Research topics Awards Edited books Review articles in Journals
Transcription
Research topics Awards Edited books Review articles in Journals
Research topics The main topics deal with green catalysis by transition metal complexes. 1. 2. 3. 4. 5. 6. 7. Activation of unsaturated molecules (acetylenes, olefins) by ruthenium catalysts for the formation of C-O, C-C and C=C bonds with atom economy Olefin and ene-yne metathesis Allylic substitution with ruthenium catalysts Ruthenium-catalyzed inert sp2C-H activation/functionalization Ruthenium-catalyzed C-C bond formation from inert sp3C-H bond involving hydrogen transfer Enantioselective hydrogenation of C=C bonds Catalytic transformations of natural compounds and bio-resources (metathesis/allylation) Awards French Chemical Society Award 2008: Coordination Chemistry section Paul Langevin Prize 2012, French Academy of Sciences Edited books 2014 “Ruthenium in catalysis”, C. Bruneau & P. H. Dixneuf Eds, Springer, Heidelberg, Top. Organomet. Chem., vol. 48; 401 pages. http://www.springer.com/series/3418 2008 “Metal Vinylidenes and allenylidenes in Catalysis : from Reactivity to Applications in Synthesis”, C. Bruneau, P. H. Dixneuf Eds, Wiley-VCH, Weinheim, 338 pages. ISBN:978-3-527-31892-6 2004 “Ruthenium catalysts and fine chemistry”, C. Bruneau & P. H. Dixneuf Eds, Springer, Heidelberg, Top. Organomet. Chem., vol. 11; 346 pages. ISBN 3-540-20543-8 Review articles in Journals 16 (Z)-selectivity. Recent advances in one of the current major challenges of olefin metathesis ChemCatChem, 2013, 5, 3436-3459. 15 Ruthenium(II)-catalyzed C-H activation and functionalization Chem. Rev., 2012, 112, 5879−5918. 14 Transition metal catalyzed nucleophilic allylic substitution: activation of allylic alcohols via -allyl species Chem. Soc. Rev., 2012, 41, 4467-4483. 13 Allylic ruthenium(IV) complexes in catalysis Coord. Chem. Rev., 2012, 256, 525-536. 12 A green route to nitrogen-containing groups: the acrylonitrile cross-metathesis and applications to plant oils derivatives Green Chem. 2011, 13, 2258-2271. 11 Cross-metathesis with acrylonitrile and applications to fatty acid derivatives Eur. J. Lipid Sci. Technol. 2010, 112, 3-9. 10 (Arene)ruthenium catalysts for olefin metathesis Chem. Today 2009, 27, 17-19. 9. Synthesis of -aminoacid derivatives via enantioselective hydrogenation of -substituted--(acylamino) acrylates" Coord. Chem. Rev. 2008, 252, 532–544. 8. Activation and functionalization of benzylic derivatives by palladium catalysts Chem. Soc. Rev. 2008, 37, 292-299. 7. Pentamethylcyclopentadienyl ruthenium catalysts for regio- and enantioselective allylation of nucleophiles Chem. Eur. J. 2006, 12, 5178-5187. 6. Metal vinylidenes and allenylidenes in catalysis. Applications in anti-Markovnikov additions to terminal alkynes and alkene metathesis Angew. Chem. Int. Ed. 2006, 45, 2176-2203. 5. Electrophilic activation and cycloisomerization of enynes : a new route to functional cyclopropanes Angew. Chem. Int. Ed. 2005, 44, 2328-2334. 4. Chiral monodentate phosphorus ligands for rhodium-catalyzed asymmetric hydrogenation Tetrahedron : Asymmetry 2004, 15, 2101-2111. 3. Metal Vinylidenes in Catalysis Acc. Chem. Res. 1999, 32, 311-323. 2. Selective transformations of alkynes with ruthenium catalysts J. Chem. Soc., Chem. Commun. 1997, 507-512. 1. Selective palladium-catalyzed transformations of cyclic alk-2-ynyl carbonates Curr. Org. Chem. 1997, 1, 197-218. Book chapters 28 Ruthenium(II)-catalyzed functionalization of C-H bonds with alkenes: alkenylation versus alkylation C. Bruneau, P. H. Dixneuf in "C-H Activation and catalytic functionalization", P. H. Dixneuf, H. Doucet Eds. Top. Organomet. Chem., Springer, 2015, 55(1), 137-188. 27 RTILs in catalytic olefin metathesis reactions C. Fischmeister, C. Bruneau, in “Ionic Liquids (ILs) in Organometallic Catalysis” J. Dupont, L. Kollar Eds, Springer, Heidelberg, Top. Organomet. Chem., 2015, 51, 287-306. 26 Indenylidene Ruthenium Catalysts for Alkene Metathesis P. H. Dixneuf, C. Bruneau, in in "Handbook of Metathesis, Volume 1: Catalyst Development and Mechanism", R. H. Grubbs, A. G. Wenzel Eds., Wiley VCH, Weinheim, 2 nd edition, 2015, pp. 389-416. 25 sp3C-H bond functionalization with ruthenium catalysts C. Bruneau, in “Ruthenium in catalysis”, C. Bruneau, P. H. Dixneuf Eds, Springer, Heidelberg, Top. Organomet. Chem., 2014, 48, 195–236. 24 "Synthesis and Applications in Catalysis of Metal Complexes with Chelating Phosphinesulfonate Ligands F. Jiang, M. Achard, C. Bruneau, in “Advances in Organometallic Chemistry”, Pedro J. Pérez, Ed., Burlington: Academic Press, 2014, Vol. 62, pp. 159-218. 23 Olefin metathesis in green organic solvents and without solvent C. Bruneau, C. Fischmeister, in "Olefin metathesis: theory and practice", K. Grela Ed., J. Wiley & Sons, Hoboken, NJ, 2014, pp. 523-535. 22 Metathesis adding a C-1 unit C. Bruneau, C. Fischmeister in Science of Synthesis "C-1 Building blocks in organic synthesis 2, 2013/8", P.W.N.M. van Leeuwen Ed., Georg Thieme Verlag KG, Stuttgart, 2014, pp. 349-365. 