MSDS Sheet

Transcription

MSDS Sheet

K- TSHK
Safety Data Sheet
according to Regulation (EC) No. 453/2010
Date of issue: 29/05/2014
Revision date: 29/05/2014
Supersedes: 29/05/2014
Version: 1
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1.
Product identifier
Product form
: Mixture
Name
: K- TSHK Bottle 1
1.2.
Relevant identified uses of the substance or mixture and uses advised against
1.2.1.
Relevant identified uses
Industrial/Professional use spec
: Industrial
For professional use only
Use of the substance/mixture
: Use as laboratory reagent
1.2.2.
Uses advised against
No additional information available
1.3.
Details of the supplier of the safety data sheet
Megazyme International Ireland
Bray Business Park
Bray - Ireland
T 1 286 1220 - F 1 286 1264
[email protected] - http://secure.megazyme.com/Homepage.aspx
1.4.
Emergency telephone number
Emergency number
Country
IRELAND (REPUBLIC
OF)
UNITED KINGDOM
: +353-1-2861220
Official advisory body
National Poisons Information Centre
Beaumont Hospital
National Poisons Information Service
(Birmingham Centre)
Address
Beaumont Hospital Beaumont Road
9 Dublin
Dudley Road
B18 7QH Birmingham
Emergency number
: +353 1 8379964
0870 600 6266 (UK only)
City Hospital
SECTION 2: Hazards identification
2.1.
Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Resp. Sens. 1 H334
Full text of H-phrases: see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
Xn; R42
Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
2.2.
Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP)
:
GHS08
Signal word (CLP)
:
Danger
Hazardous ingredients
:
alpha-amylase
Hazard statements (CLP)
:
H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled
Precautionary statements (CLP)
:
P261 - Avoid breathing Vapour
P285 - In case of inadequate ventilation wear respiratory protection
P304+P341 - IF INHALED: If breathing is difficult, remove to fresh air and keep at rest in a
position comfortable for breathing
P342+P311 - If experiencing respiratory symptoms: Call a POISON CENTRE or doctor/physician
P501A - Dispose of this material and its container at hazardous or special waste collection point.
29/05/2014
EN (English)
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K- TSHK Bottle 1
Safety Data Sheet
2.3.
Other hazards
SECTION 3: Composition/information on ingredients
3.1.
Substances
Not applicable
3.2.
Mixture
Name
Product identifier
%
Classification according to
Directive 67/548/EEC
alpha-amylase
(CAS No) 9000-90-2
(EC no) 232-565-6
(EC index no) 647-015-00-4
1-2
Xn; R42
Name
Product identifier
%
Regulation (EC) No.
1272/2008 [CLP]
alpha-amylase
(CAS No) 9000-90-2
(EC no) 232-565-6
(EC index no) 647-015-00-4
1-2
Resp. Sens. 1, H334
Full text of R-, H- and EUH-phrases: see section 16
SECTION 4: First aid measures
4.1.
Description of first aid measures
First-aid measures general
: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice
(show the label where possible).
First-aid measures after inhalation
: If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for
breathing. If experiencing respiratory symptoms: Call a POISON CENTRE or doctor/physician.
First-aid measures after skin contact
: Remove affected clothing and wash all exposed skin area with mild soap and water, followed by
warm water rinse.
First-aid measures after eye contact
: Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness
persist.
First-aid measures after ingestion
: Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.
4.2.
Most important symptoms and effects, both acute and delayed
Symptoms/injuries after inhalation
4.3.
: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
Indication of any immediate medical attention and special treatment needed
SECTION 5: Firefighting measures
5.1.
Extinguishing media
Suitable extinguishing media
: Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media
: Do not use a heavy water stream.
5.2.
Special hazards arising from the substance or mixture
5.3.
Advice for firefighters
Firefighting instructions
: Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Avoid fire-fighting water enteing the environment.
Protection during firefighting
: Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1.
Personal precautions, protective equipment and emergency procedures
6.1.1.
For non-emergency personnel
Emergency procedures
6.1.2.
: Evacuate unnecessary personnel.
For emergency responders
Protective equipment
: Equip cleanup crew with proper protection.
: Ventilate area.
6.2.
Environmental precautions
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3.
Methods and material for containment and cleaning up
Methods for cleaning up
29/05/2014
: Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect
spillage. Store aways from other materials.
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K- TSHK Bottle 1
Safety Data Sheet
6.4.
