The Column Model

Transcription

The Column Model

The Column Model
An aid to substitute assessment
1 Risks
2a Acute health hazards
(single affection, e.g. accident with
chemicals)
2bChronic health hazards
(repeated affection)
Very high risk
t Very toxic substances/preparations
(R26, R27, R28)
t Substances/preparations which may
liberate very toxic gases when in contact
with acids (R32) t Carcinogenic substances of categories 1 or 2
(Carc.Cat.1, K1, Carc.Cat.2, K2, R45, R49)
t Mutagenic substances of categories 1 or 2
(Mut.Cat.1, M1, Mut.Cat.2, M2, R46)
t Preparations containing carcinogenic or
mutagenic substances of categories 1 or 2
in concentrations ≥ 0.1%
High risk
t Toxic substances/preparations
(R23, R24, R25)
t Substances/preparations causing severe
burns (highly corrosive) (R35)
t Substances/preparations which may
liberate toxic gases when in contact with
water or acids (R29, R31)
t Skin sensitizing substances (R43, Sh)
t Substances sensitizing the respiratory tract
(R42, Sa)
t Preparations containing skin or respiratory
tract sensitizing substances in a concentra tion ≥ 1% (in case of gases ≥ 0.2%)
t Substances toxic to reproduction of
categories 1 or 2 (Repr.Cat.1, RE1, RF1,
Repr.Cat.2, RE2, RF2, R60, R61)
t Preparations containing substances toxic to
reproduction of categories 1 or 2 in concen trations ≥ 0.5% (in case of gases ≥ 0.2%)
t Carcinogenic substances of category 3
(Carc.Cat.3, K3, R40)
t Mutagenic substances of category 3
(Mut.Cat.3, M3, R68)
t Preparations containing carcinogenic or
mutagenic substances of category 3 in
concentrations ≥ 1%
t Substances which can accumulate in the
human body (R33)
Medium risk
t Substances/preparations harmful to health
(R20, R21, R22)
t Substances, which may accumulate in
breast milk (R64)
t Substances/preparations causing burns
(corrosive) (R34, pH ≥ 11.5, resp. ≤ 2)
t Substances harmful to eyesight (R41)
t Non toxic gases; may cause suffocation by
air displacement (e.g. nitrogen)
t Substances toxic to reproduction of
category 3 (Repr.Cat.3, RE3, RF3, R62, R63)
t Preparations containing substances of
category 3 toxic to reproduction in concen trations ≥ 5% (in case of gases ≥ 1%)
Low risk
t Irritant substances/preparations
(R36, R37, R38)
t Skin affections when working in wet
environment
t Substances/preparations which may cause
lung damage if swallowed (R65)
t Skin affecting substances/preparations
(R66)
t Vapours causing drowsiness and dizziness
(R67)
t Otherwise chronically affecting substances
(no R-phrase, but nonetheless a hazardous
substance!)
Negligible risk
tHarmless substances by experience (e.g. water, sugar, paraffin and similar)
1)German water pollution classes are only considered a ranking criteria with those substances/preparations,
which have not been assessed for properties harmful to the environment.
3 Environmental hazards1)
4 Fire and explosion
hazards2)
5 Exposure potential
6 Hazards caused by
procedures
t Substances/preparations
with the warning symbol
N and hazards indications
R50, R51, R53, R54, R55,
R56, R57, R58, R59
of the German water
pollution class WGK 3
t Explosive substances/
preparations (R2, R3)
t Extremely flammable
gases and liquids (R12)
t Spontaneously flammable
substances/preparations
(R17)
t Gases
t Liquids with a vapour
pressure > 250 hPa (mbar)
(e.g. dichloromethane)
t Dust producing solids
t Aerosols
t Open processing
t Possibility of direct skin
contact
t Application on large area
t Highly flammable
(R11)
t Substances/preparations,
liberating extremely
flammable gases when in
contact with water (R15)
t Oxidizing substances/
preparations (R7, R8, R9)
with specific properties
(R1, R4, R5, R6, R7, R14,
R16, R18, R19, R30, R44)
pressure of 50 ... 250 hPa
(mbar) (e.g. methanol)
without warning symbol
N, but with hazards
indications R52, R53
of the German water
t Flammable substances/
preparations (R10)
(mbar), except water
(e.g. toluene)
of the German water
t Hardly flammable
(flashpoint 55 ... 100 °C)
(mbar) (e.g. xylene)
t Not water polluting sub stances/preparations
(NWG, formerly WGK 0)
t Inflammable or very
hardly flammable
(for liquids flashpoint
> 100 °C)
pressure < 2 hPa (mbar)
(e.g. glycol)
t Solids releasing no dusts
2)Explosive dusts have to be analysed carefully in each single case because of their specific problems,
thus no risk level is attributed to them here.
t Closed processing but
exposure possibilities e.g.
when filling, sampling or
cleaning
t Tightly closed equipment
t Closed equipment with
exhaust facilities at points
of emission
FIGURE 2:
Green Screen for Safer Chemicals
Start at Benchmark 1 (red) and progress to Benchmark 4 (green)
This
chemical
passes
all of the
criteria.