21 Group 8 Metals-Catalyzed O–H Bond Addition to Unsaturated Molecules C. Bruneau in "Hydrofunctionalization", V. P. Ananikov, M. Tanaka, Eds. “Topics in Organometallic Chemistry”, Springer, 2013, 43, 203-230. 20 Anti-Markovnikov additions of O, N, P-nucleophiles to triple bonds with ruthenium catalysts C. Bruneau in "Metal Vinylidenes and allenylidenes in Catalysis : from Reactivity to Applications in Synthesis", Wiley-VCH, C. Bruneau, P. H. Dixneuf Eds, 2008, pp. 313-332 . 19 Monophosphines with chiral backbone C. Bruneau, J.-L. Renaud in "Trivalent Phosphorus Components in Asymmetric Catalysis - Synthesis and Applications", Wiley-VCH, A. Börner Ed., 2008, pp. 5-35. 18. Mono-phosphinites, -aminophosphinites, - phosphonites, -phosphoramidites, and -phosphites C. Bruneau, J.-L. Renaud in "Trivalent Phosphorus Components in Asymmetric Catalysis - Synthesis and Applications", Wiley-VCH, A. Börner Ed., 2008, pp. 36-69. 17. Catalytic cycloisomerization of enynes involving various activation processes C. Bruneau in “Metathesis Chemistry : From Nanostructure Design to Synthesis of Advanced Materials", Y. Imamoglu, V. Dragutan Eds., Springer, 2007, pp. 375-394. 16. Cascade and sequential catalytic transformations initiated by ruthenium catalysts C. Bruneau , S. Dérien, P. H. Dixneuf in "Metal-catalyzed Cascade Reactions", T. J. J. Müller Ed., “Top. Organomet. Chem.”, Springer, 2006, Vol. 19, pp. 295-326. 15. Anti-Markovnikov addition to terminal alkynes via ruthenium vinylidene intermediates C. Bruneau in Handbook of C-H Bond Transformations, G. Dyker Ed., Wiley-VCH, Weinheim, 2005, vol. 1, pp. 72-80. 14. Allenes and Cumulenes C. Bruneau, J.-L. Renaud in "Comprehensive Organic Functional Group Transformations II", A. R. Katritzky, R. J. K. Taylor, J. Cossy Eds, Elsevier Ltd, Oxford, 2005, vol. 1, pp. 1019-1081. 13. Nucleophilic additions to alkynes and reactions via vinylidene intermediates C. Fischmeister, C. Bruneau, P. H. Dixneuf in "Ruthenium in Organic Synthesis", S.-I. Murahashi Ed., Wiley, 2004, pp. 189-217. 12. Ruthenium vinylidenes and allenylidenes in catalysis C. Bruneau in "Ruthenium catalysts and fine chemistry", Top. Organomet. Chem., C. Bruneau, P. H. Dixneuf, Eds., Springer, 2004, vol. 11, pp. 125-153. 11. Ring closing versus cyclic isomerization of 1,6-dienes by ruthenium allenylidene complexes B. Cetinkaya, I. Özdemir, E. Cetinkaya, C. Bruneau, P. H. Dixneuf, in "Novel metathesis chemistry : well-defined initiator systems for specialty chemical synthesis, tailored polymers and advanced material applications", Y. Imamoglu, L. Bencze Eds., Kluwer Acad.Pub., 2003, pp. 285-293. 10. Ruthenium carbenes as catalysts for alkene metathesis C. Fischmeister, R. Castarlenas, C. Bruneau, P. H. Dixneuf in "Novel metathesis chemistry : well-defined initiator systems for specialty chemical synthesis, tailored polymers and advanced material applications", Y. Imamoglu, L. Bencze Eds., Kluwer Acad.Pub., 2003, pp. 23-42. 9. Hydrogenation of enol carbonates and 4-methylene-N-acyloxazolidinones using [Ru(II)((R)-Binap)] complexes P. H. Dixneuf, C. Bruneau, P. Le Gendre in "Catalysts for Fine Chemical Synthesis", vol. 1, "Hydrolysis, Oxidation and Reduction", S. M. Roberts, G. Poignant Edts, J. Wiley Ltd., 2002, pp. 186-189. 8. Ruthenium Catalysts as Innovative Architects for Molecule Building from Alkynes P. H. Dixneuf, C. Bruneau in "Transition Metal Catalysed Reactions", S.-I. Murahashi, S. G. Davies, Blackwell Sci. Ed., 1999, pp. 391-404. 7. Carbon-rich organoruthenium and selective catalytic transformations of alkynes P. H. Dixneuf, C. Bruneau in "Organic Synthesis via Organometallics" OSM5, G. Helmchen Ed., Vieweg Verlag, 1997, pp. 1-20. 6. Allenes and Cumulenes" C. Bruneau, P. H. Dixneuf in "Comprehensive Organic Functional Group Transformations", A. R. Katritzky, O. Meth-Cohn, C. W. Rees Editeurs, Pergamon, Cambridge, 1995, vol. 1, pp. 953-995. 5. Catalytic Additions of CO2 Adducts to Alkynes: Selective Synthesis of Carbamates, Ureas and Carbonates C. Bruneau and P. H. Dixneuf in "Carbon dioxide fixation and reduction in biological and model systems", Proceedings of the Royal Swedish Academy of Sciences Nobel Symposium 1991, C.-I. Brändén and G. Schneider (Edts), Oxford Univ. Press, 1994, pp. 131-143. 4. Catalytic Incorporation of Carbon Dioxide for the Synthesis of Organic Compounds P.H. Dixneuf, C. Bruneau and J. Fournier in "Enzymatic and Model Carboxylation and Reduction Reactions for Carbon Dioxide Utilization", M. Aresta and J.V. Schloss (Edts), NATO ASI Series, Kluwer Academic Pub., 1990, pp. 65-77. 3. Production of Oil by Hydropyrolysis of Wood; Influence of Heating Rate, Temperature and Catalyst N. Soyer, F. Hyvrard, C. Bruneau, A. Brault, C. Esnouf in "Biomass for Energy and Industry", 4th E.C. Conference, G. Grassi, B. Delmon, J.F. Molle and H. Zibetta (Edts), Applied Science Publishers Ltd, London, 1987, pp. 372-376. 2. Study of the Direct Liquefaction of Wood in the Presence of Iron Additives C. Bestue-Labazuy, N. Soyer, C. Bruneau, A. Brault in "Energy from Biomass", 3rd E.C. Conference , W. Palz, J. Coombs and D.O. Hall (Eds), Applied Science Publishers Ltd, London, 1985, pp. 924-928. 