Reference to other sections
See Heading 8. Exposure controls and personal protection.
SECTION 7: Handling and storage
7.1.
Precautions for safe handling
7.2.
: Wash hands and other exposed areas with mild soap and water before eating, drinking or
smoking and when leaving work. Provide good ventilation in process area to prevent formation of
vapour. Avoid breathing dust/fume/gas/mist/vapours/spray.
Conditions for safe storage, including any incompatibilities
Storage conditions
: Keep only in the original container in a cool, well ventilated place away from : Keep container
closed when not in use.
Incompatible materials
: Sources of ignition. Direct sunlight.
7.3.
Specific end use(s)
SECTION 8: Exposure controls/personal protection
8.1.
Control parameters
8.2.
Exposure controls
Personal protective equipment
: Avoid all unnecessary exposure.
Hand protection
: Wear protective gloves.
Eye protection
: Chemical goggles or safety glasses.
Respiratory protection
: In case of inadequate ventilation wear respiratory protection.
Other information
: Do not eat, drink or smoke during use.
SECTION 9: Physical and chemical properties
9.1.
Information on basic physical and chemical properties
Physical state
: Liquid
Colour
: Colourless.
Odour
: characteristic.
Odour threshold
: No data available
pH
: No data available
Relative evaporation rate (butylacetate=1)
: No data available
Melting point
: No data available
Freezing point
: No data available
Boiling point
: No data available
Flash point
: No data available
Self ignition temperature
: No data available
Decomposition temperature
: No data available
Flammability (solid, gas)
: No data available
Vapour pressure
: No data available
Relative vapour density at 20 °C
: No data available
Relative density
: No data available
Solubility
: No data available
Log Pow
: No data available
Log Kow
: No data available
Viscosity, kinematic
: No data available
Viscosity, dynamic
: No data available
Explosive properties
: No data available
Oxidising properties
: No data available
Explosive limits
: No data available
9.2.
Other information
SECTION 10: Stability and reactivity
10.1.
Reactivity
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EN (English)
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K- TSHK Bottle 1
Safety Data Sheet
10.2.
Chemical stability
Not established.
10.3.
Possibility of hazardous reactions
Not established.
10.4.
Conditions to avoid
Direct sunlight. Extremely high or low temperatures.
10.5.
Strong bases.
10.6.
Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide.
SECTION 11: Toxicological information
11.1.
Information on toxicological effects
Acute toxicity
alpha-amylase (9000-90-2)
LD50 oral rat
: Not classified
> 7500 mg/kg (Rat)
Skin corrosion/irritation
: Not classified
Serious eye damage/irritation
: Not classified
Respiratory or skin sensitisation
Germ cell mutagenicity
: Not classified
Carcinogenicity
: Not classified
Based on available data, the classification criteria are not met
May cause allergy or asthma symptoms or breathing difficulties if inhaled
Reproductive toxicity
: Not classified
Specific target organ toxicity (single exposure)
: Not classified
Specific target organ toxicity (repeated exposure)
: Not classified
Aspiration hazard
: Not classified
Potential Adverse human health effects and
symptoms
: Based on available data, the classification criteria are not met.
SECTION 12: Ecological information
12.1.
Toxicity
LC50 fish 1
EC50 Daphnia 1
12.2.
> 100 mg/l (Pisces; SOLUTION <50%)
> 100 mg/l (Daphnia sp.; SOLUTION <50%)
Persistence and degradability
K- TSHK Bottle 1
Not established.
Readily biodegradable in water.
12.3.
29/05/2014
Bioaccumulative potential
EN (English)
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K- TSHK Bottle 1
Safety Data Sheet
K- TSHK Bottle 1
Not established.
Bioaccumulation unlikely.
12.4.
Mobility in soil
12.5.
Results of PBT and vPvB assessment
12.6.
Other adverse effects
Other information
: Avoid release to the environment.
SECTION 13: Disposal considerations
13.1.
Waste treatment methods
Waste disposal recommendations
: Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to ...
Ecology - waste materials
SECTION 14: Transport information
In accordance with ADR / RID / ADNR / IMDG / ICAO / IATA
14.1.
UN number
No dangerous good in sense of transport regulations
14.2.
UN proper shipping name
Not applicable
14.3.
Transport hazard class(es)
Not applicable
14.4.
Packing group
Not applicable
14.5.
Environmental hazards
Other information
14.6.
Special precautions for user
14.6.1.
Overland transport
: No supplementary information available.
14.6.2.