BENCHMARK 4
ready biodegradability (low P) + low B + low Human Toxicity + low Ecotoxicity
(+ additional ecotoxicity endprints when available)
Prefer—Safer Chemical
BENCHMARK 3
If this chemical
and its breakdown products
pass all of these
criteria, then
move on to
Benchmark 4
a. moderate P or moderate B
b. moderate Ecotoxicity
c. moderate Human Toxicity
d. moderate Flammability or moderate Explosivenesness
Use but Still Opportunity for Improvement
BENCHMARK 2
If this chemical
pass all of these
criteria, then
move on to
Benchmark 3
a. moderate P + moderate B + moderate T
(moderate Human Toxicity or moderate Ecotoxicity)
b. high P + high B
c. (high P + moderate T) or (high B + moderate T)
d. moderate Human Toxicity for any priority effect or high Human Toxicity
e. high Flammability or high Explosiveness
Use but Search for Safer Substitutes
BENCHMARK 1
If this chemical
pass all of these
criteria, then
move on to
Benchmark 2
a. PBT: high P + high B + high T1 (high Human Toxicity2 or high Ecotoxicity)
b. vPvB: very high P + very high B
c. vPT (vP + high T) or vBT (vB + high T)
d. high Human Toxicity for any priority effect3
Avoid—Chemical of High Concern
FOOTNOTES:
1 Toxicity – “T” = human toxicity and ecotoxicity
2 Human Toxicity = priority effects (see below) or acute toxicity, immune
system or organ effects, sensitization, skin corrosion, or eye damage
3 Priority Effects = carcinogenicity, mutagenicity, reproductive or
developmental toxicity, endocrine disruption, or neurotoxicity
ABBREVIATIONS:
B = bioaccumulation P=persistence
T=human toxicity and ecotoxicity
vB=very bioaccumulative vP=very persistent
Green Screen for Safer Chemicals Version 1.0
Table 1 Threshold Values for Each Chemical Hazard 1 Included in the Green Screen for Safer Chemicals™ Version 1.0
Hazard
Very High (v)
Environmental Fate
High (H)
Moderate (M)
Low (L)
Persistence P (half-life in
days)1
• Soil or sediment
>180 days; or
• Water >60 days
• Soil, sediment >60 to 180 days;
• Water >40 to 60 days; or
• Potential for long-range environmental
transport
• Soil, sediment 30 to 60 days; or
• Water 7 to 40 days
• Soil, sediment <30
days;
• Water <7 days; or
• Ready biodegradability
Bioaccumulation Potential
- B1
• BCF/BAF >5000;
or
• Absent such data,
log Kow >5
• BCF/BAF >1000 to 5000;
• Absent such data, log Kow >4.5-5; or
• Weight of evidence demonstrates
bioaccumulation in humans or wildlife
• BCF/BAF 500 to 1000;
• Absent such data, log Kow >4-4.5; or
• Suggestive evidence of bioaccumulation in
humans or wildlife
• BCF/BAF <500; or
• Absent such data,
log Kow <4
Acute Aquatic Toxicity1
• LC50/EC50/IC50 <1 mg/l; or
• GHS Category 1
• LC50/EC50/IC50 1-100 mg/l; or
• GHS Category 2 or 3
• LC50/EC50/IC50 >100
mg/l
Chronic Aquatic Toxicity1
• NOEC <0.1 mg/l; or
• GHS Category 1
• NOEC 0.1-10 mg/l; or
• GHS Category 2, 3 or 4
• NOEC >10 mg/l
Ecotoxicity
Human Health
Carcinogenicity*
Mutagenicity/ Genotoxicity*
Reproductive toxicity*
• Evidence of adverse effects in humans;
• Weight of evidence demonstrates potential
for adverse effects in humans;
• NTP known or reasonably anticipated to be
human carcinogen;
• OSHA carcinogen;
• California Prop 65;
• IARC Group 1 or 2A;
• EU Category 1 or 2; or
• GHS Category 1A or 1B
• EU Category 1 o r 2; or
• NTP Center for the Evaluation of Risks to
Human Reproduction;
• California Prop 65;
• EU Category 1 or 2; or
•
•
•
•
•
•
Suggestive animal studies;
Analog data;
Chemical class known to produce toxicity;
IARC Group 2B;
EU Category 3; or
GHS Category 2
•
•
•
•
•
Analog data;
EU Category 3; or
GHS Category 2
No basis for concern
identified
•
•
•
•
•
Analog data;
EU Category 3; or
GHS Category 2
identified
• No basis for
concern identified
or
• IARC Group 3 or 4
1
*=Priority Human Health Effect. 1= Experimental data are preferred. Absent experimental data, values based on structure activity relationships are sufficient.
Abbreviations: BAF=bioaccumulation factor; BCF=bioconcentration factor; EC 50=median effective concentration; EU= European Union; GHS=Globally Harmonized
System of Classification and Labelling of Chemicals; IARC=International Agency for Research on Cancer; IC 50=mean inhibitory concentration; LC 50=median lethal
concentration: the concentration at which 50% of test animals died after exposure; LD50=median lethal dose: the dose at which 50% of test animals died during
exposure; log Kow=log-octanol water partition coefficient; NOEC=no observed effect concentration; NTP=National Toxicology Program; OSHA=Occupation Safety and
Health Administration
2
Hazard
Very High (v)
Developmental toxicity*
Endocrine Disruption*
Neurotoxicity*
Acute Toxicity (oral, dermal or
inhalation)
Corrosion/Irritation of the
Skin or Eye
Sensitization of the Skin or
Respiratory System
Immune System Effects
Systemic Toxicity/Organ Effects
(via single or repeated exposure)
High (H)
• NTP Center for the Evaluation of Risks to
Human Reproduction; or
• California Prop 65
• Evidence of adverse effects in humans; or
• Weight of evidence demonstrates that
mechanisms of action lead to adverse
effects
for adverse effects in humans
• LD50 <50 mg/kg bodyweight (oral);
• LD50 <200 mg/kg bodyweight (dermal);
• LC50 <500 ppm (gas);
• LC50 <2.0 mg/l (vapor);
• LC50 <0.5 mg/l (dust or mist);
• US EPA Extremely Hazardous Substance
List; or
• Evidence of irreversible effects in studies of
human populations;
• Weight of evidence of irreversible effects in
animal studies; or
• GHS Category 1 (skin or eye)
• GHS Category 1 – (skin or respiratory); or
• Positive responses in predictive Human
Repeat Insult Patch Tests (HRIPT) (skin)
for adverse effects in humans
• GHS Category 1 — organ/systemic toxicity
following single or repeated exposure
• Physical/Chemical Properties
Explosive
Flammable
• GHS Category: Unstable Explosives or
Divisions 1.1, 1.2 or 1.3
• GHS Category 1 - Flammable Gases;
• GHS Category 1 - Flammable Aerosols; or
• GHS Category 1 or 2 — Flammable Liquids
Moderate (M)
Low (L)
• Suggestive animal studies;
• Analog data; or
• Chemical class known to produce toxicity
identified
•
•
•
•
•
•
•
•
Analog data;
EU Draft List - Category 1 or 2; or
Japanese list
Analog data; or
Chemical class known to produce toxicity
identified
identified
• LD50 50-2000 mg/kg bodyweight (oral);
• LD50 200-2000 mg/kg bodyweight
(dermal);
• LC50 500-5000 ppm (gas);
• LC50 2-20 mg/l (vapor);
• LC50 0.5-5 mg/l (dust or mist); or
identified
• Evidence of reversible effects in humans
or animals;
• GHS Category 2 or 3 — skin irritation; or
• GHS Category 2A or 2B — eye
identified
• Suggestive animal studies;
• Analog data; or
• Chemical class known to produce toxicity
identified
•
•
•
•
•
•
•
•
Analog data; or
Chemical class known to produce toxicity
Analog data;
GHS Category 2 or 3 single exposure; or
Category 2 repeated exposure
identified
identified
• GHS Category: Divisions 1.4, 1.5
identified
• GHS Category 2- Flammable Gases;
• GHS Category 2- Flammable Aerosols; or
• GHS Category 3 or 4 - Flammable Liquids
identified
3
ACRI-BOND 105
Material Safety Data Sheet
Issued : 01. May 2007
1. IDENTIFICATION OF THE SUBSTANCE
Product name :
Supplier :
ACRI-BOND 105
Acrylic Technologies Australia Pty Ltd
Tel : 1300 788 907
Fax : 02 9639 1051
Mobile : 0414 26 09 58
E-mail : [email protected]
Composition :
Mixture of organic solvents
CAS-No.75-09-2 Dichloromethane - DCM-Approx. 90%
CAS-No.79-01-6 Trichloroethylene (stabilized) -TCE- Approx. 8%
CAS-No.80-62-6 Methyl Methacrylate Monomer (stabilized) -MMM less than 2%
Recommended use : Industrial adhesive for various plastic materials
Appearance :
Clear colourless liquid with a characteristic sweetish, ether like odour.