1. Chemical Study of the Thermal and Catalytic Liquefaction of Poplar Wood" C. Fredon, N. Soyer, C. Bruneau, A. Brault in "Energy from Biomass", 2nd E.C. Conference, A. Strub, P. Chartier and G. Schlesser (Eds), Applied Science Publishers Ltd, London, 1983, pp. 930-934. Recent publications (2000-2016) 2016 Benzimidazolium sulfonate ligand precursors and application in ruthenium-catalyzed aromatic amine alkylation with alcohols N. Kaloglu, I. Özdemir, N.Gürbüz, M. Achard, C. Bruneau, Catal. Commun. 2016, 74, 33-38. 2015 Olefin metathesis transformations in thermomorphic multicomponent solvent system S. Huang, H. Bilel, F. Zagrouba, N. Hamdi, C. Bruneau, C. Fischmeister, Catal. Commun. 2015, 63, 31-34. Cross‐metathesis of fatty acid methyl esters with acrolein: An entry to a variety of bifunctional compounds H. Bonin, A. Keraani, J.‐L. Dubois, M. Brandhorst, C. Fischmeister, C. Bruneau, Eur. J. Lipid Sci. Technol. 2015, 117, 209–216. [Cp*Ru]-catalyzed selective coupling/hydrogenation I. Labed, A. Labed, Y. Sun, F. Jiang, M. Achard, S. Dérien, Z. Kabouche, C. Bruneau, Catal. Sci. Technol. 2015, 5, 1650-1657. Iridium-catalyzed sustainable access to functionalized julolidines through hydrogen autotransfer A. Labed, F. Jiang, I. Labed, A. Lator, M. Peters, M. Achard, A. Kabouche, Z. Kabouche, G. V. M. Sharma, C. Bruneau, ChemCatChem 2015, 7, 1090-1096. Synthesis and conformational studies of /2,3-peptides derived from alternating 2,3-amino-acids and L-Ala repeats G. Sharma, T. Shridar, B. Veena, P. P. Reddy, S. V. Reddy, C. Bruneau, A. C. Kunwar, New J. Chem. 2015, 39, 3295-3309. N-Alkylation and N,C-Dialkylation of Amines with Alcohols in the Presence of Ruthenium Catalysts with Chelating N-Heterocyclic Carbene Ligands Z. Sahin, N. Gürbüz, I. Ozdemir, O. Sahin, O. Buyukgungor, M. Achard, C. Bruneau, Organometallics 2015, 34, 2296-2304. Metathesis catalysts with fluorinated unsymmetrical NHC ligands S. Masoud, A. K. Mailyan, V. Dorcet, T. Roisnel, P. H. Dixneuf, C. Bruneau, S. N. Osipov, Organometallics 2015, 34, 2305-2313. Cross metathesis of bio-sourced fatty nitriles with acrylonitrile J. Bidange, C. Fischmeister, C. Bruneau, J.-L. Dubois, J.- Couturier, Monatsh. Chem. 2015, 146, 1107–1113. sp3-sp3 Carbon-carbon bond formation using 2-alkylazoles and a bromocarylate as the reaction partners L. Zhao, F. Derridj, S. Djebbar, C. Bruneau, H. Doucet, Tetrahedron Lett. 2015, 56, 2354-4358. Ruthenium(II) and Iridium(III) complexes bearing phosphinepyridonate and phosphinequinolinolate chelates F. Jiang, M. Achard, T. Roisnel, V. Dorcet, C. Bruneau, Eur. J. Inorg. Chem. 2015, 4312-4317. Vicinal -functionalizations of amines: cyclization versus dehydrogenative hydrolysis F. Jiang, M. Achard, C. Bruneau, Chem. Eur. J. 2015, 21, 14319-14323. Selective ruthenium-catalyzed hydrochlorination of alkynes: one-step synthesis of vinylchlorides S. Dérien, H. Klein, C. Bruneau, Angew. Chem. Int. Ed. 2015, 54, 12112-12115. Cross-metathesis of unsaturated epoxides for the synthesis of polyfunctional building blocks M. K. Abderrezak, K. Sichova, N. Dominguez-Boblett, A. Dupé, Z. Kabouche, C. Bruneau, C. Fischmeister, Beilstein J. Org. Chem. 2015, 11, 1876-1880. Ruthenium(II) and iridium(III) complexes featuring NHC-sulfonate chelate A. Rajaraman, A. R. Sahoo, F. Hild, C. Fischmeister, M. Achard, C. Bruneau, Dalton Trans. 2015, 44, 1746717472. Synthesis of ruthenium N-heterocyclic carbene complexes and their catalytic activity for -alkylation of tertiary cyclic amines I. Ozdemir, S. Demir Düşünceli, N. Kaloğlu, M. Achard, C. Bruneau, J. Organomet. Chem. 2015, 799-800, 311315. Efficient domino hydroformylation/benzoin condensation: highly selective synthesis of -hydroxy ketones K. Dong, R. Sang, J.-F. Soulé, C. Bruneau, R. Franke, R. Jackstell, M. Beller, Chem. Eur. J. 2015, 21, 1803318037. 2014 Access to functionalized a-trifluoromethyl-a-aminophosphonates via intermolecular ene-yne metathesis I. M. Krylov, A. K. Mailyan, M. A. Zotova, C. Bruneau, P. H. Dixneuf, S. N. Osipov, Synlett 2014, 2624-2628. Ruthenium catalyzed ethenolysis of renewable oleonitrile J. Bidange, J.-L. Dubois, J.-L. Couturier, C. Fischmeister, C. Bruneau, Eur. J. Lipid Sci. Technol. 2014, 116, 15831589. Ruthenium catalyzed synthesis of 1,2-diketones from alkynes” Y. Miao, A. Dupé, C. Fischmeister, C. Bruneau, Eur. J. Org. Chem. 2014, 5071-5077. Iron-catalysed tandem isomerisation/hydrosilylation reaction of allylic alcohols with amines H. Li, M. Achard, C. Bruneau, J.-B. Sortais, C. Darcel, RSC Adv. 2014, 4, 25892-25897. Terminal conjugated dienes via a ruthenium-catalyzed cross-metathesis/elimination sequence: application to renewable resources H. Bilel, N. Hamdi, F. Zagrouba, C. Fischmeister, C. Bruneau, Catal. Sci. Technol. 2014, 4, 2064-2071. 2-(Diphenylphosphino)benzenesulfonic acid M. Achard, C. Bruneau, e-EROS Encyclopedia of Reagents for Organic Synthesis, Copyright © 2008 John Wiley & Sons, Ltd, Published Online : 27 May 2014, DOI: 10.1002/047084289X.rn01706. Reactivity of 3-Substituted Fluorobenzenes in Palladium-Catalysed Direct Arylations with Aryl Bromides T. Yan, L. Zhao, M. He, J.-F. Soulé, C. Bruneau, H. Doucet, Adv. Synth. Catal. 