietnam 2007 – Networking the Water Industries, 19. Oktober 2007, Ho Chi Minh City Menzel, U.: Vorstellung und Einführung des neuen Umweltschutz - Masterstudienganges: Meio ambiente urbano e industrial (MAUI) an der Universidade Federal do Paraná“. Vortrag im Rahmen des 1. offiziellen EDUBRAS - Treffens am Nationalen Umwelttechnologiezentrum SENAI im Rahmen des DAAD Projektes: „Studienangebote deutscher Hochschulen im Ausland.“, 26.09.2006, Curitiba / Brasilien Krampe, J., Pressinotti, F.: Tropfkörper bei höheren Abwassertemperaturen. 3. DWA Workshop „Betriebserfahrungen von Tropfkörperanlagen“, 15. November 2007, Markgröningen Menzel, U.: Leachate Treatment, Vortrag im Rahmen des „International Workshop on Waste- and Leachate -Treatment Technologies“ bei der Fa. Faber GmbH, 04.12.2006, Alzey Lumpp, K., Rott, U.: In-situ-Arsenelimination aus Grundwässern - Beispiel West-Bengalen. Stuttgarter Berichte zur Siedlungswasserwirtschaft, Bd. 185, 2/2006 Menzel, U.: Lançamento do Programa de Mestrado Profissional – EDUBRAS. Eröffnungsvortrag zur Einführung des Masterstudiengangs „kommunaler und industrieller Umweltschutz - EDUBRAS“ an der Universidade Federal do Paraná (UFPR) im Rahmen der Eröffnungsveranstaltung im Vortragssaal der Universidade da Indústria (UNINDUS), 14.03.2007, Curitiba, Brasilien Lumpp, K.: Untersuchungen zum Einsatz der In-situAufbereitung zur Arsenelimination in West-Bengalen / Indien. Poster, 39. Essener Tagung für Wasser- und Abfallwirtschaft, Essen, 29. - 31.03.2006 Lumpp, K., et al.: In-situ treatment of arsenic contaminated groundwater in West Bengal / India. Poster, As 2006, Natural Arsenic in Groundwaters of Latin America, Mexico City, 20. – 23.06.2006 16 Menzel, U., Neuffer, D.: Einführung von deutschen umweltschutztechnischen Studiengängen an Hochschulen in Brasilien - EDUBRAS“, Zwischenbericht 2006 des Modellprojektes „Studienangebote deutscher Hochschulen im Ausland des Deutschen Akademischen Austauschdienstes - DAAD, 25.04.2007, Stuttgart Chair of Sanitary Engineering and Water Quality Management Chair of Sanitary Engineering and Water Recycling Menzel, U.: Stuttgart teaches „Environmental Technologies (EDUBRAS)“ in Brazil. Artikel erschienen im StudyGuide Baden-Württemberg, URL: http://www.studyguide-bw.com/events/1797/. 09.07.2007, Stuttgart Menzel, U., Metzger, J.W.: Implementation of German environmental engineering Master of Science programmes at universities in Brazil under German supervision and at German standards – EDUBRAS. Vortrag im Rahmen des 3. Deutsch-Brasilianischen-Symposiums - Nachhaltige Entwicklung, an der Universität Freiburg, 23.07.2007, Freiburg Menzel, U.: UFPR lança mestrado em Meio Ambiente em parceria com Stuttgart. Artikel erschienen in „Deutsche Welle“, URL: http://www.dw-world.de/dw/ article/0,2144,2706092,00.html, 25.07.2007, Bonn Menzel, U.: In Brasilien lässt sich noch viel erreichen. Artikel erschienen in der Stuttgarter Zeitung Nr. 213/2007, 14.09.2007, Stuttgart Menzel, U.: Umwelttechnologien für Megastädte. Artikel erschienen in Baukalender Informations-Fachportal, URL: http://www.baukalender.de/nachrichten_detail2.php?nr=519, 15.9.2007, Stuttgart Menzel, U.: Processos de tratamento de água e efluentes avançados. Pós Graduação em Gerenciamento de Águas e Efluentes. Vortrag an der FACULDADE DE TECNOLOGIA SENAI BLUMENAU. 14 e 15 de Setembro e 28 e 29 de Outubro 2007, Blumenau, Brasilien Menzel, U.: Innovation through the transfer of technology and knowledge between Germany and Brazil. German Environmental Technology Master Course at UFPR and SENAI-PR (EDUBRAS). Symposium of Cooperation Projects in the area of Innovation, Research and Development, German-Brazilian Innovation Forum, Vortrag im Rahmen der Deutsch–Brasilianischen Wirtschaftstage, 20.11.2007, Blumenau /Brasilien Menzel, U.: Umwelttechnologien für Megastädte“, Artikel im Stuttgarter unikurier Ausgabe Nr. 100,Dezember 2007, S 88-89, Stuttgart Meyer, C., Rott U., Schmidt, S., Minke, R.: A novel and cost-effective approach on preventive water pollution control. Proceedings of the 3rd International Conference on Environmental Science and Technology, Houston, Texas, August 6-9, 2007 Meyer, C., Rott U.: Simultaneous Drinking Water Winning and Treatment by In-Situ Bioreactors, Proceedings of the 3rd International Conference on Environmental Science and Technology, Houston, Texas, August 6-9, 2007 Meyer, C.: Die gesplittete Abwassergebühr in der Praxis (Vortrag), Kronimus AG, Rastatt, Hotel Holiday Inn Garden Court, 08.11.2007 Meyer, C.: Die gesplittete Abwassergebühr in der Praxis (Vortrag), Kronimus AG, Baden-Baden, Holland Hotel Sophienpark, 08.11.2007 Minke, R.: Wassergefährdende Stoffe. Vortrag im Rahmen des DWA-Grundkurs „Der Gewässerschutzbeauftragte“, 10.05.2006, Stuttgart Minke, R.: Technische und organisatorische Maßnahmen im anlagenbezogenen betrieblichen Gewässerschutz. Vortrag im Rahmen des DWA-Grundkurs „Der Gewässerschutzbeauftragte“, 10.05.2006, Stuttgart Minke, R., Rott, U., Weireter, K.: Planung und Umsetzung eines innovativen Abwasserkonzepts bei der Firma Ploucquet Textiles Zittau. In: Preprints des Colloquium produktionsintegrierte Wasser-/Abwassertechnik „Innovative Wasseraufbereitung industrieller Abwässer“ vom 13.-14. September 2006, Bremen, S. D13 – D23 Minke, R., Rott, U.: Planning and Application of an Innovative Wastewater Concept in a Textile Processing Company. In: Proceedings of the 7th International Symposium on Waste Management Problems in AgroIndustries, 27-29 September 2006, Amsterdam, p. 213 – 220 Minke, R.: Wassergefährdende Stoffe: Technische und organisatorische Maßnahmen im anlagenbezogenen betrieblichen Gewässerschutz. Vortrag im Rahmen des DWA-Aufbaukurs „Der Gewässerschutzbeauftragte“, 22.11.2006, Stuttgart Minke, R.: Indirekteinleiter: Anforderungen an das Einleiten von Abwasser aus Industriebetrieben mit Fallbeispielen. Vortrag im Rahmen des DWA-Aufbaukurs „Der Gewässerschutzbeauftragte“, 23.11.2006, Stuttgart 17 Institute for Sanitary Engineering, Water Quality and Solid Waste Management Minke, R.: Farbe in der Fehla –Untersuchung der Ursachen und Erarbeitung von Lösungsansätzen. Vortrag im Rahmen der „Dienstbesprechung Industrieabwasser und Umgang mit wassergefährdenden Stoffen“ des Regierungspräsidiums Tübingen, 10.05.2007, Landratsamt Bodenseekreis Friedrichshafen Minke, R., Rott, U., Schmidt, S., Meyer, C.: A novel and cost-effective approach on Preventive Water Pollution Control. In: Proceedings of the 3rd International Conference on Environmental Science and Technology, 6.-9. August 2007, Houston, Texas Minke, R., Rott, U.: Application of a novel Concept of Wastewater Pre-Treatment in Textile Finishing Industry. In: Proceedings of the 3rd International Conference on Environmental Science and Technology, 6.-9. August 2007, Houston, Texas Minke, R., Rott, U.: An innovative Wastewater Concept including Anaerobic Fixed Bed Technology for a Textile Processing Company. In: Proceedings of the 11th World Congress on Anaerobic Digestion “Bio-Energy for our Future”, 23.-27. September 2007, Brisbane, Australien Minke, R., Rott, U.: Optimierung der anaeroben Vorbehandlungsstufe für die Teilschrittabwässer der Firma Ploucquet Textiles Zittau. In: Tagungshandbuch der DECHEMA/DWA Industrietage Wassertechnik vom 13.14. November 2007, Frankfurt, S. 3 Pressinotti, F.: Einsatz des Tropfkörperverfahrens unter verschiedenen länderspezifischen Einflussfaktoren. Vortrag auf dem kleinen Institutstreffen, 14./15. Februar 2006, Stuttgart Pressinotti, F.: Einsatz des Tropfkörperverfahrens unter verschiedenen länderspezifischen Einflussfaktoren. Workshop im Rahmen des BMBF-Verbundprojektes „Exportorientierte FuE auf dem Gebiet der Wasserverund -entsorgung“, Teil II: „Abwasserbehandlung und Wasserwiederverwendung“, 5./6. Mai 2006, Darmstadt Pressinotti, F., Krampe, J.: Avaliação de um filtro percolador alemão para tratamento de esgoto doméstico em escala piloto sob temperaturas tropicais. I Simpósio Nornestino de Saneamento Ambiental da ABES, 22.-24. November 2006, João Pessoa, Brasilien 18 Pressinotti, F.: Einsatz des Tropfkörperverfahrens unter verschiedenen länderspezifischen Einflussfaktoren. Vortrag auf dem DWA 3. Internationalen Forum (CoReferent von Prof. Dr.-Ing. Orth), 27. – 28. Februar 2007, Braunschweig Pressinotti, F.: Verschiedene Aspekte eines Tropfkörpers unter tropischen Temperaturen. Vortrag auf dem „Kleinen Institutstreffen“, 5. – 6. März 2007, Dresden Pressinotti, F.: Untersuchungen zur Abwasserreinigung im Tropfkörper bei hohen Temperaturen. Vortrag und Diskussion vor dem Fachausschuss DWA KA 6.3, 24. April 2007, Frankfurt Rott, U., Lumpp, K.: In-situ-Arsenelimination aus Grundwässern - Beispiel West-Bengalen. Stuttgarter Berichte zur Siedlungswasserwirtschaft, Bd. 185, 2/2006 Rott, U., et al.: Elimination hormonell wirksamer Substanzen und Arzneimittel aus dem Abwasser. 39. Essener Tagung für Wasser- und Abfallwirtschaft, Essen, 29.03.2006 Rott, U., et al.: In-situ treatment of arsenic contaminated groundwater in West Bengal / India. Poster, As 2006, Natural Arsenic in Groundwaters of Latin America, Mexico City, 20. – 23.06.2006 Rott, U., et al.: Arsenic Removal from Groundwater in West Bengal / India by Means of In-situ Treatment. Poster, European Groundwater Conference, Vienna, 22-23 June 2006 Rott, U., et al.: Groundwater Use in Irrigation in the Mature Delta of West Bengal. Poster, European Groundwater Conference, Vienna, 22-23 June 2006 Rott, U., Kauffmann, H.: In-Situ Groundwater Treatment. Europ. Comm. TIPOT-Project Symposium, Kolkata, 15.- 17.01.2007 Rott, U., Kauffmann, H.: In-Situ Groundwater Treatment. Europ. Comm. TIPOT-Project Symposium, Jamshedpur, 19.01.2007 Rott, U., Minke, R.: Application of a novel concept of wastewater pre-treatment in Textile Finishing Industry. Int. Conf. Env. Sc. and Techn., Houston, Texas, USA, 06.- 09.08.2007 Chair of Sanitary Engineering and Water Quality Management Chair of Sanitary Engineering and Water Recycling Rott, U., et al.: A novel and cost-effective approach on preventive water pollution control. Int. Conf. Env. Sc. and Techn., Houston, Texas, USA, 06.- 09.08.2007 Rott, U., Meyer, C.: Simultaneous Drinking Water Winning and Treatment by In-situ Bioreactors. Int. Conf. Env. Sc. and Techn., Houston, Texas, USA, 06.08.2007 Rott, U., Minke, R.: Optimierung der anaeroben Vorbehandlungsstufe für Teilschrittabwässer der Textilveredelung. Dechema Industrietage Wassertechnik, Frankfurt, 14.- 14.11.2007 Schmidt, S., Rott U., Meyer C., Minke R.: „A novel and cost-effective approach on preventive water pollution control“ (Poster) the 3rd International Conference on Environmental Science and Technology, Houston, Texas, August 6-9, 2007 Steinmetz*, H., Hansen, J., Knerr, H., Engelhart, M., Sagawe, G., Krystkiewicz, D.: Schließung von Wasserund Stoffkreisläufen - BMBF - Verbundprojekt KOMPLETT. Tagungsband 25 „siwawi 2030- Themen und Lösungsansätze für die nächsten 25 Jahre“, FG Siedlungswasserwirtschaft, TU Kaiserslautern, S.195-210 Steinmetz, H., Ebert, A.: Intelligente Visualisierung zur Erhöhung der Prozesstransparenz von Abwasserreinigungsanlagen. Tagungsband 25 „siwawi 2030-Themen und Lösungsansätze für die nächsten 25 Jahre“, FG Siedlungswasserwirtschaft, TU Kaiserslautern, S.177194 Steinmetz, H.: Potential und Bedarf zur Optimierung von Belebungsanlagen. Stuttgarter Berichte zur Siedlungswasserwirtschaft, Band 186, „Betriebsoptimierung von Belebungsanlagen“ S.19-46 Steinmetz*, H., Wiese, J.; Stahl, A.: Application of Cases-Based Reasoning to predict sludge settling and endogenous denitrification. Congress Proceedings 5th World Water Congress, Peking, Paper Ref. No.594270 Steinmetz, H., Wiese, H.: Instrumentation, control and Automation for full-scale Sequencing Batch Reactor Plants. Water Practice & Technology, Vol.1 No.4, 2006 Steinmetz*, H., Wiese, J.; Simon, J.: A process-dependent real-time controller for sequencing batch reactor plants- Results of full scale opereration. Water Science and Technology, Vol.53, No. 4-5, S. 153-160, 2006 Steinmetz*, H., Einsfeld, K., Ebert, A., Wölle, J.: Multiple Dynamic Perspectives to Industrial Processes ISBN: 0-88986-598-1 (2006) Steinmetz*, H., Hansen, J., Schmitt, T.G.: Notwendigkeit und Konzepte für eine nachhaltige Abwasserentsorgung. Zukunftsweisende Abwasserentsorgung - Fachtagung der Standtentwässerung Kaiserslautern in Zusammenarbeit mit dem Landesverband Hessen/ Rheinland-Pfalz/Saarland der DWA am 7./8. September 2006, Kaiserslautern Steinmetz, H.: Optimierungspotenziale auf Kläranlagen. 21. Karlsruher Flockungstage, Schriftenreihe SWW - Band 127 „Die optimierte Kläranlage Vision oder Realität?“ S. 1-10, 2007 Steinmetz*, H., Wölle, J., Hansen, J., Einsfeld, K., Ebert, A.: An Intelligent Visualization and Decision Support System for Decentralized Wastewater Treatment Plants. Water Science and Technology Vol. 56 No. 5 pp.183-191, 2007 Steinmetz, H.: Ansätze für energieoptimierte Kläranlagen. Stuttgarter Berichte zur Siedlungswasserwirtschaft, Band 191, „Innovative Energiekonzepte für Kläranlagen“ S.5-24, 2007 Steinmetz, H.: Entwicklung und Perspektiven der kommunalen Abwasserentsorgung in Deutschland und weltweit. Wasser und Abfall 5, S. 10-13, 2007 Steinmetz*, H., Wölle, J., Hansen, J., Einsfeld, K., Ebert, A.: An Intelligent Visualization and Decision Support System for Decentralized Wastewater Treatment Plants. Advanced Sanitation Eurogress, 12./13. März 2007, Aachen, ISSN 0342-6068 Steinmetz*, H., Knerr, H., Wölle, J., Hansen, J., Sagawe, G., Engelhart, M., Krystkiewicz, D.: Development, combination and implementation of innovative components of process engineering, information technology and sanitary equipment to a sustainable key technology for closed loop - Project ‚KOMPLETT‘ Advanced Sanitation Eurogress, 12./13. März 2007, Aachen, ISSN 0342-6068 * Order of authors changed to facilitate tracking 19 Institute for Sanitary Engineering, Water Quality and Solid Waste Management Steinmetz*, H., Knerr, H., Hansen, J., Sagawe, G., Engelhart, M., Krystkiewicz, D.: Development, combination and implementation of innovative components of process engineering, information technology and sanitary equipment to a sustainable key technology for closed loop - Project ‚KOMPLETT‘. Proceedings of the 3th ZERO-M International Conference on Sustainable Water Management, 21.-24. March 2007, Tunis, Tunisia ISBN: 978-3-901425-12-7 Steinmetz, H.: Energieeinsparpotenziale auf der Kläranlage. 36. kommunaler Erfahrungsaustausch der des DWA- Landesverbandes BW, 09.05.2007, Abtsgmünd Steinmetz, H.: Energieeinsparpotenziale auf der Kläranlage. 36. kommunaler Erfahrungsaustausch der des DWA- Landesverbandes BW, 23.05.2007, Kehl Steinmetz, H.: Anforderungen an die kommunale Abwasserentsorgung in Deutschland und weltweit. Münchner Kolloquium Wassergüte und Abfallwirtschaft am 18.07.2007, München Steinmetz, H., Menzel, U.: Historische Entwicklung biologischer Abwasserbehandlungsverfahren in kommunaler und industrieller Anwendung. 1. Stuttgarter Wassersymposium, 13.09.2007, Stuttgart Steinmetz, H.: Entwicklungsstand und Perspektiven der kommunalen Abwasserentsorgung. Forum kommunale Abwasserentsorgung für morgen am 04.10.2007, Frankfurt Steinmetz*, H., Knerr, H.; Hansen, J., Engelhart, M., Wölle, J.: Black water of different origin - characterization and biological treatment. 6th Conference on Wastewater Reclamation and Reuse for Sustainability, 09.-12. October 2007, Antwerp, Belgium. Steinmetz*, H., Wölle, J., Schmitt, T. G.: An Intelligent Visualization and Decision Support System for decentralized Wastewater Treatment Plants. 6th Conference on Wastewater Reclamation and Reuse for Sustainability, 09-12 October 2007, Antwerp, Belgium 20 Steinmetz*, H., Knerr, H., Hansen, J., Engelhart, M.: The project KOMPLETT - A new approach for closed loop urban water cycles. 2nd International Conference SmallWat07 on Wastewater Treatment in Small Communities, 11.-15. November 2007, Seville, Spain. Weidelener, A., Gutknecht, R., Böhler, A., Krampe, J., Rott, U.: Einsatz von nachgeschalteten Membranen zur Verbesserung der Ablaufqualität bei der Badischen Staatsbrauerei Rothaus AG. Stuttgarter Berichte zur Siedlungswasserwirtschaft, Band 186, S. 139-152, Oldenbourg, München, 2006 Weidelener, A.: Fremdwasser-Messungen, Auswirkungen, Sanierung Fachseminar Laboranalytik und Prozess-Messtechnik, 12. Juli 2006, Ingolstadt, Hach Lange GmbH, Düsseldorf, 2006 Weidelener, A., Krampe, J., Rott, U. Strategien zum Umgang mit dem Fremdwasser 7. Kölner Kanal Kolloquium, 6./7. September 2006, Köln, Gesellschaft zur Förderung der Siedlungswasserwirtschaft an der RWTH Aachen e.V., Aachen Weidelener, A., Maier, W., Krampe, J.: Phosphorrückgewinnung als Magnesium-Ammonium-Phosphat (MAP) mittels saurer Rücklösung aus Faulschlämmen. GWF Wasser/Abwasser 148 (2007) Nr. 4, S. 269-272 Weidelener, A., Antakyali, D., Krampe, J.: Tendencies and Overview on the Nutrient Recovery from Sewage Sludge in Germany. IWA Spezialist Conference „Facing Sludge Diversities: Challenges, Risks and Opportunities“, Belek-Antalya, Turkey, 28-30 March 2007 Weidelener, A., Maier, W., Krampe, J.: Recovery of Phosphorus from Sewage Sludge. WEFTEC ´07, 13.17. October 2007, San Diego, CA, USA Chair of Sanitary Engineering and Water Quality Management Chair of Sanitary Engineering and Water Recycling Contact o. Prof. Dr.-Ing. Ulrich Rott Tel.: ++49 (0)711/685-63711 Fax: ++49 (0)711/685-63729 E-Mail: [email protected] o. Prof. Dr.-Ing. Heidrun Steinmetz Tel.: ++49 (0)711/685-63723 Fax: ++49 (0)711/685-63729 E-Mail: [email protected] Secretary´s office Gabriele Glaßmann Tel.: ++49 (0)711/685-63711 Fax: ++49 (0)711/685-63729 E-Mail: [email protected] Water Quality Management and Water Supply Dipl.-Ing. Ralf Minke, Akad. Oberrat Tel.: ++49 (0)711/685-65423 Fax: ++49 (0)711/685-63729 E-Mail: [email protected] Industrial Water and Wastewater Technology Dr.-Ing. Uwe Menzel, Akad. Direktor Tel.: ++49 (0)711/685-65417 Fax: ++49 (0)711/685-63729 E-Mail: [email protected] Wastewater Technology Dr.-Ing. Jörg Krampe, Akad. Oberrat Telefon: ++49 (0)711 / 685 - 65420 Telefax: ++49 (0)711 / 685 - 67637 E-Mail: [email protected] 21 Chair of Sanitary Engineering and Water Quality Management Water Quality Management and Water Supply Research topics: • Water collection and water treat ment • Removal of iron, manganese and arsenic by subterranian groundwater treatment • In-situ bioreactors for decentralized groundwater treatment and supply • Ecosystem research of rivers and groundwater • Stormwater run-off management, rainwater harvesting and water conservation • Protection of drinking water resources • Investigation of anaerobic treatability of wastewaterand concentrates • Water quality management and its interaction with indirect dischargers and operation of the wastewater treatment plant With us, effluent is just water under the bridge Our field of work consists of all aspects of extraction and provision of water from surface and groundwater sources. Most notably, this involves subterranian groundwater treatment, and all questions relating to the transport, storage and distribution of water. The technical, economical and hygienic aspects play the primary role in this. In the field of water supply, we deal with the problems shown in the margin, whereby the technology of groundwater treatment is increasingly applied to contaminated site remediation. For the treatment of water for industrial use, we employ membranes, oxidation, UV disinfection and anaerobic biological processes. The transport and distribution of drinking water, and the associated hygienic problems, are also subjects of our investigations. We have also listed the focal points of our work in water quality management. Generally, this involves anthropogenic influences on water quality and the protection of drinking water resources. One important example of our research is the investigation of the interaction between wastewater pretreatment in industry and the operation of municipal wastewater treatment plants, and their influence on water quality. The final aim is the optimum disposal of sewage from both a business management and an economical point of view. The development, optimization and implementation of sustainable, cost effective and ecologically sensible water treatment technologies on the one hand and technologically advanced procedures on the other, remains a central task in view of the global drinking water supply crisis. One of the main research areas for the future will therefore be the analysis and defeat of transfer and implementation restraints. In addition, it is also necessary, due to the limited global water resources, to increase research in the fields of water resource control and management in terms of safeguarding drinking water supplies. 22 Water Quality Management and Water Supply WGW Projects Development of a low cost technology for in-situ treatment of groundwater for potable and irrigation purposes In many regions of the world arsenic contaminated water represents a huge problem for the health and the environment. One of those affected regions is for example eastern India (West Bengal). In the course of the project “Development of a low cost technology for in-situ treatment of groundwater for potable and irrigation purposes” several activities concerning this topic took place. In order to remove arsenic from groundwater and to improve groundwater quality a low cost technology for in-situ (subterranean) treatment of groundwater was established in eastern India and a field trial was carried out in order to investigate the practical implementation of this technology on location. Beside the establishment of a low cost technology for subterranean removal of arsenic amongst others workings concerning the improvement of agriculture and farming practices to reduce arsenic contamination in the food chain and public relations were conducted. Financing institution: European Union (EU) Project partner: 1. Queen’s University Belfast - School of Chemical Engineering and Queen‘s University Environmental Science and Technology Research Centre (Questor Centre), Großbritannien 2. University of Stuttgart, Germany 3. Miguel Hernandez University, Spain 4. Leiden University, Netherlands 5. National Metallurgical Laboratory, Indien 6. Institute of Environmental Management and Studies, Indien Storage tank for the aerated water to be reintroduced Contact: Prof. Dr.-Ing. U. Rott Dipl.-Ing. Ralf Minke, AOR Dipl.-Ing. H. Kauffmann Co-funded by the European Union under: Outer view of the well “Asia Pro Eco Programme - a programme dedicated to promote sustainable solutions to environmental problems in Asia”. „The contents of this publication is the sole responsibility of ISWA - WGW and can in no way be taken to reflect the views of the European Union“. 23 Chair of Sanitary Engineering and Water Quality Management Subterranean Arsenic Removal: From Experiment to Delivery Together with the Indian applicant organisation Ramakrishna Vivekananda Mission – Institute of Advanced studies (RKVM-IAS) the Institute for Sanitary Engineering, Water Quality and Solid Waste Management (ISWA) of the University of Stuttgart is implementing the project “Subterranean Arsenic Removal: From Experiment to Delivery”. The objective of this project is to reduce in an affordable and sustainable manner the health consequences of arsenic contaminated water in rural communities of West Bengal, India by in-situ treatment of groundwater. Within the project six insitu treatment plants shall be established. The in-situ treatment plants shall be manufactured and distributed/serviced by local entrepreneurs. Further on they shall be managed by self-sustained community groups with the support of classroom and hands-on training. Financing institution: Development of strategies for water circuit closure for selected industries with split flow concept Most industries used to treat or pre-treat the cumulative waste waters of a factory, targeting in some cases for a partial recycling. Some factories collect waste waters according to their origin and treat these waste waters independently. Nonetheless, often waste waters are thereby blended from individual sources, differing greatly in quantity and quality. These blend waste waters are often difficult to be purified, since the waste water constituents may vary greatly. The treatment steps needed for a purification of such waste waters will become complex and demanding, mastering all eventualities. Thus, a recycling of waste waters is not considered for economical reasons. Paper industry World Bank under Development Marketplace 2006 Project partner: 1. Queen’s University Belfast - School of Chemical Engineering and Queen‘s University Environmental Science and Technology Research Centre (Questor Centre), Großbritannien 2. University of Stuttgart, Germany 3. Ramakrishna Vivekananda Mission – Institute of Advanced studies (RKVM-IAS) Contact: Prof. Dr.-Ing. U. Rott Dipl.-Ing. Ralf Minke, AOR Dipl.-Ing. H. Kauffmann Main focus was given to the application of membrane processes, mainly ultrafiltration and nanofiltration. Ultrafiltration is much less costly than nanofiltration, but only with nanofiltration and reverse osmosis solute salts can be removed. Therewith, an effective sink is created for the removal of salts, accumulating in the circuits otherwise. Thus, with nanofiltration or reverse osmosis applied, water circuits can be concentrated or even closed, without deteriorating product quality. Research is conducted both with waste waters from paper mills producing white paper and mills producing brown paper. The corresponding water circuits differ significantly in respect to organic and inorganic waste water constituents. The COD-levels in the water circuits for instance are usually more than 10 times higher in mills producing brown paper as they are in mills producing white paper. The same applies to the concentration of soluble salts, expressed in terms of conductivity, with a factor of at least 5. Besides the research on finding suitable membranes and membrane combinations, focus is also given on where to apply membrane processes. Biologically treated water is usually easier to treat with membranes, yet resulting in large amounts of concentrates to be disposed. A membrane step close to the production, i.e. the direct filtration of waste waters from the water circuits, can result in a more cost-effective configuration of subsequent biological treatment steps for the resulting concentrates, since smaller streams with higher concentration levels can be applied to for example 24 Water Quality Management and Water Supply WGW anaerobic treatment. Thus, waste waters form different places of origin are considered in the research project. Milk industry For the milk industry, waste waters from different cleaning steps were treated with different membranes. The concentration of constituents in these rinsing waters varies greatly over flushing time. With a separate collection of variable contaminated parts of these flushing waters into streams that either can be reused without treatment, can be fed to membranes directly or need a more complex treatment scheme, including e.g. biological reactors in combination with membranes, the necessary treatment schemes can be applied most cost-effective and purposeful. Apart from this research close to the production processes, experiments were conducted with the effluent of the waster water treatment plant of a milk processing company, whether there are opportunities to recycle the effluent as boiler feed water with reverse osmosis. The quality requirements for boiler feed water are demanding, an almost complete removal of inorganic and organic constituents is required. Financing institution: Willy-Hager-Stiftung Contact: Dipl.-Ing. Ralf Minke, AOR Dipl.-Ing. A. Neft Dipl.-Ing. C. Meyer Membrane pilot-plant to treat wastewater from milk processing by ultrafiltration and nanofiltration 25 Chair of Sanitary Engineering and Water Quality Management A novel and cost-effective approach on preventive water pollution control An improvement of water pollution control in the municipal waste water practice is either achieved long term by process integrated in-plant measures in order to reduce the waste water quantity respectively improve the waste water quality or near-term by cost-intensive advanced treatment (end-of-pipe). The generally fluctuating water quality and quantity results in extremely varying dirt load peaks the treatment plant has to cope with, i.e. the waste water treatment plants rarely work in their optimal range. Temporarily either the compulsory limit values are exceeded resulting in potential water pollution or the waste water treatment plants capacity is not efficiently used. A solution to this problem can be integrated approach to the entire waste water system. Often free storage or treatment capacity is not detected or used. The objective of a case study of the University of Stuttgart, Institute of Sanitary Engineering, Water Quality and Solid Waste Management, is to achieve a preventive water pollution control by setting up a sophisticated interaction of industrial indirect dischargers, municipal waste water treatment plant, sewage network and storm water treatment. The main idea is to establish a load controlled concept based both on online measurement and data from an integrated dynamic simulation model embracing the complete sewage system. A major task of the project is to design this simulation model. The sewage system consisting of a trickling filter treatment plant (ca. 130.000 PT), the sewage draining system, i.e. sewage transport network and storm water treatment facilities, is fed with municipal and industrial waste water (the latter mainly indirectly discharged by a paper mill). To meet the challenges of project the following steps have to be accomplished: • collection and analysis of data and samples from the waste water treatment plant, especially evaluation of the operational journals and the continuous online-measurement data of the biological treatment stage (trickling filter) • collection of meteorological data • set-up of the online measurement (e.g. COD, NH4+, NO3-) • extensive collection and analysis of data and samples from the indirect discharger (paper mill), e.g. basic waste water flows and waste water quality dependent on various conditions like paper grade or internal process impacts) Scheme of optimised cooperation of indirect discharger, sewage network and waste water treatment plant 26 Water Quality Management and Water Supply WGW • analysis of the existing sewage network, e.g. surveying hydraulic conditions of the sewers and respective facilities • calculation of relevant sewage network flow times, utilisation ratios of sewers, hydrostatic water levels and flows under dry weather and storm weather conditions • design, calibration and verification of an integrated dynamic simulation model • installation of structural measures concerning the control facilities of the storm water treatment, the indirect discharger and the sewage network • application of the simulation model and coupling with the online measurement and control facilities With the help of these measures the municipal waste water treament plant is likely to continuous operation in optimal range. The risk of concentration and dirt load peaks polluting receiving waters is avoided or minimised. By a sophisticated discharge control of the industrial waste water point sources and the control of the sewage system facilities based on the conti- nuous model and online measurement information on the free storage capacity of the sewage network and storm water treatment facilities in dependence on the present hydraulic situation (dry weather flow, storm weather flow) as well as on the current state of the municipal waste water treatment plant, an optimal quantitative and qualitative (head parameter = chemical oxygen demand [COD]) feed to the treatment plant is achieved. Thus, long-term an improvement of the water quality without the necessity of expensive new investments in advanced treatment stages can be expected. Financing institution: Ministry for the environment Baden-Württemberg Project partner: University of Stuttgart, Germany City of Heidenheim Voith Paper Technology Center (Heidenheim) Contact: Dipl.