Transport by sea
14.6.3.
Air transport
14.7.
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
SECTION 15: Regulatory information
15.1.
Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1.
EU-Regulations
No REACH Annex XVII restrictions
Contains no REACH candidate substance
15.1.2.
National regulations
15.2.
Chemical safety assessment
No chemical safety assessment has been carried out
SECTION 16: Other information
29/05/2014
EN (English)
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K- TSHK Bottle 1
Safety Data Sheet
Data sources
: REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE
COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and
mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending
Regulation (EC) No 1907/2006.
Other information
: None.
Full text of R-, H- and EUH-phrases::
Resp. Sens. 1
H334
R42
Xn
Sensitisation — Respiratory, category 1
May cause sensitization by inhalation
Harmful
SDS EU (REACH Annex II)
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be
construed as guaranteeing any specific property of the product
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K- TSHK Bottle 2
Safety Data Sheet
1.1.
Product identifier
Product form
: Mixture
Name
: K- TSHK Bottle 2
1.2.
1.2.1.
: Industrial
For professional use only
1.2.2.
1.3.
Bray Business Park
Bray - Ireland
T 1 286 1220 - F 1 286 1264
1.4.
Emergency number
Country
IRELAND (REPUBLIC
OF)
UNITED KINGDOM
: +353-1-2861220
Beaumont Hospital
(Birmingham Centre)
Address
9 Dublin
Dudley Road
B18 7QH Birmingham
Emergency number
: +353 1 8379964
0870 600 6266 (UK only)
City Hospital
2.1.
Resp. Sens. 1 H334
Xn; R42
2.2.
Label elements
:
Signal word (CLP)
: Danger
: Glucoamylase
: H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled
: P261 - Avoid breathing spray
P285 - In case of inadequate ventilation wear respiratory protection
P304+P341 - IF INHALED: If breathing is difficult, remove to fresh air and keep at rest in a
position comfortable for breathing
P342+P311 - If experiencing respiratory symptoms: Call a POISON CENTRE or doctor/physician
P501A - Dispose of this material and its container at hazardous or special waste collection point
GHS08
2.3.
Other hazards
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EN (English)
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K- TSHK Bottle 2
Safety Data Sheet
3.1.
Substances
Not applicable
3.2.
Mixture
Name
Product identifier
%
Glucoamylase
(CAS No) 9032-08-0
(EC no) 232-877-2
30 - 40
Xn; R42
Name
Product identifier
%
Regulation (EC) No.
1272/2008 [CLP]
Glucoamylase
(CAS No) 9032-08-0
(EC no) 232-877-2
30 - 40
Resp. Sens. 1, H334
4.1.
: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice
(show the label where possible).
: If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for
breathing. If experiencing respiratory symptoms: Call a POISON CENTRE or doctor/physician.
: Remove affected clothing and wash all exposed skin area with mild soap and water, followed by
warm water rinse.
: Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness
persist.
: Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.
4.2.
Symptoms/injuries after inhalation
4.3.
5.1.
Extinguishing media
5.2.
5.3.
6.1.
6.1.1.
6.1.2.
: Ventilate area.
6.2.
6.3.
6.4.
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K- TSHK Bottle 2
Safety Data Sheet
7.1.
7.2.
vapour. Avoid breathing dust/fume/gas/mist/vapours/spray.
Storage conditions
: Keep only in the original container in a cool, well ventilated place away from : Keep container
closed when not in use.
7.3.
Specific end use(s)
8.1.
Control parameters
8.2.
Exposure controls
Hand protection
Eye protection
: Chemical goggles or safety glasses.
: In case of inadequate ventilation wear respiratory protection.
Other information
9.1.
Physical state
: Liquid
Colour
: Colourless.
Odour
: characteristic.
Odour threshold
: No data available
pH
: No data available
: No data available
Melting point
: No data available
Freezing point
: No data available
Boiling point
: No data available
Flash point
: No data available
: No data available
: No data available
: No data available
Vapour pressure
: No data available
: No data available
Relative density
: No data available
Solubility
: No data available
Log Pow
: No data available
Log Kow
: No data available
: No data available
Viscosity, dynamic
: No data available
: No data available
: No data available
Explosive limits
: No data available
9.2.
Other information
10.1.
Reactivity
10.2.
Chemical stability
Not established.
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K- TSHK Bottle 2
Safety Data Sheet
10.3.
Not established.
10.4.
Conditions to avoid
10.5.