2014, 356, 1586-1596. Reactivity of C–H bonds of polychlorobenzenes for palladium-catalysed direct arylations with aryl bromides L. Zhao, T. Yan, C. Bruneau, H. Doucet, Catal. Sci. Technol. 2014, 4, 352-360. 2013 Ruthenium(II)-catalyzed selective monoarylation in water and sequential functionalisations of C-H bonds P. B. Arockiam, C. Fischmeister, C. Bruneau, P. H. Dixneuf, Green Chem. 2013, 15, 67-71. Palladium-catalyzed direct polyarylation of pyrrole derivatives L. Zhao, C. Bruneau, H. Doucet, ChemCatChem 2013, 5, 255-262. Synthesis and characterization of sterically enlarged Hoveyda type olefin metathesis catalysts S. Shahane, L. Toupet, C. Fischmeister, C. Bruneau, Eur. J. Inorg. Chem. 2012, 54-60. Selective Carbon-Carbon Bond Formation : Terpenylations of Amines Involving Hydrogen Transfers Z. Sahli, B. Sundararaju, C. Bruneau, M. Achard, Green Chem. 2013, 15, 775–779. N-Heterocyclic carbene–palladium catalysts for the direct arylation of pyrrole derivatives with aryl chlorides I. Özdemir, N. Gürbüz, N. Kaloğlu, Ö. Doğan, M. Kaloğlu, C. Bruneau, H. Doucet, Beilstein J. Org. Chem. 2013, 9, 303–312. Ruthenium-Catalysed Synthesis of Functional Conjugated Dienes from Propargylic Carbonates and Silyl Diazo Compounds S. Moulin, H. Zhang, S. Raju, C. Bruneau, S. Dérien, Chem. Eur. J. 2013, 19, 3292-3296. Palladium-Acetate Catalyst for Regioselective Direct Arylation at C2 of 3-Furanyl or 3-Thiophenyl Acrylates with Inhibition of Heck Type Reaction L. Chen, C. Bruneau, P.H. Dixneuf, H. Doucet, Tetrahedron 2013, 69, 4381-4388. Stepwise catalytic transformations of renewable feedstock arising from plant oils A. Dupé, V. Le Ravalec, C. Fischmeister, C. Bruneau, Eur. J. Lipid Sci. Technol. 2013, 115, 490–500. Autocatalytic intermolecular versus intramolecular deprotonation in C-H bond activation of functionalized arenes by ruthenium(II) or palladium(II) complexes I. Fabre, N. von Wolff, G. Le Duc, E. Ferrer Flegeau, C. Bruneau, P. H. Dixneuf, A. Jutand, Chem.-Eur. J. 2013, 19, 7595- 7604. A straightforward access to guaiazulene derivatives using palladium-catalyzed sp2 or sp3C-H bond functionalization L. Zhao, C. Bruneau, H. Doucet, Chem. Commun. 2013, 49, 5598-5600. Palladium-catalyzed regioselective direct arylations of heteroarenes by bromobenzamides: direct synthesis of heteroaryl benzamides L. Chen, C. Bruneau, P.H. Dixneuf, H. Doucet, ChemCatChem 2013, 5, 1956-1963. Synthesis of CF3-containing 1,2,3,4-tetrahydroisoquinoline-3-phosphonates via regioselective ruthenium-catalyzed co-cyclotrimerization of 1,7-aza-diynes M. A. Zotova, D. V. Vorobyeva, P. H. Dixneuf, C. Bruneau, S. N. Osipov, Synlett 2013, 1517-1522. Phosphine-free palladium-catalysed direct C2-arylation of benzothiophenes with aryl bromides L. Zhao, C. Bruneau, H. Doucet, Tetrahedron 2013, 69, 7082-7089. Interest of the precatalyst design for olefin metathesis operating in a discontinuous nanofiltration membrane reactor G. Nasser, T. Renouard, S. Shahane, C. Fischmeister, C. Bruneau, M. Rabiller-Baudry, ChemPlusChem 2013, 78, 728-736. Ruthenium Containing Phosphinesulfonate Chelate for Hydrogenation of Arylketones F. Jiang, K. Yuan, M. Achard, C. Bruneau, Chem.-Eur. J. 2013, 19, 10343-10352. Access to cyclic -CF3-substituted -amino acid derivatives by ring closing metathesis of functionalized 1,7-enynes A. K. Mailyan, I. M. Krylov, C. Bruneau, P. H. Dixneuf, S. N. Osipov, Eur. J. Org. Chem. 2013, 5353-5363. Ring Closing and Macrocyclization of β-Dipeptides via Olefin Metathesis B. Sundararaju, T. Sridhar, M. Achard, G. V. M. Sharma, C. Bruneau, Eur. J. Org. Chem. 2013, 6433-6442. Synthesis of heteroarylated polyfluorobiphenyls via palladium-catalyzed sequential sp2C-H bonds functionalizations T. Yan, L. Chen, C. Bruneau, P.H. Dixneuf, H. Doucet, J. Org. Chem. 2013, 78, 4177-4183. (Z)-selectivity. recent advances in one of the current major challenges of olefin metathesis S. Shahane, C. Bruneau, C. Fischmeister, ChemCatChem 2013, 5, 3436-3459. 2012 Allylic ruthenium(IV) complexes in catalysis C. Bruneau, M. Achard, Coord. Chem. Rev. 2012, 256, 525-536. New ruthenium metathesis catalysts with chelating indenylidene ligands: synthesis, characterization and reactivity A. Kabro, G. Ghattas, T. Roisnel, C. Fischmeister, C. Bruneau, Dalton Trans. 2012, 41, 3695-3700. Silica and zirconia supported olefin metathesis precatalysts: Synthesis, catalytic activity and multiple-use in dimethyl carbonate A. Keraani, C. Fischmeister, T. Renouard, M. Le Floch, A. Baudry, C. Bruneau, M. Rabiller-Baudry, J. Mol. Catal. A : Chem. 2012, 357, 73-80. Isoquinoline derivatives via stepwise regioselective sp2 and sp3C-H bond functionalization T. Boudiar, Z. Sahli, B. Sundararaju, M. Achard, Z. Kabouche, H. Doucet, C. Bruneau, J. Org. Chem. 2012, 77, 3674-3678. Ester as a blocking group for palladium-catalysed direct forced arylation at the unfavourable site of heteroaromatics: simple access to the less accessible regioisomers L. Chen, C. Bruneau, P. H. Dixneuf, H. Doucet, Green Chem. 2012, 14, 1111-1124. Transition metal catalyzed nucleophilic allylic substitution: activation of allylic alcohols via -allyl species B. Sundararaju, M. Achard, C. Bruneau, Chem. Soc. Rev. 2012, 41, 4467-4483. Regio- and stereoselective syntheses of piperidine derivatives via ruthenium-catalyzed coupling of propargylic amides and allylic alcohols S. Murugesan, F. Jiang, M. Achard, C. Bruneau, S. Dérien, Chem. Commun. 