-Ing. Ralf Minke, AOR Dipl.-Ing. C. Meyer Dipl.-Ing. S. Schmidt Diploma- and Master Thesis Untersuchungen zur Aufbereitung gering belasteter Spülwässer aus der Joghurt- und Dessertherstellung mit Hilfe von Membranverfahren Fanch Corfmat (Umweltschutztechnik) (2006) Supervisor: Dipl.-Ing. K. Lumpp; Dipl.-Ing. R. Minke, AOR; Prof. Dr.-Ing. U. Rott Untersuchungen zum Einsatz der Ultrafiltration bei der Aufbereitung von Flusswasser aus dem Neckar Hongtao He (Umweltschutztechnik) (2006) Supervisor: Dipl.-Ing. R. Minke, AOR; Prof. Dr.-Ing. U. Rott Untersuchungen zum Einsatz eines anaeroben Festbettreaktors zur Vorbehandlung von Teilschrittabwässern eines Textilveredlungsbetriebes Matthias Künstel (Umweltschutztechnik) (2006) Supervisor: Dipl.-Ing. R. Minke, AOR; Prof. Dr.-Ing. U. Rott Wasserverlustüberwachung mit neuer Sensortechnik Ana Patricia Garzón Fuentes (WAREM) (2006) Supervisor: Dipl.-Ing. R. Minke, AOR; Prof. Dr.-Ing. U. Rott Verfahrenstechnische Optimierung einer Wasseraufbereitungsanlage zur Enteisenung und Entsäuerung eines stark reduzierten Grundwassers Burkhard Obenauer (Weiterbildendes Studium Wasser und Umwelt, Universität Weimar) (2006) Supervisor: Dipl.-Ing. R. Minke, AOR; Prof. Dr.-Ing. U. Rott Present Difficulties of Monitoring the Millenium Development Goals for Access to Water Supply and Sanitation and Ideas for Improvement –discussed on the example of the African RegionChristine Laures (WAREM) (2007) Supervisor: Dipl.-Ing. R. Minke, AOR; Prof. Dr.-Ing. U. Rott 27 Chair of Sanitary Engineering and Water Quality Management Entwicklung eines einfachen Verfahrens zur Grauwasseraufbereitung Selective Transfer of Network Monitoring Utilities into the Water Supply Systems in Lebanon Matthias Sattler (Umweltschutztechnik) (2007) Supervisor: Dipl.-Ing. R. Minke, AOR; Prof. Dr.-Ing. U. Rott Maguy Sadek (WAREM) (2007) Supervisor: Dipl.-Ing. R. Minke, AOR; Prof. Dr.-Ing. U. Rott Evaluation of Flux Decline in Nanofiltration of Paper mills Effluents Benchmarking of Urban Water Utilities Using the IWA-Performance Indicator System: Case Study NWSC, Uganda. Fedy Gusti Kostiano (WAREM) (2007) Supervisor: Dipl.-Ing. A. Neft; Prof. Dr.-Ing. U. Rott Benchmarking of Selected Yemeni Water Utilities Christine Laures (WAREM) (2007) Supervisor: Dipl.-Ing. A. Neft; Prof. Dr.-Ing. U. Rott Dissolved oxygen prediction in aerating runners Johannes Etter (Umweltschutztechnik) (2007) Supervisor: Dipl.-Ing. R. Minke, AOR; Dipl.-Ing. A. Neft; Prof. Dr.-Ing. U. Rott Untersuchungen zur Optimierung einer Entfärbungsstufe für Abwässer aus der Textilveredelungsindustrie am Beispiel der Kläranlage Burladingen Christof Zinßer (Umweltschutztechnik) (2007) Supervisor: Dipl.-Ing. R. Minke, AOR; Prof. Dr.-Ing. U. Rott 28 Lutaaya Mahmood Hakimu (INFRASTRUCTURE PLANNING) (2007) Supervisor: Dipl.-Ing. R. Minke, AOR; Prof. Dr.-Ing. U. Rott Optimierung einer anaerob-biologischen Behandlungsstufe für Textilveredlungsabwässer Christine Dobslaw (Umweltschutztechnik) (2007) Supervisor: Dipl.-Ing. R. Minke, AOR; Prof. Dr.-Ing. U. Rott Water Quality Management and Water Supply WGW Contact Dipl.-Ing. Ralf Minke, AOR Dipl.-Ing. Christof Zinßer Tel.: ++49 (0)711/685-65423 Fax: ++49 (0)711/685-63729 E-Mail: [email protected] Tel.: ++49 (0)711/685-60497 Fax: ++49 (0)711/685-63729 E-Mail: [email protected] Secretary´s office Laboratory Gabriele Glaßmann Tel.: ++49 (0)711/685-63711 Fax: ++49 (0)711/685-63729 E-Mail: [email protected] CTA Ellen Raith-Bausch Tel.: ++49 (0)711/685-65400 Fax: ++49 (0)711/685-63729 E-Mail: [email protected] Research Assistants Dipl.-Ing. Christine Dobslaw Tel.: ++49 (0)711/685-65849 Fax: ++49 (0)711/685-63729 E-Mail: [email protected] M. Sc. Kenan Güney Tel.: ++49 (0)711/685-65425 Fax: ++49 (0)711/685-63729 E-Mail: [email protected] Dipl.-Ing. Holger Kauffmann Tel.: ++49 (0)711/685-65849 Fax: ++49 (0)711/685-63729 E-Mail: [email protected] Dipl.-Ing. Carsten Meyer Tel.: ++49 (0)711/685-63754 Fax: ++49 (0)711/685-63729 E-Mail: [email protected] Dipl.-Ing. Andreas Neft Tel.: ++49 (0)711/685-65425 Fax: ++49 (0)711/685-63729 E-Mail: [email protected] Dipl.-Ing. Sabine Schmidt Tel.: ++49 (0)711/685-63738 Fax: ++49 (0)711/685-63729 E-Mail: [email protected] 29 Chair of Sanitary Engineering and Water Quality Management Industrial Water and Wastewater Technology Research topics: • Process and production integrated environmental protection • Treatment and reuse of process water e.g. in the automobile industry • Adsorption processes in industrial water and wastewater technology, e.g. in the textile industry • Reduction of lipophilic substances in the food and cosmetics industries • Biological and chemo-physical treatment of industrial wastewater • Aerobic and anaerobic degradation tests • Testing Centre of the German Institute for Construction Technology (DIBt) • International Consulting and export-oriented research for example Middle and South America It will all come out in the wash At the department IWT (Industrial Water and Wastewater Technology), we specialize in refining internal plant processes and aim at integrating environmental protection as well as minimizing the industrial emissions by implementing a water circulation and plant-internal treatment processes. We plan environmental moderations for customers in the industrial process as well as integrated solutions in the manufacturing process. The first step we take in order to make a current assessment of the situation at the plant is an on-site inventory survey. According to the survey we can then localize water consumption, wastewater amount and dirt load accruement points. In order to determine the dirt loads accumulated during the manufacturing process, partial wastewater flows are sampled and the relevant parameters are then analyzed. After consulting with the respective company, the tap water quality required for the production process can be specified, in order to minimize fresh water consumption. This can be done by implementing a water circuit consisting of treated wastewater. Production related water consumption and wastewater volumes are then determined by precise recording of the productions figures. This subsequent changes in the production figures allow precise projections of the associated parameters. Based on the survey and the formulation of goals a customer-specified procedure for wastewater treatment can then be agreed upon, which normally leads to further in-depth tests, such as e.g. determination of biodegradability. Due to our systematic procedures and many years of experience we are able to represent our customers with new sustainable solution and potentials. 30 Industrial Water and Wastewater Technology IWT We emphasis mainly in offering our professional advice to clients from the textile finishing industry and paper industry, gastronomy- and food-industry, the cosmetic and pharmaceutical industry, the chemical as well as the metal and automobile industry. Alongside plant internal solutions we also create decentral as well as central solutions by developing extensive purification processes for the treatment of industrial wastewater at communal treatment plant. Therefore a series of aerobic and anaerobic biological degradation tests are carried out in advance. Further emphasis of ours is the treatment of leachate of landfills using biological and chemical-physical processes. For example we are developing adaptable modular processes for the aftercare operations of landfills at reduced leachate levels and toxic concentrations. Therefore the use of carbon adsorption processes and membrane processes play an essential role in our work. Here at the IWT department we also deal with topics such as water and waste recycling as well as saving resources. Exemplary is our expert’s assessment of industrial residues as alternative fuel in the cement industry as well as the sludge incineration in cement plants. Our department is an official control center of the “Deutsches Institut für Bautechnik (DIBt)” in Berlin which is responsible for controlling plants for the limitation of hydrocarbons in wastewater including mineral oils. Our department also offers lectures in the following courses: Civil Engineering, Environmental Engineering, Process Engineering, WAREM (Water Resources Engineering and Management) and WASTE (Air Quality Control, Solid Waste and Wastewater Process Engineering). Our department also offers its courses at different universities abroad, e.g. to Brazil and cooperates with Latin American facilities. Which enables such programs as the cooperation of the Universidade Federal do Parana (UFPR) and the national environmental protection industry Servico Nacional de Aprendizagen Industrial (SENAI/ PR) in Curitiba/ Brazil to create the new Masters program EDUBRAS-MAUI (communal and industrial environmental protection) under management of the IWT Department and under German standards. Furthermore our Department offers so called “Summer Schools” in the area of environmental protection in various Brazilian states. Projects An example of economically, flexible and sustainable treatments based on the case of hazardous wastewater from landfill The treatment of leakage from landfill with active charcoal is state of the art technology. The goal of this landfill leakage treatment is to reduce the parameter of chemical oxygen demand (COD) and adsorbable organic halogens (AOX). This goal is easily achieved by using activated charcoal. For this procedure it is common to use granulated activated charcoal. At the Institute for Sanitary Engineering, Water Quality and Solid Waste Management at the University of Stuttgart there was a project called ”development of a process for the separation and reuse of powdered activated charcoal (PAC) in the wastewater treatment”, which was sponsored by the BMBF. During the course of this project an extra research topic came up regarding a process that justifies the use of PAC in the landfill leakage treatment according to the variable needs of the landfill operators. After a landfill is filled and no new waste is allowed to be added, it is normally covered up in order to minimize additional rainwater from seeping in and creating additional leakage. From this point on the amount of land leakage sinks, but at the same time the structure of the leakage changes. Due to the low cost and short usage time it make sense to implement a flexible process that easily adapts itself to the changing amounts of landfill leakage and to its polluting load. Since the year 2005 according to the regulations of TA Siedlungsabfall it is only allowed to deposit waste containing dry organic solids less than 3 mass-% and 5 mass-%. This fact makes it indispensable having 31 Chair of Sanitary Engineering and Water Quality Management a process that is adaptable to decreased amounts of landfill leakage and to decreased pollution loads. After considering the latter aspects it has been proven that an adsorption process with PAC and then a following treatment of PAC in the sewage treatment plant is not only an affordable, but also a flexible treatment procedure during the period that the landfill is shut down. This method guarantees the necessary cleaning performance through the adsorption of the pollution load to the PAC. The treatment loaded PAC at a communal sewage treatment plant makes it possible to manage without PAC separation and therefore it isn’t necessary to drain the PAC-sludge, which makes this procedure extremely interesting from an economical point of view. Before beginning the process of loaded PAC in a communal sewage treatment plant with a biological treatment, at ISWA a number of experiments were carried out on a laboratory scale to ensure that the substance leading to COD and AOX adsorbed in the PAC do not dissolve from the loaded PAC. Despite these results there is still great need for further research in order to ensure such a process that is risk free for the environment and the operator. The purpose of this research is to find out what the results are of initiating the use of loaded PAC from the landfill leakage treatment in a communal sewage treatment plant. Simultaneously we are also looking into the matter of transporting the PAC-suspension to the sewage treatment plant by means of the communal sewer system, and comparing this with alternative transport methods such as a truck. The latter described adsorption process without separated the loaded PAC should be compared with the more conventional methods of landfill leakage purification by conducting a cost-effectiveness analysis. The accumulated knowledge from the research related to the influence of loaded PAC in a communal sewage treatment plant can prove to be beneficial in many cases throughout different industrial branches. Financing institution: Bundesministerium (BMBF) The execution and evaluation of the biodegradation test through the respiration index (Sapromat), interpretation of the results and an expert’s assessment for a plant-internal wastewater-purification-concept policy The WALA Heilmittel GmbH company is an anthropological philosophy. The company develops, produces and sells medicine and cosmetic products. The company’s extensive range of products include about 1.2000 drug products and 100 natural cosmetic compositions for the face, hair, body and sun-care products under the name “Dr. Hauschka Kosmetik”. These products are exported worldwide in over 30 different countries. The current wastewater installation consists essentially from a precipitation/flocculation in which wastewater from a container-purification system is treated. Especially containers containing product residues or raw waste material are cleaned. It usually contains creams, plant and mineral raw material. Due to an expansion of the product-line and the decision to use a new container purification system, the composition and amount of the wastewater are likely to in the near future. Due to a considerable increase in residual material from the production it can therefore be estimated that there will be an increase of organic load as well as in the daily wastewater accumulation at 20-30 m³/d. Therefore the current wastewater treatment plant must be modified, and a new environmental-friendly wastewater concept has to be developed. Therefore experiments with biological research through the respiration index (Sapromat) are being carried out at the Institute for Sanitary Engineering, Water Quality and Solid Waste Management at the University of Stuttgart. The goal of the latter experiments is to create an environmental-friendly plant-internal purification-concept that is capable of economically purifying and keeping to the limit for indirect discharger. Client: für Bildung und Forschung WALA Heilmittel GmbH, Bad Boll/Eckwälden Project partner: Project partner: Wehrle Umwelt GmbH Abfallwirtschaftsbetrieb Main-Tauber-Kreis (AWMT) Georgi Wassertechnik GmbH, Riederich Contact: Contact: Dr.-Ing. Uwe Menzel, Akad. Direktor Dipl.-Ing. Stefan Schölpple 32 Dr. Ing. Uwe Menzel, Akad. Direktor Industrial Water and Wastewater Technology IWT Aspects and fundamental possibilities of incineration of certain material groups as alternative fuel in the cement industry with a special consideration from an ecological and a legal point of view. The Holcim GmbH in Dotternhausen (southern Germany) is a subsidiary of the worldwide active construction company Holcim Ltd.. The company’s main fields of production are: cement, gravel and concrete. Alongside the cement plant in Dotternhausen, there are other plants such as the gravel and concrete plant in Offenburg, Lörrach-Brombach, Weil am Rhein, Haltingen and Grenzach-Wyhlen. These plants produce different kinds of building material for different purposes. The integration of new knowledge should be able reduce the impact of the manufacturing-process on the environment. And thanks to investments in new technology and concepts the company as well as the resources are spared. In the cement plant Dotternhausen about 470.000 tons of clinker, 300.000 tons of burned oil-slate 650.000 tons of cement and 200.000 tons of special binding agent are produced yearly. Limestone and oil-slate are used as raw material. Oilslate is incinerated and produces most of the plant’s energy needs. Besides coal alternative raw materials and fuels are being used, for example: old tiers, dried sewage sludge, waste from paper production and plastic. The goal of this study is to find the most economical options for the co-incineration of certain groups of materials that also fall under a positive ecological judgment and can be applied by the Holcim GmbH. Not only is the technical application of great importance to us, but the legality as well as the reflection of the legislator’s political standpoint from a German perspective and in a European context as well. Client: Holcim (Süddeutschland) GmbH, Dotternhausen Contact: Dr.- Ing. Uwe Menzel, Akad. Direktor Dipl.-Ing. Stefan Schölpple Consultation in the form of a workshop regarding the options of biological elimination of carbohydrate from process water from car wash installations as well as the development of an appropriate process which will then be put to an test at the Alfred Kärcher GmbH & co company. Waste water from car wash installations contains organic compounds such as carbohydrates which, according to the German law must be reduced by a water treatment plant to levels under 20 mg/l in order to be used for the purpose of water recycling or discharge into the sewer network. The Alfred Kärcher GmbH have been treating such process water in chemo-physical treatment plants such as precipitation/flocculation. On the one hand this reduces the usage of fossil fuels, for example coal and oil contribute towards sparing resources and on the other hand reduces the exhaust of carbon dioxide. Due to the fact that biological processes are environmentally friendlier than chemical ones, the Alfred Kärcher GmbH & co. are striving to develop a practical and affordable biological process which should then be put to the test under practical conditions. After an extensive literature research it should be determined what kind of materials are possible to be incinerated along with common fuels used by the cement industry, and also take the ecological and legal aspects into consideration. Part 1: A workshop Part 2: Consultation during the development and construction of a prototype Part 3:Practical tests and research in the testing stage When compiling the study we are looking for certain streams of material from industrial processes that contain residues and byproducts that are to certain degree suitable as alternative fuels for the cement production. Examples of such materials are: oil-emulsions, from the automobile and metal industry, residues from the paper and photograph industry, residues from the plastic production and used tiers are suitable. Client: Alfred Kärcher GmbH & Co., Winnenden Contact: Dr.- Ing. Uwe Menzel, Akad. Direktor 33 Chair of Sanitary Engineering and Water Quality Management The accompanying and testing of a wastewater treatment system for the purification of mineral oil contaminated wastewater using a water circuit The Mall GmbH company has applied for a granting of a general construction permit at the Deutschen Institut fuer Bautechnik in order to build a wastewater treatment system for the purification of mineral oil contaminated wastewater using a water circuit. The practical test will be carried out by the Fischle GmbH company in Esslingen, which already has such system in use. The system in question concerns the use of a biological process with pre-separation. The system will then be coated with wastewater from a bus-wash installation as well as wastewater from a workshop of the Fischle GmbH company. In order to broaden the application fields a truck will be driven through the wash-installation as a test. Client: Firma Mall GmbH, Pfohren A short assessment of a wastewater treatment concept, in which an application for an approval for indirectly discharging pre-purified industrial wastewater from the inner cleaning of a fuel installation into the public sewer network of the city of Graz The Grazer Waschbetriebe GmbH company is planning to apply for approval for indirectly discharge pre-purified industrial wastewater from the inner cleaning of a fuel installation into the public sewer network of the city of Graz. The wastewater treatment-concept is based on the proposal made by the office of Dipl.-Ing. Dr. Bernhard S. Mayr. The contents of this concept shall be examined in order to create a short assessment into the matter. Client: Fa. TCS, Stuttgart Contact: Dr.-Ing. U. Menzel, Akad. Direktor Contract: Dr.-Ing. U. Menzel, Akad. Direktor The official inspection office, responsible for carrying out practical tests at different plants to ensure the reduction of hydrocarbon in wastewater containing mineral oil. As a result of Dr. Menzel being appointed part of the expert-committees: “Abscheider und Mineralölhaltiges Abwasser -A- (428)” “Mineralölhaltiges Abwasser -B 3-(428c)” “Miniralölhaltiges –B 4-(428d)” by the “Deutsches Institut für Bautechnik (DIBt)” in Berlin, the Institute for Sanitary Engineering, Water Quality and Solid Waste Management at the University of Stuttgart (IWT department) was then appointed as the official inspection office. The department is responsible for carrying out practical tests at different plants to ensure the reduction of hydrocarbon in wastewater containing mineral oil. Client: Deutsches Institut für Bautechnik (DIBt), Berlin Contact: Dr.-Ing. U. Menzel, Akad. Direktor 34 The development of a process for the treatment of process water from the separation of chlorite-sulfate and bypass-dust from the cement industry. The Schwenk Zement KG company was found in the year 1847, making it the oldest cement company in the European cement industry. Alongside manufacturing cement Schwenk Zement KG also specializes in dam technology, façade technology as well as the manufacturing of transport concrete. Further more the Schwenk Zement KG is the leading company in the German branch known for renting/leasing concretepumps. In the company’s 4 cement plants in Germany partially up to 100% of the used fuels are alternative/ recovered fuels. In each cement plant about one or two tons of bypassdust accumulates per hour, and therefore creating amounts of 10.000 tons of accumulated bypass-dust a year. This means that at a total production rate of 1 Mio. tons of cement a year adds up to 40.000 tons of accumulated bypass-dust. This bypass-dust is amongst other things fortified with a high concentration of chloride-sulfate which encourages caking and corrosion. Industrial Water and Wastewater Technology IWT Therefore the Schwenk Zement KG company intends to gather the chlorine load from the bypass-dust. In order to achieve this four or five times the amount of heated water is added to the dust. This leads to the dissolving of the salts in the bypass-dust, and therefore enabling the dust to be used in an environmental friendly manner. The salt from the process water should be gathered in a suitable process-combination. This process should be affordable and efficient and therefore enabling the use of a water circuit of the process water. For this purpose an environmental friendly process or processcombination should be developed, tested and applied on a big scale in the industry. Here is a description of the research process: Part 1: Literature and application studies Part 2:The research of the conclusion from part 1 through laboratory or technical tests Part 3: Suitability test in a pilot-installation Part 4:Consultation and monitoring of the technical implementation of the project Client: Schwenk Zement KG, Ulm Contact: Dr.- Ing. Uwe Menzel, Akad. Direktor Dipl.-Ing. MSc. Sebastian Platz Aspects and fundamental possible processes for the treatment, disposal and utilization of sewage sludge with a special consideration from an ecological and a legal point of view. The Holcim GmbH in Dotternhausen (southern Germany) is a subsidiary of the worldwide active construction company Holcim Ltd.. The company’s main fields of production are: cement, gravel and concrete. In the cement plant Dotternhausen about 470.000 tons of clinker, 300.000 tons of burned oil-slate 650.000 tons of cement and 200.000 tons of special binding agent are produced yearly. Limestone and oil-slate are used as raw material. Oilslate is incinerated and produces most of the plant’s energy needs. Besides coal alternative raw materials and fuels are being used, for example: old tiers, dried sewage sludge, waste from paper production and plastic. On the one hand this reduces the usage of fossil fuels, for example coal and oil contribute towards sparing resources and on the other hand reduces the exhaust of carbon dioxide. After an extensive literature research it should be determined fundamental possible processes for the treatment, disposal and utilization of sewage sludge, and also take the ecological and legal aspects into consideration. When compiling the study we are looking for certain materials and especially if sewage sludge is suitable as an alternative fuel for the cement production. The way the sludge is utilized should be assessed with a special consideration of the regulation TA Siedlungsabfall. The goal of this study is to find the most economical options for the co-incineration of certain groups of materials that also fall under a positive ecological judgment and can be applied by the Holcim GmbH. Client: Holcim (Süddeutschland) GmbH, Dotternhausen Contact: Dr.- Ing. Uwe Menzel, Akad. Direktor Alongside the cement plant in Dotternhausen, there are other plants such as the gravel and concrete plant in Offenburg, Loerrach-brombach, Weil am Rhein, Haltingen and Grenzach-Wyhlen. These plants produce different kinds of building material for different purposes. The integration of new knowledge should be able reduce the impact of the manufacturing-process on the environment. And thanks to investments in new technology and concepts the company as well as the resources are spared. 35 Chair of Sanitary Engineering and Water Quality Management The execution and evaluation of the biodegradation test through the respiration index according to the OECD-guidelines such as DIN 38405, Teil 52 (Sapromat), interpretation of the results and creating assessment statement The sewage treatment plant in Laupheim is currently extended to capacitate 35.000 populations equivalent and treats domestic as well as industrial wastewater. Along with other industrial plants the company CCL Rapid Spray GmbH & Co.KG indirectly discharge their wastewater into the communal treatment plant in Laupheim. The CCL Rapid Spray GmbH & Co.KG company produces deodorant sprays and other hygiene products. In this case wastewater is mainly created when the reactors, which were used for mixing the products, were cleaned. The wastewater accumulated during the production process is distinguished by a high concentration of lipophilics and detergents. Before being discharged into the sewer network, the partial flows of wastewater flow through a 25 cubic meter buffer tank. After the wastewater from CCL Rapid Spray GmbH & Co.KG reaches the communal treatment plant in Laupheim, the oxygen concentration in the aeration tank sink to levels under 0,5 mg/l, although the maximal efficiency of the blower system is being worked with. This condition can last for hours. The goal of the research is to find the reason for the sinking oxygen level in the aeration tank in the treatment plant in Laupheim, especially to test if a component in the wastewater of the CCL Rapid Spray GmbH & Co.KG company could be the course of the high oxygen sag. Client: Stadt Laupheim Contact: Dr.