2. HAZARDS IDENTIFICATION
ACRI-BOND 105 IS HAZARDOUS SUBSTANCE ACCORDING TO WORKSAFE CRITERIA
Classified as Dangerous Goods for the purpose of transport by road or rail. Refer to relevant regulations
for storage and transport requirements.
DCM
TCE
MMM
6.1 Toxic :
6.1 Toxic :
3:
Poison Schedule :
S3 :
S6:
N/A
R-phrase(s) :
N/A :
R40(3)
R11; R36/37/38; R43
Class :
R40(3)- Possible risks of irreversible effects.
R11- Highly flammable.
R36/37/38- Irritating to eyes, respiratory system and skin.
R43- May cause sensitation by skin contact.
3. FIRST AID MEASURES
Ingestion :
Immediately rinse mouth with water. Give water to drink. Do NOT induce vomiting. If vomiting
occurs give further water. Do not give milk, oils or alcohol. Seek immediate medical assistance.
Eye contact :
Immediately irrigate with copious quantity of water for at least 15 minutes. Eyelids to be held
open. Remove clothing if contaminated and wash skin. Urgently seek medical assistance.
Skin contact :
Immediately wash contaminated skin with plenty of water. Remove contaminated clothing
and wash before reuse. If swelling, redness, blistering or irritation occurs seek medical advice.
Inhalation :
Remove victim from exposure-avoid becoming a casualty. Remove contaminated clothing and
wash before reuse. Allow patient to assume most comfortable position and keep warm. Keep
at rest until fully recovered. If breathing laboured and patient cyanotic (blue), ensure airways
are clear and have qualified person give oxygen through face mask. If breathing has stopped
apply artificial respiration at once. In event of cardiac arrest, apply external cardiac massage.
Seek medical advice.
Notes to
physician :
Treat symptomatically. Adrenaline and similar sympathomimetic drugs should be avoided
following exposure as cardiac arrhythmia may result, with possible subsequent cardiac arrest(1).
Treat as for exposure to chlorinated hydrocarbons (solvents). Gastric lavage may be effective
when performed within 4 hours of ingestion. Following ingestion adsorbents such as activated
charcoal may be of value (6).
Product Name : ACRI-BOND 105
Page 1 of 6
ACRI-BOND 105
4. FIRE-FIGHTING MEASURES
Specific hazard :
Not classified as flammable under normal working conditions. Certain mixtures in air
can be ignited with high intensity sources of heat (1). Welding or cutting should not be
carried out on any vessel likely to contain this solvent mixture.
Fire Fighting advice : Not combustible. Vapourises rapidly on heating. Can decompose upon contact with
a flame or very hot surface liberating toxic fumes including those of hydrogen chloride,
carbon oxides and phosgene. Fire fighters to ware self-contained breathing apparatus
if risk of exposure to products of decomposition.
Suitable
Water fog (or if unavailable fine water spray), foam, dry agent (carbon dioxide, dry
extinguishing media : chemical powder).
5. ACCIDENTAL RELEASE MEASURES
Work up wind. Increase ventilation. Clear area of all unprotected personnel. Wear protective equipment to
prevent skin and eye contamination and inhalation of vapours. Contain-prevent contamination of drains and
waterways. Use absorbent (soil, sand or other inert material ). Collect and seal in properly labelled drums
for disposal. If contamination of sewers or waterways has occurred advise the local emergency services. In
the event of spillage notify the local environmental protection authority or emergency services.
6. HANDLING AND STORAGE
Storage :
Store in a cool place and out of direct sunlight. Store in well ventilated area. Store away from
nitric acid, amines, alkalis, food stuffs and sources of heat and ignition. Store in original
container only. Keep containers closed at all times and check regularly for leaks.
This material is a Toxic Substance S3 and Scheduled Poison S6 and must be stored, maintained
and used in accordance with the relevant regulations.
7. EXPOSURE CONTROLS / PERSONAL PROTECTION
National occupational exposure limits :
Dichloromethane - DCM
Trichloroethylene -TCE
Methyl Methacrylate Monomer -MMM
TWE
ppm
50
50
100
mg/m3
174
270
410
STEL
ppm
-200
CARCINOGEN
CATEGORY
mg/m3
-1080
A2
As published by National Occupational Health and Safety Commission (Worksafe Australia)
WES-TWE
Work Exposure Standard - is the Time Weighted Average airborne concentration over an eighthour working day, for a five day working week, over an entire working life. According to current
knowledge this concentration should neither impair the health or, not cause undue discomfort
to nearly all workers.
WES-STEL Work Exposure Standard - Short Term Exposure Limit is the average airborne concentration
over a 15 minute period which should not be exceeded at any time during a normal eight hour
work day.
CARCINOGEN CATEGORY A2 Suspected Human Carcinogen
Page 2 of 6
ACRI-BOND 105
These Workplace Expose Standards are guidelines to be used in the control of occupational health hazards.
All atmospheric contamination should be kept to as low a level as is workable. WES should not be used as
fine dividing lines between safe and dangerous concentration of chemicals. They are not a measure of relative
toxicity.
Personal Protection Equipment : H-Overalls, Safety shoes, Chemical goggles, Glaves (S), Respirator.
Avoid skin and eye contact and inhalation of vapour. Wear overalls, chemical goggles and impervious gloves.
Use with adequate ventilation. Available information (5) suggests that gloves made from supported polyvinyl
alcohol should be suitable for intermittent contact. However, due to variations in glove construction and local
conditions, a final assessment should be made by the user. If inhalation risk exists wear organic vapour
respirator meeting the requirements of AS/NZS 1715 and AS/NZS 1716. Always wash hands before smoking,
eating, drinking or using the toilet. Wash contaminated clothing and other protective equipment before storing
or re-using.
8. PHYSICAL AND CHEMICAL PROPERTIES
Form/Colour/Odour :
Clear, colourless liquid with a characteristicether-like odour
DCM
TCE
MMM
Specific gravity (4 C)
Rel. Vapour Density (air=1)
Vapour Pressure (20 C)
Vapour Pressure (30 C)
Flammability Limits (%)
Autoignition Temperature (C)
Melting Point (C)
Boiling Point (C)
Viscosity
Solubility in Water (g/L)
Evapotation Rate
Conversion Factor (in air)
Flash Point (C)
Decomposition Point (C)
pH
1.32
2.93
46.5 kPa
66.7 kPa
14-22
662
-97
40
0.449 Cst
20 (20 C)
N Av
1 ppm=3.53 mg/m3
N App
N Av
N Av
1.47 (20 C)
4.54
7.87 kPa
N Av
N Av
N Av
-87
86-88
0.58 Cp
0.11% w/w
N Av
N Av
None
N Av
N App
0.949 (15.5 C)
3.5 @ 20 C
3.6 kPa
N Av
2.1-12.5
421
-48
100.5
N Av
1.6% @20 C
N Av
N Av
11.5
N Av
N App
% Volatile by volume
N Av
100
100
N Av = Not available
N App- Not applicable
9. STABILITY AND REACTIVITY
DCM forms detonable mixtures with nitric acid. It may react with certain amines like polyurethane catalysts.