Strong bases.
10.6.
fume. Carbon monoxide. Carbon dioxide.
11.1.
Acute toxicity
: Not classified
: Not classified
: Not classified
: Not classified
Carcinogenicity
: Not classified
: Not classified
: Not classified
Specific target organ toxicity (repeated
exposure)
: Not classified
Aspiration hazard
: Not classified
symptoms
12.1.
Toxicity
12.2.
K- TSHK Bottle 2
12.3.
Not established.
K- TSHK Bottle 2
12.4.
Not established.
Mobility in soil
12.5.
12.6.
Other information
13.1.
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EN (English)
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K- TSHK Bottle 2
Safety Data Sheet
14.1.
UN number
14.2.
Not applicable
14.3.
Not applicable
14.4.
Packing group
Not applicable
14.5.
Other information
14.6.
14.6.1.
Overland transport
14.6.2.
Transport by sea
14.6.3.
Air transport
14.7.
Not applicable
15.1.
15.1.1.
EU-Regulations
15.1.2.
15.2.
Data sources
Other information
: None.
Resp. Sens. 1
H334
R42
Xn
Sensitisation — Respiratory, category 1
May cause sensitization by inhalation
Harmful
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EN (English)
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K- TSHK Bottle 3
Safety Data Sheet
1.1.
Product identifier
Product form
: Mixture
Name
: K- TSHK Bottle 3
Product group
: Trade product
1.2.
1.2.1.
: For professional use only
1.2.2.
1.3.
Bray Business Park
Bray - Ireland
T 1 286 1220 - F 1 286 1264
1.4.
Emergency number
Country
IRELAND (REPUBLIC
OF)
UNITED KINGDOM
: +353-1-2861220
Address
9 Dublin
Beaumont Hospital
Dudley Road
B18 7QH Birmingham
(Birmingham Centre)
Emergency number
: +353 1 8379964
0870 600 6266 (UK only)
City Hospital
2.1.
Skin Corr. 1C H314
Repr. 2
H361
Repr.Cat.3; R63
C; R34
2.2.
Label elements
:
Signal word (CLP)
: Danger
: 1H-imidazole
: H314 - Causes severe skin burns and eye damage
H361 - Suspected of damaging fertility. Suspected of damaging the unborn child
: P201 - Obtain special instructions before use
P202 - Do not handle until all safety precautions have been read and understood
P260 - Do not breathe Vapours
P264 - Wash Wash hands and other exposed areas with mild soap and water before eating,
drinking or smoking and when leaving work thoroughly after handling
P280 - Wear eye protection, protective gloves, protective clothing
GHS05
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EN (English)
GHS08
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K- TSHK Bottle 3
Safety Data Sheet
P301+P330+P331 - If swallowed: Rinse mouth. Do NOT induce vomiting
P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated
clothing. Rinse skin with water/shower
P304+P340 - IF INHALED: Remove to fresh air and keep at rest in a position comfortable for
breathing
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing
P308+P313 - IF exposed or concerned: Get medical advice/attention
P310 - Immediately call a POISON CENTRE or doctor/physician
P321 - Specific treatment (see Details on this label)
P405 - Store locked up
P501A - Dispose of this material and its container at hazardous or special waste collection point
2.3.
Other hazards
3.1.
Substances
Not applicable
3.2.
Mixture
Name
Product identifier
%
1H-imidazole
(CAS No) 288-32-4
(EC no) 206-019-2
10 - 20
Xn; R22
C; R34
Repr.Cat.3; R63
Name
Product identifier
%
Regulation (EC) No.
1272/2008 [CLP]
1H-imidazole
(CAS No) 288-32-4
(EC no) 206-019-2
10 - 20
Acute Tox. 4 (Oral), H302
Skin Corr. 1B, H314
Repr. 2, H361d
4.1.
: Never give anything by mouth to an unconscious person. IF exposed or concerned: Get medical
advice/attention.
: Assure fresh air breathing. Allow the victim to rest. Remove to fresh air and keep at rest in a
position comfortable for breathing. Immediately call a POISON CENTRE or doctor/physician.
: Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
Immediately call a POISON CENTRE or doctor/physician.
: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. Immediately call a POISON CENTRE or doctor/physician.
: Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTRE or
doctor/physician.
4.2.
Symptoms/injuries
4.3.
: Causes severe skin burns and eye damage. Suspected of damaging fertility. May damage the
unborn child.
5.1.