2012, 48, 6589-6591. Acceptorless Ruthenium Catalyzed Dehydrogenation of Alcohols to Ketones and Esters S. Shahane, C. Fischmeister, C. Bruneau, Catal. Sci. Technol. 2012, 2, 1425-1428. Polyamide precursors from renewable 10-undecenenitrile and methyl acrylate via olefin cross-metathesis X. Miao, C. Fischmeister, P. H. Dixneuf, C. Bruneau, J.-L. Dubois, J.-L. Couturier, Green Chem . 2012, 14, 21792183. Tandem Catalytic Acrylonitrile Cross-Metathesis and Hydrogenation of Nitriles with Ruthenium Catalysts: Direct Access to Linear -Aminoesters from Renewables X. Miao, C. Fischmeister, P. H. Dixneuf, C. Bruneau, J.-L. Dubois, J.-L. Couturier, ChemSusChem 2012, 5, 14101414. Iridium-catalyzed oxidant free dehydrogenative C-H bond functionalization: selective preparation of N-arylpiperidines through tandem hydrogen transfers K. Yuan, F. Jiang, Z. Sahli, M. Achard, C. Bruneau, Angew. Chem. Int. Ed. 2012, 51, 8876-8880. Palladium-catalyzed direct heteroarylations of heteroaromatics using esters as blocking groups at C2 of bromofuran and bromothiophene derivatives: a one-step access to biheteroaryls H. Y. Fu, L. Zhao, C. Bruneau, H. Doucet, Synlett 2012, 2077-2082. Palladium-catalyzed direct arylation of 5-chloropyrazoles : a selective access to 4-aryl pyrazoles T. Yan, L. Chen, C. Bruneau, P. H. Dixneuf, H. Doucet, J. Org. Chem. 2012, 77, 7659-7664. Eugenol as a renewable feedstock for the production of polyfunctional alkenes via olefin cross-metathesis H. Bilel, N. Hamdi, F. Zagrouba, C. Fischmeister, C. Bruneau, RSC Adv. 2012, 2, 9584-9589. One-Step Synthesis of 1-Halo-1,3-butadienes via Ruthenium-Catalysed Hydrohalogenative Dimerisation of Alkynes H. Klein, T. Roisnel, C. Bruneau, S. Dérien, Chem. Commun. 2012, 48, 11032-11034. Cyclobutene Ring-opening of bicyclo[4.2.0]octa-1,6-dienes: access to CF3-substituted 5,6,7,8-tetrahydro-1,7naphthyridines A. K. Mailyan, A. S. Peregudov, P. H. Dixneuf, C. Bruneau, S. N. Osipov, J. Org. Chem. 2012, 77, 8518-8526. Ruthenium(II)-catalyzed C-H activation and functionalization P. B. Arockiam, C. Bruneau, P. H. Dixneuf, Chem. Rev. 2012, 112, 5879−5918. Methyl ricinoleate as platform chemical for simultaneous production of fine chemicals and polymer precursors A. Dupé, M. Achard, C. Fischmeister, C. Bruneau, ChemSusChem 2012, 5, 2249-2254. Ruthenium-benzylidenes and -indenylidenes as efficient catalysts for the hydrogenation of aliphatic nitriles into primary amines X. Miao, J. Bidange, P. H. Dixneuf, C. Fischmeister, C. Bruneau, J.-L. Dubois, J.-L. Couturier, ChemCatChem 2012, 4, 1911-1916. 2011 Palladium-Catalyzed Direct Arylation of Thiophenes Tolerant to Silyl Groups L. Chen, J. Roger, C. Bruneau, P.H. Dixneuf, H. Doucet, Chem. Commun. 2011, 47, 1872-1874. Ene-yne cross-metathesis with ruthenium carbene catalysts C. Fischmeister, C. Bruneau, Beilstein J. Org. Chem. 2011, 7, 156-166. Synthesis of functionalized CF3-containing heterocycles via [2,3]-sigmatropic rearrangement and sequential catalytic carbocyclization D. V. Vorobyeva, A. K. Mailyan, A. S. Peregudov, N. M. Karimova, T. P. Vasilyeva, I. S. Bushmarinov, C. Bruneau, P. H. Dixneuf, S. N. Osipov, Tetrahedron 2011, 67, 3524-3532. Preparation of chiral ruthenium(IV) complexes and applications in regio- and enantioselective allylation of phenols Z. Sahli, N. Derrien, S. Pascal, B. Demerseman, T. Roisnel, F. Barriere, M. Achard, C. Bruneau, Dalton Trans. 2011, 40, 5625-5630. Cross-metathesis transformations of terpenoids in dialkyl carbonate solvents H. Bilel, N. Hamdi, F. Zagrouba, C. Fischmeister, C. Bruneau, Green Chem. 2011, 13, 1448-1452. Autocatalysis for C-H Bond Activation by Ruthenium(II) Complexes in Catalytic Arylation of Functional Arenes E. Ferrer Flegeau, C. Bruneau, P. H. Dixneuf, A. Jutand, J. Am. Chem. Soc. 2011, 133, 10161-10170. sp3C-H bond activation with ruthenium(II) catalysts and C(3)-alkylation of cyclic amines B. Sundararaju, M. Achard, G. V. M. Sharma, C. Bruneau, J. Am. Chem. Soc. 2011, 133, 10340-10343. Ruthenium-catalyzed reductive amination of allylic alcohols Z. Sahli, B. Sundararaju, M. Achard, C. Bruneau, Org. 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Phosphine free palladium catalytic system for inhibition of Heck type reaction and selective direct arylation of furans or thiophenes bearing alkenes L. Chen, J. Roger, C. Bruneau, P. H. Dixneuf, H. Doucet, Adv. Synth. Catal. 2011, 353, 2749-2760. Ruthenium Diacetate-catalysed Oxidative Alkenylation of C-H Bonds in Air: Synthesis of Alkenyl N-Arylpyrazoles P. B. Arockiam, C. Fischmeister, C. Bruneau, P. H. Dixneuf, Green Chem. 2011, 13, 3075-3078. sp3C-H bond activation with ruthenium(II) catalysts and C(3)-alkylation of cyclic amines B. Sundararaju, Z. TANG, M. Achard, G. V. M. Sharma, C. Bruneau, Synform, 2011/11. Synstories -Views and News, Published online: 19.10.2011, DOI: 10.1055/s-0031-1289252. Dendralenes preparation via ene-yne cross-metathesis from in situ generated 1,3-enynes H. Srour, K. Abidi, Z. Sahli, B. Sundararaju, N. Hamdi, M. Achard, C. Bruneau, ChemCatChem 2011, 3, 18761879. 