Prolonged contact with aluminum or light alloys may cause a reaction with gas generation and pressure
buildup (1).
TCE can decompose to dichloroethylene, phosgene, carbon monoxide and chloroacetylenes on contact with
strong alkalis. It is also photoreactive.
MMM is stable in the presence of inhibitor. It is liable to polymerize in the presence of catalyst or prolonged
heating. Incompatible with strong acids, alkalis, oxidizing agents and polymerization catalyst. I does not
decompose up to the auto-ignition temperature.(9)
Page 3 of 6
ACRI-BOND 105
10. TOXICOLOGICAL INFORMATION
Main symptoms :
No adverse health effects expected if the product is handled in accordance with this Safety Data Sheet and
product label. Symptoms that may arise if the product is mishandled are:
Ingestion :
Swallowing large amounts can result in nausea, vomiting, headaches, dizziness, gastrointestinal irritation,
drowsiness, unconsciousness(1) and central nervous system depression.
Eye contact :
DCM liquid is a moderate eye irritant (1). Liquid splashes may result in transient eye damage. (1). No eye irritation
was reported by volunteers exposed to about 1000 ppm vapour for two hours. Marked irritative conjunctivitis and
lacrimation were noted at vapour concentrations high enough to produce unconsciousness (2). TCE vapour and
liquid are mild to moderate irritants. Permanent damage is unlikely (6). MMM is eye irritant. High vapour
concentration will cause irritation (9).
Skin contact :
The liquid can be absorbed through the skin. Contact with skin may result in slight to mild irritation(6). Will have
degreasing action on the skin. Repeated or prolonged contact may cause reddening, burning and blistering of
the skin (1).
Inhalation :
Vapour may be irritant to mucous membranes and respiratory tract. Inhalation of high concentrations will lead to
anesthetic effects and adverse effects to the central nervous system. Symptoms may include lightheadedness
(1000 ppm for 20 minutes), dizziness, nausea, vomiting and headache. Inhalation of very high concentrations can
result in loss of consciousness and irregular heart beat and prove suddenly fatal(1). Methylene chloride is
converted to carbon monoxide in the body, which reduces the oxygen carrying capacity of the blood. This is
reflected by a raised carboxyheamoglobin concentration in the blood (1).
Long term effects :
Repeated exposure to high levels of DCM and/or TCE may produce liver and kidney damage (1). Evidence
available indicates that DCM is an animal carcinogen and therefore should be considered a possible human
carcinogen. This data are not considered relevant to normal industrial use but emphasize the need for care in
handling. A condition known as " Degreaser's Flush ", a pronounced redness of the skin, may occur on the face,
hands, arms, feet and trunk of some individuals following repeated exposure to TCE and consumption of alcohol.
This effect can intensify over a 30 minute period but usually disappears completely after 1 hour. The symptoms
may occur up to 6 weeks after the last exposure to TCE and can reoccur if exposure continues. There is no
reason to believe that MMM represents a carcinogenic or mutagenic hazard to man based upon evidence from
well conducted animal studies and adequate epidemiology studies in relevant cohorts. Recent studies in animals
have shown that high exposures do not produce embryo or foetotoxic nor teratogenic effects in the presence of
mathernal toxicity (9).
Acute Toxicity/Chronic Toxicity :
DCM
Oral LD50(rat): 2100 mg/kg (3)
Inhalation LD50(rat): 200mg/m3/15 minutes (3)
No adverse effects on blood count, blood pressure, pulmonary function, neurological function cognitive function,
alertness and coordination were detected when healthy adults were exposed repeatedly to up to 250 ppm of DCM
for 7.5 hrs/day, 5 days/week for two weeks or in the case of the male subjects, at 500 ppm on two consecutive
days (4). Several major studies on human workers showed no casual relationship between exposure to DCM and
an increase in the evidence of cancer (1).
A chronic inhalation study in the mouse has shown that DCM is carcinogenic in this species, when exposed to
levels well above the exposure level, causing tumors both in the liver and the lung (1).
Additional studies in the mouse, rat and the hamster have shown no further significant evidence of carcinogenic
effect. The effect in mice is specific to this species and is very unlikely to occur in humans. This is due to well
established differences in the metabolic pathways between rodents and humans (1).
DCM has been classified (IARC) as group 2B agent - The agent is possibly carcinogenic to humans.
Page 4 of 6
ACRI-BOND 105
Acute Toxicity/Chronic Toxicity :
TCE
Oral LD50(rats, cats and rabbits): 6000-7000 mg/kg (7)
A volunteer exposed to 1000 ppm of TCE for two hours experienced adverse effects on visual perception and
motor skill. When the volunteer was exposed to 100 and 300 ppm for two hours no significant effects were
reported (7).
Long term daily exposure of animals with high oral doses have resulted in liver and kidney damage. Repeated
exposure of humans in the workplace appears to have no marked toxic effects on the kidney or liver (4).
The genotoxic potential of TCE has been studied widely using in vivo and in vitro test systems; many of these
extensively reported studies used material containing potentially mutagenic epoxide stabilizers. Overall there is
no convincing evidence that TCE is genotoxic(8).
TCE has been associated with cancer in rodents. Extensive evaluations of possible mechanisms have led to
the conclusion that they are of little, if any, relevance to humans even at high exposure levels. Studies in workers
have failed to demonstrate a relationship between exposure to TCE and cancer (6).
TCE has been classified by the International Agency for Research on Cancer (IARC) as a Group 2A agent The agent is probably carcinogenic to humans. Classified by the American Conference of Governmental
Industrial Hygienists (ACGIH) as A5- Not suspected as a human carcinogen (7).
MMM
Oral LD50(rat): 7872 mg/kg (10)
Inhalation LC50 (mouse): 18500 mg/m3/2 hrs (10)
Inhalation Lowest Toxic Concentration (human): 50 ppm (10).
Results from animal studies that are relevant to occupational exposure indicate that there is no evidence of
carcinogenicity (1,3). Based on the above mutagenicity and carcinogenicity results, MMM is not expected to
pose a carcinogenic hazard to humans. MMM has been classified by the IARC as a Group 3 agent.
Group 3 - The agent is not classifiable as to its carcinogenicity to humans.
11. TRANSPORT INFORMATION
Classified as Dangerous Goods for the purpose of transport by road or rail. Refer to relevant regulations for
storage and transport requirements.