-Ing. U. Menzel, Akad. Direktor An assessment report of the situation at the plant and an evaluation of the current wastewater treatment, as well as the development of an efficient and secure process-concept for the process water treatment at the Zeller + Gmelin GmbH & co as well as Südöl Mineralöl-Raffinerie GmbH in Eislingen Germany. The companies Zeller + Gmelin GmbH & co as well as Südöl Mineralöl-Raffinerie GmbH are middle classes companies with more than 650 workers and with international connections. The company Zeller + Gmelin GmbH & co offer a variety of products for the automobile- and industrial lubricants, chemical and print colors where as the company Südöl offers the environmental service of an disposal concept for solid and liquid workshop waste as well as treatment of used oil. During the treatment-process about 200 cubic meter of wastewater from the production are produced daily. Characteristics of this water is high levels of organic components, and a COD of 50-70 mg/l. The COD load which is then created as a result of the high COD levels, creates about 50% of the COD load of the city of Eislingen, which is then directed to the communal sewage treatment plant Göppingen for further treatment. Sapromat-test tube 36 Alongside the high levels of organic components the wastewater parameter AOX and heavy metals represent a problem for the plant-intern purification system, which consists mainly at the process of precipitation/flocculation and flotation, and therefore is pushed Industrial Water and Wastewater Technology IWT to the limit. During the indirect discharge of COD, AOX and heavy metals, the limits are not always securely kept. And besides that extra fees for strongly polluted wastewater up to 250.000 Euros must be paid annually. Further costs are caused by the chemo-physically treatment of the process water with flocculation chemicals such as FeCl2 and CaCl2, which on the one hand causes the unavoidable high salt concentration in the wastewater and on the other hand causes large amounts of hydroxide sludge. Annually about 600 tons of sludge is accumulated. The purchasing of the necessary precipitation chemicals as well as the disposal of the accumulated hydroxide sludge creates such high costs so that the company had to increase their annual budged of 500.000 Euros for this purpose. Therefore this process is to be seen critically from an ecological and economical point of view. The goal is to create a secure and economical plantintern wastewater treatment plant, particularly regarding the point of keeping the discharged compounds to the set limits. The task list is split u into four parts: Part 1: Documentation and an on-the spot analysis of the workflow in the current wastewater treatment plant by evaluating the plant records and the existing wastewater cadastral register. Part 2: The development of an efficient process-concept for the process water treatment Part 3: Testing the developed process from part 2 on a half technical scale at the plant Part 4: Testing the possibilities of online-recording of analysis and process parameters within the wastewater treatment plant Client: Zeller + Gmelin GmbH & Co sowie Südöl MineralölRaffinerie GmbH, Eislingen Contact: Dr.-Ing. U. Menzel, Akad. Direktor Experimental plant for the biological wastewater treatment 37 Chair of Sanitary Engineering and Water Quality Management International curriculum exchange Study course offers from German universities and academies abroad The initiation of German environmental Master of Science programs at Brazilian universities under German supervision and at German standards – EDUBRAS At the pace of the current booming industrialization, environmental pollution causes serious problems in emerging and developing countries. In Brazil, which is the most populous country in South America, this is particularly visible in densely populated areas. Due to the successful years at experience that the lectures from the University of Stuttgart have had in creating new environmental study courses such as “Umweltschutztechnik” and the English Master of Science program WAREM and WASTE, this experience should now be transported to Brazil through the EDUBRAS program which takes place in the Brazilian state Parana. EDUBRAS is meant to be an exemplary program, which can then later be implemented at other universities abroad. The basic concept behind the planned study program were established based on the environmental inventory of Dr. Menzel during the research project “Export oriented research on the field of water supply and water disposal, part 2: wastewater treatment and water reuse” funded by the German “Federal Ministry for Education and Research (BMBF)”. This revealed the desperate need to import new and modern environmental technologies to Brazil. It also revealed the need and the interest in educating local skilled specialists in order to operate the imported technologies and thereby creating a sustainable environmental-protection system. After the success of the “Summer-School-courses” from 2002-2005 dealing with the topics of wastewater/industrial wastewater and waste/industrial waste, not only showed a great interest for environmental topics, but the need for such courses or similar ones to be given on a permanent basis as local study courses at Brazilian universities as well. This is crucial in order to train local specialized staff in order to ensure the sustainability and success of all environmental proce- Signing of the cooperation treaty for the initiation of the master course EDUBRAS-MAUI in Curitiba by the director of the „Universidade Federal do Paraná – UFPR“ Carlos Augusto Moreira Junior and the EDUBRAS project director Dr. Uwe Menzel 38 Industrial Water and Wastewater Technology IWT dures. With the help of the program “Course offers from German universities in foreign countries” offered by the DAAD, it will be possible for Brazilian universities to offer additional study courses in Brazil. In July 2007 the master program environmental engineering was inducted at the national university “Universidade Federal do Parana – UFPR” in Curitiba, Brazil. The goal is to create a “Master of science” program which is accepted in Brazil or alternatively in German and Brazil, and to achieve an accreditation of that program. The study program will be financed by tuition fees. It is intended to first link the university lectures and research through close cooperation with the University of Stuttgart and later on by building an infrastructure at the UFPR. The lectures will be held in German as well as in Portuguese. Alongside the lectures German language courses will be offered in order to strengthen the relationship with Germany. German will take part in creating the courses’ curriculum as well as being responsible for the quality control of the courses. The German side will be in charge of administrating and coordinating the overall project. The structure of the study program offers a wide range of courses in the field of environmental engineering, and the positions will be occupied by Germans and Brazilians. The coordination with the project-partner UFPR is regulated by a cooperation treaty. The UFPR is responsible for providing the infrastructure and the lecturers as well as for the fee and coordination on the Brazilian side. Due to the public relations and the contact to the industry, and the partnership in the industrial alliance SENAI it is therefore possible to guarantee practicaloriented programs as well. Extensive treatment processes for water and wastewater. Post-graduation-specializing course at the “FACULDADE DE TECNOLOGIA SENAI BLUMENAU”, the national environmental protection center of the industry (SENAI-SC) in Blumenau/ Santa Catarina Brazil. The national environmental protection center of the industry (SENAI-SC) in Blumenau/ Santa Catarina offers a post-graduate-specializing course “Gerenciamento de Aquas e Efluentes”. As part of these courses Dr. Menzel gives a series of lectures called “Advanced Treatment Technologies for Process-Water and Wastewater”. Financing institution: Nationales Umweltschutzzentrum (SENAI) in Blumenau der Industrie Contact: Dr.-Ing. U. Menzel, Akad. Direktor “Environmental management in the industry” post-graduate-specializing course at the Universidade Federal do Parana (UFPR) in cooperation with the national environmental protection center of the industry (SENAI) Over the past few years the Universidade Federal do Parana (UFPR) has lead the post-graduate-specializing course “Environmental Management in Industries” in cooperation with SENAI. As part of this course Dr. Menzel gives a series of lectures called “Management of Industrial Wastewater”. Financing institution: Deutscher Akademischer Austauschdienst DAAD Universidade Federal do Parana (UFPR) in Curitiba Nationales Umweltschutzzentrum der Industrie (SENAI) in Curitiba Project partner: Project partner: Universidade Federal do Paraná (UFPR) Serviço Nacional de Aprendizagem Industrial (SENAI) Universidade Federal do Parana (UFPR) in Curitiba Nationales Umweltschutzzentrum der Industrie (SENAI) in Curitiba Contact: Contact: Dr.-Ing. U. Menzel (IWT), Akad. Direktor Dr.-Ing. D. Neuffer (IWT) Dr.-Ing. K. Fischer (SIA) Prof. Dr. rer. nat. J. Metzger (CH) Dr.-Ing. U. Menzel, Akad. Direktor Financing institution: 39 Chair of Sanitary Engineering and Water Quality Management Environmental engineering study offers in Brazilian Summer School at Fundacentro (Fundao Jorge Duprat Figueiredo de Segurance e Mediciana do Trabalho (research institute at the ministry of work) in Sao Paulo and CEFET (Centro Federal de Educacao Tecnologica do Parana) in Curitiba, Brazil. Alongside political and legal conditions it is also crucial to obtain the know-how and qualified personal in order to create a sustainable environmental protection program and solve environmental problems. As part of the model-project “Umweltschutztechnische Studienangebote in Brasilien – Summer School” lecturers of the University of Stuttgart will hold a three week learning event in Brazil in which the field of waste-economy, waste technology and industrial water and wastewater technology will be taught. The participants in the Summer School should be able to apply their acquired knowledge in order to contribute to the environmental protection in Brazil. The Participants include professors, students from higher semesters and colleges, as well as professionals from industrial and communal branches. The Summer Schools are executed due to strong cooperation between the IWT department at the University of Stuttgart and Brazilian universities and academic institutions in Brazil. The experiences and contacts made during this modelproject should contribute to the development of new study events and programs in Brazil as well as create a bond to the University of Stuttgart. As far as the participating partners are concerned this project is an opportunity to cooperate in the fields of science, research, joined projects as well as student exchange programs etc. with the University of Stuttgart. The participants of the summer school in Belo Horizonte during the visit of the goldmine of the Anglogold company 40 Industrial Water and Wastewater Technology IWT Teaching topics of the Summer Schools: „Industrial Waste Water Treatment“ • • • • • • • • • • • • • Intro waste water treatment technology Volume, types and contents of waste water Fundamentals of industrial watermanagement Abstract of process technologies Preparing measures Mechanical-physical treatment Biological treatment Conditioning of sludge and sludge disposal Physicochemical treatment Case study: combined processes Examples of practical applications Exercises in groups Excursion „Solid Waste Management and Treatment“ • Environmental aspects of solid waste • Source, composition, quantities of solid waste • Waste management systems • • • • Collection and transport of solid waste Sorting and recycling Waste disposal – landfill, incineration Composting and anaerobic digestion of separate collected biowaste • Air purification • Analysis of solid waste Financing institution: Deutscher Akademischer Austauschdienst DAAD Project partner: Fundacentro (Fundacao Jorge Duprat Figueiredo de Seguranca e Medicina do Trabalho (Forschungsinstitut am Arbeitsministerium) in Sao Paulo; CEFET (Centro Federal de Educacao Tecnologica do Parana) in Curitiba Contact: Dr.-Ing. U. Menzel, Akad. Direktor Dr.-Ing. D. Neuffer Dr.-Ing. K. Fischer (SIA) Dipl.-Geol. D. Clauß (SIA) Diploma- and Master Thesis Untersuchungen zur Reinigung von sulfat- und schwermetallhaltigen Abwässern durch kombinierte Membranverfahren im Vergleich zu konventionellen Fällungs- und Flockungsverfahren Entwicklung und Optimierung eines Prototypen zur biologischen Aufbereitung von Abwasser aus der Fahrzeugwäsche bei der Firma Alfred Kärcher GmbH & Co. Angela Aray (WAREM) (2006) Supervisor: Dr.-Ing. U. Menzel Master Thesis Michael Eckert (Umweltschutztechnik) (2007) Supervisor: Dr.-Ing. U. Menzel Wirtschaftlichkeitsbetrachtung für Prozessund Abwasserbehandlungsverfahren in China (2006) Yongquan Yan (Umweltschutztechnik) (2006) Supervisor: Dr.-Ing. U. Menzel JZR Process for High Load Wastewater Treatment Zhang Yanrong (WAREM) (2006) Supervisor: Dr.-Ing. U. Menzel Master Thesis Abwasserbehandlungsstrategie in der Industriezone Zekou Stadt Qianjiang Hubei, China Chenjie Jiang (Umweltschutztechnik) (2007) Supervisor: Dr.-Ing. U. Menzel Zentrale oder dezentrale Abwasserbehandlung in Ze Kou – Industriezone Qian Jiang, Hu Bei, China Kun Zhang (Umweltschutztechnik) (2007) Supervisor: Dr.-Ing. U. Menzel 41 Chair of Sanitary Engineering and Water Quality Management Choice and verification of a suitable process technology for the waste water treatment of sweetproduction by field tests Entwicklung eines Verfahrens zur Ammoniumeliminierung für eine bestehende Grundwasserreinigungsanlage Larisa Nikitina (WASTE) (2007) Supervisor: Dr.-Ing. U. Menzel Master Thesis Wencheng Yan (Umweltschutztechnik) (2007) Supervisor: Dr.-Ing. W.R. Müller (Biology), Dr.-Ing. U. Menzel Untersuchungen zur Biomassenabtrennung an einen Strahlzonenschlaufenreaktor und weitergehende Behandlung mittels Nanofiltration bei einem Abwasser der Textilindustrie Ridong Huang (Umweltschutztechnik) (2007) Supervisor: Dr.-Ing. U. Menzel 42 Industrial Water and Wastewater Technology IWT Contact Dr.-Ing. Uwe Menzel, Akad. Direktor Tel: Fax: Mobil: Email: ++49 (0)711/685-65417 ++49 (0)711/685-63729 ++49 (0)172/7303330 [email protected] Secretary´s office Christine Schulmeister Tel: ++49 (0)711/685-63742 Fax: ++49 (0)711/685-63729 Email: [email protected] Research Assistants Dr.-Ing. Daniela Neuffer Email: [email protected] Email: [email protected] Dipl.-Ing. Stefan Schölppe Tel: ++49 (0)711/685-65419 Fax: ++49 (0)711/685-63729 Email: [email protected] Dipl.-Ing. MSc. Sebastian Platz Tel: ++49 (0)711/685-65470 Fax: ++49 (0)711/685-63729 Email: [email protected] Dipl.-Ing. Kay Kolata Tel: ++49 (0)711/685-65419 Fax: ++49 (0)711/685-63729 Email: [email protected] Dipl.-Ing. Karen Amaral Tel: 0711/685-65470 Fax: 0711/685-63729 Email: [email protected] Laboratory CTA Silvia Brechtel Tel: Fax: ++49 (0)711/685-63731 ++49 (0)711/685-63729 43 Chair of Sanitary Engineering and Water Recycling Wastewater Technology Research topics: • Membrane processes for wastewater treatment and reuse • Removal of organic trace compounds • Integration of fuel cells in wastewater treatment plants • Phosphorus recovery from wastewater and sewage sludge • Treatment of process water from sludge dewatering • Fixed-bed processes for biological wastewater treatment • Infiltration water in wastewater treatment plants • Stormwater treatment in combined and separate systems • Monitoring and control of pollution loads in sewer networks • Reduction of germs in stormwater and wastewater Muddy waters? Not with us! Our Wastewater Technology department undertakes research primarily on municipal sewage treatment and discharge. Our activities are focused on research in current problems of sewage technology, training and continuing professional development of personnel for sewage treatment plants and sewer networks. Furthermore, the department acts as an independent consultant for plant operators and engineers in all issues related to the operation and planning of sewage treatment plants and sewer networks. The aim of our consulting and research activities is to achieve long-term protection of surface waters taking economic factors into consideration. Some of the most significant developments in wastewater treatment in Germany have been influenced by our department. For example, in 1982 the first tests involving separation of activated sludge using membranes took place here. Since then the importance of this process has increased. In more recent projects, we have investigated the use of membrane technology for the retention of pathogens and organic trace substances. Our wastewater discharge projects also include sewer network management. Here, monitoring systems and the control of pollution loads are at the forefront. Moreover, we explore the economical and ecological effects of infiltration water into sewers and establish systematic concepts for its recognition and reduction. We provide a number of advanced training opportunities for domestic and foreign wastewater professionals. The long term aim of these courses is to enable foreign sewage treatment works personnel to achieve the level of training common in Germany. Since the technical state of treatment plants in other countries is continuously improving, these plants can only be optimally utilized by appropriately qualified personnel. This training is also of great importance for German companies in terms of the development of new markets, as most of the technologies taught in such courses are principally German in origin. 44 Wastewater Technology AWT Projects Effects of a longer power failure on surface waters through wastewater treatment plants Energy is becoming a more important aspect for the analysis of waste water treatment plants (WWTP). Numerous research studies were carried out in the recent past on this topic, with the goal being predominantly aligned to the energy optimization and balance of wastewater treatment plants. In doing so, the intention was to find the most efficient technologies to cover the energy demand of wastewater treatment plants as well as to optimize their operation and develop alternative processes. Unfortunately, the effects of a long power failure on the operation of wastewater treatment plants and the resulting influence on the waterbody quality remain practically unexplored. In the context of this project two aspects should be examined; Firstly, assessment of secure supply of electricity and determination of the degree of the self-power supply of purification plants. Secondly, estimation of the water contamination loading at a longer power failure at wastewater treatment plants. In the Figure below the absolute numbers of the current consumption, production and the degree of the self-power supply for the waste water treatment plants in Baden-Württemberg are plotted. In the diagram a clear potential for the increase of the self-power supply is to be recognized. However, for class 4 it must be marked that in the range of 10.000 P.E to 100.000 P.E. the degree of self-power supply is unfavourable due to predominant economic reasons. Because of the dimensions in class 5, the few waste water treatment plants without combined heat and power plant (BHKW) have significant effects on the balance presented in Illustration 1. However, in the context of the inquiry, numerous waste water treatment plants foretold the planning and the construction of such plants. The following Figure shows the estimated effects of an insufficient self-power supply on water bodies. In the diagram the lower bar represents the waterbody contamination loading during regular operation of waste water treatment plants. According to the boundary conditions defined for the current project, the operation of all waste water treatment plants in BadenWürttemberg is ceased after four days. On this end, the maximum waterbody contamination loading that can be expected, approximately 1.500.000 kg COD per day, occurs. The time period after which the complete purification capacity of all wastewater treatment plants is restored following the re-establishment of Current consumption and production of waste water treatment plants, degrees of the self-power supply 45 Chair of Sanitary Engineering and Water Recycling power supply, was not a subject in this investigation. The restoration to regular operation is therefore only qualitatively to be considered. In the context of the current investigation it can be perceived, that optimal waste water treatment plant operation is tightly associated to self-power and security-power supply, which both require substantial improvement. This prerequisite, aiming at an improved waterbody protection even during long power failures, necessitates common efforts on diverse levels. Financing institution: Ministry of Environment, Baden-Württemberg Duration: 02/2005 - 01/2007 Contact: Dipl.-Ing. Klaus Keicher Dr.-Ing. Jörg Krampe Internet: http:// www.iswa.uni-stuttgart.de/awt/en/research. html Estimated waterbody contamination due to the operation of waste water treatment plants 46 Wastewater Technology AWT Examinations to improve the hygienic river quality of the Körsch The determination of significant anthropogenic pollutions and the evaluation of their effects on the ecological current state of the surface water are an important part of the European Union water framework directive (2000/690/EG). The causes of poor quality (hygienic) of river water are mainly the anthropogenic loads, especially sewage discharges. These degrade river water not only hygienic-biologically, but optically as well (e.g. foam formation, sanitary products etc.). Koersch is a small river south of the Stuttgart metropolitan area and an important inflow into the Neckar. It is significantly affected by anthropogenic sources, 2 wastewater treatment plants and 52 stormwater overflow tanks (only within the boarders of Stuttgart City). Under the scope of the current research project, microbiological examinations of the river Koersch, the discharges from certain stormwater overflow tanks and the two wastewater treatment plants Stuttgart-Möhringen and Stuttgart-Plieningen were to be carried out. After the first period of examination the impact of the sewage became conspicuous during dry weather periods (discharges from the wastewater treatment plants) as well as by rainy weather periods (discharges from the sewage overflow tanks). The concentrations of the pathogens in the river were higher at rainy weather than that at dry weather by 1 to 2 orders of magnitude. The limit values according to the EU Directive on Bathing Water Quality were exceeded permanently. The aim of the research project is to develop measures for improving the river water quality. The project contains an integrated management of sewer system, wastewater treatment plant and surface water. The wastewater treatment plant Stuttgart-Plieningen is ideal for simulating sewage network control because of seasonal reserves in summer time due to absence of water quantities originating from de-icing process at the airport in Echterdingen during winter. Especially at rainy weather conditions there are possibilities to optimize the sewage network control, e.g. by increasing inflow to the wastewater treatment plant. Measures to reduce the negative impact on the river Koersch are prioritized depending on feasibility and effectiveness. Financing institution: Stadtentwässerung Stuttgart (SES) Duration: 10/2006 – 04/2009 Contact: Dipl.-Ing. Juliane Gasse Internet: www.iswa.uni-stuttgart.de/awt/en/research.html Escherichia coli concentrations of the river Körsch as well as the confluence Ramsbach and the discharges of municipal wastewater during dry and rain weather conditions 47 Chair of Sanitary Engineering and Water Recycling Comparative examinations of innovative processes for disinfection of Stuttgart’s wastewater treatment plants The City Drainage of Stuttgart (SES) operates four wastewater treatment plants (1,6 Mio. PE) and a sewer system 1.700 km long. Besides the stormwater overflow and the agricultural effluents, wastewater treatment plant effluents are in general the main emission source of pathogens into the rivers in spite of the high degree of purification. Different pathogens and germs have a significant influence on the utilisation of surface water as bathing water. Therefore innovative disinfection systems (UV and membrane facilities) for improving the hygienic quality of effluents were operated in parallel and were evaluated technically and economically. The examinations were carried out at the Sewage treatment plant for Research and Education of the Universität Stuttgart. The disinfection systems were operated at the same time and with the same wastewater (effluent of microsieves or effluent of secondary sedimentation tank). For the investigation constant (Qmax/2 and Qmax) and proportional to the inflow of the LFKW loading rates (Qinflow-proportional) were implemented. The expected degree of disinfection was not given at the outset. The first experimental period (influent pilot plants = effluent microsieves) was affected by optimizing measures on the part of the manufacturing compa- nies. In the second experimental period the degree of disinfection in all pilot plants was excellent. The concentration of total coliforms and faecal coliforms dropped far below the guide values of the EU Directive on Bathing Water Quality. Hence, the disinfection capability of these technologies has been acknowledged. Considering large-scale utilisation, UV disinfection is the most economical process. Membrane systems exhibit very high operational costs due to energy consumption and chemical cleaning requirements. They could be recommended only for wastewater treatment plants that require an improvement concerning other parameters (e.g. suspended solids, total phosphorous) and that do not yet have sand filters or similar systems in operation. This would be conceivable in the wastewater treatment plant in Stuttgart-Möhringen. Financing institution: Stadtentwässerung Stuttgart (SES) Duration: 03/2006 – 11/2006 Contact: Dipl.-Ing. Corinna Schrader Dipl.-Ing. Juliane Gasse Internet: www.iswa.uni-stuttgart.de/awt/en/research.html Faecal coliforms in the influent and effluent of the pilot plants (influent = second clarifier effluent) 48 Wastewater Technology AWT Recovery of Phosphorus from Sewage Sludge The production of industrial fertilizer containing phosphorus requires the exploitation of geological sources which leads to a reduction of decomposable rock and therefore contradicts the rule of sustainability. To preserve the natural resources, a process was developed to recover phosphorus from municipal sewage sludge. Phosphorus is leached out of digested sludge at pH=2 by the use of sulphuric acid. In this step, amongst phosphorus, metals contained in the sludge are dissolved. The phosphorus-enriched liquid phase is then separated from the remaining solid phase by a chamber filter press. In the liquid phase, interfering metal ions are complexed with citric acid to exclude them from further chemical reactions (e.g. precipitation of phosphorus as metal-phosphates). For the following MAP-precipitation, pH has to be adjusted to 8,5 by adding NaOH. The phosphorus in the liquid phase is then precipitated by the addition of MgCl2. Dissolution container MAP-precipitation container 49 Chair of Sanitary Engineering and Water Recycling The produced MAP can be directly used as fertilizer. The latest research (Römer, 2006; Simon and Clemens, 2006; Goto, 2001) showed that the fertilizer value of MAP is comparable to that of commercial fertilizers. The quality of the produced MAP is comparable to that of commercial mineral fertilizers in terms of heavy metal concentration. Financing institution: Ministry of Environment, Baden-Württemberg Project partner: iat-Ingenieurberatung GmbH, Stuttgart Duration: 04/2006 – 12/2007 Contact: Dipl.-Ing. Alexander Weidelener Internet: www.iswa.uni-stuttgart.de/awt/en/research.html Facility diagram 50 Wastewater Technology AWT Investigations of the Use of Sediment Traps in Combined Sewer Systems in Municipalities in Baden-Württemberg Combined sewer systems are traditionally widespread in Baden-Württemberg. Thereby, it became obvious that sewer sediments in local drainage systems may cause operational problems. Mineral solids entering machinery and mechanical installations in sewer networks can lead to damaging of pumps, pressure pipes, fine-meshed sieves and rakes. This increases maintenance requirements and operational costs. The installation of sediment traps in combined sewer systems is an alternative method, serving as protection device and bringing significant financial advantages. Within the scope of the current project, a survey on species and domain inventory of sediment trap facilities in Baden-Württemberg has been carried out. The systems under consideration were evaluated in respect to their efficiency and functionality. Export-oriented Research and Development in the Field of the Wastewater Treatment Subproject: Use of the Trickling Filter Process under Different Country-Specific Influence Factors The European and American dimensioning standards for trickling filters do not sufficiently comprehend influence of high temperatures. As biological activity is directly influenced by temperature, the non-critical use of these standards in warm climate countries can theoretically lead to oversized plants. Aiming the adjustment/adaptation of the trickling filter technology for the international market in warm climate countries, a semi-scale trickling filter was operated and investigated in a climate chamber under high temperatures on the premises of the wastewater treatment plant of the Universität Stuttgart. Air temperature was kept at 30°C with help of an air conditioning system. Water Financing institution: DWA Landesverband Baden-Württemberg Duration: 03/2006 – 01/2007 Contact: Dr.