2010 New 1,2,4,5-Tetrakis-(N-Imidazoliniummethyl)Benzene and 1,2,4,5-Tetrakis-(NBenzimidazoliummethyl)benzene salts as N-heterocyclic tetracarbene precursors : synthesis and involvement in ruthenium catalyzed allylation reactions N. Gürbüz, S. Demir, I. Özdemir, B. Cetinkaya, C. Bruneau, Tetrahedron 2010, 66, 1346-1351. A new access to the 6,8-dioxabicyclo[3.2.1]octane ring system using a three-component reaction: enantioselective synthesis of (+)-iso-exo-brevicomin A. Bouziane, T. Régnier, F. Carreaux, B. Carboni, C. Bruneau, J.-L. Renaud, Synlett 2010, 207-210. Cross-metathesis with acrylonitrile and applications to fatty acid derivatives C. Bruneau, C. Fischmeister, X. Miao, R. Malacea, P. H. Dixneuf, Eur. J. Lipid Sci. Technol. 2010, 112, 3-9. Hydrogenation of -N-substituted enaminoesters in the presence of ruthenium catalysts H. Hebbache, T. Jerphagnon, Z. Hank, C. Bruneau, J.-L. Renaud, J. Organomet. Chem. 2010, 695, 870–874. Synthesis of α-Alkynyl-β,β,β-trifluoroalanine Derivatives by Sonogashira Cross-Coupling Reaction G. T. Shchetnikov, M. A. Zotova, C. Bruneau, P. H. Dixneuf, S. N. Osipov, Eur. J. Org. Chem. 2010, 15871592. Ruthenium(IV) complexes featuring P,O-chelating ligands: regioselective substitution directly from allylic alcohols B. Sundararaju, M. Achard, B. Demerseman, L. Toupet, G. V. M. Sharma, C. Bruneau, Angew. Chem. Int. Ed. 2010, 49, 2782-2785. N-Heterocyclic carbenes: useful ligands for the palladium-catalysed direct C5 arylation of heteroaromatics with aryl bromides or electron-deficient aryl chlorides I. Ozdemir, Y. Gök, Ö. Özeroglu, M. Kaloglu, H. Doucet, C. Bruneau, Eur. J. Org. Chem. 2010, 1798-1805. Indirect and direct catalytic asymmetric reductive amination of 2-tetralone O. Bondarev, C. Bruneau, Tetrahedron : Asymmetry 2010, 21, 1350-1354. C-H Bond Functionalization in Water Catalyzed by Carboxylato Ruthenium(II) Systems P. B. Arockiam, C. Fischmeister, C. Bruneau, P. H. Dixneuf, Angew. Chem. Int. Ed. 2010, 49, 6629-6632. Preparation of sugar β-amino acid derivatives with cyclic structures via ring closing metathesis B. Sundararaju, T. Sridhar, M. Achard, G. V. M. Sharma, C. Bruneau, Eur. J. Org. Chem. 2010, 6092-6096. New Ruthenium-Indenylidene Olefin Metathesis Catalyst with Enhanced Thermal Stability A. Kabro, C. Fischmeister, C. Bruneau, Chem. Eur. J. 2010, 16, 12255-12261. Imidazolium-Oxazoline Salts in Ruthenium-Catalyzed Allylic Substitution and Cross Metathesis of Formed Branched Isomers H. Ben Ammar, B. Ben Hassine, C. Fischmeister, P. H. Dixneuf, C. Bruneau, Eur. J. Inorg. Chem. 2010, 47524756. Allenylidene to Indenylidene Rearrangement in Cationic p-Cymene Ruthenium(II) Complexes: Solvent, Counteranion, and Substituent Effects in the Key Step toward Catalytic Olefin Metathesis A. Antonucci, M. Bassetti, C. Bruneau, P. H. Dixneuf, C. Pasquini, Organometallics 2010, 29, 4524-4531. Immobilization of an ionically tagged Hoveyda catalyst on a supported ionic liquid membrane: an innovative approach for metathesis reactions in a catalytic membrane reactor A. Keraani, M. Rabiller-Baudry, C. Fischmeister, C. Bruneau, Catalysis Today 2010, 156, 268-275. Alkylidene-Ruthenium-Tin Catalysts for the Formation of Fatty Nitriles and Esters via Cross-Metathesis of Plant Oil Derivatives X. Miao, A. Blokhin, A. Pasynskii, S. Nefedov, S. N. Osipov, T. Roisnel, C. Bruneau, P. H. Dixneuf, Organometallics 2010, 29, 5257–5262. Improving sustainability in ene-yne cross-metathesis for transformation of unsaturated fatty esters V. Le Ravalec, A. Dupé, C. Fischmeister, C. Bruneau, ChemSusChem 2010, 3, 1291-1297. Ruthenium-catalyzed cascade N- and C(3)-dialkylation of cyclic amines with alcohols involving hydrogen autotransfer processes B. Sundararaju, Z. Tang, M. Achard, G. V. M. Sharma, L. Toupet, C. Bruneau, Adv. Synth. Catal. 2010, 352, 3141-3146. 2009 Ruthenium-catalyzed synthesis of functionalized 1,3-dienes M. Achard, N. Derrien, B. Demerseman, H.-J. Zhang, C. Bruneau, Org. Lett. 2009, 11, 185-188. Renewable materials as precursors of linear nitrile-acid derivatives via cross-metathesis of fatty esters and acids with acrylonitrile and fumaronitrile R. Malacea, C. Fischmeister, C. Bruneau, J.-L. Dubois, J.-L. Couturier, P. H. Dixneuf, Green Chem. 2009, 11, 152-155. Synthesis, Characterization, and Catalytic Activity of New N-Heterocyclic Bis(carbene)-Ruthenium Complexes I. Özdemir, S. Demir, N. Gürbüz, B. Çetinkaya, L. Toupet, C. Bruneau, P. H. Dixneuf, Eur. J. Inorg. Chem. 2009, 1942-1949. First transformation of unsaturated fatty esters involving enyne cross-metathesis V. Le Ravalec, C. Fischmeister, C. Bruneau, Adv. Synth. Catal. 2009, 351, 1115-1122. A direct route to bifunctional aldehyde derivatives via self- and cross-metathesis of unsaturated aldehydes X. Miao, C. Fischmeister, C. Bruneau, P. H. Dixneuf, ChemSusChem 2009, 2, 542-545. (Arene)ruthenium catalysts for olefin metathesis C. Bruneau, C. Fischmeister, P. H. Dixneuf, Chem. Today 2009, 27, 17-19. Synthesis of chiral 2-cyanomethyl oxazolines and their applications in ruthenium-catalyzed allylic substitution C. Youssef, H. Ben Ammar, R. Ben Salem, C. Bruneau, P. H. Dixneuf, J. Soc. Chim. Tunisie 2009, 11, 9-13. Hydrogenation of -N-Substituted and -N,N-Disubstituted Enaminoesters in the presence of Iridium(I) Catalyst H. Hebbache, Z. Hank, C. Bruneau, J.