UN-No :
Class :
Hazchem code :
Packing group :
EPG :
Shipping Name:
ACRIBOND 105
as a mixtrure
DCM
TCE
MMM
2810
6.1 Toxic
2Z
3
1593
6.1 Toxic
2Z
3
1710
6.1 Toxic
2Z
3
6B7
1247
3 Flammable Liquid
3[Y]
2
3A1:
Toxic Liquid, Organic, N.O.S.
12. DISPOSAL CONSIDERATIONS
Refer to Local City, District or regional Council Waste Management Authority. Transfer solvent residues
to a labeled, sealed container for disposal or recovery. Waste disposal must be an accredited contractor.
Page 5 of 6
ACRI-BOND 105
13. OTHER INFORMATION
(1) Hazard Data Sheet - Methylene chloride, Version 4, ICI UK, 21/02/96
(2) Health and Safety Executive, Toxicity Review 12, Dichloromethane, Her Majesty's Stationary Office:
London, 1985.
(3) In 'Dictionary of Substances and their Effects', ( Ed. Richardson M.L. and Gangolli S.), Vol. 3, P 326-327,
(Royal Society of Chemistry 1994).
(4) In 'Documentation of the Treshold Limit Values and Biological Exposure Indices 6th Edition' (Ed. American
Conference of Governmental Industrial Hygienists), p 985, (Ed. American Conference of Governmental
Industrial Hygienists : Cincinatti 1991).
(5) In ' Ansell Edmont Chemical Resistance Guide 5th Ed', (Ansell Edmont Industrial Inc. 1990).
(6) Safety Data Sheet - Triklone LE; ICI UK C&P; 01/96
(7) In ' Treshold Limit Values and Biological Exposure Indices 1996' (Ed.ACGIH), P 36, (ACGIH: Cincinatti 1996).
(8) European Centre for Ecotoxicology and Toxicology of Chemicals- Technical Report No. 60 , Trichloroethylene:
Assesstment of Human Carcinogenic Hazard; ECETOC, Belgium 1994.
(9) Safety and Health of the Dept of Health and Human Services, USA.
(10) Australian Atmospheric Exposure Standards, Commonwealth of Australia (1991).
This Material Safety Data Sheet summarises at the date of issue our best knowledge of the health and safety
hazard information of the product, and in particular how to safely handle and use the product in the workplace.
Since Adhesive Solutions Australia can not anticipate or control the conditions under which the product may
be used, each user must, prior to usage, review this MSDS in the context of how the user intends to handle
and use the product in the workplace.
Page 6 of 6
FICHE DE DONNÉES DE SÉCURITÉ
conformément à la
directive CE/2001/58
VERTREL ® XH
Cleaning agent
Version 3.0
Date de révision 26.10.2004
Réf. 130000000666
Cette FDS est conforme aux normes et aux réglementations de la France et ne correspond peut-être pas aux
réglementations dans un autre pays.
1. IDENTIFICATION DE LA SUBSTANCE/PRÉPARATION ET DE LA SOCIÉTÉ/ENTREPRISE
Informations sur le produit
®
XH
Cleaning agent
Nom du produit
:
VERTREL
Utilisation de la
substance/de la préparation
:
produit de nettoyage
Société
:
Téléphone
Téléfax
:
:
DuPont de Nemours (Nederland) B.V.
Dordrecht Works
Baanhoekweg 22
3313 LA Dordrecht
+31786301720
+31786301192
Téléphone en cas
d'urgence
:
+352-3666-6543
2. COMPOSITION/INFORMATION SUR LES COMPOSANTS
Nom Chimique
Décafluoropentane
No.-CAS
138495-42-8
Heptane
142-82-5
No.-CE
Classification
420-640-8 R52/53
Concentration [%]
93
205-563-8 F; R11
Xn; R65
Xi; R38
R67
N; R50 -R53
7
Pour le texte complet des phrases R mentionnées dans cet article, voir article 16.
3. IDENTIFICATION DES DANGERS
Lors de l'utilisation, formation possible de mélange vapeur-air inflammable/explosif.
Toxique pour les organismes aquatiques, peut entraîner des effets néfastes à long terme pour l'environnement
aquatique.
Les vapeurs sont plus lourdes que l'air et peuvent provoquer la suffocation par réduction de la teneur en oxygène.
Le contact prolongé avec la peau peut dégraisser la peau et provoquer une dermatose.
4. PREMIERS SECOURS
Conseils généraux
:
Ne jamais rien faire avaler à une personne inconsciente. La victime doit rester
allongée en position de repos, la couvrir et la garder au chaud. Respiration
artificielle en cas de respiration irrégulière ou d'arrêt respiratoire.
Inhalation
:
Mettre la victime à l'air libre. Coucher la personne concernée et la maintenir au
chaud. Respiration artificielle et/ou oxygène peuvent être nécessaires.
Contact avec la peau
:
Laver à l'eau chaude. Enlever immédiatement tout vêtement souillé.
1/6
conformément à la
VERTREL ® XH
Cleaning agent
Version 3.0
Réf. 130000000666
Contact avec les yeux
:
Bien rincer avec beaucoup d'eau, y compris sous les paupières. Consulter un
médecin.
Ingestion
:
Ne pas faire vomir sans l'avis d'un médecin. Boire 1 ou 2 verres d'eau.
Consulter un médecin.
:
Ne pas donner d'adrénaline ou de médicaments similaires.
Avis aux médecins
Traitement
5. MESURES DE LUTTE CONTRE L’INCENDIE
Dangers spécifiques
pendant la lutte contre
l'incendie
:
Le feu ou une chaleur intense peuvent entraîner la rupture de l'emballage.
Equipements spéciaux pour
la protection des
intervenants
:
En cas d'incendie, porter un appareil de protection respiratoire autonome.
Utiliser un équipement de protection individuelle.
Information supplémentaire
:
Utiliser des moyens d'extinction appropriés aux conditions locales et à
l'environnement voisin. Refroidir les récipients/réservoirs par pulvérisation d'eau.
Les résidus d'incendie et l'eau d'extinction contaminée doivent être éliminés
conformément à la réglementation locale en vigueur.
6. MESURES À PRENDRE EN CAS DE DISPERSION ACCIDENTELLE
Précautions individuelles
:
Évacuer le personnel vers des endroits sûrs. Ventiler la zone. Voir mesures de
protection sous chapitre 7 et 8.
Précautions pour la
protection de
l'environnement
:
Eviter une fuite ou un déversement supplémentaire Éviter l'extension de la
surface (p.e. par bac de rétention ou barrières à huile). Ne pas décharger dans
l'environnement.
Méthodes de nettoyage
:
Contenir et collecter le matériel répandu à l'aide d'un matériau absorbant non
combustible, (p.e. sable, terre, kieselgur, vermiculite) et le mettre dans un
conteneur pour l'élimination conformément aux réglementations locales /
nationales (voir chapitre 13).