-Ing. Gebhard Stotz Internet: http:// www.iswa.uni-stuttgart.de/awt/en/research. html Trickling filter Climate chamber 51 Chair of Sanitary Engineering and Water Recycling temperature was adjusted to 25 °C by means of heat exchangers. To make a comparison of packing media possible, the trickling filter was vertically filled with two packing materials: lava slag and plastic packing medium (cross-flow). The volumetric organic loading was gradually increased up to approximately 1.2 kg BOD5/(m3•d). In order to estimate enhancement of performance due to high temperatures, performance curves for different volumetric organic loadings were obtained and compared with curves from literature. The results indicate correlation between enhancement of performance and volumetric organic loading. For small volumetric organic loadings enhancement of performance was not observed. On the other hand, for high volumetric or- ganic loadings performance is remarkably increased. The operation of a high-loaded trickling filter for sole carbon removal with high temperatures leads to a volume saving of approximately 60%. Financing institution: German Ferderal Ministry of Education and Research (BMBF) Duration: 02/2005 – 01/2007 Contact: Fabio Pressinotti, M.Sc. Internet: www.iswa.uni-stuttgart.de/awt/en/research_current.html#weidelener2 BOD5 removal rates of the semi-scale TF (25 °C) and of TFs in Germany (temperate temperatures (Imhoff, 1979)) 52 Wastewater Technology AWT Biological hydrogen production from organic substrates in the biological wastewater treatment ly converted to methane in the methanogenic phase. This hydrogen can be utilised with the help of fuel cells for an almost emission-free energy production. Worldwide, the energy demand is still predominantly supplied from fossil fuels. Increasing energy consumption and limited natural resources require the development of alternative methods for energy production. Fuel cells that use hydrogen as fuel present a promising alternative for energy production. Reforming of hydrogen-rich hydrocarbons, e.g. natural gas, for hydrogen production is considered to be technically and economically the most suitable process until to date. However, for a sustainable energy production transition to alternative energy resources is required. Several different types of sewage sludge shall be tested for their suitability with regard to hydrogen production. Initially, optimum boundary conditions (such as ph value, partial pressure of hydrogen, nutrient supply, retention time in the reactor, inhibition of methanogenic bacteria) in lab-scale experiments are to be assessed. Aim is the maximisation of gas yield and hydrogen content. Within the scope of the current project the possibility of hydrogen production from organic substrates in the biological wastewater treatment is investigated. During anaerobic sludge digestion, hydrogen is produced as an intermediate product, which is subsequent- Preliminary results of lab-scale batch experiments with sucrose as substrate for hydrogen yield optimisation demonstrate that the optimum pH lies between pH = 6 and pH = 6,5. Substrate concentration exhibits also an optimum range. In this case, hydrogen yield is higher when the pH is continuously adjusted than when it is just set to an initial value. Investigation of the optimum pH for hydrogen production (in respect to sucrose consumption) 53 Chair of Sanitary Engineering and Water Recycling In the remaining time the following aspects are to be investigated: • Suitability of different types of sewage sludge for biological hydrogen production. The possibility of co-fermentation of biological waste will be investigated as well. • Enrichment in hydrogen with the help of a selective membrane. • Testing of a two-stage continuous process for sludge stabilisation and complete utilisation of the sludge’s energy content. Accordingly, hydrogen and methane will be produced during the first and second stage respectively. Financing institution: Ministry of Environment, Baden-Württemberg Duration: 03/2007 - 03/2009 Contact: Iosif Mariakakis, M.Sc. Dr.-Ing. Jörg Krampe Internet: www.iswa.uni-stuttgart.de/awt/en/research_current.html#hydrogen • Evaluation of the process energetically Investigation of the optimum substrate concentration for hydrogen production (sucrose as substrate) 54 Wastewater Technology AWT MODULAARE: Integrated Modules for Efficient Wastewater Treatment, Solid Waste Disposal and Regenerative Energy Recovery in Tourist Resorts Tourism is a rapidly growing sector and sustainability in tourism requires an environmentally conscious management. Particularly in arid provinces, large amounts of water required for the irrigation may constitute a problem. Preferred regions often include naturally vulnerable areas in which hotels or holiday villages are located far from central infrastructure, such as wastewater treatment plants and landfills. The transport of wastes to central systems is a costly process. On one hand’s side, large amounts of wastewater and solid waste are produced due to increased needs on holiday, on the other side wastewater, even though polluted, constitutes an important water resource and can be reused if properly treated. In this context, an innovative, decentralised and modular concept for wastewater treatment, solid waste disposal and energy production was developed. The concept was applied within the framework of a research project (MODULAARE) and conducted by a consortium including University of Stuttgart. The emphasis of the project was placed on the practical and the economical feasibility of the concept. Thus for the implementation of the project a Turkish tourist resort connected to a municipal waste water treatment plant has been selected as pilot hotel. A pilot plant combining wastewater treatment and solid waste processing were installed and operated. A simple laboratory was established in the hotel grounds. The modular pilot plant combined a membrane bioreactor for wastewater recycling with a digester unit for energy recovery out of organic waste from the kitchen and green areas as well as the excess sludge of the membrane bioreactor. The wastewater module was constructed in a cargo container in Germany and then transported to the hotel at the beginning of the summer season 2005. The process was based on a low loaded membrane bioreactor consisting of several steps to remove nitrogen and carbonaceous substances and ending with membrane filtration. Wastewater produced in the hotel is collected in a central shaft and only a small part of it is brought to the plant (7 m³/d - 10 m³/d). After being stored in a mass balancing tank, wastewater was pumped into a primary sedimentation unit. This was followed by separate anoxic and aerobic zones, interconnected by a recirculation line. Treated wastewater was then permeated through submerged ultrafiltration membranes placed in the aerobic tank and stored in a separate chamber connected to the irrigation pond. Separate analyses of different wastewater streams 55 Chair of Sanitary Engineering and Water Recycling The membrane bioreactor was operated during 3 summer seasons from 2005 to 2007 in the large tourist. Treatment efficiency was monitored through chemical and microbiological analyses. Data related to water use was collected. Specific user values were calculated. Wastewater was analysed in different production points. Acceptance of guests about environmental applications on holiday was investigated. According to the results, the water consumption in Iberotel remained in average range compared to other given literature. Kitchen and laundry together constituted the largest potable water use station after the garden. A considerably higher water use per guest was observed in low occupancy. Regarding the water use points in the hotel, the most concentrated pollution loads originated from the kitchen, laundry and the rooms. Figure below presents the pollution loads in wastewater from the kitchen, laundry and rooms comparatively. The wastewater of Iberotel in general represented a very concentrated wastewater, differing from common domestic wastewater also with its extremely high solid matter content. Therefore an extra sieve had to be constructed after the first operation season. An efficient wastewater treatment was achieved in membrane bioreactor. COD removal rates were mostly above 98 % where nitrogen removal varied in a wider range between 90 % and 98 %. Besides operational parameters, the heavy metal content was investigated in some permeate samples. All of the measured values remained far below the critical threshold levels of FAO (1992). During microbiological investigations t. coli and e. coli were analysed in 20 permeate samples. All of the measured values remained far below the limit values of EU-directive for bathing and recreational purposes (76/160/EEC), most were smaller than the recommended values. Also according to the WHO guidelines for the use of treated wastewater in agriculture the treated wastewater from the wastewater module was within the acceptable range. Both chemical and microbiological analyses proved the treated wastewater to be “safe to use” for recreational purposes. The acceptance study presented surprisingly positive results. A significant majority of the participants gave opinions in favour of decentralised processes in holiday resorts and wastewater reuse. This modular and decentralised system is expected to be suitable for applications in sensitive regions such as tourism regions, coral reefs, islands, coasts, natural parks etc. as well as remote settlements which experience difficulties to get connected to the central systems. Such applications can also help minimising the environmental pollution in naturally valuable regions that do not have the required infrastructure. Due to the modular concept, an adaptation to various places and climatic zones seems to be easily realisable. The practical phase of the project has been completed in October 2007. Data evaluation is being conducted. The results will show whether such decentralised plants can be operated optimally in terms of both economical issues and quality of secondary products. Financing institution: German Ferderal Ministry of Education and Research (BMBF) Project partner: • AT-Verband (Verband zur Förderung angepasster, sozial- und umweltverträglicher Technologien e.V.) • Universität Stuttgart, Institut für Siedlungswasserbau, Wassergüte- und Abfallwirtschaft, Abteilung Siedlungsabfall • Memos Membranes Modules Systems GmbH • Bio-Sytem Selecta GmbH • Iberotel Sarigerme Park, TUI AG - Umweltmanagement Duration: 10/2003 – 03/2007 Contact: Demet Antakyalı, M.Sc. Dr.-Ing. Jörg Krampe Internet: www.iswa.uni-stuttgart.de/awt/en/research_current.html#modulaare 56 Wastewater Technology AWT Independent Studies, Master- and Diploma Thesis Untersuchung und vergleichende Bewertung der Leistungsfähigkeit von radikalisch initiierten oxidativen Verfahren zum Abbau persistenter organischer Wasserschadstoffe aus Konzentraten der Nanofiltration Einsatz von Ultrafiltrationsmembranen zur Aufbereitung von Druckgussabwässern Sebastian Tews (Umweltschutztechnik) (2007) Supervisor: Dr.-Ing. Jörg Krampe, Prof. Dr.-Ing. Heidrun Steinmetz Katrin Frey (Umweltschutztechnik) (2006) Supervisor: Dr.-Ing. Jörg Krampe, Prof. Dr.-Ing. Kh. Krauth Clogging and Fouling of Membrane Diffuses in Activated Sludge Processes Weiterentwicklung eines Verfahrens zur Phosphorrückgewinnung aus Klärschlämmen mit hohem Anteil an Aluminiumphospaten Seth Agbottah (WASTE) (2006) Supervisor: Dr.-Ing. Jörg Krampe, Prof. Dr.-Ing. Ulrich Rott Mara Steinhilber (Hochschule Reutlingen) (2006) Supervisor: Dipl.-Ing. Alexander Weidelener, Prof. Dr. Siegfried Blösl, Hochschule Reutlingen Application of Membrane Bioreactors in the Paper Industry Untersuchungen zum Verblockungsverhalten verschiedener Druckbelüftungssysteme Jenny Maria Rojas (WASTE) (2007) Supervisor: Dr.-Ing. Jörg Krampe, Dr.-Ing. Gebhard Stotz Lara Cifre Magraner (Uni Barcelona) (2006) Supervisor: Dr.-Ing. Jörg Krampe, Prof. Dr.-Ing. Ulrich Rott A Lab-Scale Investigation for the Effects of a Power Failure on Biological Wastewater Treatment Processes Entwicklung und Probebetrieb einer halbtechnischen Versuchsanlage für die Festo Didactic GmbH & Co. KG Ghulam Mursid (WASTE) (2007) Supervisor: Dipl.-Ing. Klaus Keicher, Prof. Dr.-Ing. Ulrich Rott Shanfeng Sun (Bauingeniuerwesen) (2006) Supervisor: Dipl.-Ing. Alexander Weidelener, Prof. Dr.-Ing. Ulrich Rott Modeling of a Trickling Filter with Focus on Biofilm Processes Betriebsoptimierung einer rotierenden Ultrafiltrationsmembran zur Biomassenabtrennung Iosif Mariakakis (WASTE) (2007) Supervisor: Fabio Chui Pressinotti, M.Sc., Dr.-Ing. Jörg Krampe, Prof. Dr.-Ing. Heidrun Steinmetz Kai Wu (Umweltschutztechnik) (2006) Supervisor: Dr.-Ing. Jörg Krampe, Prof. Dr.-Ing. Ulrich Rott Corrosion of Pipes in Water Supply and Waste Water Disposal Systems Betriebsprobleme mit feinblasigen Druckbelüftungssystemen auf kommunalen Kläranlagen in Baden-Württemberg Odusami Adedapo (WAREM) (2007) Supervisor: Dr.-Ing. Gebhard Stotz, Prof. Dr.-Ing. Heidrun Steinmetz Sabine Kaebert (Umweltschutztechnik) (2006) Supervisor: Dr.-Ing. Jörg Krampe, Prof. Dr.-Ing. Ulrich Rott Assessment of Wastewater and its Impact on Environment in Kathmandu Valley, Nepal, Prabin K.C.(MIP) (2007) Supervisor: Dr.-Ing. Gebhard Stotz, Prof. Dr. Giselher Kaule, ILPÖ 57 Chair of Sanitary Engineering and Water Recycling Möglichkeiten zur Ertüchtigung der Abwasserentsorung im ländlichen Raum – Modellvorhaben in 2 chinesischen Dörfern der Stadt Hangzhou Yalin Fan (Umweltschutztechnik) (2007) Supervisor: Dr.-Ing. Gebhard Stotz, Prof. Dr.-Ing. Heidrun Steinmetz Recovery of Phosphorous as MAP (Struvite) from Digested Sewage Sludge by Using Metal Separation with a Nafion Ion Exchange Membrane Kenan Güney (WAREM) (2007) Supervisor: Dipl.-Ing. Alexander Weidelener, Prof. Dr.-Ing. Heidrun Steinmetz The Influence of Particle Settling Velocity on Sizing Stormwater Sedimentation Tanks Economical and Procedural Comparison of Different Combined Heat and Power Units (CHP) fort he Use on Wastewater Treatment Plants Omodara Olakunle (WAREM) (2006) Supervisor: Dr. Gebhard Stotz, Prof. Dr. Silke Wieprecht Maria M. Medellín Govea (WAREM) (2007) Supervisor: Dipl.-Ing. Klaus Keicher, Prof. Dr.-Ing. Heidrun Steinmetz Sustainable Urban Drainage System; Assessment of a Combined Filtration and Below Ground Stormwater Detention and Utilisation System A Case Study; Water Balance in Iberotel Sarigerme Park, Turkey and Evaluation of Wastewater reuse Opportunities Using MEMOS Membrane Bioreactor Dipl. Biol. Birgit Fabritius (WAREM) (2007) Supervisor: Dr. Miklas Scholz (University of Edinburgh), Prof. Dr.-Ing. Heidrun Steinmetz Variantenbetrachtung mit Hilfe der dynamischen Simulation am Beispiel der Kläranlage Hirsau Christian Locher (Umweltschutztechnik) (2007) Supervisor: Prof. Dr.-Ing. Heidrun Steinmetz 58 A. Baran Özcan (WAREM) (2007) Supervisor: Demet Antakyali, Prof. Dr.-Ing. Heidrun Steinmetz Potential and restrictions for sustainable sanitation concepts Imelda Leiwakabessy (WASTE) (2007) Supervisor: Prof. Dr.-Ing. Heidrun Steinmetz Wastewater Technology AWT Contact Dr.-Ing. Jörg Krampe (Akad. Oberrat) Laboratory Tel.: ++49 (0) 711 / 685 - 65420 Fax: ++49 (0) 711 / 685 - 67637 E-Mail: [email protected] Chief: Siegfried Schmitz E-Mail: [email protected] Research Assistants Dr.-Ing. Gebhard Stotz Chemical technical employee Tel.: ++49 (0) 711 / 685 - 65439 Fax: ++49 (0) 711 / 685 - 63729 E-Mail: [email protected] Harald Duvinage Bärbel Huber Harald Müller Dipl.-Ing. Juliane Gasse Tel.: 0711 / 685 - 65410 Fax: 0711 / 685 - 63729 E-Mail: [email protected] Dipl.-Ing. Alexander Weidelener Tel.: ++49 (0) 711 / 685 - 63740 Fax: ++49 (0) 711 / 685 - 63729 E-Mail: [email protected] Demet Antakyalı, M.Sc. Tel.: ++49 (0) 711 / 685 - 63895 Fax: ++49 (0) 711 / 685 - 63729 E-Mail: [email protected] Fabio Chui Pressinotti, M.Sc. Tel.: ++49 (0) 711 / 685 - 65445 Fax: ++49 (0) 711 / 685 - 63729 E-Mail: [email protected] Dipl.-Ing. Christian Locher Tel.: ++49 (0) 711 / 685 - 65422 Fax: ++49 (0) 711 / 685 - 63729 E-Mail: [email protected] Iosif Mariakakis, M.Sc. Tel.: ++49 (0) 711 / 685 - 65405 Fax: ++49 (0) 711 / 685 - 63729 E-Mail: [email protected] 59 60 Chair of Waste Management and Emissions o. Prof. Dr. -Ing. Martin Kranert Solid Waste Management Dr. -Ing. K. Fischer SIA Hazardous Waste and Contaminated Sites SOA Prof. Dr. -Ing. E. Thomanetz Measuring in Air Pollution Control TAL Dr. -Ing. M. Reiser Biological Air Purification ALR Prof. Dr. rer. nat. K.-H. Engesser 61 Institute for Sanitary Engineering, Water Quality and Solid Waste Management Chair of Waste Management and Emissions The aim of research and education at the Chair of Waste Management and Emissions is to assure resource conservation and climate protection in a sustainable manner. Within this context, material flows that become waste as result of the use of resources, their treatment processes, along with the emissions from waste treatment plants, are considered. The topic of biological waste air purification is dealt in a special department within the chair. Considering that sustainable waste management gives priority to actions that counteract the generation of waste, fundamental waste management processes, which serve as cornerstones for sustainable resource management, span from the generation of waste and its avoidance, over the recovery of materials and energy from waste, up to the environmentally sound disposal of wastes and the control of the associated emissions. Education and research encompass a holistic approach to waste management, from waste avoidance, to the valorisation of wastes, up to the environmentally sound disposal of residual waste. Beside the lectures offered for Civil Engineering students, courses are specially tailored for the German taught Environmental Engineering program, and the international Master of Science program „Air Quality Control, Solid Waste and Waste Water Process Engineering – WASTE”. Research is focused on the following fields: • Modelling, simulation and evaluation of waste management systems and concepts taking into consideration resource conservation and climate protection. • Biotechnological waste treatment processes (composting, anaerobic digestion), concentrating specially on process modelling and simulation of anaerobic systems, and regenerative energy recovery from organic waste and renewable resources. • Examination and evaluation of decentralized disposal systems for the joint treatment of solid waste and wastewater, as well as energy recovery (zero waste and wastewater processes e.g. tourist areas, islands). • Infrastructure development for future megacities, particularly in developing and emerging economies. Scientific accompaniment of the implementation of sustainable material management systems and waste treatment technologies. • Analysis of wastes and emissions, including contactless measurement of methane emissions from surfaces. 62 The Chair of Waste Management and Emissions is a member of several competence networks e.g. Competence Centre Environmental Engineering (Kompetenzzentrum für Umweltschutz Region Stuttgart (KURS e.V.)) and several standardization committees and scientific advisory boards, and a result has established numerous contacts and cooperation agreements with several research institutions, public waste management authorities and private enterprises. Cooperation with foreign universities and research institutions have been established through international research projects. Activities in Education The Chair’s staff, including lecturers, researchers and external readers, holds lectures covering several study courses, and supervises students from different academic programmes: German taught Diploma “Civil Engineering” and “Environmental Engineering”: • Core course “Sanitary Engineering (and Waste Disposal)”, Subarea: Solid Waste Management • Specialization field “Solid Waste Management” (including 13 spezialized lectures, laboratory work, seminars) International Master Programme „Infrastructure Planning“: • Solid waste Management • Ecology III International Master Programme „WAREM“: • Waste Disposal International Master Programme „WASTE“ (Established in 2002): • • • • • • Solid Waste Management Biological Waste Treatment Landfill Waste (Practical Work) Hazardous Waste and Contaminated Sites Waste Management in Low and Middle Income Countries • Design of Solid Waste Treatment Plants • Chemistry of Solid Waste • Emissions from Solid Waste Treatment Plants Seminars, laboratory work, design exercises, and excursions supplement the lectures. Chair of Waste Management and Emissions In order to comply with the new Bachelor / Master scheme, all study programmes have been restructured and modularized, and these changes will be introduced from the winter semester 2008/09 onwards. waste management within the scope of the distance education programme “Water and Environment” offered by the Bauhaus-Universität Weimar. Finally, in collaboration with the Turkish Environmental Ministry, the tradition of the German-Turkish Conferences has been revived. International Cooperation agreements in research and education have established with the Institute of Environmental Engineering and Biotechnology at the Tampere University of Technology (Finland) as well as the Dokuz Eylül University at Izmir (Turkey), the University of Salerno (Italy), the University of Thessaloniki (Greece) and the Technical University of Temesvar (Romania). Furthermore, several staff members of the Chair are active as associated lecturers at other institutions worldwide. Conferences Beyond research and academic activities, the Chair is involved in the continuing education and advanced training of professionals. Conferences organized by the Chair include the “Baden-Wuerttembergischen Waste Days”, hosted together with the Environmental Ministry of the federal state of Baden-Wuerrtemberg; the waste management colloquia; the landfill seminars, in association with the Environmental Protection Agency of the federal state of Baden-Wuerrtemberg; continuing education courses in cooperation with the Society of Engineers for Water Management, Waste Management and Agricultural Infrastructure (Bund der Ingenieure für Wasserwirtschaft, Abfallwirtschaft und Kulturbau (BWK)); as well as lectures in the field of Committees Beside their academic activities, staff members are also involved in several committees, including academic councils, professional associations and advisory boards. These include the German Institute of Stadardization (DIN), the Association of German Engineers (VDI e.V.), the Society of Engineers for Water Management, Waste Management and Agricultural Infrastructure (Bund der Ingenieure für Wasserwirtschaft, Abfallwirtschaft und Kulturbau (BWK)), Working Group for the Valorization of Municipal Solid Waste (Arbeitskreis zur Nutzbarmachung von Siedlungsabfällen (ANS e.V.)), German Association for Water, Wastewater and Waste (DWA e.V.), Association for Quality Control of Compost derived from Sewage Sludge (Vereinigung zur Gütesicherung von Abwasserschlammkomposten (VGVA e.V.)), the ORBIT Association, the European Compost Network (ECN), and the Federal Compost Quality Association (Bundesgütegemeinschaft Kompost (BGK)). Additionally, the chairholder serves as referee for several research funding institutions, scholarship foundations and accreditation agencies. Furthermore, several staff members play a leading role in the Competence Centre “Environmental Engineering” (Kompetenzzentrum für Umweltschutz Region Stuttgart (KURS e.V.)). Dissertations Agricultural Waste Products as Filter Media an as Cover Materials in Biofilters for Mediterranean Countries, 2006 Doctoral candidate: Emine Bolcu Özcan Principal examiner: Prof. Dr.-Ing. Martin Kranert Secondary examiner: Prof. Dr. rer.nat. Johannes Jager Secondary examiner: Prof. Dr.-Ing. Oktay Tabasaran Title: Agricultural Waste Products as Filter Media and as Cover Materials in Biofilters for Mediterranean Countries, 2006 Forschungs- und Entwicklungssinstitut für Industrie- und Siedlungswasserwirtschaft sowie Abfallwirtschaft e.V. Stuttgart (FEI). München: Oldenbourg Industrieverlag GmbH, 2005. (Stuttgarter Berichte zur Abfallwirtschaft; Bd.88) 242 S., 66 Abb., 47 Tab., ISBN 3-8356-3113-6 63 Institute for Sanitary Engineering, Water Quality and Solid Waste Management Co-Supervision of Dissertations and Habilitations Aussagefähigkeiten von Ökobilanzen - Sensitivitätsanalyse der Wirkungsabschätzung im Rahmen der ökologischen Bewertung an Beispielen der Klärschlammentsorgung in Nordrhein-Westfalen. Jochen Schubert Supervisor: Prof. Dr.-Ing. Renatus Widmann, Universität Duisburg-Essen (2006) Dissertation Regelungsverfahren für die anaerobe Behandlung von organischen Abfällen. Jan Liebetrau Supervisor: Prof. Dr.-Ing. habil. Werner Bidlingmaier, Bauhaus Universität Weimar (2006) Dissertation Development and application of a method to calculate optimal recycling rates with the help of cost-benefit scenarios Markus Hiebel Supervisor: Prof. Dr.-Ing. Renatus Widmann, Universität Duisburg-Essen (2007) Dissertation Methanisierung stapelbarer Biomasse in diskontinuierlich betriebenen Feststofffermentationsanlagen Sigrid Kusch Supervisor: Prof. Dr. Thomas Jungbluth, Universität Hohenheim Dissertation 64 Sickerkreislauf zur Behandlung von Sickerwässern der aerob-biologischen Restabfallbehandlung Peter Degener Supervisor: Prof. Dr.-Ing. Peter Spillmann, Universität Rostock (2007) Dissertation Solare Konvektionstrocknung wasserreicher organischer Reststoffe am Beispiel von Klärschlamm Dr. sc. agr. Markus Bux Supervisor: Prof. Dr. J. Müller, Universität Hohenheim (2006) Habilitation Neue Ansätze zur Beschreibung biologischer Systeme in Abwasser- und Abfallbehandlungsanlagen: Methoden und Anwendung Dr. rer.nat. Martin Denecke Supervisor: Prof. Dr.-Ing. Renatus Widmann, Universität Duisburg-Essen (2006) Habilitation Chair of Waste Management and Emissions Publications Bidlingmaier, W., Fricke, K., Kranert, M. (Hrsg.) (2007): Getrennte Erfassung von Bioabfall und Wertstoffen. CD. ORBIT e.V. Weimar 2007. Kranert, M., Clauß, D. (2006): Abfallmanagement. In: Bullinger (Hrsg.): Technologieführer, S. 518-521, Springer Berlin, Heidelberg, New York 2006. Cimatoribus C. (2006): Capitolo 7. Scelta dello schema di controllo: il processo Tennesse-Eastman. In: Trotta A., Sistemi di controllo nei processi chimici, Ed. Progetto, Padova, 2006. Kranert, M., Clauß, D. (2006): Abfallströme seit Juni 2005 - Übersicht und Entwicklungen, 76. Darmstädter Seminar Abfalltechnik an der TU Darmstadt, veröffentlicht im Tagungsband Schriftenreihe WAR Nr. 173, , S. 13-22, Darmstadt 2006. Cimatoribus, C., Kranert, M. (2006): Parameter estimation for ADM 1: Application to a full scale plant for sewage sludge treatment ORBIT Kongress 2006, 13. - 15. September 2006, Weimar, in: Kraft et al (Hrsg.) Proceedings of ORBIT, , S. 809 – 814, Weimar 2006. Cimatoribus, C., Kranert, M. (2007): A parameter estimation protocol for anaerobic digestion. Fortschritt beim Biogas - Progress in Biogas, September 19-21, 2007, Hohenheim, Germany, Proceedings S. 141-146, 2007. Doedens, H., Kranert, M. et al. (2007): Status der MBA in Deutschland, Müll und Abfall, 12/2007, S. 576-579, 2007. Esacalante, N., Kranert, M., Hafner, G. (2007): Environmental evaluation of household waste management systems in Southern Germany. Sardinia 2007, 11. International Waste Management and Landfill Symposium, Cagliari, 1.-5.10.2007. In: Cossu et al (Hrsg.), Proceedings and executive summaries, CISA, S. 739740 und 12 S. (CD), 2007. Faiella M., Cimatoribus C. (2007): Trockenfermentation in Boxenfermentern. Substratmischung und Gasausbeute. Wasser und Abfall 9: S.30-33, 2007. Fischer, K. (2006): Sustainable Solid waste Management, Int. Tagung 4 Motoren Europas zur Nachhaltigen Entwicklung, Skhirat, Marokko, 16.-17.01.2006. Hafner, G., Kranert, M. et al. (2007): MODULAARE, integrated modules for high efficient waste water purification, waste treatment and regenerative energy recovery in tourism resorts. Sardinia 2007, 11. International Waste Management and Landfill Symposium, Cagliari, 1.-5.10.2007. In: Cossu et al (Hrsg.), Proceedings and executive summaries, CISA, S. 875-876 und 11 S. (CD), 2007. Kranert, M., Fischer, K., Hafner, G., Esacalante, N. (2006): Neue Ansätze zur Umgestaltung der Hausmüllentsorgung. In: Hrgs.: Universität Stuttgart Wechselwirkungen, Jahrbuch aus Lehre und Forschung, Stuttgart 2006 S. 22-35, 2006. Kranert, M. et al (2006): „Abfallentsorgung mit geringeren Lasten für Haushalte, weitgehender Abfallverwertung und dauerhaft umwltverträglicher Abfallbeseitigung - Konzepte zur langfristigen Umgestaltung der heutigen Hausmüllentsorgung“, Forschungsbericht, Umweltministerium Baden-Württemberg, Reihe Abfall Band 78, Stuttgart 2006. Kranert, M., Fischer, K., Esacalante, N. (2006): Ökologische Bewertung der Sammelsysteme für Haushaltsabfälle. 6. Sächsischer Kreislaufwirtschaftstag des Sächsischen Staatsministeriums für Umwelt und Landwirtschaft, Freiberg 6. April 2006, veröffentlicht in den Tagungsunterlagen, Freiberg 2006. Kranert, M. (2006): Technologies for aerobic and anaerobic management of organic and residual waste 1. Baltische Bioabfallkonferenz des ECN, Tallin, 23.24.05.2006, Tallin (Estonia) Tagungsunterlagen ECN Weimar 2006. Kranert, M. (2006): Strategies for the reduction of environmental impacts of organic waste treatment plants, 1. Baltische Bioabfallkonferenz des ECN, 23.24.05.2006, Tallin (Estonia). Veröffentlicht in den Tagungsunterlagen, ECN Weimar 2006. Kranert, M., Hafner, G., Esacalante, N. (2006): New Strategies and evaluation of waste management systems - the example of Baden-Wuerttemberg, ECOBALTICA 2006 St. Petersburg 21.-23. Juni 2006, veröffentlicht in den Tagungsunterlagen, St. Petersburg 2006. Kranert, M. (2006): Ways towards sustainable waste management systems. 2nd International Waste Management and Recycling Fair and Conference, Recycling-Istanbul-Konferenz, 22. - 25. Juni 2006, veröffentlicht in den Tagungsunterlagen, Istanbul 2006 Kranert, M., Fischer, K., Hafner, G., Esacalante, N. (2006): Zukunft der getrennten Erfassung von Abfällen. 67. Landesgruppen- und Fachtagung des VKS im VKU, 20.-21.07.06 Heidelberg, veröffentlicht im Tagungsband, V9 S. 1-S.19, Heidelberg 2006 Kranert, M., Kusch, S., Oechsner, H., Jungbluth, T. 65 Institute for Sanitary Engineering, Water Quality and Solid Waste Management (2006): Aufkonzentrierung des Prozesswassers bei der Feststoffvergärung in Boxenfermentern. Korrespondenz Abwasser, Heft 8, S. 804-811, 2006. Kranert, M., BERKNER (2006): Compost from Sewage - Status and results of quality assurance in Germany ORBIT 2006, International Conference, Weimar 12.-15. September 2006, veröffentlicht in: Kraft et.al (Hrsg.): Proceedings ORBIT 2006, Verlag ORBIT e.V, S. 571-578., Weimar 2006 Kranert, M., Hafner, G., Esacalante, N. (2006): Role and evalation of biological waste treatment in the frame of new waste management strategies ORBIT 2006, International Conference, Proceedings, ORBIT-Verlag, Weimar (2006), Seite 2047-1056 (reviewed article) Kranert, M., Fischer, K., Hafner, G., Esacalante, N. (2006): Neue konzeptionelle Ansätze zur Hausabfallentsorgung. Wasser und Abfall 10-2006, S. 20 – 25; 2006. Kranert, M., Hafner, G., Schultheis, A., Steinbach, D., Krampe, J., Antakyali, D., (2006): Projekt Modulaare - integrierte Module zur hocheffizienten Abwasserreinigung, Abfallbehandlung und regenerativen Energiegewinnung in Tourismusressorts. Vortrag auf: 1. Aachener Kongress Dezentrale Infrastruktur 17. - 18. Oktober 2006, Aachen veröffentlicht in den Tagungsunterlagen, 2006. Kranert, M., Hafner, G., Esacalante, N. (2006): Abfallentsorgung mit geringen Lasten für Haushalte. Regionales Abfallforum des EVS, Otzenhausen (November 2006) veröffentlicht in den Tagungsunterlagen, Saarbrücken 2006. Kranert, M., Fischer, K., Hafner, G., Esacalante, N. (2006): Neue strategische Ansätze zur Hausabfallentsorgung - Situation und Bewertung - Depotech 2006, Montanuniversität Leoben (A), 22.