-L. Renaud, Synthesis 2009, 2627-2633. Ruthenium-catalyzed nucleophilic allylic substitution reactions from -silylated allylic carbonates H.-J. Zhang, B. Demerseman, L. Toupet, Z. Xi, C. Bruneau, Organometallics, 2009, 28, 5173-5182. Ruthenium-catalyzed selective N,N-diallylation- and N,N,O-triallylation of free amino acids B. Sundararaju, M. Achard, G. V. M. Sharma, C. Bruneau, Org. Biomol. Chem. 2009, 7, 3906-3909. Hydride-induced Novel Cyclization of Dienedinitriles Leading to Multi-functionalized Cyclopentadienes H.-J. Zhang, T. Meng, B. Demerseman, C. Bruneau, Z. Xi, Org. Lett. 2009, 11, 4458-4461. Efficient ruthenium(IV)-catalyzed synthesis of [3]dendralenes from 1,3-dienic allylic carbonates K. Beydoun, H.-J. Zhang, B. Sundararaju, B. Demerseman, M. Achard, Z. Xi, C. Bruneau, Chem. Commun., 2009, 6580-6582. Diethyl carbonate as a solvent for ruthenium catalysed C–H bond functionalisation P. Arockiam, V. Poirier, C. Fischmeister, C. Bruneau, P. H. Dixneuf, Green Chem. 2009, 11, 1871-1875. Ruthenium Catalysts for Controlled Mono- and Bis-Allylation of Active Methylene Compounds with Aliphatic Allylic Substrates H.-J. Zhang, B. Demerseman, Z. Xi, C. Bruneau, Adv. Synth. Catal. 2009, 351, 2724-2728. 2008 Activation and functionalization of benzylic derivatives by palladium catalysts B. Liégault, J.-L. Renaud, C. Bruneau, Chem. Soc. Rev. 2008, 37, 290-299. Synthesis of stereo-defined 1,1,4,4-tetrahalo- and 1,1,4,4-mixed-tetrahalo-1,3-butadienes H. Zhang, Z. Song, C. Wang, C. Bruneau, Z. Xi, Tetrahedron Lett. 2008, 49, 624-627. Synthesis of -aminoacid derivatives via enantioselective hydrogenation of -substituted--(acylamino) acrylates C. Bruneau, J.-L. Renaud, T. Jerphagnon, Coord. Chem. Rev. 2008, 252, 532–544. Synthesis of new perhydroindole derivatives and their evaluation in ruthenium-catalyzed hydrogen transfer reduction B. Liégault, X. Tang, C. Bruneau, J.-L. Renaud, Eur. J. Org. Chem. 2008, 934-940. Tris(acetonitrile)(pentamethylcyclopentadienyl]ruthenium, hexafluorophosphate C. Bruneau, B. Demerseman, L. Paquette, P. Fuchs, D. Crich, G. Molander Eds, in Encyclopedia of Reagents for Organic Synthesis, Copyright © 2008 John Wiley & Sons, Ltd, DOI: 10.1002/047084289X.rn00810, Article Online Posting Date: March 14, 2008. Ethenolysis of methyl oleate in room-temperature ionic liquids C. Thurier, C. Fischmeister, C. Bruneau, H. Olivier-Bourbigou, P. H. Dixneuf, ChemSusChem 2008, 1, 118-122. Ruthenium catalysts for nucleophilic allylic substitution C. Bruneau, J.-L. Renaud, B. Demerseman, Pure Appl. Chem. 2008, 80, 861-871. Direct arylation of arene C-H bonds by cooperative action of NHCarbene-ruthenium(II) catalyst and carbonate via proton abstraction mechanism I. Özdemir, S. Demir, B. Çetinkaya, C. Gourlaouen, F. Maseras, C. Bruneau, P. H. Dixneuf, J. Am. Chem. Soc. 2008, 130, 1156-1157. Ruthenium-catalyzed cyclotrimerization of 1,6- and 1,7-azadiynes. New access to fluorinated bicyclic amino acids G. T. Shchetnikov, S. N. Osipov, C. Bruneau, P. H. Dixneuf, Synlett 2008, 578-582. Synthesis of benzylic imidazolidinium, 3,4,5,6-tetrahydropyrimidinium, and benzimidazolium salts, and their applications in ruthenium-catalyzed allylic substitution S. Yasar, I. Özdemir, B. Cetinkaya, J.-L. Renaud, C. Bruneau, Eur. J. Org. Chem. 2008, 2142-2149. Iron salts-catalyzed synthesis of -N-substituted aminoacrylates H. Hebbache, Z. Hank, S. Boutamine, M. Meklati, C. Bruneau, J.-L. Renaud, Compt. Rend. Acad. Sci. 2008, 11, 612-619. Ruthenium-catalyzed tandem allylic substitution-isomerization : a direct route to propiophenones from cinnamyl chloride derivatives M. Helou, J.-L. Renaud, B. Demerseman, F. Carreaux, C. Bruneau, New J. Chem. 2008, 32, 929-931. Ruthenium-catalyzed synthesis of allylic alcohols : boronic acid as hydroxide source A. Bouziane, M. Helou, B. Carboni, F. Carreaux, B. Demerseman, C. Bruneau, J.-L. Renaud, Chem. Eur. J. 2008, 14, 5630-5637. Novel [Ru(C5Me4R)(2-quinolinecarboxylato)(allyl)][PF6] Complexes as Efficient Catalysts for Highly Regioselective Nucleophilic Substitution of Aliphatic Allylic Substrates H.-J. Zhang, B. Demerseman, L. Toupet, Z. Xi, C. Bruneau, Adv. Synth. Catal. 2008, 350, 1601-1609. New ruthenium complexes bearing bulky pentasubstituted cyclopentadienyl ligands and evaluation of [Ru(5C5Me4R)(MeCN)3][PF6] in nucleophilic allylic substitution H.-J. Zhang, B. Demerseman, Z. Xi, C. Bruneau, Eur. J. Inorg. Chem. 2008, 3212-3217. Dimethylcarbonate: an eco-friendly solvent in ruthenium-catalyzed olefin metathesis transformations X. Miao, C. Fischmeister, C. Bruneau, P. H. Dixneuf, ChemSusChem 2008, 1, 813-816. Pentamethylcyclopentadienyl ruthenium : an efficient catalyst for the redox isomerization of functionalized allylic alcohols into carbonyl compounds A. Bouziane, B. Carboni, C. Bruneau, F. Carreaux, J.-L. Renaud, Tetrahedron 2008, 64, 11745-11750. 