7. MANIPULATION ET STOCKAGE
Manipulation
Conseils pour une
manipulation sans danger
:
Prévoir un renouvellement d'air et/ou une ventilation suffisante dans les ateliers.
Équipement de protection individuel, voir section 8. Éviter le contact avec la
peau, les yeux et les vêtements.
Indications pour la
protection contre l'incendie
et l'explosion
:
Eviter toute formation de poussieres de mélanges de fluorocarbones et de
métal.
Stockage
2/6
conformément à la
VERTREL ® XH
Cleaning agent
Version 3.0
Réf. 130000000666
Exigences concernant les
aires de stockage et les
conteneurs
:
Tenir le récipient bien fermé dans un endroit sec et bien aéré. Conserver dans
le conteneur original.
Précautions pour le
stockage en commun
:
Pas de matières à signaler spécialement.
Classe de stockage
(Allemagne)
:
12 : Substances liquides non combustibles
Autres données
:
Pas de décomposition si le produit est entreposé et utilisé selon les
prescriptions.
8. CONTRÔLE DE L'EXPOSITION/PROTECTION INDIVIDUELLE
Mesures d'ordre technique
Assurer une ventilation adéquate, surtout dans les endroits clos.
Équipement de protection individuelle
Protection respiratoire
:
Utiliser un appareil de protection respiratoire autonome lors des opérations de
sauvetage et d'entretien dans les cuves de stockage. Les vapeurs sont plus
lourdes que l'air et peuvent provoquer la suffocation par réduction de la teneur
en oxygène.
Protection des mains
:
Matériel: Gants résistants à l'acide hydrofluorique et aux solvants (gants en
VITON*).
Épaisseur du gant: 0,7 mm
Temps d'utilisation: 2 h
Protection des yeux
:
lunettes de sécurité
Protection de la peau et du
corps
:
vêtement de protection
Mesures d'hygiène
:
À manipuler conformément aux bonnes pratiques d'hygiène industrielle et aux
consignes de sécurité. Lors de l'utilisation, ne pas manger, boire ou fumer. Ne
pas respirer les vapeurs ou le brouillard de pulvérisation. Éviter le contact avec
la peau, les yeux et les vêtements.
9. PROPRIÉTÉS PHYSIQUES ET CHIMIQUES
Forme
:
liquide,
Couleur
:
incolore,
Odeur
:
légère, d'éther,
pH
:
neutre
Point/intervalle de fusion
:
< -80,0 °C
3/6
conformément à la
VERTREL ® XH
Cleaning agent
Version 3.0
Réf. 130000000666
Point/intervalle d'ébullition
:
53,0 °C à 1 013 hPa
Point d'éclair
: , Méthode: ISO 3679 n'a pas de point d'éclair
Limite d'explosivité,
supérieure
: , non applicable
Pression de vapeur
: 269 hPa à 52 °C
Densité
:
Solubilité dans l'eau
: ca. 0,093 - 0,159 g/l à 20 °C
1,47 g/cm3 à 25 °C
10. STABILITÉ ET RÉACTIVITÉ
Conditions à éviter
:
Le produit n'est pas inflammable dans l'air, a température et pression ambiante.
Mis sous pression d'air ou d'oxygene, le mélange peut devenir inflammable.
Certains mélanges de HCFCs ou HFCs avec du chlore peuvent devenir
inflammable ou réactif sous certaines conditions.
Matières à éviter
: métaux alcalins, métaux alcalino-terreux, poudres métalliques, sels métalliques
en poudre
Produits de décomposition
dangereux
: hydrocarbures fluorés, fluorure d'hydrogène, dioxyde de carbone (CO2),
Monoxyde de carbone
Réactions dangereuses
: Pas de décomposition si le produit est entreposé et utilisé selon les
prescriptions.
11. INFORMATIONS TOXICOLOGIQUES
Toxicité orale aiguë
• Décafluoropentane
:
DL50/rat : > 5 000 mg/kg
Toxicité aiguë par inhalation
:
CL50/4 h/rat : 114 mg/l
Irritation de la peau
:
Pas d'irritation de la peau Contacts prolongés ou répétés avec la préparation
peuvent enlever la graisse naturelle de la peau et provoquer ainsi dermatites
nonallergiques de contact et absorption a travers l'épiderme.
Irritation des yeux
:
Pas d'irritation des yeux
Sensibilisation
:
N'a pas d'effet sensibilisant sur les animaux de laboratoire.
4/6
conformément à la
VERTREL ® XH
Cleaning agent
Version 3.0
Expérience chez l'homme
Réf. 130000000666
:
Les expositions excessives peuvent affecter la santé humaine, comme suit:
Inhalation
narcose, insuffisance respiratoire grave, Activité cardiaque irrégulière
12. INFORMATIONS ÉCOLOGIQUES
Toxicité pour les poissons
:
CL50/96 h/Poisson zèbre: 13 mg/l
• Heptane
:
CL50/96 h/: 1,53 mg/l
Toxicité pour les algues
:
CE50/72 h/Algues: > 120 mg/l
Toxicité aquatique
:
CE50/24 h/Daphnie: 62,0 mg/l
13. CONSIDÉRATIONS RELATIVES À L'ÉLIMINATION
Produit
:
Peut être utilisé après reconditionnement. Si le recyclage n'est pas possible,
éliminer conformément aux réglementations locales. Empêcher le produit de
pénétrer dans les égouts, les cours d'eau ou le sol.
Emballages contaminés
:
Si le recyclage n'est pas possible, éliminer conformément aux réglementations
locales.
14. INFORMATIONS RELATIVES AU TRANSPORT
Autres Informations
:
Produit non dangereux au sens des réglementations pour le transport.
15. INFORMATIONS RÉGLEMENTAIRES
Étiquetage selon les Directives CE
Symbole(s)
:
N
Dangereux pour l’environnement
Phrase(s) de risque
:
R18
Lors de l'utilisation, formation possible de mélange vapeurair inflammable/explosif.
Toxique pour les organismes aquatiques, peut entraîner des
R51/53
5/6
conformément à la
VERTREL ® XH
Cleaning agent
Version 3.0
Réf. 130000000666
effets néfastes à long terme pour l'environnement aquatique.
Phrase(s) de sécurité
:
S57
S60
Étiquetage exceptionnel
pour préparations spéciales
:
Utiliser un récipient approprié pour éviter toute contamination
du milieu ambiant.
Éliminer le produit et son récipient comme un déchet
dangereux.
Peut devenir facilement inflammable pendant l'utilisation.
16. AUTRES INFORMATIONS
Texte des phrases R mentionnées sous l'article 2
R11
R38
R50
R52/53
R53
R65
R67
Facilement inflammable.
Irritant pour la peau.
Très toxique pour les organismes aquatiques.
Nocif pour les organismes aquatiques, peut entraîner des effets néfastes à long terme
pour l'environnement aquatique.
Peut entraîner des effets néfastes à long terme pour l'environnement aquatique.