-24. November 2006, In: Lorber et al. (Hrsg.) Abfall und Deponietechnik, Abfallwirtschaft, Altlasten, VGE-Verlag Essen S. 137 – 144, 2006. Kranert, M., Steinbach, D., Schultheis, A., Krampe, J., Antakyali, D., Hafner, G. (2006): Integrierte Module zur hocheffizienten Abwasserreinigung, Abfallbehandlung und regenerativen Energiegewinnung in Tourismusressorts. Vortrag auf der Türkisch-deutschen Abfalltagung 2006 - Biologische Abfallbehandlung, Izmir (TR), 14. - 16. Dezember 2006, veröffentlicht im Tagungsband, Hrsg.: Erdin et al. Dokuz Eylül Universitesi, Izmir, S. 147-162, 2006. 66 Kranert, M., Gottschall, R. et al. (2007): Vergleich der energetischen Verwertung und Kompostierung mit stofflicher Verwertung von Grünabfällen unter den Aspekten des Primärressouceneinsatzes und der CO2-Bilanz.- In: Flamme et al (Hrsg.): Münsteraner Schriften zur Abfallwirtschaft, 10. Münsteraner Abfallwirtschaftstage , 5.-7. Februar 2007, Münster, S. 162 – 168, 2007. Kranert, M., Hafner, G., Gottschall, R., Bruns, C. (2007): Greenwaste treatment options; impacts on soil and climate change. International conference sustainable use of biomass, Dublin (Ireland), 19.-21. February 2007, veröffentlicht in den Tagungsunterlagen ECN Weimar 2007. Kranert, M. (2007): Composting-status, trend and marketing. FICCI Environment Conclave 2007, 20.21. Februar/New Delhi, India. Veröffentlicht in den Tagungsunterlagen, 12 Seiten, New Delhi: 2007 Kranert, M., Hafner, G., Steinbach, D., Schultheis, A., Krampe, J., Antakyali, D. (2007): Modulaare - Integrated modules for high efficient wastewater purification, waste treatment and regenorative energy recovery in tourism ressorts. GeTUnivation German-Turkish University Conference der HRK Yök BMBF, Braunschweig 26.-28.02.2007. Veröffentlicht in den Tagungsunterlagen. Braunschweig 2007. Kranert, M., Clauß, D. (2007): Entwicklung der Gewerbeabfallströme und Kapazitäten 40. Essener Tagung für Wasser- und Abfallwirtschaft, 14.-16. März 2007 in Aachen, In: Pinnekamp (Hrsg.): Gewässerschutz, Wasser, Abwasser Band 207, S. 50/1 - 50/6, Aachen 2007. Kranert, M., Berkner, I., Erdin, E. (2007): Compost from sewage sludge - a product with quality assurance system. IWA-Conference Facing Sludge Diversities 28.-30. March 2007. Antalya. In: Filibeli et al. Facing Sludge diversities. Proceedings Antalya (Turkey) S. 681-688, 2007. Kranert, M., Hafner, G., Gottschall, R., Bruns, C. (2007): Comparison of the energy recovery and usage of compost from green waste under aspects of primary ressources, 2nd BOKU Waste Conference, Vienna 16.19. April 2007. Veröffentlicht im Tagungsband Wien 2007. Kranert, M. (2007): Ziele 2020 - Abfallwirtschaft im Umbruch. Deutsch-Französisches Statusseminar EULife-Projekt OPTIGEDE. 29.06.2007 in Böblingen, veröffentlicht in den Tagungsunterlagen (12 Seiten), 2007 Chair of Waste Management and Emissions Kranert, M., Fischer, K. (2007): Export von Know-how im Bereich Umwelttechnik nach Lateinamerika, Asien und Afrika. In: Stuttgart Wissenschaften - Lösungen für die „Eine Welt“ Tagung am 03.07.2007, StuttgartHohenheim, veröffentlicht im Tagungsband, 2007. Kranert, M. (2007): Assessment of new strategic approaches for the treatment of household waste. Deutsch-Brasilianisches Symposium „Nachhaltige Entwicklung“, Freiburg 22.-27.07.2007. In: Hildebrand et al, Tagungsband - Book of Abstracts, Brasilien-Zentrum Tübingen, S. 66, 2007. Kranert, M., Hafner, G. (2007): Möglichkeiten der Ausschleusung von Ersatzbrennstoffen aus Restabfällen. Berliner Abfallwirtschafts- und Energiekonferenz 24.25.09.2007, Berlin. In: Thomé-Kozmiensky (Hrsg.): Energie aus Abfall, TK-Verlag, Berlin S. 115-123, 2007. Kranert, M., Hafner, G., Gottschall, R., Bruns, C. (2007): Comparison of the energy recovery and usage of compost from green waste: What is the effect on primary resources? Sardinia 2007, 11. International Waste Management and Landfill Symposium, Cagliari, 1.-5.10.2007. In: Cossu et al (Hrsg.), Proceedings and executive summaries, CISA, S. 55 und 10 S. (CD),2007. Kranert, M. (2007): Bewertung neuer Konzepte zur Hausabfallentsorgung. In: Bilitweski et al (Hrsg.): Müll-Handbuch, KZ 510, E. Schmidt Verlag, Berlin 10/2007, S. 1-20 Kranert, M. (2007): Strategische Ansätze zur Abfallwirtschaft in Deutschland. Deutsch-Französisches Kolloquium, OPTIGEDE, 25.-26.10.2007, Compiegne (F). Veröffentlicht im Tagungsband, 10 Seiten, 2007. Kranert, M. (2007): Wissenschaftliche Arbeiten im Modulaare-Konzept. Modulaare Workshop 30.-31.10.2007 in Sarigerme Park (TR), veröffentlicht in den Tagungsunterlagen (15 S.), 2007. Kranert, M., Clauß, D. (2007): Collection and Recycling of packaging from households - separate or mixed with other waste? 5th International Packaging Congress, Izmir (TR), 22.-24.11.2007. In: Chamber of Chemical Engineers Ege Branch, Izmir (TR), Proceedings S. 936944, 2007. Kranert, M., Hafner, G. (2007): Beurteilung neuer strategischer Ansätze zur Hausabfallentsorgung unter den Aspekten der Ressourceneffizienz und Klimarelevanz. 68. Informationsgespräche des ANS, 5.-6.12.2007, Bonn In: Fricke, Bergs et al (Hrsg.): Kosten- und Res- sourceneffizienz in der Abfallwirtschaft ORBIT e.V., Weimar, S. 65-74, 2007. Pokryvalio, A., Wald, S., Veldhuizen, E.M.van, Reiser, M., et. al. (2006): High-Power Pulsed Corona for Treatment of Pollutants in Heterogeneous Media. IEEE Transactions on Plasma Science, Vol. 34, No.5, 1731, New York 2006. Reiser, M. (2006): Einsatz von Niedertemperaturplasma-Verfahren zur Abluftreinigung, Vortrag bei „Fachgespräche Gerüche erfassen – bewerten – vermeiden“, HLUG, 10.10.2006, Wiesbaden. (http://www.hlug.de/ medien/abfall/bioabfall/fachgespraeche.htm) Reiser, M., Zarra, T. (2007) Geruchsmessung mit allen Mitteln – wie aufwendig muss die Analytik von Geruchsemissionen sein? VDI-Berichte Nr. 1995, VDI-Verlag, Düsseldorf, S.277 – 280, 2007. Reiser, M. (2007): TDLAS zur Bestimmung von Methan-Emissionen bei Mülldeponien. Vortrag im umwelttechnischen Seminar am PCI, Universität Heidelberg, 2.02.2007. Reiser, M.; Homans, W.J. (2007): Die Problematik von Geruchsmessungen in der Luftreinhaltung. In: Baumbach, G. et. al. (Hrsg.), ALS-Kolloqium (Arbeitsgruppe Luftreinhaltung der Universität Stuttgart), Oktober 2007, S. 63 – 72, 2007. Thomanetz, E.:„Entsorgung von Sonderabfällen nach dem Stand der Technik“. Vortrag und Veröffentlichung auf dem 30. Deutsch-Türkischen Abfallseminar, Konak Izmir, Türkei 25.-27. Mai 2005 Thomanetz, E.:„Modern Aspects of Hazardous Waste Management in Europe“ Vortrag und Veröffentlichung auf der Recycling Istanbul 2005. 01.07.2005 Thomanetz, E.:„Mechanismen der Selbsterhitzung und Selbstentzündung organischer Materialien“ Vortrag und Veröffentlichung auf der Tagung: Ersatzbrennstoffe - Herstellung und Verwertung. 22./23.Nov.2005, TK Verlag Berlin. Thomanetz, E.:„Underground Storage of Hazardous Waste – a Sustainable Pathway on Waste Management“. Vortrag und Veröffentlichung auf dem DAADSymposium: Landfill Technique – Presence and Future, Universität von Sarajewo. 22.-23. Mai 2006. Sammelband der Manuskripte Thomanetz, E.:„Principles and Guidelines of Solid Waste Management in Germany“. Vortrag und Veröffentlichung auf dem DAAD-Symposium: Landfill Technique 67 Institute for Sanitary Engineering, Water Quality and Solid Waste Management – Presence and Future, Universität von Sarajewo. 22.23. Mai 2006 Thomanetz, E.:„Salt Preservation of High-TOC-Waste for Underground Storage“. Im Tagungsband zur 8. Depotech Konferenz, Montanuniversität Leoben/Österreich, 22.-24. Nov. 2006. VGE-Verlag GmbH Essen (2006) Thomanetz, E., Rapf, M. and Karapanagiotis, L.: „TOCbio as a new parameter in the decision making process in waste management“. Vortrag und Veröffentlichung auf dem 31. Deutsch-Türkischen Abfallseminar, Izmir, Türkei 14.-15. Dezember 2006. Sammelband der Manuskripte Thomanetz, E.:„Problems on Sampling for Solid Waste Analysis and Solutions“. Vortrag und Veröffentlichung auf dem 31. Deutsch-Türkischen Abfallseminar, Izmir, Türkei 14.-15. Dezember 2006. Sammelband der Manuskripte Thomanetz, E.:„Modern Hazardous Waste Management for Columbia“, Presentation and Publication, Special Lecture in the Universidad de los Andes, Bogota, 22.November 2007 Steinbach, D., Schultheis, A., Kranert, M., Krampe, J., Antakyali, D., Hafner, G. (2006): Modulaare - an innovative technology for waste and wastewater treatment in decentralized operations as a part of sustainable development in resort hotels and tourism centres ORBIT 2006, International Conference, Weimar 12.-15. September 2006, veröffentlicht in: Kraft et.al (Hrsg.): Proceedings ORBIT 2006, Verlag ORBIT e.V., S. 721728, Weimar 2006. Terrel-Gutierrez, M., Kranert, M., Reiser, M. (2006): Methane Emissions Monitoring in the Environment using a Portable TDLAS. In: Anwendungen und Trends in der Optischen Analysenmesstechnik, 5. Konferenz über Optische Analysenmesstechnik, 26. – 27.09.2006, Mannheim, VDI-Berichte 1959, VDI-Verlag, Düsseldorf 2006. Zarra, T., Naddeo, V., Belgiorno, V., Reiser, M., Kranert, M. (2007) Odour monitoring of small wastewater treatment plant located in sensitive environment, angenommen für 8th IWA Conference on Small Water and Wastewater Systems and 2nd specialized Conference on Decentralized Water and Wastewater International Network in Coimbatore, India, from February 6th - 9th 2008. 68 Chair of Waste Management and Emissions Contact o. Prof. Dr.-Ing. Martin Kranert Tel.: ++49 (0)711/685-65500 oder 65495 Fax: ++49 (0)711/685-65460 E-Mail: [email protected] Secretary´s office Gudrun Heinl Tel.: ++49 (0)711/685-65495 Fax: ++49 (0)711/685-65460 E-Mail: [email protected] Solid Waste Dr.-Ing. Klaus Fischer Tel.: ++49 (0)711/685-65427 Fax: ++49 (0)711/685-65460 E-Mail: [email protected] Hazardous Waste and Contaminated Sites Prof. Dr.-Ing. Erwin Thomanetz Tel: ++49 (0)711/685-63709 Fax:++49 (0)711/685-65460 E-Mail: [email protected] Measuring in Air Pollution Control Dr.-Ing. Martin Reiser Tel.: ++49 (0)711/685-65416 Fax: ++49 (0)711/685-63729 E-Mail: [email protected] Biological Air Purification Prof. Dr. rer. nat. habil. Karl-Heinrich Engesser Tel: ++49 (0)711/685-63734 Fax: ++49 (0)711/685-63785 E-Mail: [email protected] 69 Chair of Waste Management and Emissions Solid Waste Management Research topics: • Waste avoidance • Development of new waste management strategies • Simulation of solid waste management systems • Collection and transport of solid waste • Recycling of valuable materials • Biological treatment: composting and fermentation • New measurement methods for the analysis of odour, dust and germs • Environmental impact assessment of earth burial and cremation • Decentralized waste management systems in tourist regions • Physical and chemical analysis of solid waste In our job, we’re on top of the pile Waste is a potentially valuable material in the wrong place. This statement is the central principle of many activities of our municipal solid waste section. Focal points are avoidance, utilisation and environmentally friendly treatment of municipal and commercial waste. Both ecological and economical aspects are dealt with. It has been shown, e.g., that avoidance of waste in commercial operations can be financially interesting for the companies concerned. We are intensively busy with the question of how waste management of the future may look. Some questions here are: which waste types should continue to be collected separately? Which mixtures of substances can be separated using new technical methods? Can part of the waste be economically transported by rail? Several research projects are occupied with the treatment of biological waste, among others with the questions: do pollutants exist in organic wastes? Are these pollutants reduced during composting? What energy potential is concealed in organic waste, if they are used in fermentation plants to generate biogas or employed in biomass power stations? For the creation of waste management concepts for communities or counties, the simulation and modelling of waste streams and utilisation techniques play a major role. Because even humans can become a waste problem from an ecological point of view, we have carried out investigations on the ecological effects of burials and cremations. For a number of communities, our investigations on decentral concepts for waste treatment in tourist regions are of particular interest. These island solutions allow processes for waste and sewage treatment to be combined with the generation of service water and power. Decentral and adapted technology is of prime importance for the sustainable development of third-world and fast-developing countries. This is why we have established cooperation and joint projects with institutions in Brazil, Costa Rica, Egypt, Turkey, China and other countries. 70 Solid Waste Management SIA Projects Waste disposal with smaller loads The objective of the large-scale study was the development of concepts for long-term optimisation and reformation of present domestic waste disposal. In this connection existing environmental standards were to be maintained on the one hand and waste management was to be simplified especially for households on the other hand. The achievements are based on data concerning the waste management systems in ten selected counties in Baden-Württemberg. The particular actual state as well as typical waste management concepts, which usually exist in the regions of Baden-Württemberg, were implied as different versions in the examination. Further versions, which were inspected, include the alternative collection systems which are presently discussed in professional circles, for example the Yellow-in-Grey-Concepts (German: Gelb-in-Grau–Konzepte GiG) as well as the dry bin for recyclable materials. They are to be considered seeing that today there are technical systems for the separation of materials available on the market which could partly dispense with the separate collection of materials. Furthermore observations were made to find out to what extent complete material recycling is to be aspired or whether energy recovery, e.g. of parts of light packaging, might make sense in economical as well as in ecological respect. In this context versions were investigated which partly aim at energy recovery of light packaging. As an example the use of energy recovery as derived fuel in cement works was inspected. Against the background of the waste management aim for 2020 formulated by the Federal Environment Ministry in 1999, waste is no longer to be deposited aboveground and so, by this time, all municipal waste in Germany is to be utilised completely and sustainably. The intensified quantitative and qualitative avoidance of the amount and the harmfulness of the waste that is to be treated is a significant measure for the achievement of these aims and is especially to be guaranteed by the area of production. In this context the instrument of responsibility for products is to be developed further whereby the closing of cycles of matter and the introduction of new recycling technologies can also be forwarded. To achieve this objective waste recycling has be extended even more. Especially reutilisation and material recycling of the substances mentioned above is to be given the preference. However the enlargement of energy recovery of non-recyclable products is not be enforced. This also involves the advancement of treatment methods in order to attain preferably completely and high-grade recycled waste or substances. In future, waste management measures in Germany will increasingly be coupled with economical criteria, yet maintaining a high standard in environmental compatibility. Seen from a higher level, future waste management will be dominated by two significant trends. One can reckon that resources (materials and energy) will increasingly run short due to the economic revival of developing countries, e.g. District Type C Costs per inhabitant [€/a] 71 Chair of Waste Management and Emissions in Asia. Therefore waste management will become essentially important in the future as a measure for the preservation of resources. Another major aspect is climate change. Waste management can make a contribution here as well by avoiding gases relevant to the climate during processes of treatment and disposal of waste and by simultaneously using the energy within the waste including regenerative shares. In the long run waste management measures will be evaluated in how far they can cover these two aims. Financing institution: Umweltministerium Baden-Württemberg Fachtechnische Begleitung: Landesanstalt für Umwelt, Messungen und Naturschutz Baden-Württemberg (LUBW) Project partner: Lkr. Böblingen, Enzkreis, Hohenlohekreis, Lkr. Lörrach, Lkr. Ludwigsburg, Neckar-Odenwald-Kreis, Ortenaukreis, Schwarzwald-Baar-Kreis, Sigmaringen, Zollernalbkreis Duration: 2004-2006 Contact: Prof. Dr.-Ing. Martin Kranert Dr.-Ing. Klaus Fischer Dipl.-Ing. Gerold Hafner Results of LCA related to MSW Value per inhabitant per tonne MSW 72 Solid Waste Management SIA FORWAST: Project full title: Overall mapping of physical flows and stocks of resources to forecast waste quantities in Europe and identify lifecycle environmental stakes of waste prevention and recycling. Project summary: The FORWAST project intends to provide: • an inventory of the historically cumulated physical stock of materials in EU-27 (EU-25 plus Romania and Bulgaria), and to forecast the expected amounts of waste generated, per resource category, in the next 25 years. • an assessment of the life-cycle wide environmental impacts from different scenarios of waste prevention, recycling and waste treatment in the EU27. The work programme is designed to favour the synergy between these objectives, by applying a generic model for material flows, stocks and emissions. The proposed model is an environmentally extended, physical, quasi-dynamic input-output model. This model combined with a robust method of Material Flow Analysis will guide the mining of new data, which is the main focus of the project. It will take place as a combination of “in-depth” studies in selected countries where high-quality statistics are available, and an EUwide effort consolidating and calibrating different statistical and technical data sources. The model will be applied to historical time series of resource inflows into the economy, and calibrated to known quantities of waste generation, the core question being to estimate coefficients for stocks life time for the different materials (sand/gravel, wood, metals, paper, etc.) and interpret dynamically the causes of the variation of stocks (accumulation versus waste generation or dispersive losses). The policy relevance of the project will be strengthened by the definition of 25 years horizon scenarios of waste generation combined with technological options for waste prevention and recycling. The waste with the higher stakes to reduce environmental pressures will be assessed trough simulations. It is expected that the FORWAST project will bring a new insight into Life Cycle Thinking, and above all, more confidence in the use of environmental indicators in natural resources and waste management policies. Project objective(s): The FORWAST project intends to provide comprehensive and validated data on the material flows, stocks and environmental pressures coming from the different sectors of the life cycle of resources to waste. In the wider context of sustainable development and environment protection, the connections between the use of natural resources, their accumulation in economy and waste generation and management need to be more clearly understood. Waste management policies may affect potentially all sectors. Their influence on the use of natural resources must also account for the potential recovery of these resources from stocks, the technical and economical constraints of recycling, the side effects on the by-products associated with natural resources, and at the end, the global balance of the environmental costs and benefits. The current uncertainties on the environmental stakes of waste policies are pre-dominantly due to a lack of real physical data on the quantities and qualities of flows of resources, either natural or coming from waste recovery. Particularly important for the latter is to account for the actual stocks of these resources that will end-up in the waste flows in the future. The objectives of the proposed FORWAST project are therefore to: • Provide an inventory of the historically cumulated physical stock of materials in EU-27 (EU-25 plus Romania and Bulgaria), and to forecast the expected amounts of waste generated, per resource category, in the next 25 years. • Provide an assessment of the life-cycle wide environmental impacts from different scenarios of waste prevention, recycling and waste treatment in the EU-27. With this STREP proposal, sound experiences on resources and waste management are combined in order to give direct decision and policy support. The partnership experience is mainly characterised by: • European and National experience in policy support; • The access to data from various countries (particularly East and South); • Availability of a successfully applied assessment tool (NAMEA, MFA), along with more insight in processes for various waste streams (AWAST simulator); 73 Chair of Waste Management and Emissions • An extensive network in resources and waste management. The project aims at accounting for all sectors in the economy (the figure below shows a possible conceptual organisation of the system) the flows, stocks and linked environmental pressures to increase the reliability of source data used in “Life Cycle Approaches” to waste management issues. Waste policies influence the „primary production“ due to recycling and prevention, the „manufacturing and consumption“ stages due to recycling, reuse and prevention and the „waste management“ sector. The input/output (I/O) balance of each stage is (dynamically) linked to the others. As an example, the following figure shows the situation of sand and gravels in Austria. The net balance between the consumption and the stock (104-10 Tg/ year) represent the net balance of the primary sector (105-9 Tg/year), which means that the evolution of this stock (age) is of primary importance for a policy aiming at resources saving. The difficulties of establishing that type of figure for resources saving in Europe are at two levels: • Data quality: considering the disparity of I/O country data quality in the EU, it is anticipated to set out a global mapping of materials cycles in three steps: 1) elaboration of a global model for matter balance applicable in all countries, 2) calculation of the so-called “transfer coefficients” with “reliable and complete” country data (four countries), and 3) extension to EU-27 macro-economic data. • Completeness: considering the variety of resources, and eventually associated secondary resources (as in ores), and their mixed occurrence in the products, it will be necessary to combine the “materials flows and stocks setting” approach with a more global Input/output modelling for individual countries and for EU. Further, the objective is to forecast the waste generation in the next 25 years. The need is to establish a relation between stocks quantities and qualities and waste generation, the core question being to estimate stocks life time for the different materials (sand/gravel, wood, metals, paper, etc.), products and waste types, and interpret dynamically the causes of the variation of stocks (accumulation versus waste generation or dispersive losses). As a result, the following support can be given directly to policy and decision makers: Conceptual system description 74 Solid Waste Management SIA • Estimation of the material stock of the EU-27. • Overall mapping of environmental pressures of waste, enabling an understanding of the environmental issues of waste; • As a result of scenarios simulations, links between the stocks and waste generation in terms of quantities and quality/composition in the next 25 years. • The identification of the costs and benefits associated with: • Prevention of the wastes has the highest potential to reduce the environmental pressures on the use of resources; • Recovery or recycling of the waste has the highest potential to reduce the environmental pressures on the use of resources; and • Treatment of the wastes is the most polluting. Additionally, the “leaks” of materials in the system above mentioned as “uncontrolled waste disposal” point out the difficulties in making reliable balances on materials life-cycle. These quantified data anyhow allow the drawing of tracks of interpretation. These will be explored providing the knowledge gaps to be filled for assessing the environmental impacts over the enti- re life cycle including dispersive losses of the physical stocks to the environment (e.g. corrosion and weathering) and losses of materials as a result of materials management (e.g. transport and processing), including energy use of recycling. Financing institution: EU DG Research Project partner: • Bureau de Recherches Géologiques et Minières, Orléans • 2.-0 LCA consultants ApS, Copenhagen • Resource Management Agency, Vienna • University of Technology - Institute for Water Quality and Waste Management, Vienna • University of Stuttgart – Institute of Sanitary, Water Quality and Solid Waste Management • Aristotle University of Thessaloniki • Central Mining Institute, Katowice Duration: 2007 - 2009 Contact: Prof. Dr.-Ing. Martin Kranert Dipl.-Ing. Gerold Hafner Internet: http://forwast.brgm.fr/ Materials balance for sand and Gravel in Austria 2001 75 Chair of Waste Management and Emissions Comparison of the energy recovery and usage of compost from green waste: What is the impact on primary resources? Introduction: According to §2 and §3 of the Biomass Regulation (2001), the use of green waste (from yards and parks) for power generation is allowed. The generated electricity is subject to the regulations of EEG (regulation for renewable energy), which means a monetary support of 4 – 7 € Cent/kWh. Objectives of the research project: Objectives of the Investigation Project: a)Verifying relative preferences of the two mentioned recovery scenarios for green waste, esp. regarding primary resources and CO2-balances Bilanz and to develop b)Instructions / Recommendations for stake holders in waste management and legislation. Working Packages: The aim of the governmental promotion is to substitute primary resources by using renewable primary products - particularly to generate a positive effect on the greenhouse gas situation with regard to power generation. Unlike energy recovery, material recovery of green waste is currently not supported in Germany. Humic material in compost, though, assures a partial storage of carbon, achievable even more efficiently when compost substitutes turf (garden earths and substrate). Turf is in fact a primary resource connected to greenhouse gas emissions through the excavation from moors (moors are sinks of carbon dioxide). More arguments for the employ of turf substitutes result from economic considerations and partially from business management considerations in earth industries as well. In this context we have to consider the annual need of turf: ca. 10 Mio m³ p.a., generating an actual annual import up to ca. 3 Mio. m³ p. a. (2003). The German turf reserves will last another 20 years. Currently ca. 300.000 m³ compost from green waste are used as turf substitutes. The medium term potential capacity is ca. 1,2-1,8 Mio. m³ p.a., the long term potential capacity is ca. 2,5-3 Mio. m³ p.a. Although there is a want for data regarding energy recovery, it is estimated that ca. 0,5-2 Mio. t/a of green waste are treated to recover energy. Evaluations of the two competing alternatives (energy or material use of green waste) are not possible due to the lack of basic data. Although existing studies and reports do not give a clear preference to one of the two alternatives, no governmental support of material usage is available, whereas the energy use of green waste is promoted (ca. 85-160 €/t green waste). This current practice needs revision, especially considering the relevance of these benefits. 76 a)Data mining and analyses concerning calorific values of green waste (different types of materials, different seasons, different types of output from plants). b)Data mining concerning power requirement of technical systems and substitution of primary ressources through both recovery scenarios (energy and material recovery). c)Calculation of greenhouse gas emissions, including secondary effects. d)Comparison of the results from c) with other woody energy sources (esp. old timber, wood chip etc.). e)Valuation of the investigated systems in c) and d), esp. in relation to primary resources and greenhouse gases. f) Estimation of potential masses/quantities and elaboration of recommendations for future waste management concerning recovery systems for green waste. Data mining for green waste: Samples of different types of green waste and secondary fuel are analyzed in the Laboratory of the University of Stuttgart to create a database with chemical-physical characterization (Calorific value, water content etc.), for different seasons and different types of plants. Balances: Process balances will be arranged for the following process units: Bio-/Green Waste, old timber, wood chips: Solid Waste Management SIA Transport and storage (where required) Recovery of green waste: relevant processes Garden waste composting: material flows 77 Chair of Waste Management and Emissions Collection, Transport 1, Treatment 1, Composting, Treatment 2, Transport 2, Utilisation Peat: Coverage, excavation, supply, raw material transport, treatment including packaging, transport of products (wholesale), transport of products (consumer). Evaluation criteria and borders of balances: The evaluation criteria of the investigated processes are mass flows, energy- and CO2-balances. The respective borders of the balances result from the concept of „completed recovery“. Financing institution: Entsorgungsgemeinschaft der deutschen Entsorgungswirtschaft (EdDE e. V.), Köln Project partner: Arbeitsgemeinschaft Universität Stuttgart (Institut für Siedlungswasserbau, Wassergüte- u. Abfallwirtschaft – ISWA); Humus & Erden Kontor GmbH Project direction : Prof. Dr.