2007 Tertiary 3-aminopropenones and 3-aminopropenoates: their preparation with and without Lewis acid, from secondary amines and 1,3-diketo compounds R. K. Vohra, C. Bruneau, J.-L. Renaud, Synthesis 2007, 731-738. Ionic imidazolium containing ruthenium complexes and olefin metathesis in ionic liquids C. Thurier, C.Fischmeister, C. Bruneau, H. Olivier-Bourbigou, P. H. Dixneuf, J. Mol. Catal. A: Chem. 2007, 268, 127-133. Palladium-catalyzed preparation of functional tetralins via benzylic activation B. Liégault, J.-L. Renaud, C. Bruneau, Adv. Synth. Catal. 2007, 349, 841-845. Catalytic cycloisomerization of enynes involving various activation processes C. Bruneau in “Metathesis Chemistry : From Nanostructure Design to Synthesis of Advanced Materials", Y. Imamoglu, V. Dragutan Eds., Springer, 2007, pp. 375-394. Ruthenium catalyzed transformations of cyclopropylethynes I. Emme, C. Bruneau, P. H. Dixneuf, H.-C. Militzer, A. de Meijere, Synthesis 2007, 22, 3574-3588. 2006 Lewis acid-catalyzed sequential transformations: straightforward preparation of functional dihydropyridines R. K. Vohra, C. Bruneau, J.-L. Renaud, Adv. Synth. Catal. 2006, 348, 2571-2574. (S,S,S)-Perhydroindolic acid: efficient catalyst for direct asymmetric aldol reaction from aromatic aldehydes X. Tang, B. Liegault, J.-L. Renaud, C. Bruneau, Tetrahedron : Asymmetry 2006, 17, 2187-2190. Cascade and sequential catalytic transformations initiated by ruthenium catalysts C. Bruneau , S. Dérien, P. H. Dixneuf in "Metal-catalyzed Cascade Reactions", Ed. T. J. J. Müller, “Topics in Organometallic Chemistry”, Springer, 2006, Vol. 19, pp. 295-326. Allylic Alkylation and Etherification Catalyzed by in situ generated N-Heterocyclic Carbene Ruthenium Complexes N. Gürbüz, I. Özdemir, B. Çetinkaya, J.-L. Renaud, B. Demerseman, C. Bruneau, Tetrahedron Lett. 2006, 47, 535-538. Pentamethylcyclopentadienyl ruthenium catalysts for regio- and enantioselective allylation of nucleophiles C. Bruneau, J.-L. Renaud, B. Demerseman, Chem. Eur. J. 2006, 12, 5178-5187. -Allylruthenium Complexes and Ruthenium-Catalyzed Nucleophilic Substitution of Allylic Substrates J.-L. Renaud, C. Bruneau, B. Demerseman, M. D. Mbaye, Curr. Org. Chem. 2006, 10, 115-133. Synthesis and Reactivity of Cationic [Cp*(L)(MeCN)2Ru]PF6 (L= Ph2POMe or Ph2P-o-tolyl) and {Cp*[Ph2PCH2C(tBu)=O](MeCN)Ru] PF6 Complexes, their Involvement as Catalyst Precursors for Regioselective Allylic Substitution Reactions, and Related [Cp*(3-CH2CHCHR)(Ph2POMe)RuCl][PF6] Ruthenium(IV) Intermediates B. Demerseman, J.-L. Renaud, L. Toupet, C. Hubert, C. Bruneau, Eur. J. Inorg. Chem. 2006, 1371-1380. Metal vinylidenes and allenylidenes in catalysis. Applications in anti-Markovnikov additions to terminal alkynes and alkene metathesis C. Bruneau, P. H. Dixneuf, Angew. Chem. Int. Ed. 2006, 45, 2176-2203. Direct Preparation of Ru(2-O2CO)(6-Arene)(L) Carbonate Complexes (L = Phosphane, Carbene), and their Use as Precursors of RuH2(p-Cymene)(PCy3) and [Ru(6-Arene)(L)(MeCN)2][BF4]2. X-Ray Crystal Structure Determination of Ru(2-O2CO)(p-Cymene)(PCy3)·1/2CH2Cl2 and of Ru(2-O2CO)(6-C6Me6)(PMe3)·H2O B. Demerseman, M. D. Mbaye, D. Sémeril, L. Toupet, C. Bruneau, P. H. Dixneuf, Eur. J. Inorg. Chem. 2006, 1174-1181. 2005 Anti-Markovnikov addition to terminal alkynes via ruthenium vinylidene intermediates C. Bruneau, Wiley-VCH Handbook of C H Bond Transformation, G. Dyker Ed., Weinheim, 2005, vol. 1, pp 7280. Ruthenium-Catalyzed Allylation Reaction in Ionic Liquid C. Hubert, J.-L. Renaud, B. Demerseman, C. Fischmeister, C. Bruneau, J. Mol. Catal. A: Chem. 2005, 237, 161164. Homologation of monoterpenoids into new sesquiterpenoids via tandem isomerization/Claisen rearrangement reactions with three component ruthenium catalysts and Ru(methallyl) 2(cod) revealed by high throughput screening techniques J. Le Nôtre, R. Touzani, O. Lavastre, C. Bruneau, P.H. Dixneuf, Adv. Synth. Catal. 2005, 347, 783-791. -Diimines as nitrogen ligands for ruthenium-catalyzed allylation reactions and related (pentamethylcyclopentadienyl)ruthenium complexes M.D. Mbaye, B. Demerseman, J.-L. Renaud, C. Bruneau, J. Organomet. Chem. 2005, 690, 2149-2158. Electrophilic activation and cycloisomerization of enynes : a new route to functional cyclopropanes C. Bruneau, Angew. Chem. Int. Ed. 2005, 44, 2328-2334. Concomitant monoreduction/hydrogenation of unsaturated cyclic imides to lactams catalyzed by ruthenium precursors R. Aoun, J.-L. Renaud, P. H. Dixneuf, C. Bruneau, Angew. Chem. Int. Ed. 2005, 44, 2021-2023. Ruthenium-catalyzed synthesis of alkylidenecyclobutenes via head-to-head dimerization of propargylic alcohols and cyclobutadiene ruthenium intermediates J. Le Paih, S. Dérien, B. Demerseman, C. Bruneau, P.H. Dixneuf, L. Toupet, G. Dazinger, K. Kirchner, Chem. Eur. J. 2005, 11, 1312-1324. Allenes and Cumulenes C. Bruneau, J.-L. Renaud in "Comprehensive Organic Functional Group Transformations II", A. R. Katritzky, R. J. K. Taylor, J. Cossy Eds, Elsevier Ltd, Oxford, 2005, vol. 1, pp. 1019-1081. 2004 Nucleophilic additions to alkynes and reactions via vinylidene intermediates C. Fischmeister, C. Bruneau, P. H. 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