Nocif: peut provoquer une atteinte des poumons en cas d'ingestion.
L'inhalation de vapeurs peut provoquer somnolence et vertiges.
Autres informations
Consulter les informations de sécurité de DuPont avant utilisation., Pour de plus amples renseignements veuillez
®
contacter le bureau le plus proche de DuPont ou de son distributeur officiel., Marque déposée de DuPont
Les informations contenues dans la présente fiche de sécurité ont été établies sur la base de nos connaissances à
la date de publication de ce document. Ces informations ne sont données qu'à titre indicatif en vue de permettre des
opérations de manipulation, fabrication, stockage, transport, distribution, mise à disposition, utilisation et élimination
dans des conditions satisfaisantes de sécurité, et ne sauraient donc être interprétées comme une garantie ou
considérées comme des spécifications de qualité. Ces informations ne concernent en outre que le produit
nommément désigné et, sauf indication contraire spécifique, peuvent ne pas être applicables en cas de mélange
dudit produit avec d'autres substances ou utilisables pour tout procédé de fabrication.
Autre
6/6
Safety Data Sheet
Dow Chemical Company Ltd
Product Name: ESTASOL (TM)
Revision Date: 2006/11/30
Print Date: 07 Feb 2008
Dow Chemical Company Ltd encourages and expects you to read and understand the entire (M)SDS,
as there is important information throughout the document. We expect you to follow the precautions
identified in this document unless your use conditions would necessitate other appropriate methods or
actions.
1.
Identification of the substance/preparation and of the company/undertaking
Product Name
ESTASOL (TM)
Use of the substance/preparation
Solvent.
COMPANY IDENTIFICATION
Dow Chemical Company Ltd
Diamond House, Lotus Park
Kingsbury Crescent
TW18 3AG Staines, Middlesex
United Kingdom
Customer Information Number:
0203 139 4000
EMERGENCY TELEPHONE NUMBER
24-Hour Emergency Contact:
Local Emergency Contact:
2.
Composition/information on ingredients
Component
Dimethyl succinate
Dimethyl adipate
Dimethyl glutarate
3.
+44 (0) 1553 761 251
00 44 155 37 61 251
Amount
>= 15.0 - <= 25.0 %
>= 10.0 - <= 25.0 %
>= 55.0 - <= 65.0 %
Classification:
CAS #
EC #
Not classified.
Not classified.
Not classified.
106-65-0
627-93-0
1119-40-0
203-419-9
211-020-6
214-277-2
Hazards Identification
This product is not classified as dangerous according to EC criteria.
* Indicates a Trademark
Page 1 of 6
4.
First-aid measures
Eye Contact: Immediately flush eyes with water; remove contact lenses, if present, after the first 5
minutes, then continue flushing eyes for at least 15 minutes. Obtain medical attention without delay,
preferably from an ophthalmologist.
Skin Contact: Wash skin with plenty of water.
Inhalation: Move person to fresh air; if effects occur, consult a physician.
Ingestion: If swallowed, seek medical attention. Do not induce vomiting unless directed to do so by
medical personnel.
Notes to Physician: No specific antidote. Treatment of exposure should be directed at the control of
symptoms and the clinical condition of the patient.
5.
Fire Fighting Measures
Extinguishing Media: Water fog or fine spray. Dry chemical fire extinguishers. Carbon dioxide fire
extinguishers. Foam. Do not use direct water stream. May spread fire. Alcohol resistant foams (ATC
type) are preferred. General purpose synthetic foams (including AFFF) or protein foams may function,
but will be less effective. Water fog, applied gently may be used as a blanket for fire extinguishment.
Fire Fighting Procedures: Keep people away. Isolate fire and deny unnecessary entry. Do not use
direct water stream. May spread fire. Burning liquids may be moved by flushing with water to protect
personnel and minimize property damage. Water fog, applied gently may be used as a blanket for fire
extinguishment.
Special Protective Equipment for Firefighters: Wear positive-pressure self-contained breathing
apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers,
boots, and gloves). If protective equipment is not available or not used, fight fire from a protected
location or safe distance.
Unusual Fire and Explosion Hazards: Violent steam generation or eruption may occur upon
application of direct water stream to hot liquids.
Hazardous Combustion Products: During a fire, smoke may contain the original material in addition
to combustion products of varying composition which may be toxic and/or irritating. Combustion
products may include and are not limited to: Carbon monoxide. Carbon dioxide.
6.
Accidental Release Measures
Steps to be Taken if Material is Released or Spilled: Absorb with materials such as: Sand.
Sawdust. Collect in suitable and properly labeled containers. See Section 13, Disposal
Considerations, for additional information.
Personal Precautions: Use appropriate safety equipment. For additional information, refer to Section
8, Exposure Controls and Personal Protection.
Environmental Precautions: Prevent from entering into soil, ditches, sewers, waterways and/or
groundwater. See Section 12, Ecological Information.
7.
Handling and Storage
Handling
General Handling: Avoid contact with eyes, skin, and clothing. Wash thoroughly after handling.
Storage
Store in original container.
Page 2 of 6
8.
Exposure Controls / Personal Protection
Exposure Limits
None established
Personal Protection
Eye/Face Protection: Use chemical goggles. Chemical goggles should be consistent with EN 166 or
equivalent.
Skin Protection: Use protective clothing chemically resistant to this material. Selection of specific
items such as face shield, boots, apron, or full body suit will depend on the task.
Hand protection: Use chemical resistant gloves classified under Standard EN374: Protective
gloves against chemicals and micro-organisms. Examples of preferred glove barrier materials
include: Butyl rubber. Chlorinated polyethylene. Polyethylene. Ethyl vinyl alcohol laminate
("EVAL"). Polyvinyl alcohol ("PVA"). Examples of acceptable glove barrier materials include:
Natural rubber ("latex"). Neoprene. Nitrile/butadiene rubber ("nitrile" or "NBR"). Polyvinyl
chloride ("PVC" or "vinyl"). Viton. When prolonged or frequently repeated contact may occur,
a glove with a protection class of 4 or higher (breakthrough time greater than 120 minutes
according to EN 374) is recommended. When only brief contact is expected, a glove with a
protection class of 1 or higher (breakthrough time greater than 10 minutes according to EN
374) is recommended. NOTICE: The selection of a specific glove for a particular application
and duration of use in a workplace should also take into account all relevant workplace factors
such as, but not limited to: Other chemicals which may be handled, physical requirements
(cut/puncture protection, dexterity, thermal protection), potential body reactions to glove
materials, as well as the instructions/specifications provided by the glove supplier.
Respiratory Protection: Respiratory protection should be worn when there is a potential to exceed
the exposure limit requirements or guidelines. If there are no applicable exposure limit requirements
or guidelines, wear respiratory protection when adverse effects, such as respiratory irritation or
discomfort have been experienced, or where indicated by your risk assessment process. Use the
following CE approved air-purifying respirator: Organic vapor cartridge, type A (boiling point >65 ºC)
Ingestion: Use good personal hygiene. Do not consume or store food in the work area. Wash hands
before smoking or eating.