-Ing. M. Kranert (ISWA), Dipl.-Ing. R. Gottschall (Humus & Erden Kontor GmbH) Duration: 12/2007 Contact: The first Figure shows the main processes which have to be considered related to the recovery of green waste. A part of the material is more suitable for an energy recovery whereas another part should be used for composting. A third fraction of green waste is suitable for both recovery scenarios. First results: The following figures show examples of results from CO2-calculations related to different scenarios of green waste recovery. Two time frames are considered: 2 years and 50 years. After 50 years the biomass used for the recovery is renewed (growing of plants). It is illustrated a positive balance for the energy recovery of raw green waste from spring. The energy recovery for conditioned green waste (screening) is much more efficient and has a similar dimension as the CO2-balance for the substitution of german peat by substrates from green waste compost. Conclusion: Both scenarios for the recovery of green waste lead to a reduction of greenhouse gas emissions, although with varying efficiency. Significant savings result from energy recovery as well as from material recovery (similar dimension). Therefore a similar or even equal political treatment – e.g. basing on saved greenhouse gases - is reasonable. The investigation project will also deliver a database and the parameters to provide a basis for future political decisions. 78 Dr. Dipl.-Ing. agr. C. Bruns Dipl.-Ing. R. Gottschall Dipl.-Ing. G. Hafner Prof. Dr.-Ing. M. Kranert Dipl.-Ing. O. Schiere Dipl.-Forsting., Dipl.-Ing. C. Seibel Solid Waste Management SIA WasteNet – A new international network for research activities in the area of sustainable solid waste management WasteNet brings together 12 partners from 3 continents committed to action for conflict transformation through sharing of skills, knowledge, experiences and resources in the area of sustainable solid waste management. WasteNet members from universities and institutions participating in the programme are as follows. Latin America: Costa Rica, Bolivia, Columbia, Brazil, Chile Asia: China, Malaysia und Thailand Europe: Finland, Turkey und Germany. Aim of WasteNet? Developing countries have sometimes restricted access to information sources concerning solid and hazardous waste management which has led to a generalised lack of knowledge about the problem, resulting in nonexistent, inappropriate or incomplete technical, political and operational measures. On the other hand, countries with advanced know-how about waste management and treatment technologies are unaware of the research and policy needs in developing countries, being unable to access these potential markets. Through the establishment of an international knowledge network for the advancement of sustainable and appropriate waste management both issues can be addressed. In this sense, WasteNet strengthens the international research in sustainable and appropriate waste management strategies and technologies. WasteNet can thereby act as a platform for communication with its highly qualified scientists from Latin America, Asia and Europe to intensify multilateral exchange of experiences and knowledge in the field of waste management. The first meeting of Latin America Partner took place in October 2007 in Bogota, Columbia. Despite some differences between individual partner countries, the evaluation of solid waste management in urban and rural areas has shown a surprisingly high compliance. One important insight gained through this meeting is: Recyclable Waste Seperation in Bogota 79 Chair of Waste Management and Emissions Whereas almost all big cities in each partner country can ensure a relatively good collection and treatment of waste, the situation in the rural areas is yet completely unsatisfying. In many cases only a minor part of the waste collected, the disposal happens in illegal dump sites, in rivers or anywhere in the landscape. Even that the situation in the partner countries is not entirely comparable, our estimations still show that more than 50% of waste appearance occurs in rural areas and therefore is treated inadequately. The environmental impact on soil, ground and surface water and on the atmosphere is without any doubts profound. A further critical point has been elaborated: Waste from hospitals and hazardous waste (industrial as well as household waste, e.g. batteries or fluorescent tubes). As one of the first Latin-American countries, Columbia compiles a cadastral register of hazardous waste. The next step will be the development of waste treatment and disposal facility plants. Financing institution: EU, DG International Cooperation INCO Project partner: • Costa Rica; Universidad de Costa Rica San Pedro de Montes de Oca, San Jose • Brazil; Centro Integrado de Tecnologia e Educação Profissional da Cidade Industrial de Curitiba • Bolivia; Catholic Bolivian University „San Pablo“, La Paz • Chile; Technical University Federico Santa María, Valparaiso • Colombia; Los Andes University, Bogota • Thailand; King Mongkut‘s Institute of Technology North Bangkok • Malaysia; University Sains Malaysia, Penang Duration: 2007 - 2008 Contact: Dr.-Ing. Klaus Fischer M.Sc. Anghana Klongkarn M.Sc. Maria Espinoza Results, examples and other useful information including dictionary for solid waste management in German, English, Spanish can be found in our website www.wastenet.de . Photo of Participants - WasteNet Meeting at Los Andes University in Bogota /Columbia 80 Solid Waste Management SIA MODULAARE – Integrated modules for high efficient wastewater purification, waste treatment and regenerative energy recovery in tourism resorts Modules for wastewater purification with membranes and for fermentation of sewage sludge and organic wastes: an integrated concept for recovery of process water, production of hygiene fertiliser and regenerative energy and for waste minimisation Introduction: Background Information: Germany, as one of the large travel nations, has a special responsibility for a sustainable and environmentally aware tourism. Therefore, one of the main targets of this investigation project is to verify the operation of an innovative, decentralized and modular system for waste water purification, waste treatment and production of energy from biogas in a large Tourists Resort located in Turkey. This modular system combines a membrane system for the purification of wastewater with a fermentation/biogas system for the recovery of relevant quantities of organic wastes. The advantages of both treatment procedures strengthen themselves and remove disadvantages of the respective procedures, so that the two systems can be operated with a high efficiency regarding economic and environmental aspects. In the context of this research and demonstration project, a low loaded membrane facility has been installed in a representative Tourists Resort (approx. 900 beds). Efficiency and possible applications for the purified wastewater are determined and examined. Remaining excess sludge is fed directly into the biogas facility where it is co-fermented with organic solid waste (waste from kitchen, restaurant and garden). This modular, decentralised system is especially suitable for the application in sensitive areas, e.g. tourism regions, corral reefs, islands, coasts, nature parks, etc.. The demonstration project MODULAARE should assess whether this modular concept can be operated economically and routinely. Therefore the tests in the practical use and the integration into the processes within the tourists resort are of special interest. The analysis program of the fermentation module covers both the technical adjustment to the input material and the optimisation and simplification of the handling. Innovative Character: Substrates, processing, fermenter, residues and biogas are investigated regarding optimisation. Wastewater resulting from the fermentation process can be supplied to the membrane module. An additional important aspect is the option to realize an energy concept for the optimal use of the biogas and the combination with other regenerative sources of energy (e.g. solar, wind). The innovative character of the MODULAARE concept can be outlined by the following key points: • Combination of waste recycling + wastewater treatment + energy concept • Modular units can be adapted to extensions of the hotel • Decentralised use is possible (bays, little villages without regular wastewater treatment and waste disposal) 81 Chair of Waste Management and Emissions • Development of a sustainable, recycling management resulting in an nearly waste- and wastewater-free tourists resort. • By modifying the solid content and switching on/ off individual membrane modules the membrane facility can be adapted very easily to seasonal fluctuations (guest numbers) • Advanced development to self-sufficient systems (e.g. by including other regenerative energy sources) • Membrane and sanitation stage (fermentation) enable short cycles (no germs, exciter, etc.) • Altogether, the membrane system will demand low attention during operation because the settling of the activated sludge plays a role no more • Difficulties with wastewater in fermentation facilities are solved by means of the membrane facility • Excess sludge problems are solved by fermentation system 82 Advantages: MODULAARE promotes substantially the sustainable management of both the hotel system and the environment. The largest advantage which can be expected is the use of the benefits (high-efficient cleaning, recycling of waste, regenerative energy) of both systems. Simultaneous the problems determined by the system (power requirement of the membrane, excess sludge, fermentation wastewater) will be neutralised. Further advantages are: • Avoidance of pollution of high-sensitive ecological systems (e.g. corral reefs, mud flats, etc.) by insufficiently treated wastewater • Discharge to dumps which often indicate insufficient standards in tourism regions (methane production leachate, setting, hygiene aspects) will be minimised • Regenerative energy can be used to save fossil sources of energy • The modular system makes extensions simple and economically possible (construction, integration into existing modules etc.) Solid Waste Management SIA • Direct water utilisation as process water or for irrigation (substitution of drinking water and water for domestic use) • Depending upon the respective local situation, fermentation residues can be used directly in agriculture or be made applicable in hotel gardens by drainage and maturing to compost • Water retention capacity of soils and content of humic substances will be increased by application of compost The biogas module comprises the following technical components: • • • • • • • • Delivery storage tank Digester Gas storage Gas flare Storage tank for the fermentation output Digester input Digester Output Fermentation residues Results and conclusions: • Preservation of resources (water, artificial fertiliser, etc.) • Production of valuable soil-conditioner; saving of artificial fertiliser (costs), compost contributes to improve humus generation and to increase CO2 fixation in the soils (Kyoto Protocol) • No problems with organically highly loaded fermentation residues • Enrichment of ground-water by spray irrigation of green belts and infiltration of the purified waste • Reduction of environmental pollution as chlorinated water will not be utilised any more • Cost saving within the area of water supply and wastewater disposal Description of the demonstration plant: The demonstration plant, located in Iberotel Sarigerme Park (Sarigerme, Turkey), consists of the waste water treatment module (container on the right) and the biogas module. This article describes the anaerobic digestion module. In this module, organic waste and sludge from the membrane wastewater purification are digested under anaerobic conditions, while producing biogas and anaerobic digestion residues. The digestate can be used as an organic fertilizer if tested suitable. The demonstration plant, located at a large tourism resort in Turkey shows the feasibility of the MODULAARE-concept under technical and economical aspects. Results from scientific analyses and measurements show a high efficiency of both components - the waste water treatment module and the biogas module. The two components complement each other. Excess sludge from waste water treatment is utilized within the fermentation process. Biogas of high quality substitutes primary energy resources. The digestate can be used (and sold) as fertilizer or – if more suitable – can be treated within the wastewater treatment module. Financing institution: Bundesministerium BMBF für Bildung und Forschung Project partner: • AT-Verband (Verband zur Förderung angepasster, sozial- und umweltverträglicher Technologien e.V.) • Universität Stuttgart, Institut für Siedlungswasserbau, Wassergüte- und Abfallwirtschaft, Abteilung Abwassertechnik • Memos Membranes Modules Systems GmbH • Bio-Sytem Selecta GmbH • Iberotel Sarigerme Park, TUI AG - Umweltmanagement Duration: 10/2003 - 01/2007 Contact: Prof. Dr.-Ing. Martin Kranert Dipl.-Geogr. Dieter Steinbach Dipl.-Geogr. Andrea Schultheis Dr.-Ing. Klaus Fischer Dipl.-Ing. Gerold Hafner 83 Chair of Waste Management and Emissions Independent Studies, Master- and Diploma Thesis Environmental impacts of sugar cane cultivation and sugar production, example Brazil Verfahrensentwicklung Gärresten zur Aufarbeitung von Solange Da Castro Menezes (WASTE) (2007) Supervisor: Dr.-Ing. K. Fischer Prof. Dr. E. Thomanetz Lorena Piles Tortajada (Environment protection and food production) (2007) Supervisor: Dr.-Ing. K. Fischer Prof. Dr. M. Kranert, Prof. Dr. J. Jungbluth Solid waste management in Bhutan Ngawang Gyaltshen (Infrastructure Planning) (2007) Supervisor: Dr.-Ing. K. Fischer Prof. Dr. G. Kaule Carbon Emission Reduction Certificates recovery from Leachate Treatment Recyclingverfahren für Farbstoffsolarzellen Daniela Prado (WASTE) (2007) Supervisor: Dr.-Ing. K. Fischer Dr. W.R. Müller Jingjing Huang (UMW) (2007) Supervisor: Dr.-Ing. K. Fischer Prof. Dr. M. Kranert Integrated Solid Waste Management: A sustainable to reduce load on landfill site in Pokhara city, Nepal Konzepte zur Senkung von CO2-Emissionen in Entwicklungsländern, Bereich Abfallwirtschaft Purna Prasad Bhandari (Infrastructure Planning) (2007) Supervisor: Dr.-Ing. K. Fischer Prof. Dr. M. Kranert Prof. Dr. G. Kaule Diana Heitzmann (Geographie) (2007) Supervisor: Dr.-Ing. K. Fischer Prof. Dr. W.D. Blümel Stoffstromanalyse ausgewählten Abfallrelevanten Rohstoff für die Bundesrepublik Deutschland Nataliya Kurz (UMW) (2007) Supervisor: Dr.-Ing. K. Fischer Prof. Dr. M. Kranert Management system and feasibility study for an integrated treatment of organic wastes and wastewater in a Tourism Centre Tatiana Medon (WASTE) (2007) Supervisor: Dr.-Ing. K. Fischer Prof. Dr. E. Thomanetz Experimental investigation of soot permeability in catalyzed Diesel particulate filter Packaging from Hospitals – collection and recycling Samuel Sasu (WASTE) (2007) Supervisor: Dr.-Ing. K. Fischer Prof. Dr. M. Kranert Qualitative and quantitive Vermeidung, Pfandsysteme in EU and China Wei Wei Wang (UMW) (2007) Supervisor: Dr.-Ing. K. Fischer Prof. Dr. M. Kranert Recycling von PET, Textilherstellung Yuming Wang (UMW) (2007) Supervisor: Dr.-Ing. K. Fischer Co-Vergärung am Beispiel einer Hotelanlage Kavitha Pathmanathan (WASTE) (2007) Supervisor: Dr.-Ing. K. Fischer Dr. D. Schmidt Dieter Werkle (Bauing.) (2007) Supervisor: Dr.-Ing. K. Fischer Prof. Dr. M. Kranert Vergleich der Umweltrechtlichen Anforderungen an Betriebe der Automobilherstellung in USA, Brasilien, Südafrika und Deutschland Hospital Waste and Landfill management in India Kristy Pena Munoz (WASTE) (2007) Supervisor: Dr.-Ing. K. Fischer Prof. Dr. E. Thomanetz Shamaila Zia Zia (Infrastructure Planning) (2007) Supervisor: Dr.-Ing. K. Fischer Prof. Dr. G. Kaule 84 Solid Waste Management SIA Contact Dr.-Ing. Klaus Fischer Laboratory Tel.: ++49 (0)711/685-65427 Fax: ++49 (0)711/685-67634 E-Mail: [email protected] CTA Catharina Le Huray-Horel Secretary´s office Tel.: ++49 (0)711/685-65436 Fax: ++49 (0)711/685-67634 E-Mail: [email protected] Gudrun Heinl CTA Jürgen Wolf Tel.: ++49 (0)711/685-65495 Fax: ++49 (0)711/685-65460 E-Mail: [email protected] Tel.: ++49 (0)711/685-65503 Fax: ++49 (0)711/685-67634 E-Mail: [email protected] Research Assistants Doctoral Candidates Dipl.-Geol. Detlef Clauß Dipl.-Ing. Carla Cimatoribus Tel.: ++49 (0)711/685-65502 Fax: ++49 (0)711/685-65460 E-Mail: [email protected] Tel.: ++49 (0)711/685-62567 Fax: ++49 (0)711/685-65460 E-Mail: [email protected] MSc. Maria Alejandra Espinoza MSc. Sebnem Bastan Yilman Tel.: ++49 (0)711/685-65477 Fax: ++49 (0)711/685-65460 E-Mail: [email protected] Tel.: ++49 (0)711/685-62567 Fax: ++49 (0)711/685-65460 E-Mail: [email protected] Dipl.-Ing. Gerold Hafner MSc. Nicolas Escalante Tel.: ++49 (0)711/685-67636 Fax: ++49 (0)711/685-65460 E-Mail: [email protected] Tel.: ++49 (0)711/685-62567 Fax: ++49 (0)711/685-65460 E-Mail: [email protected] MSc. Angkhana Klongkarn Tel.: ++49 (0)711/685-65477 Fax: ++49 (0)711/685-65460 E-Mail: [email protected] Dipl.-Ing. Oliver Schiere Tel.: ++49 (0)711/685-65506 Fax: ++49 (0)711/685-65460 E-Mail: [email protected] Dipl.-Biol. Andreas Sihler Tel.: ++49 (0)711/685-65498 Fax: ++49 (0)711/685-65460 E-Mail: [email protected] 85 Chair of Waste Management and Emissions Hazardous Waste and Contaminated Sites Research topics: • UV wet oxidation of liquid hazardous waste and industrial wastewater • Development of microsensors for rapid investigation of contaminated sites using the cone penetration test • Development of adequate waste sampling methods • Development of adequate (large scale) waste analysis methods • Pyrolysis of hazardous waste • Fire inquest investigations of hazardous waste for rock filling and underground storage • Long term waste investigations within large lysimeter units • Determination of the spontaneous combustion properties of hazardous waste Nothing is too dangerous for us Special procedures for the treatment of hazardous industrial waste as well as investigation and remediation methods for contaminated sites form the focal point of the teaching and research activities within our work area “Hazardous waste and contaminated sites”. We are also widely experienced in sampling and analysis of solid, liquid and paste-like waste. Our research covers the following subjects, e. g.: • Backfilling of mines (stowing): we have developed and introduced methods to industrial routine to quantify the generation of hydrogen in industrial waste and thus to enable avoidance of the hazards presented by hydrogen in the subsurface. Of particular importance for underground waste sites are the methods developed for a new waste parameter: TOCbio – that is the microbially reducible TOC. This parameter has already found its way into the new edition of the Ordinance on Underground Waste Stowage. • Intermediate storage of special spontaneous-ignition industrial waste: here, procedures were developed that help to understand the spontaneous combustion mechanism and thus to avoid this hazard. • Development of practical UV wet oxidation reactors for industrial sewage or hazardous liquid waste: not only are UV treatment reactors in disposal scale available for this purpose (the largest has a capacity of 1 cubic metre and 40 kilowatts), but also laboratory reactors of 10 litres capacity for initial investigations. Further activities in brief: The development of “chemical noses” for rapid investigation of waste spoil tips and contaminated sites by means of CPT technology; development of methods for returning reverse osmosis leachate concentrate to the body of the landfill; testing of suitable indicator parameters for determination of the influence of a landfill on its surroundings (tritium, boron and others); development of bespoke industrial solutions with regard to waste and wastewater. 86 Hazardous Waste and Contaminated Sites SOA Projects “Elimination of hardly degradable Substances from Effluents with a Biologically Regenerating Adsorptive Rotary Disc Reactor” In receiving water courses of biological purifying plants damage on aquatic organisms due to traces of hard to degrade organic industrial chemicals and pharmaceutical products can be observed. The Baden-Württemberg Ministry of Environment considered the removal of these substances currently one of the vital topics in environmental research. The project firstly, by means of experiments with an appropriate laboratory scale setup, aims at proving that microorganisms settling on activated carbon can degrade the endocrine substances primarily adsorbed hereon. Based on the thus gained data, the design of a technical process is to be investigated with which an industrial scale pilot plant can be erected. The project will be carried out in cooperation with the Department of Chemistry (CH) of our institute and with the company Stengelin-Specker Kläranlagen GmbH, who invented the Rotating Disc Reactor for the Biological Purification of Waste Water in the 1950es. Furthermore, the departments Biology (BIO), Waste Water Technology (AWT) and Industrial Water and Waste Water Technology (IWT) of our institute can provide their comprehensive experience on the field. Financing institution: Willy-Hager-Stiftung Duration: 10/2007 - 09/2009 Contact: Prof. Dr.-Ing. Erwin Thomanetz Dipl.-Geoökol. M. Borchers CTA Brigitte Bergfort Hollow Discs filled with Adsorbent Granulate 87 Chair of Waste Management and Emissions “Solar Photocatalytic Hygienisation and Detoxification of Water” The Advanced Oxidation Process (AOP) used for water purification in this project, is based on the semi-conductor properties of Titanium Dioxide when irradiated with ultraviolet light. Experiments are carried out in laboratory scale to investigate how specially modified and immobilised Titanium Dioxide can act as photocatalyst even in diffuse daylight, and thus generate oxidative radicals. The University of Hohenheim Institute of Environmental and Animal Hygiene is our partner concerning the microbiological aspects. Reaction Equations Titanium Dioxide 88 Financing institution: AiF Project partner: Firma Stengelin-Specker Kläranlagen GmbH, Dürbheim Duration: 01/2007 - 03/2009 Contact: Prof. Dr.-Ing. Erwin Thomanetz Dipl.-Ing. M. Rapf CTA Brigitte Bergfort Hazardous Waste and Contaminated Sites SOA “Development of a Compact Air Stripper for Ground Water Remediation” Volatile organic substances in Ground Water, mostly BTEX-aromates and halogenated hydrocarbons, are commonly removed by Air Stripping with vertical packed columns. Because of the height of the columns (6 up to 12 metres), and also because of technical problems like scaling of the packing material with iron and manganese salts, vertical column strippers can not be used in many practical cases. Therefore a compact air stripper, that can be built into mobile construction site containers, has been designed. A pilot plant has been built up and tested under practical conditions. Concerning substance removal as well as energy consumption, the new stripper is as efficient as or even better than the classical column stripper. After the successful pilot experiments the previous knowledge will be used to construct a industrial scale compact stripper. Financing institution: ZÜBLIN Umwelttechnik GmbH, Stuttgart Duration: since 06/2006 Contact: Prof. Dr.-Ing. Erwin Thomanetz Dipl.-Ing. M. Rapf Horizontally operating Brush Air Stripper 89 Chair of Waste Management and Emissions “Basic Investigations on Salt Preservation of Waste for Underground Storage” Microbial activity is completely stopped in a saturated solution of Sodium Chloride (common salt). Therefore it is possible to mix solid wastes high in organics thoroughly with Waste Salt, to prevent the biogenic generation of gas and odour, which are disgusting and dangerous for the staff underground. However, odours already contained in the waste cannot be removed by the conditioning procedure. Hence experiments have been performed to find out with what kinds and amounts of additives selected waste samples can be biologically inactivated and deodorised completely. Relation: Microbial Growth and Water Activity 90 Client: Firma UEV Umwelt, Entsorgung und Verwertung GmbH, Heilbronn Duration: 06/2006 - 02/2007 Contact: Prof. Dr.-Ing. Erwin Thomanetz CTA Brigitte Bergfort Hazardous Waste and Contaminated Sites SOA “Planning and Realisation of a Large Scale Test for the Zollernalbkreis concerning the Substitution of Fossil Fuels at Holcim Cement Company by a Mix of Bio Waste and Low-Quality Waste Paper” The District of Zollernalb is planning to collect bio-waste and low quality waste paper together in one bin and to subsequently produce from the thus gained waste mix a secondary fuel low in pollutants. The background is the intent to reduce the number of bins in front of the citizens’ houses, to lessen the hygiene problems with bio waste in the warm season and also to become independent from the usual price fluctuations on the recycling market. Ball Mill for Municipal Waste For that purpose about 60 tons of a Mix out of bio-waste and waste paper have been shredded, sieved, dried in solar and conventional driers. Finally the thermal utilisation of the mix in a cement kiln, as well as in a novel fluidized bed gasifier have been tested. Based on the results of these experiments, further attempts are planned to co-incinerate more dried Mix in a Biomass Power Station. Client: Landratsamt des Zollernalbkreises, Balingen Duration: 07/2005 - 01/2007, 09/2007 - to date Contact: Prof. Dr.-Ing. Erwin Thomanetz Dipl.-Ing. M. Rapf Dipl.-Ing. G. Hafner Rotary Cement Kiln, injection side Single-shafted Rotary Shear Shredder Solar Dryer 91 Chair of Waste Management and Emissions Independent Studies, Master- and Diploma Thesis “Acceleration of the BET-Surface Measurement for Activated Carbon by Variation of Pressure and Temperature” Yaoyao Yuan (2008 to date) Supervisor: Prof. Dr.-Ing. E. Thomanetz Master Thesis “Pyrolysis of Plant Waste in order to Produce Coke Fuel ” Parik Sabungan Sirumapea (2007 to date) Supervisor: Prof. Dr.-Ing. E. Thomanetz Master Thesis „Aufbereitung von organisch hochbelastetem Prozessabwasser am Beispiel eines Betriebes der Erfrischungsgetränke-Grundstoffproduktion“ „Testmethode für die biologische Abbaubarkeit des TOC (TOCbio) von Industrieabfallproben: Untersuchungen zur Optimierung der Leitfähigkeitsmessung“ Chen Yang (UMW) (2007) Supervisor: Prof. Dr.- Ing. E. Thomanetz Diploma Thesis Ying Zhu (UMW) (2007) Supervisor: Prof. Dr.- Ing. E. Thomanetz Diploma Thesis „Optimierung und großtechnische Umsetzung einer Kompaktstrippanlage“ „Untersuchungen zur Funktionsweise einer Kompaktstrippanlage“ Steffen Vogel (UMW) (2007) Supervisor: Prof. Dr.- Ing. E. Thomanetz Diploma Thesis Timo Pittmann (UMW) (2007) Supervisor: Prof. Dr.- Ing. E. Thomanetz Independent Study “Conditioning of Hazardous Wastes for Incineration“ “Untersuchungen zur Optimierung der Luftstrippung für Grundwassersanierung“ Gloria Patricia Galindo Vanegas (2007 to date) Supervisor: Prof. Dr.-Ing. E. Thomanetz Independent Study Gangyi Luo (UMW) (2007) Supervisor: Prof. Dr.- Ing. E. Thomanetz Diploma Thesis “Aftercare of Landfill Sites Using Hydrogen Peroxide as Oxygen Supply for Microbial Processes” Piyathida Baingern (2007 to date) Supervisor: Prof. Dr.-Ing. E. Thomanetz Master Thesis “Development of a Test Method to Determine the Biodegradable Part of the TOC (TOCbio) of Solid Waste” Leonidas Karapanagiotis (2006) Supervisor: Prof. Dr.-Ing. E. Thomanetz Master Thesis Dissertations “Optimisation of AOP-Treatment for Industrial Waste Water and Toxicological Characterisation of the Effluent” “Entropy Production as Measure for the Environmental Impact of Technical Processes with Examples from Waste Management” M.Sc. Ibrahim Abdel Fattah (2007 to 2010) Supervisor: Prof. Dr.-Ing. M. Kranert Prof. Dr.-Ing. E. Thomanetz Doctoral Thesis Dipl.-Ing. Matthias Rapf Durationfrom (2007 to 2010) Supervisor: Prof. Dr.-Ing. M. Kranert Prof. Dr.-Ing. B. Weigand Prof. Dr.-Ing. E. Thomanetz Doctoral Thesis 92 Hazardous Waste and Contaminated Sites SOA Contact Prof. Dr.-Ing. Erwin Thomanetz Tel: ++49 (0)711/685-63709 Fax:++49 (0)711/685-65460 E-Mail: [email protected] Secretary´s office Gudrun Heinl Tel.: ++49 (0)711/685-65495 Fax: ++49 (0)711/685-65460 E-Mail: [email protected] Research Assistants Dipl.-Geoökol. M. Borchers Tel.: ++49 (0)711/685-60495 Fax: ++49 (0)711/685-65460 E-Mail: [email protected] Dipl.