Extinguishing media
5.2.
Reactivity
5.3.
: Thermal decomposition generates : Corrosive vapours.
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K- TSHK Bottle 3
Safety Data Sheet
6.1.
6.1.1.
6.1.2.
: Ventilate area.
6.2.
6.3.
6.4.
7.1.
vapour. Do not breathe Vapours. Obtain special instructions before use. Do not handle until all
safety precautions have been read and understood.
Hygiene measures
: Wash Wash hands and other exposed areas with mild soap and water before eating, drinking or
smoking and when leaving work thoroughly after handling. Wash contaminated clothing before
reuse.
7.2.
Technical measures
: Comply with applicable regulations.
Storage conditions
: Keep only in the original container in a cool, well ventilated place away from : Direct sunlight.
Keep container closed when not in use.
7.3.
Specific end use(s)
8.1.
Control parameters
8.2.
Exposure controls
Hand protection
Eye protection
: Chemical goggles or face shield.
Skin and body protection
: Wear suitable protective clothing.
: Wear appropriate mask.
Other information
9.1.
Physical state
: Liquid
Colour
: Colourless.
Odour
: characteristic.
Odour threshold
: No data available
pH
: No data available
: No data available
Melting point
: No data available
Freezing point
: No data available
Boiling point
: No data available
Flash point
: No data available
: No data available
: No data available
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K- TSHK Bottle 3
Safety Data Sheet
: No data available
Vapour pressure
: No data available
: No data available
Relative density
: No data available
Solubility
: No data available
Log Pow
: No data available
Log Kow
: No data available
: No data available
Viscosity, dynamic
: No data available
: No data available
: No data available
Explosive limits
: No data available
9.2.
Other information
10.1.
Reactivity
Thermal decomposition generates : Corrosive vapours.
10.2.
Chemical stability
Not established.
10.3.
Not established.
10.4.
Conditions to avoid
10.5.
Strong bases.
10.6.
fume. Carbon monoxide. Carbon dioxide. Thermal decomposition generates : Corrosive vapours.
11.1.
Acute toxicity
1H-imidazole (288-32-4)
LD50 oral rat
ATE (oral)
: Not classified
970 mg/kg rat
970.000 mg/kg bodyweight
: Causes severe skin burns and eye damage.
: Eye damage, category 1, implicit
: Not classified
: Not classified
Carcinogenicity
: Not classified
: Suspected of damaging fertility. Suspected of damaging the unborn child.
: Not classified
Causes severe skin burns and eye damage
Suspected of damaging fertility or the unborn child
Specific target organ toxicity (repeated
exposure)
: Not classified
Aspiration hazard
: Not classified
symptoms
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K- TSHK Bottle 3
Safety Data Sheet
12.1.
Toxicity
LC50 fish 1
EC50 Daphnia 1
12.2.
2259 mg/l (96 h; Pisces; QSAR)
341.5 mg/l (48 h; Daphnia magna)
K- TSHK Bottle 3
Not established.
Readily biodegradable in water.
12.3.
K- TSHK Bottle 3
Not established.
BCF fish 1
Log Pow
1 (Pimephales promelas; QSAR)
-0.02
Bioaccumulation unlikely.
12.4.
Mobility in soil
12.5.
12.6.
Other information
13.1.
14.1.
UN number
14.2.
Not applicable
14.3.
Not applicable
14.4.
Packing group
Not applicable
14.5.
Other information
14.6.
14.6.1.
Overland transport
14.6.2.
Transport by sea
14.6.3.
Air transport
14.7.
Not applicable
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K- TSHK Bottle 3
Safety Data Sheet
15.1.
15.1.1.
EU-Regulations
15.1.2.
15.2.
Indication of changes:
Revision - See : *.
Data sources
Other information
: None.
Acute Tox. 4 (Oral)
Repr. 2
Repr. 2
Skin Corr. 1B
Skin Corr. 1C
H302
H314
H361
H361d
R22
R34
R63
C
Xn
Acute toxicity (oral), Category 4
Reproductive toxicity, Category 2
Reproductive toxicity, Category 2
Skin corrosion/irritation, Category 1B
Skin corrosion/irritation, Category 1C
Harmful if swallowed
Suspected of damaging fertility or the unborn child
Suspected of damaging the unborn child
Harmful if swallowed
Causes burns
Possible risk of harm to the unborn child
Corrosive
Harmful
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EN (English)
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MSDS Sheet

Transcription

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