Engineering Controls
Ventilation: Use local exhaust ventilation, or other engineering controls to maintain airborne levels
below exposure limit requirements or guidelines. If there are no applicable exposure limit
requirements or guidelines, general ventilation should be sufficient for most operations. Local exhaust
ventilation may be necessary for some operations.
9.
Physical and Chemical Properties
Physical State
Color
Odor
Flash Point - Closed Cup
Flammable Limits In Air
Autoignition Temperature
Vapor Pressure
Boiling Point (760 mmHg)
Vapor Density (air = 1)
Specific Gravity (H2O = 1)
Freezing Point
Melting Point
Solubility in Water (by
weight)
pH
Kinematic Viscosity
Liquid
Colorless
Ester
108 °C Literature
Lower: 1.5 %(V) Literature
Upper: 12.5 %(V) Literature
370 °C Literature
0.06 mmHg @ 20 °C Literature
200 - 230 °C Literature (@ 1 atmosphere).
No test data available
1.09 Literature
-25 °C Literature
-25 °C Literature
5 % @ 20 °C Literature
5 - 6 Literature
2.40 - 2.50 mm2/s @ 20 °C Literature
Page 3 of 6
10.
Stability and Reactivity
Stability/Instability
Stable.
Conditions to Avoid: Exposure to elevated temperatures can cause product to decompose.
Incompatible Materials: Avoid contact with: Oxidizers.
Hazardous Polymerization
Will not occur.
Thermal Decomposition
Decomposition products depend upon temperature, air supply and the presence of other materials.
11.
Toxicological Information
Acute Toxicity
Ingestion
Very low toxicity if swallowed. Harmful effects not anticipated from swallowing small amounts.
Swallowing may result in gastrointestinal irritation.
Single dose oral LD50 has not been determined.
Based on information for component(s): Estimated LD50, Rat > 5,000 mg/kg
Eye Contact
May cause eye irritation. May cause corneal injury.
Skin Contact
Brief contact may cause skin irritation with local redness.
Skin Absorption
Prolonged skin contact is unlikely to result in absorption of harmful amounts.
The dermal LD50 has not been determined.
Based on information for component(s): Estimated LD50, Rabbit > 2,250 mg/kg
Inhalation
Vapor may cause irritation of the upper respiratory tract (nose and throat).
12.
Ecological Information
CHEMICAL FATE
Data for Component: Dimethyl succinate
Movement & Partitioning
Bioconcentration potential is low (BCF < 100 or Log Pow < 3). Potential for mobility in soil is
very high (Koc between 0 and 50).
Henry's Law Constant (H): 3.154E-06 atm*m3/mole; 25 °C Estimated from vapor pressure
and water solubility.
Partition coefficient, n-octanol/water (log Pow): Measured
Partition coefficient, soil organic carbon/water (Koc): 10 Estimated
Persistence and Degradability
Indirect Photodegradation with OH Radicals
Rate Constant
Atmospheric Half-life
1.1475E-12 cm3/s
9.3 d
OECD Biodegradation Tests:
Biodegradation
Exposure Time
> 95 %
3 - 10 d
Method
Estimated
Method
OECD 302B Test
Page 4 of 6
Theoretical Oxygen Demand: 1.42 mg/mg
Data for Component: Dimethyl adipate
very high (Koc between 0 and 50).
Partition coefficient, n-octanol/water (log Pow): Measured
Rate Constant
3.9736E-12 cm3/s
2.7 d
Method
Estimated
Data for Component: Dimethyl glutarate
very high (Koc between 0 and 50). Given its very low Henry's constant, volatilization from
natural bodies of water or moist soil is not expected to be an important fate process.
Partition coefficient, n-octanol/water (log Pow): 0.62 Measured
Rate Constant
2.5605E-12 cm3/s
4.177 d
OECD Biodegradation Tests:
Biodegradation
Exposure Time
75 %
28 d
Theoretical Oxygen Demand: 1.60 mg/mg
Method
Estimated
Method
OECD 301C Test
ECOTOXICITY
Data for Component: Dimethyl succinate
Fish Acute & Prolonged Toxicity
LC50, zebra fish (Brachydanio rerio), static, 96 h: 50 - 100 mg/l
Toxicity to Micro-organisms
EC50; activated sludge, respiration inhibition, 3 h: > 1,000 mg/l
Data for Component: Dimethyl adipate
Aquatic Invertebrate Acute Toxicity
EC50, water flea Daphnia magna, static, 48 h, immobilization: 72 mg/l
Aquatic Plant Toxicity
EC50, green alga Selenastrum capricornutum, Growth rate inhibition, 72 h: > 100 mg/l
Data for Component: Dimethyl glutarate
Fish Acute & Prolonged Toxicity
LC50, fathead minnow (Pimephales promelas), static, 96 h: 19.6 - 26.2 mg/l
Aquatic Invertebrate Acute Toxicity
EC50, water flea Daphnia magna, 48 h, immobilization: 122.1 - 163.5 mg/l
13.
Disposal Considerations
Page 5 of 6
All disposal practices must be in compliance with all Federal, State/Provincial and local laws and
regulations. Do not dump into any sewers, on the ground, or into any body of water.
14.
Transport Information
ROAD & RAIL
NOT REGULATED
OCEAN
NOT REGULATED
AIR
NOT REGULATED
INLAND WATERWAYS
NOT REGULATED
15.
Regulatory Information
European Inventory of Existing Commercial Chemical Substances (EINECS)
The components of this product are on the EINECS inventory or are exempt from inventory
requirements.
EC Classification and User Label Information
This product is not classified as dangerous according to EC criteria.
16.
Other Information
Revision
Identification Number: 70279 / 3005 / Issue Date 2006/11/30 / Version: 1.0
Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this
document.
Dow Chemical Company Ltd urges each customer or recipient of this (M)SDS to study it carefully and
consult appropriate expertise, as necessary or appropriate, to become aware of and understand the
data contained in this (M)SDS and any hazards associated with the product. The information herein is
provided in good faith and believed to be accurate as of the effective date shown above. However, no
warranty, express or implied, is given. Regulatory requirements are subject to change and may differ
between various locations. It is the buyer's/user's responsibility to ensure that his activities comply with
all federal, state, provincial or local laws. The information presented here pertains only to the product
as shipped. Since conditions for use of the product are not under the control of the manufacturer, it is
the buyer's/user's duty to determine the conditions necessary for the safe use of this product. Due to
the proliferation of sources for information such as manufacturer-specific (M)SDSs, we are not and
cannot be responsible for (M)SDSs obtained from any source other than ourselves. If you have
obtained an (M)SDS from another source or if you are not sure that the (M)SDS you have is current,
please contact us for the most current version.
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The Column Model

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