-Ing. Matthias Rapf Tel.: ++49 (0)711/685-63709 Fax: ++49 (0)711/685-67634 E-Mail:[email protected] Laboratory CTA Brigitte Bergfort Tel: ++49 (0)711/685-63709 Fax:++49 (0)711/685-67634 93 Chair of Waste Management and Emissions Measuring and Air Pollution Control Research topics: • Analysis of emissions from waste treatment plants • On site clearing of olfactory disturbance and air pollution • Development and optimization of waste gas purification plants • Gas chromatographic analysis of olfactory compounds using an “olfactory detection port” (ODP) • Analysis of volatile organic compounds (VOC) And sometimes, the job just stinks If it stinks, the people in this section are in their element. To find out what, when and why it stinks, exactly where and how strongly it stinks, is part of the research focus of this group. Exhaust gases of all kinds are investigated with the aid of modern gas analysis equipment. The spectrum of available methods covers classical methods such as gas chromatography with mass spectrometers and flame ionisation detectors, to more unusual methods such as olfactometry and “sniffing port“. But the analysis doesn’t stop there. Those services availed upon by both the municipal authorities and industry go as far as practical solutions for the construction and operation of emission reduction facilities. It was possible, for example, to improve the biological exhaust air purification of a slaughter house, or to determine the reasons for the strong odours emanating from a cardboard plant, causing nuisance to local residents. In practice, the purification of odour intensive exhaust gases presents a number of difficulties: the malodorous components often remain unrecognized. Measures are therefore aimed at simply reducing the principal components of the exhaust gases determined using standard analysis methods, while the stinking trace substances remain unregarded. However, employing a combination of the analytical methods available to us, exhaust gases can be investigated for their specific odour relevant components. It is then possible to optimise exhaust gas purification (for odour emissions these are often biological methods). Our work is embedded in both a scientific-technical and economics context. Currently, national and international research projects are underway, the aim of which is to develop effective and economically viable exhaust gas purification methods by a combination of a variety of processes. Our experience flows into national and international regulations. 94 Measuring and Air Pollution Control TAL Projects „VOCleanplas“: Procedural basis for VOC loaded flue gas cleaning with a microwave plasma source for low or medium flue gas volume flows under atmospheric pressure. Financing institution: Motive of this research project was to develop a technical flue gas cleaning method in critical gas flows with the help of a microwave plasma source under atmospheric pressure. Fraunhofer Institut für Chemische Technologie, Pfinztal Universität Stuttgart, Institut für Plasmaforschung (IPF) AIF Arbeitsgemeinschaft industrieller Forschungsvereinigungen, Köln Project partner: Duration: The method should be a compact facility, which can be used not only for low but critical flue gas flow rates from the thin-film deposition, but also for the typical VOC-loaded flue gas streams from low and medium production plants. A higher demand for these flue gas streams is expected, for which no satisfying solution is found until now. The most used VOC-loaded flue gas cleaning method is thermal after-treatment. The loaded flue gas is conducted to a combustion chamber, where a gas- or oilincinerator, supplemented with appropriate catalysts, leads to decomposition and combustion of the VOCs. Since the total gas volume is heated, heat recovery becomes an important component of such a facility. During heat production flue gas is generated by the incinerator. Therefore such facilities are only equitable for flue gas volume flow, which is considerably higher than the flue gas volume flow generated by the facility itself. Hence the facilities for thermal after-treatment have large-volume structures. Facilities for low and medium flue gas flow rates (< 10 m3/h is already a micro-unit) - which are called Scrubber - are so far only cost-effectively replaceable for special critical flue gas in low volume flows, as they are generated in the production of semi-conductor or thin-film deposition. A rapidly increasing trade demand of low and medium VOC-loaded flue gas cleaning facilities appears due to the growing market. 07/2005 - 06/2007 Contact: Dr.-Ing. Martin Reiser Microwave plasma test facility In the frame of this project, several test facilities were built up with microwave plasma technique; experiments of VOC-loaded and fluorinated gas were carried out with the same technique. In ISWA, experiments of VOC-elimination and corresponding gas analysis were performed. Moreover, gas components were analysed on the test facility of the project partner by means of FT-IR technique. It is shown by the project that, due to different aspects the thermal microwave plasma technique is only limitedly appropriate for VOC-elimination. For the application in fluorinated carbohydrates from thin-film deposition the test facility turned out to be successful and effective. 95 Chair of Waste Management and Emissions Minimization of odour emission in foundry sections – Part II The odour emissions from foundries remains a severe problem. In the surrounding area of foundries odour immission occurs, which causes affliction to the already highly critical neighbourhood. To make sure the public acceptance of the foundries on their traditional locations, or due to public pressure, the plants are forced to find a remedy. During recent years the foundries have made some progress in odour reduction. However it appears that the progress is quite little, and most relevant people are only satisfied when the odour in foundries is completely gone. Besides the technologies of foundries are so manifold and the odour sources so complex, that to use a new binder or to modify some technologies can achieve only little progress in a group of foundries. Therefore in some aspects further improvements is needed. Purpose of the project is to find out further solution of reduction on odour emission in iron foundries, especially in foundry sections. That means information about odour emission from form auxiliary materials and additives for both foundry industry and chemical supply industry should be provided. Foundry industries should obtain details of process control, while supply industries obtain details about formation and origination of odorous substances. With further development of measuring technique, it is possible to evaluate and optimize the variety of molding materials and forming auxiliary materials in the odour technical aspect. Furthermore, the results of olfactory – with respect to reproducibility and prediction accuracy – should be improved by optimizing basic conditions of measuring technology. Besides, the research methods which are developed in former project should be further developed. The analytical methods for detection of odorous substances are expanded in detail: • Through variation of adsoption as well as desorption conditions the odorous substances with lower molecular weight (such as hydrogen sulphide, formic acid, formaldehyde, propylene,…) should be detected by analysis. • By expansion of the detector system. With an additional Flame ionization detector it should result in a more detailed quantification of the relevant odorous compounds. The GC/MS/FID-System connected with the Olfactory-Detection-Port (ODP), which is also called Sniffing-Detector, has proved itself effective. • By extension of the spectrum library and literature research about substance-specific odor thresholds, the proportion in identified flue gas components should be enhanced. Financing institution: AIF Arbeitsgemeinschaft industrieller Forschungsvereinigungen, Köln Project partner: IfG – Institut für Gießereitechnik GmbH, Abteilung Arbeits- und Umweltschutz, Düsseldorf Duration: 10/2005 - 03/2008 Contact: Dr.-Ing. Martin Reiser „Olfactory-detection-port (ODP) “for identification of odorous components in mixed gas 96 Measuring and Air Pollution Control TAL Preliminary exploration of construction stage IV on Landfill Dorfweiher for project measures planning to shorten the aftercare period Im Rahmen dieses Vorprojekts wurden Messungen und Arbeiten zur Probenahme und Belüftung des Deponieabschnitts durchgeführt. Das Ziel war, Daten über die Zusammensetzung und Beschaffenheit des Mülls sowie von Deponiegas und Sickerwasser zu sammeln, um sich ein möglichst genaues Bild über diesen Teil der Deponie machen zu können. Anhand der Erkenntnisse aus diesem Pilotprojekt soll eine Sanierungsmaßnahme „Aerobisierung der Deponie“ geplant und beantragt werden, die dann im Rahmen eines Folgeprojekts durchgeführt werden soll In frame of the technical pre-project, measurements, sampling and air ventilation into the landfill section were carried out. The aim was collecting data on the composition and character of the waste, landfill gas and leachate, in order to make a sketch of this part of the landfill as accurately as possible. With the knowledge from this pilot project, a remediation measure “Aeration of the Landfill” should be planned and applied for, which should be conducted in the frame of a follow-up project later on. Emission measurements with a tunable diode laser for methane measurement over long distances Financing institution: Landkreis Konstanz Project partner: Fa. Lhotzky & Partner, Braunschweig Duration: 10/2007 - 12/2007 Contact: Dr.-Ing. Martin Reiser M.Sc. Han Zhu Independent Studies and Diploma Thesis Contact Odour Measurements in Solid Waste Transfer Station located in Dußlingen Tel.: ++49 (0) 711/685-65416 Fax: ++49 (0) 711/685-63729 E-Mail: [email protected] Marta Eugenia Escoto de Tejada (WASTE) (2007) Supervisor: Dr.-Ing. Martin Reiser Independent Study Elimination von VOC’s und Gerüchen aus Abgasen durch nichtthermisches Plasma Thomas Eckhardt (Umweltschutztechnik) (2006) Supervisor: Dr.-Ing. Martin Reiser Diploma Thesis Dr.-Ing. Martin Reiser Hans-Jürgen Heiden (CTA) Tel.: ++49 (0) 711/685-63712 Fax: ++49 (0) 711/685-63729 E-Mail: [email protected] Axel Goschnick (CTA) Tel.: ++49 (0) 711/685-63712 Fax: ++49 (0) 711/685-63729 E-Mail: [email protected] 97 Chair of Waste Management and Emissions Biological Air Purification Research topics: • Detection of degradative potentials • Isolation of xenobiotics degrating bacteria and fungi • Elucidation of bacterial degradative pathways by use of genetical, chemical and biochemical techniques • Development of new waste air purification concepts • Design, dimensioning and operation of Biological Waste Air Purification (BWAP) plants • Biosynthesis of fine chemicals with high value It’s not just hot air to us The biological cleaning of exhaust air and the biodegradation of xenobiotics (i.e. non-biodegradable substances) by bacteria represent the focal point of our work. In addition, the department provides assistance in the planning and dimensioning of biofiltration apparatus of various types (biofilter, biotrickling filter and biowasher). Moreover, it is possible to provide scientific supervision of these apparatus and equipment during normal operations and in case of faults. This is in the interest of research in a real practical context, because the weaknesses revealed in any of the functions can be drawn upon to develop new or optimised concepts. A further field of research is the degradation of xenobiotics: exposing degradation potential, isolating xenobiotic degrading bacteria strains and fungi, investigating bacterial degradation paths and, as a spinoff, the biosynthesis of materials. Using the example of the metabolism of styrene (vinyl benzene), it is possible to demonstrate the effects of our research: we have applied our knowledge concerning the degradability of chemicals and the microorganisms involved in diverse environmental engineering industry contracts. In the case of styrene, we have participated in the construction and operation of biofilter plants for the purification of exhaust air from the manufacture of glass-fibre reinforced plastic tubes. Further focal points in this context are the metabolism of halobenzene derivates, on their own and in admixtures with toluene, as well as the degradation of aromatic and non-aromatic ethers. In the waste air field, we are involved in the investigation of the problematic metabolism of substance mixtures and with the “clogging“ of filter materials (i.e. the blockage of filters as the result of excessive biomass production). One approach to the solution here is the development of filters with moving beds, as already implemented in the rotorfilter, but now continued using a different direction. 98 Biological Air Purification ALR Projects Preparation of a continuation proposal with the title: Halogenated and alkylated benzenes mineralizing bacteria: characterization of degradation pathways for fluoromuconate and methylsubstiuted lactones / to be submitted to the DFG in 2008; envisaged funding institution: DFG; Contents: see PhD work of Dipl.-Ing. N. Strunk and Dipl.-Ing. D. Dobslaw. Evaluations and Industry Contracts Optimization of industrial biofilter for treatment of benzylic alcohol and benzaldehyde containing waste air Company: Plasma Air AG and G-Elit GmbH An industrial waste air cleaning plant was optimized, the running conditions were determined and special rules were set for the critical phase of start-up. Espaecially important were the optimization of the scrubber unit, the control of pH-value and the monitoring of the biomass. The work is not yet finished and will be continued in 2008. Investigations on industrial biofilter material Company: Firma Handte GmbH Umwelttechnik Process Optimization in reclaim waters of the chip industries In collaboration with a `Clean Water`-Supplying Company a biotrickling filter device was constructed purifying production water streams in order to reuse them instead of introducing fresh water (product integrated approach). Special bacteria were isolated, characterized and tested with respect to their degradative behaviour, their growth potentials and stability. The work will be applied in industry, the results will be patented. Optimization of a ammonium treatment plant in the milk industries In a milk treating industrial plant operating according to the sequencing batch procedure destillates are to be treated with rather high loads of ammonium. The operating conditions for ammonium degradation have to be optimized under the specific conditions of sludge separation in a UF-unit. Independent Studies, Master- and Diploma Thesis Biological treatment of chromate containing waste waters- Introductive steps to a clean-up strategy Diego Salamanca (2007) Independent Study Investigations on a biofilter in a benzyl-alcohol utilizing company Ms. Sc Oktay Karas (WAREM) (2007) Master Thesis Anreicherung von acetonabbauenden Bakterienstämmen - Isopropanolabbau in einer Tropfkörperanlage – Enrichment of acetone degrading microorganisms in a trickling filter device „Abreinigung von Isophoron in einem Biotricklingfilter – Untersuchungen zur Genetik des Hauptleistungsträgers Iph200“/ Characterization of a isophorone degrading strain, IPH200 as the active component in a biotrickling filter Natalia Neumann (UMW) (2007) Independent Studiy Nina Gaissert Diploma Thesis 99 Chair of Waste Management and Emissions Biologische Behandlung von mit Toluol und Chlorbenzol belasteten Grundwasser durch die Bakterienstämme Burkholderia fungorum FLU 100 sowie Pseudomonas putida GJ 31 – Biological treatment of ground water contaminated with chlorobenzene and toluene by strains of Burkholderia fungorum FLU100 and Pseudomonas putida GJ 31 Roland Kurz (2007) Diploma Thesis Doctoral Thesis Investigation on the bacterial degradation of halogenated aromatics by strain Burkholderia fungorum FLU 100 and its application in pilot biofilters Technology, microbial physiology and genetics of degradational pathways for chlorosubstituted and methylsubstituted aromatics in biological waste air purification plants Dipl. Ing. N. Strunk (2007) Supervisor: Prof. Dr. K.-H. Engesser PhD Thesis Dipl. Ing. D. Dobslaw (to be finished yet) Supervisor: Prof. Dr. K.-H. Engesser PhD Thesis Meetings and Talks The regulation of the degradation pathways for alkanes degradation in bacteria Workshop in Osnabrück during the annual meeting of the German VAAM (`Society of general and applied Microbiology) Strunk, N; Dobslaw, D; Pieper, D and Engesser, KH Isolation and characterization of strain FLU100, a bacterium with the rare capability to simultaneously degrade toluene and all monohalosubstituted benzenes including fluorobenzene. BIOSPECTRUM Tagungsband Jena, (2006), KC 13 Kim, YH; Kang, I; Bergeron, H; Lau, PCK; Engesser, KH and Kim, SJ Physiological, biochemical, and genetic characterization of an alicyclic amine-degrading Mycobacterium sp strain THO100 isolated from a morpholine-containing culture of activated sewage sludge. ARCHIVES OF MICROBIOLOGY, 186 (2006) Nr. 5, S. 425-434 100 Dobslaw, D; Dobslaw, C; Fütterer, N and Engesser, KH. Optimization of a bioscrubber in printing industry for treatment of crude air containing alcohols and ethers. BIOSPECTRUM Tagungsband Osnabrück, (2007), KE 001, S. 56 Onaca, C; Kieninger, M; Engesser, KH and Altenbuchner, J Degradation of alkyl methyl ketones by Pseudomonas veronii MEK700. JOURNAL OF BACTERIOLOGY, 189 (2007) Nr. 10, S. 3759-3767 Dobslaw, D; Dobslaw, C.; Fütterer, N. and Engesser, KH Biologische Abluftreinigung von Druckereiablüften: Optimierung eines Biowäscher. CIT - Chemie Ingenieur Technik, (2007) Heft 10, DOI: 10.1002/ cite.200700069 Biological Air Purification ALR Contact Prof. Dr.-rer. nat. habil. K.-H. Engesser Tel: ++49 (0) 711/685-63734 Fax:++49 (0) 711/685-63729 Email: [email protected] Research Assistants Dipl.-Ing. Strunk Tel: ++49 (0) 711/685-63730 Fax:++49 (0) 711/685-63729 Email: [email protected] Dipl.-Ing. Dobslaw Tel: ++49 (0) 711/685-65406 Fax:++49 (0) 711/685-63729 Email: [email protected] 101 102 Chair of Hydrochemistry and Hydrobiology o. Prof. rer. nat. habil Jörg W. Metzger Hydrochemistry CH o. Prof. Dr. rer. nat. habil. Jörg W. Metzger Hydrobiology BIO Dr.-Ing. Wolf-Rüdiger Müller, Akad. Oberrat 103 Institute for Sanitary Engineering, Water Quality and Solid Waste Management Chair of Hydrochemistry and Hydrobiology At the chair of Hydrochemistry and Hydrobiology actual practice-oriented topics are investigated and natural science based solutions are developed in interdisciplinary co-operation with engineers. A basic knowledge in natural sciences is required to understand interdisciplinary contexts concerning all areas of Environmental Engineering. Biological and chemical processes are of high importance for the treatment processes of drinking water and wastewater as well as for composting of solid and green waste or for the decontamination of groundwater. The quality of water, no matter if it is wastewater, surface water, groundwater or drinking water, is defined by chemical and microbiological parameters, for which the legislator has set limits (e.g. in the Drinking Water Ordinance). Since it is not allowed to exceed these limits, it is important to reiterate the analytical monitoring process at regular intervals. The task of the Environmental Analysis is to develop and to apply methods which allow to identify and quantify inorganic and organic compounds, either as single substances or in total (as so called summary parameter) in various environmental compartments, such as water, waste water, landfill leachate, soil, sediment, sewage sludge etc. The high toxicity of some substances and the problematic ecotoxicological properties, e.g. the tendency to undergo geo- or bioaccumulation, demands a specific and selective determination of substances in very low concentrations despite possible interferences with other matrix components. Therefore the methods have to be constantly optimised and interpretation of analytical data has always to consider measurement uncertainty. New technologies in the wastewater treatment or drinking water purification are most effectively developed by a close co-operation at the interface between the Engineering and Natural Sciences, e.g. the determination of the efficiency of a water purification method. Effect-related analysis, in which the concentrations of a pollutant in a sample are correlated with its biological effects as basis for a risk-assessment is one of the numerous interdisciplinary networking areas of biology and chemistry. Suitable biological test systems (bioassays), preferably as simply as possible, represent the basis for the practicable application of this concept. Also formation of the investigation of the environmental behaviour of native and anthropogenic substances, e.g. degradation pathways and metabolites as well as the identification of microorganisms participating in the degradation reaction, requires that chemists and biologists work hand in hand. 104 The Chair for Hydrochemistry and Hydrobiology at the ISWA has been supervised by Prof. Dr. rer. nat Jörg W. Metzger since 1996, being also the Head of the Department of Hydrochemistry. The division of Applied Biology is managed by Dr.-Ing. Wolf Rüdiger Müller. Teaching Activities The Department of Hydrochemistry offers a broad range of basic and advanced courses for the students of the Bachelor and Master programs Civil Engineering and Environmental Engineering and the master programs WAREM and WASTE at the Universität Stuttgart. The lectures cover all important topics of Chemistry of Water and Waste Water, Water- and Soil Protection and Environmental Analysis. A deeper insight to these issues is given by practical courses, e.g. for sampling or chemical analysis in the chemical and microbiological laboratories of the department. Courses for Environmental Engineering • Umweltchemie mit Praktikum; Environmental Chemistry (lecture and practical laboratory work) • Umweltanalytik II mit Praktikum; Environmental Analysis (lecture and practical laboratory work) • Chemische Grundlagen des Gewässerschutzes; Chemical Basis for Water Resource Protection • Ökotoxikologie und Bewertung von Schadstoffen; Ecotoxicology and Risk Assessment of Pollutants • Wasser- und Abwasserchemie mit Praktikum; Chemistry of Water and Waste Water (lecture and practical laboratory work) • Praktikum chemische Wassertechnologie; Chemical Water Technology (practical laboratory work) • Qualitätssicherung in der chemischen Analytik; Quality Assurance in Chemical Analysis • Messen und Analysieren von Gewässerverunreinigungen mit Praktikum; Measurement and Analysis of Water Pollution (lecture and practical laboratory work) • Schadstoffanalytik mit Praktikum; Analysis of Pollutants (lecture and practical laboratory work) Courses for Civil Engineering • Chemie für Bauingenieure; Chemistry for Civil Engineers • Wasser- und Abwasserchemie; Chemistry of Water and Waste Water • Biologie und Chemie von Wasser und Abwasser mit Praktikum; Biology and Chemistry of Water and Waste Water (lecture and practical laboratory work) Chair of Hydrochemistry and Hydrobiology Courses for WASTE • Introductory course Bioorganic Chemistry • Chemistry and Microbiology of Potable and Waste Water • Water Analysis and Analytical Quality Control (lecture and practical laboratory work) Courses for WAREM • Introductory course Bioorganic Chemistry • Chemistry and Microbiology of Potable and Waste Water • Water Analysis and Analytical Quality Control • Chemische Grundlagen des Gewässerschutzes; Chemical Fundamentals of Water Resource Protection • Umweltanalytik II mit Praktikum¸Environmental Analysis (lecture and practical laboratory work) International In co-operation with the Universidade Federal do Paraná, Curitiba (Brasil) and the Brazilian industry association SENAI, a postgraduate master program in Environmental Engineering EDUBRAS (Educação Brasil) was launched supported by DAAD. Within the scope of this program the lectures Environmental Chemistry, Environmental Analysis, Chemistry of Water and Waste Water and Ecotoxicology and Risk Assessment of Pollutants are offered by Prof. Jörg Metzger from March 2008 on. This master program conclude after four semester with a master of science degree. Within the activities of proficiency testing in analytical chemistry (AQS Baden-Württemberg) the institute has co-operations with the following organisations: • Physikalisch-Technische Bundesanstalt, Braunschweig, Germany • International Atomic Energy Agency, Vienna, Austria • Southern African Development Community Cooperation in Measurement Traceability, Pretoria, South Africa Ph.D. Thesis Final Reports of the Chair Développement de nouvelles techniques de détermination des pesticides et contribution à la réduction de leur impact sur les eaux par utilisation des Substances Organiques Naturelles (S.O.N.) Metzger, J. und Scholz-Muramatsu, H. (2007): Mikrobiologische Charakterisierung der reduktiven Dechlorierung von chlorierten Ethenen und Ermittlung der Bedingungen für den vollständigen Abbau in-situ. Verbundprojekt: Untersuchungen zur Indikation von mikrobiellem LCKW-Abbau am Beispiel des Standortes Perleberg. Schlussbericht Forschungsvorhaben im Förderschwerpunkt KORA, BMBF 02WN0372 Hicham EL BAKOURI, Thèse de Doctorat, 21.01.2006 Département de Génie Chimique de la Faculté des Sciences et Techniques, Université Abdelmalek Essaadi, Tanger (Maroc). Président de Jury: Dr.-Ing. Wolf-Rüdiger Müller Kuch, Bertram; Rupp, Silke; Fischer, Klaus; Kranert, Martin; Metzger, Jörg W. (2007): Untersuchungen von Komposten und Gärsubstraten auf organische Schadstoffe in Baden-Württemberg. Schlussbericht des Forschungsvorhabens FZKA-BWPLUS, BWR 24026. 105 Institute for Sanitary Engineering, Water Quality and Solid Waste Management Publications Boley, Angela; Unger, Beatriz; Müller, Wolf-Rüdiger; Kuch, Bertram; Deger, Ayse (2006): Biological drinking water treatment for nitrate and pesticide (endosulfan) elimination. Wat.Sci.Technol., Water Supply 6, 123-127. Boley, Angela; Frommert, Irene; Müller, Wolf-Rüdiger (2006): A biological filtration process for denitrification with polycaprolactone as solid substrate in a rotating reactor. In: Gimbel, R., Graham, J.D. and Collins, M.R. (ed.): Recent progress in slow sand and alternative biofiltration processes. IWA Publishing, London. Koch, Michael (2006): Messunsicherheit in der Trinkwasseranalytik. Bundesgesundheitsblatt-Gesundheitsforschung-Gesundheitsschutz 10 49, 1027-1033. König, Andreas; Baumeister, Frank (2006): A microbial sensor for measuring Biochemical Oxygen Demand of nitrification and nitrification inhibitors. Biosensors and Bioassays Based on Microorganisms. K. Riedel, G. Kunze and K.H.R. Baronian. Kerala, India, Research Signpost: 87-104. Metzger, Jörg W. (2006): Organische Spurenstoffe im Wasserkreislauf - (K)ein Problem für das Trinkwasser? Begleitband der Vortragsreihe Stiftung für Lebensmittelsicherheit und Verbraucherschutz, 26-29. Metzger, J. und Scholz-Muramatsu, H. (2007): Mikrobiologische Charakterisierung der reduktiven Dechlorierung von chlorierten Ethenen und Ermittlung der Bedingungen für den vollständigen Abbau in-situ. Verbundprojekt: Untersuchungen zur Indikation von mikrobiellem LCKW-Abbau am Beispiel des Standortes Perleberg. Schlussbericht Forschungsvorhaben im Forschwerpunkt KORA, BMBF 02WN0372. Rienitz, Olaf; Schiel, Detlef; Güttler, Bernd; Koch, Michael; Borchers, Ulrich (2007): A convenient and economic approach to achieve SI-traceable reference values to be used in drinking-water interlaboratory comparisons. Accred Qual Assur - Springer Verlag 12, 615-622. Tebbe, Ch. C.; Freygang, M.; Scholz-Muramatsu, H. (2007): Untersuchungen zur Indikation von mikrobiellem LCKW-Abbau am Beispiel des Standortes Perleberg. Standortbeschreibung, Schadstoffspektrum und -Verteilung (Ausgangssituation). 3. BMBF-Statusseminar KORA, 27.09.2007, Stuttgart. 106 Tebbe, Ch. C.; Scholz-Muramatsu, H. (2007): Untersuchungen zur Indikation von mikrobiellem LCKW-Abbau am Beispiel des Standortes Perleberg. Molekulare und mikrobiologische Analysen zur Untersuchung des reduktiven LCKW Abbaus. 3. BMBF-Statusseminar KORA, 27.09.2007, Stuttgart. Tebbe, Ch. C.; Scholz-Muramatsu, H.; Vigelahn, L. (2007): Untersuchungen zur Indikation von mikrobiellem LCKW-Abbau am Beispiel des Standortes Perleberg. Stimulierung des reduktiven LCKW-Abbaus durch Melasse-Infiltration. 3. BMBF-Statusseminar KORA, 27.09.2007, Stuttgart. Tebbe Ch. C.; Dowideit K.; Miethling-Graff R.; Vigelahn L.; Freygang M.; Scholz-Muramatsu H. (2007): Untersuchungen zur Indikation von mikrobiellem LCKW-Abbau am Beispiel des Standortes Perleberg (1) Standortbeschreibung, (2) Molekulare und mikrobiologische Analysen zur Untersuchung des reduktiven LCKW Abbaus, (3) Stimulierung des reduktiven LCKW Abbaus durch Melasse-Infiltration. Poster 3. BMBF-Statusseminar KORA, 27.09.2007, Stuttgart. Vigelahn L.; Freygang M.; Scholz-Muramatsu H. (2006): Säulenversuche zur Bestimmung der Dechlorierungsrate in Bodenproben. In: DECHEMA, Forschungs- und Projektkoordination, Frankfurt-Main (Hrsg.), Kontrollierter natürlicher Rückhalt und Abbau von Schadstoffen bei der Sanierung kontaminierter Grundwässer und Böden (KORA), Statusseminar 2006. Zulian, Alessandra; Petronilli, Valeria; Bova, Sergio; Dabbeni-Sala, Federica; Cargnelli, Gabriella; Cavalli, Maurizio; Rennison, David; Stäb, Jessica; Laita, Olivia; Lee, Dong Jun; Brimble, Margaret A.; Hopkins, Brian; Bernardi, Paolo; Ricchelli, Fernanda (2007): Assessing the molecular basis for rat-selective induction of the mitochondrial permeability transition by norbormide. Biochimica est biophysica Acta (BBA) - Bioenergetics 1767(7), 980-988. Chair of Hydrochemistry and Hydrobiology Contact o. Prof. Dr. rer. nat. habil. Jörg W. Metzger Tel.: ++49 (0)711/685-63721 Fax: ++49 (0)711/685-63729 E-Mail: [email protected] Secretary´s office Dörte Hahn Tel.: ++49 (0)711/685-63721 Fax: ++49 (0)711/685-63729 E-Mail: [email protected] Hydrochemistry o. Prof. Dr. rer. nat. habil. Jörg W. Metzger Tel.: ++49 (0)711/685-63721 Fax: ++49 (0)711/685-63729 E-Mail: [email protected] Biology Dr.-Ing. Wolf-Rüdiger Müller, Akad. Oberrat Tel.: ++49 (0)711 685-65411 Fax: ++49 (0)711 685-63729 E-Mail: [email protected] 107 Chair of Hydrochemistry and Hydrobiology Hydrochemistry Research topics: • Environmental analysis • Examination of occurence and fate as well as risk assessment of environmentally relevant chemicals • Biosensors for the determination of inhibition of nitrification • Biological in-vitro test systems, for the determination of hormonal activity of environmental samples, i.e. E-SCREENAssay and YES-Assay • Quality Assurance in Analytical Chemistry We have a nose for it In the hydrochemistry department the main subjects dealt with are environmental chemistry and, in particular, environmental analyses. Some of the research work here deals with the question of the volume of medicines entering domestic wastewater, how these are degraded in a treatment plant and the influence they have on aquatic communities. We are especially interested in the volume of such chemicals retained in treatment plants, either by degradation processes in the various purification stages or by enrichment in the sewage sludge. As a consequence, we also investigate water bodies, above all with the question of whether and to what extent chemicals in the water are ingested by aquatic organisms (e.g. fish), are enriched within their bodies, or degraded or altered by their metabolism. A whole series of trace analysis methods are available for these investigations; these methods were, in part, specially developed in the hydrochemistry department. We are also engaged in the monitoring of treatment plants with regard to substances in the water that can interfere with components of the biological purification stages. A specially developed bio-sensor test system can be implemented for this purpose; it is suitable for recognition of nitrification-inhibiting compounds. Moreover, we also deal with external quality assurance in water chemistry laboratories and competence assessments. In the fields of drinking water, wastewater and groundwater analysis, this involves proficiency tests for laboratories, which are in part obligatory for state recognition of the laboratories. In addition, further water chemistry problems in the fields mentioned are investigated. 108 Hydrochemistry CH Projects Elimination of pharmaceuticals and bacteria from hospital waste water in a membrane bioreactor Pathogens, resistant bacteria, pharmaceutical active substances and endocrine disrupting substances (EDS) may enter municipal WWTPs via wastewater of hospitals. Some of these substances which are hardly removable in the WWTPs are discharged in the receiving water. A rotation disk filter, which treats directly the hospital waste water, was developed at the Instítute for Interfacial Engineering (university of Stuttgart, IGVT) and the Fraunhofer Institute for Interfacial Engineering and Biotechnology IGB. The system improves the removal of pathogens and pharmaceuticals using the technology of a membrane bio reactor. The cooperation of IGVT, IGB and the Institute of Sanitary Engineering, Water Quality and Solid Waste Management will investigate the fate of pharmaceuticals in the filter system which will be installed in the “Robert-Bosch”-hospital in Stuttgart. Financing institution: Willy-Hager-Stiftung Project partner: Fraunhofer Institut für Grenzflächen- und Bioverfahrenstechnik (IGB), Stuttgart Duration: 2005/2006 Contact: Dr. Bertram Kuch Determination of organic contaminants in composts and digestates in the state of Baden-Württemberg, South-West-Germany the range of 1200 - 3500 µg/kg d.w., PCB were found in concentrations between 20 and 35 µg/kg d.w.. For both classes of substances as a tendency lower concentrations were found in green compost. Seasonal variations were observed for PAH, nonylphenols and DDE, a stable degradation product of DDT. Financing institution: Programm Lebensgrundlage Umwelt und ihre Sicherung (BWPLUS), Förderkennzeichen BWR 24026, Duration: 10/2005 – 09/2006 Contact: Prof. Dr. Jörg W. Metzger, Prof. Dr. Martin Kranert (Lehrstuhl Abfallwirtschaft und Abluft), Dr. Klaus Fischer (Abt. SIA), Dr. Bertram Kuch. Comparison of the cleaning efficiency of sand filtration and ultrafiltration by the example of a municipal wastewater treatment plant located on the “Schwäbische Alb” The small WWTP (2300 p.e) investigated in this project discharges its purificated waste water directly into the soil. The location near a water protection zone requires advanced wastewater treatment steps. To compare the effiency of different techniques the purificated wastewater is treated parallel with large-scaled sand filtration units and ultrafiltration membranes. Downstream the UF effluent additionally two activated carbon filtration units (granulated AC) are installed. The results for some of the examined parameters available up to now show an efficient reduction (COD, Ntot, Ptot, organic micropollutants, hygienic parameters). Financing institution: Numerous investigations prove the occurrence of organic pollutants in sewage sludge. Therefore the agricultural use of sewage sludge is controversially discussed. For the final assessment of possible risks connected to the agricultural use of compost and digestate the current knowledge is not sufficient. Gemeinde Merklingen, Regierungspräsidium Tübingen, Ministerium für Umwelt und Verkehr BadenWürttemberg In this monitoring study the output material of 16 composting plants in Baden-Wuerttemberg was analysed for various organic trace pollutants such as polychlorinated biphenyls (PCB), polycyclic aromatic hydrocarbons (PAH), polybrominated flame retardants and nonylphenols, which are a class of endocrine disrupting compounds. The concentrations of PAH were in Contact: Project partner: Gemeinde Merklingen, Ingenieurbüro Dr.-Ing. Jedele und Partner GmbH, Stuttgart Dr. Bertram Kuch 109 Chair of Hydrochemistry and Hydrobiology AQS Baden-Württemberg (analytical quality control Baden-Württemberg) The Institute for Sanitary Engineering, Water Quality and Solid Waste Management is one of the largest proficiency test (PT) provider for chemical water analysis in Europe. These Pts are organized on behalf of the ministry of environment and the ministry of nutrition and rural affairs in Baden-Württemberg. Three PT rounds for the analysis drinking water and usually two rounds for analysis of waste water are conducted per year for officially notified laboratories in Germany. Besides that one PT round for rapid test analysis in waster treatment plants and one round in the framework of a large groundwater monitoring programme are organized. Client: Umweltministerium Baden-Württemberg, Ministerium für Ernährung und Ländlichen Raum BadenWürttemberg Project manager: o. Prof. Dr. rer. nat. habil. Jörg W. Metzger Dr.-Ing. Michael Koch PT manager: Dr.-Ing. Michael Koch Secretary´s office: Heidemarie Sanwald Further informations: http://www.aqsbw.de The actual programme can be found on http://www. aqsbw.de. Chemicals used for the production of PT samples 110 High-precision balances for the net weight of chemicals and solutions Hydrochemistry CH Sample preparation for the proficiency test (PT) High-grade steel vessel (2,1 m3) for pasteurisation of waste water, drinking water and ground water Stock solutions for the preparation of PT samples 111 Chair of Hydrochemistry and Hydrobiology Master- and Diploma Thesis Study on a new way to realize a solid substrate framework for denitrification Pongtawat Wattana (2007) Master Thesis Long-term stability and management of iron treated soil contaminated with chromated c o p p e r arsenate (CCA) Untersuchung zur Extraktion von Arsenspezies aus Algen / Investigations of the extraction of arsenic species from algae Ludger Schrempf (2006) Diploma Thesis Untersuchung der Belastung von Böden mit persistenten organischen Spurenstoffen / Analyses of persistent organic pollutants in soil Die Testung mikrobieller Biosensoren für die Bestimmung nitrikationshemmender Substanzen und Abwasserproben einer Industriekläranlage im Vergleich zu dem Verfahren nach DIN EN ISO 9509 / Testing of microbial biosensors for the determination of nitrification inhibiting substances and waste water samples from an industrial waste water treatment plant in comparison with the methods according to DIN EN ISO 9509 Jessica Stäb (2007) Diploma Thesis Bin Huang (2006) Diploma Thesis Untersuchung zur Bestimmung von polycyclischen aromatischen Kohlenwasserstoffen (PAK) mittels GC/MS / Investigations on the determination of polycyclic aromatic hydrocarbons (PAH) using GC/MS Eintrag und Abbauverhalten bisher wenig untersuchter Pharmazeutika in der aquatischenUmwelt / Input and biodegradability of less investigated pharmaceuticals in the aquatic environment Susanne Görgens (2007) Diploma Thesis Christoph Trautwein (2006) Diploma Thesis Ermittlung des Vorkommens und der Elimination von estrogen aktiven Substanzen im Lehr- und Forschungsklärwerk Stuttgart-Büsnau - Bewertung des E-Screen-Assays als in vitro-Testverfahren / Determination of occurance and elimination of estrogenic substances in the research treatment plant Stuttgart-Büsnau – evaluation of the E-screen-assay as in-vitro-test Bestimmung von Moschusduftstoffen in Körperpflegeprodukten und Bedarfsgegenständen mittels Gaschromatographie-Massenspektrometrie (GC-MS) / Determination of musks in body care products and articles of daily use using gas chromatography – mass spectrometry (GC/MS) Eva Staudigl (2007) Master Thesis Cornelia Klaus (2007) Diploma Thesis 112 Thilo Kunst (2006) Diploma Thesis Hydrochemistry CH Contact o. Prof. Dr. rer. nat. habil. Jörg W. Metzger Dipl.-Chem. Jessica Stäb Tel: ++49 (0) 711/685-63721 Fax: ++49 (0) 711/685-63729 E-Mail: [email protected] Tel: ++49 (0) 711/685-63727 Fax: ++49 (0) 711/685-67809 E-Mail: [email protected] Christina Weber Secretary´s office Dörte Hahn (Hydrochemie) Tel: ++49 (0) 711/685-63720 Fax: ++49 (0) 711/685-67809 E-Mail: [email protected] Tel: ++49 (0) 711/685-63721 Fax: ++49 (0) 711/685-63729 E-Mail: [email protected] Laboratory Heidemarie Sanwald (AQS) Chemical technical employee Tel: ++49 (0) 711/685-65446 Fax: ++49 (0) 711/685-67809 E-Mail: [email protected] Michael Braun (Chemo technician) Tel: ++49 (0) 711/685-65446 Maria Gebauer (CTA) Lab- and Project Management AQS Tel: ++49 (0) 711/685-65454 Dr.-Ing. Michael Koch Gertrud Joas (CTA) Tel: ++49 (0) 711/685-65444 Fax: ++49 (0) 711/685-67809 E-Mail: [email protected] Tel: ++49 (0) 711/685-65453 Andrea Kern (LTA) Research Assistants Tel: ++49 (0) 711/685-63727 Dr.-Ing. Frank Baumeister Cornelia Orth (Dipl.-Ing., FH) Tel: ++49 (0) 711/685-65442 Fax: ++49 (0) 711/685-67809 E-Mail: [email protected] Tel: ++49 (0) 711/685-65454 Dr. rer. nat. Bertram Kuch Tel: ++49 (0) 711/685-65454 Ellen Raith-Bausch (Chemo technician) Tel: ++49 (0) 711/685-65443 Fax: ++49 (0) 711/685-67809 E-Mail: [email protected] Dipl.-Biol. Biljana Maric Tel: ++49 (0) 711/685-65447 Fax: ++49 (0) 711/685-67809 E-Mail: [email protected] Dipl.-Ing. Jörg Alexander Pfeiffer Tel: ++49 (0) 711/685-63720 Fax: ++49 (0) 711/685-67809 E-Mail: [email protected] 113 Chair of Hydrochemistry and Hydrobiology Biology Research topics: • Biological degradation and risk assessment of pollutants, chemicals, and organic solid substrates as well as polymers • Development of specific test equipments • Low-tech effective biological water treatment with biodegradable polymers • Biological remediation of organic pollutants from contaminated aquifers The biology section deals with methods for investigation of the biological degradation of pollutants, chemicals, solid organic substances and polymers in water and the soil. The focal points of our work include remediation methods and measuring and verification methods. In many cases of biological degradation, a thorough verification of the fate of substances and their intermediate products is required, in order to address the hazard of accumulation in the environment. To be able to classify a substance as “completely degradable“, its conversion to mineralization products must be proven. This is why the Sapromat, designed at the institute, was enhanced to facilitate the verification of complete, aerobic, biological degradation of an organic substance to carbon dioxide, water and biomass. Further inhouse developments, the “Denimat“ and the “Methanomat“, allow automated degradation investigations under anoxic and anaerobic conditions. Typical problems involved with drinking water supplies in rural areas include the high nitrate and pesticide content in groundwater. Using our invention, which utilizes biodegradable polymers as carrier substances and as a source of carbon for a single-stage process in water treatment, it is possible to achieve simultaneous biological nitrate and pollutant elimination in drinking water treatment, in wastewater treatment, and in fish production and aquariums. Numerous groundwater reservoirs in Germany are polluted by industrial pollutants. Chlorinated solvents are among the most widespread substances. Investigations aimed at the remediation of contaminated areas are carried out within the context of a programme sponsored by the Federal Ministry of Education and Research. The aim of this project is to gain an understanding of the fundamentals involved in the participation of microorganisms in the conversion of volatile organic hydrocarbons. 114 Biology BIO Projects Microbiological characterization of the reductive dechlorination of volatile chlorinated hydrocarbons and investigation of optimum conditions for complete in-situ attenuation, within the BMBF funding priority “KORA, Retention and degradation processes to reduce contaminants in groundwater and soil” thematic network 3, chemical industry, metal processing. The volatile chlorinated hydrocarbon contaminated site “Perleberg”, Northern Germany is considered as example to identify the processes and the environmental conditions, which control and limit a complete reductive dechlorination of the chlorinated ethenes in the aquifer. In laboratory experiments (microcosm studies, column experiments with undisturbed aquifer samples under conditions close to those in-situ) as well as in the field the spreading of the dechlorinating bacteria and the dechlorinating processes are to be determined in association with the environmental conditions. Financing institution: German Ferderal Ministry of Education and Research (BMBF) Project partner: 1. Bundesforschungsanstalt für Landwirtschaft, Institut für Agrarökologie, „FAL”, Projektleiter Dr. C. Tebbe 2. Brandenburgische Bodengesellschaft für Grundstücksverwaltung und –verwertung mbH, Projektleiterin Dipl.-Ing. M. Freygang Duration: 07/2002 - 10/2006 Contact: Dr. rer.nat. Heidrun Scholz-Muramatsu Schema of reductive dechlorination of tetrachlorethene Dechlororespiration for remediation of groundwater 115 Chair of Hydrochemistry and Hydrobiology In-situ ultrasound cleaning for small membrane systems in drinking water treatment The objective of this study was the development of a new process for the in-situ cleaning of fouled membranes in drinking water treatment systems with the help of ultrasound. The application of this method could reduce chemical cleaning and be suitable for small decentralized drinking water treatment units. Occurrence of membrane fouling due to organic and inorganic pollutants generally results in decreasing membrane performance combined with increasing resistance. For conventional cleaning processes the membrane operation has to be interrupted, chemicals are added and large amounts of water are used for backwashing. This is not acceptable for small decentralized treatment units. In this study different combinations of ultrasound cleaning and membrane filtration were examined. Flat membranes as well as tubular membranes were applied. The system, which appeared to be best suitable for upscaling, was used for the development of an ultrafiltration module with ultrasound in a „functional model“ and tested in long-term experiments in comparison with a reference module without ultrasound. This concept was realized and tested both with ceramic and polymer membranes. These experiments resulted in an ultrasound enhanced backwashing ultrafiltration process. However in all experiments with ceramic membranes damages on the membrane surfaces were observed, which were due to the effect of ultrasonic cavitation. An automated membrane cleaning by means of ultrasound appears feasible and could be used in an autarkic operating, decentralized small membrane system. However the destructive cavitation effects of the ultrasound have to be avoided. To overcome these problems different possibilities were examined theoretically and practically, e.g. higher fre-quencies of the ultrasound and protection of the ceramic layers by coatings. However such solutions would not be marketable due to high costs, despite partial successful results. With this study a basis for optimization approaches is available for future product developments. 116 Semi-technical pilot plant for long-term experiments with the ultrasound membrane module Financing institution: German Federal Ministry of Economics and Technology (“InnoNet”) Project partner: 1.Fraunhofer-Institut für Solare Energie Systeme, Freiburg 2.Grünbeck Wasseraufbereitung GmbH, Höchstädt/ Donau 3.Dr. Hielscher GmbH, Berlin 4.ItN Nanovation GmbH, Saarbrücken 5.Biofilm Center Universität Duisburg-Essen Duration: 07/2003 – 12/2006 Contact: Dr. Angela Boley Dr.-Ing. Wolf-Rüdiger Müller Biology BIO Joint project: Development of Novel Processes for Simultaneous Elimination of Organic Pollutants and Nitrate from Drinking Water by Means of Biodegradable Solid Substrates Even with many legislative regulations not everywhere efforts have been successful to diminish concentrations of Nitrate and Pesticides in groundwater. The aim of this project is the development of a simple and costeffective combined process which allows not only the biological removal of Nitrate but also Pesticides. In this technology we use biodegradable polymers (BDP) as substrates for the heterotrophic denitrification process, e.g. PHB (Poly-Hydroxy-Butyric Acid) or PCL (Poly-εCaprolactone). The water insoluble polymer granules act as growth surface for microorganisms and at the same time as organic substrate which can be activated via bacterial exoenzymes and on this way being used for denitrification. In addition the polymers perform as sorbents for the dissolved organic contaminants, e.g. pesticides. In the scope of the project different technical realizations in form of reactor configurations and reactor types are being examined. The performance of different available biodegradable polymers is tested in advance with long term biological test processes thus complementing the pilot testing with semi-technical reactors. As this process is aimed to be applied in drinking water treatment all aspects of the use of BDPs shall be examined. This means between others the examination of the „leachate“ products of the biodegradable polymers, the products which occur during the anoxic bi- odegradation step and of course also the examination of the biocenosis in the reactors. A check of potentially pathogenic bacteria will be carried out. A long-term objective of the project is the authorization of polymers according to the „List of Treatment Substances and Disinfection Processes“ as per § 11 of the German Drinking Water Ordinance (TrinkwV 2001) and the treatment processes connected with. This List is maintained at the Federal Environment Agency on behalf of the Federal Ministry of Health, Berlin. Financing institution: Projektträger: Forschungszentrum Karlsruhe - Bereich Wassertechnologie und Entsorgung Representing the German Ministry of Education and Research (BMBF) Project partner: 1. Forschungszentrum Karlsruhe (FZKA) 2. Technologiezentrum Wasser, Karlsruhe (TZW) 3. Universität Karlsruhe, Engler-Bunte-Institut, Lehrstuhl für Wasserchemie(UKA) 4. Martin-Luther-Universität Halle-Wittenberg (MLU) 5. Firma Nordic Water GmbH 6. Firma Formtechnik in Südbaden GmbH & Co. KG 7. Tsinghua University, Institute for Nuclear Energy Technology Beijing Duration: 10/2006 - 09/2009 Contact: Dr. Angela Boley Dr.-Ing. Wolf-Rüdiger Müller Dipl.-Ing. Martin Kieninger Pilot plant for the denitrification and pesticide removal with biodegradable polymers „Dynasand-Reactor“ (Nordic Water) „Roto-Bio-Reactor“ (Formtechnik in Südbaden) 117 Chair of Hydrochemistry and Hydrobiology Woche der Umwelt 2007, Schloss Bellevue, Berlin The „Woche der Umwelt“ („Week of Environment“) has been organized for the third time by the German Foundation Environment DBU (Deutsche Bundesstiftung Umwelt) under the patronage of the German President Horst Köhler. A steering committee selected promising projects in the area Environmental Technology, Climate Protection, Water Pollution Control and Soil Conservation to be presented. Our exhibit was particular in that sense that we presented a biologically fully active pilot, in which we demonstrated the use of a biodegradable polymer PCL (= Poly-ε-Caprolactone) for denitrification purposes (biological Nitrate Elimination) in water treatment, see Scheme. The effluent of the fixed bed reactor is conducted through a 2nd spectrometer back to the complete mixed tank. With the flow rate and the difference of concentrations measured by the spectrometers the volumetric denitrification performance of the reactor can be determined. In order to provide the Nitrate consumed, a HNO3solution is dosed via a pH-control unit. The complete mixed tank has to be aerated to remove the CO2 produced. Financing institution: Financial means of the Institute, within the project of the Federal Ministry of Education and Research (BMBF, Berlin), see above Contact: Dr. Angela Boley Dipl.-Ing. Martin Kieninger Dr.-Ing. Wolf-Rüdiger Müller The water is pumped from the complete mixed tank via a UV-spectrometer unit into the fixed bed reactor with PCL-granules. Nitrate is reduced via Nitrite to Nitrogen gas. In addition carbon dioxide and biomass is formed, the pH will increase. Scheme of a Pilot „ISWA-Denitrification Unit” in Batch Operation Mode 118 Biology BIO Independent Studies, Master- and Diploma Thesis An overview of the techniques to clean membranes used in micro- and ultrafiltration for drinking and wastewater treatment. Study on a new process with a solid substrate as a carbon source for denitrification. Kenan Güney (WAREM) (2006) Tutor: Dr. Angela Boley Supervisor: Dr.-Ing. Wolf-Rüdiger Müller Independent Study Pongtawat Wattana (WASTE) (2007) Tutor: Dr. Angela Boley Supervisor: Prof. Dr. rer. nat. habil. Jörg W. Metzger, Dr.-Ing. Wolf-Rüdiger Müller Master Thesis Comparative study of ultrasonic cleaning method on microfiltration / ultrafiltration membranes. A general research on ultrasonic cleaning of ceramic and polymer membranes. Kumar Narasimhan (WASTE) (2006) Tutor: Dr. Angela Boley Supervisor: Dr.-Ing. Wolf-Rüdiger Müller Independent Study Kumar Narasimhan (WASTE) (2007) Tutor: Dr. Angela Boley Supervisor: Dr.-Ing. Wolf-Rüdiger Müller, Dr.-Ing. Jörg Krampe Master Thesis Theoretical and experimental simulation of the production of NO2-, N2O and N2 in the denitrification process with the use of a new device for the determination of N2O and CO2. Ghulam Murshid (WASTE) (2007) Tutors: Dr. Angela Boley, Irene Frommert Supervisor: Dr.-Ing. Wolf-Rüdiger Müller Independent Study Aspects of the use of the zeolite clinoptilolite for ammonia removal in the treatment of polluted groundwater recovery. Ceren Balkanay (WASTE) (2007) Tutor: Dr.-Ing. Wolf-Rüdiger Müller, Irene Frommert Supervisor: Dr.-Ing. Wolf-Rüdiger Müller Independent Study Aspects of PHB-production in a WWTP with raw WW and activated sludge. Analytical determination and characterization of potential metabolites generated by the biodegradation of Poly(ε-caprolactone) under denitrifying conditions. Jennifer Schmeier, (WASTE) ( 2007) Tutors: Dr. Angela Boley, Dr. Bertram Kuch Supervisor: Prof. Dr. rer. nat. habil. Jörg W. Metzger, Dr.-Ing. Wolf-Rüdiger Müller Master Thesis Remediation of an existing groundwater purification plant to guarantee the ammonia-elimination Wengchen Yan (Umweltschutztechnik) (2007) Tutor: Dr.-Ing. Wolf-Rüdiger Müller Supervisor: Dr.-Ing. Uwe Menzel, Dr.-Ing. Wolf-Rüdiger Müller Diploma Thesis Iosif Mariakakis (WASTE) (2007) Tutors: Irene Frommert, Dr.-Ing. Wolf-Rüdiger Müller Supervisor: Dr.-Ing. Wolf-Rüdiger Müller Independent Study Study on a new approach for denitrification with solid substrates. Eva Mia Siska, (WAREM) (2006) Tutor: Dr. Angela Boley Supervisor: Prof. Dr. rer. nat. habil. Jörg W. Metzger, Dr.-Ing. Wolf-Rüdiger Müller Master Thesis 119 Chair of Hydrochemistry and Hydrobiology Co-Supervision Diploma- und Master Thesis An evaluation into the performance of an anaerobic reactor from a wastewater treatment plant in Knittlingen. Erika Lothes (WAREM) (2007) Tutors: Dipl.-Ing. Marius Mohr, Dr.-Ing. Werner Sternad, Fraunhofer Institut für Grenzflaechen- und Bioverfahrenstechnik Supervisor: Prof. Dr.-Ing. Herwig Brunner, Dr.-Ing. Wolf-Rüdiger Müller Master Thesis An evaluation of high load anaerobic digestion of primary sludge produced in a semi-centralized wastewater treatment plant in relation with the concept DEUS 21. Ceren Balkanay (WASTE) (2007) Tutors: Dipl.-Ing. Marius Mohr, Dr.-Ing. Werner Sternad, Fraunhofer Institut für Grenzflaechen- und Bioverfahrenstechnik Supervisor: Prof. Dr.-Ing. Herwig Brunner, Dr.-Ing. Wolf-Rüdiger Müller Master Thesis Co-Report Ph.D. Thesis Développement de nouvelles techniques de détermination des pesticides et contribution à la réduction de leur impact sur les eaux par utilisation des Substances Organiques Naturelles (S.O.N.) Hicham EL BAKOURI, Thèse de Doctorat, 21.01.2006 Département de Génie Chimique de la Faculté des Sciences et Techniques, Université Abdelmalek Essaadi, Tanger (Maroc). Président de Jury: Dr.-Ing. Wolf-Rüdiger Müller Co-Report Ph.D. Thesis 120 The influence of microbial processes on the H2content and the highly volatile chlorinated hydrocarbon compounds in Fe0-Reaction sheet pile walls. Christina Melanie Haberer (Umweltschutztechnik) (2007) Supervisor: Prof. Dr. rer. nat. habil. Karl-Heinrich Engesser, Dr. Andreas Tiehm, DVGW Technologiezentrum Wasser, Karlsruhe, Dr.-Ing. Wolf-Rüdiger Müller Diploma Thesis Biology BIO Contact Dr.-Ing. Wolf-Rüdiger Müller, Akad. Oberrat Tel.: ++49 (0)711 685 65411 Fax: ++49 (0)711 685 63729 E-Mail: [email protected] Research Assistants Dr. rer. nat. Angela Boley Tel.: ++49 (0)711 685 65441 Fax: ++49 (0)711 685 63729 E-Mail: [email protected] Dr. rer. nat. Heidrun Scholz-Muramatsu Tel.: ++49 (0)711 685 65474 Fax: ++49 (0)711 685 63729 E-Mail: [email protected] Dipl.-Ing. Martin Kieninger Tel.: ++49 (0)711 685 63733 Fax: ++49 (0)711 685 63729 E-Mail: [email protected] 121 Institute for Sanitary Engineering, Water Quality and Solid Waste Management Sewage Treatment Plant for Research and Education The facilities of the LFKW play an important part in the traditionally practice-oriented education at our institute. Within the scope of practical training measures, the assistance in research projects and working on Master’s theses, the students are provided with plenty of opportunities to become familiar with the details of the equipment and the operation of a highly mechanized sewage treatment plant. The LFKW is operated under real conditions: its primary task is the purification of the wastewater from the university campus in Stuttgart-Vaihingen and from the nearby Büsnau district of which the total daily volume is about 2.000 cubic metres. In order to comply with the strong official discharge regulations and to provide opportunities for research at the same time, the LFKW has a multitrack purification system: all process steps required for advanced wastewater treatment consist of at least two parallel units. In this way separate plant components can be used at any time for fullscale research, independent of the other units and without any adverse effects on the quality of the final effluent. Additional experimental areas inside and outside of a large two-storey hall offer a wide variety of options for research work and individually contracted investigations on a semi-technical scale. The LFKW also offers its services to technical companies, operators of municipal environmental facilities and engineer’s offices: from the testing of measuring devices, chemical aids etc. under practical conditions through the manufacturing of laboratory test equipment to the leasing of complete pilot plants for the treatment of wastewater, sludge and exhaust air. 122 Sewage Treatment Plant for Research and Education LFKW 123 Institute for Sanitary Engineering, Water Quality and Solid Waste Management 124 Sewage Treatment Plant for Research and Education LFKW 125 Institute for Sanitary Engineering, Water Quality and Solid Waste Management 126 Sewage Treatment Plant for Research and Education LFKW 127 Institute for Sanitary Engineering, Water Quality and Solid Waste Management 128 Sewage Treatment Plant for Research and Education LFKW 129 Institute for Sanitary Engineering, Water Quality and Solid Waste Management 130 Sewage Treatment Plant for Research and Education LFKW 131 Institute for Sanitary Engineering, Water Quality and Solid Waste Management 132 Sewage Treatment Plant for Research and Education LFKW 133 Institute for Sanitary Engineering, Water Quality and Solid Waste Management 134 Sewage Treatment Plant for Research and Education LFKW 135 Institute for Sanitary Engineering, Water Quality and Solid Waste Management 136 Sewage Treatment Plant for Research and Education LFKW Contact Dr.-Ing. Manfred Roth Tel: ++49 (0)711/685-63724 Fax:++49 (0)711/685-67637 E-Mail: [email protected] 137 Imprint Publisher: Institute for Sanitary Engineering, Water Quality and Solid Waste Management Bandtäle 2 70569 Stuttgart Germany www.iswa.uni-stuttgart.de/index.en.html Cover: Solutioncube GmbH Conception: Dipl.-Geol. Detlef Clauß M.A. Constanze Sanwald © 2008 138 Universität Stuttgart Universität Stuttgart Universität Stuttgart Institute report 2006-2007 Chair of Sanitary Engineering and Water Quality Management o. Prof. Dr.-Ing. Ulrich Rott Tel.: ++49 (0) 711/685-63711 Water Quality Management and Water Supply | WGW Dipl.-Ing. Ralf Minke Tel.: ++49 (0) 711/685-65423 Industrial Water and Wastewater Technology | IWT Solid Waste | SIA Institute for Sanitary Engineering, Water Quality and Solid Waste Management Dr.-Ing. Klaus Fischer Tel.: ++49 (0) 711/685-65427 Hazardous Waste and Contaminated Sites | SOA Prof. Dr.-Ing. Erwin Thomanetz Tel.: ++49 (0) 711/685-65438 | ALR Measuring in Air Pollution Control | TAL Dr.-Ing. Martin Reiser Tel.: ++49 (0) 711/685-65416 | AWT Dr.-Ing. Uwe Menzel Tel.: ++49 (0) 711/685-65417 o. Prof. Dr.-Ing. Heidrun Steinmetz Tel.: ++49 (0) 711/685-63723 Hydrochemistry | CH o. Prof. Dr. rer. nat. habil. Jörg W. Metzger . Tel.: ++49 (0) 711/685-63721 Biology | BIO Wastewater Technology | AWT Dr.-Ing. Jörg Krampe Tel.: ++49 (0) 711/685-65420 Chair of Waste Management and Emissions Dr.-Ing. Wolf-Rüdiger Müller Tel.: ++49 (0) 711/685-65411 Sewage Treatment Plant for Research and Education | LFKW Dr.-Ing. Manfred Roth Tel.: ++49 (0) 711/685-63724 o. Prof. Dr.-Ing. Martin Kranert Tel.: ++49 (0) 711/685-65500 Administrative Office Biological Air Purification | ALR Dipl.-Ing. Stephan Mollweide Tel.: ++49 (0) 711/685-63713 Prof. Dr. rer. nat. Karl-Heinrich Engesser . Tel.: ++49 (0) 711/685-63734 | BIO Bandtäle 2 70569 Stuttgart Germany Tel.: ++49 (0) 711/685-63711 Fax: ++49 (0) 711/685-63729 www.iswa.uni-stuttgart.de Institute report 2006-2007 Chair of Sanitary Engineering and Waterrecycling Chair of Hydrochemistry and Hydrobiology | CH | IWT | LFKW | SIA | SOA | TAL | WGW