Siliporite(R) Molecular Sieves (Extrudates or Beads)

Siliporite(R) Molecular Sieves (Extrudates or Beads)
Material Safety Data Sheet
EHS - MSDS
Received: 9/28/06
Arkema Inc.
1 PRODUCT AND COMPANY IDENTIFICATION
EMERGENCY PHONE NUMBERS:
Chemtrec: (800) 424-9300 (24hrs) or (703) 527-3887
Medical: Rocky Mountain Poison Control Center
(866) 767-5089 (24Hrs)
Specialty Chemicals
2000 Market Street
Philadelphia, PA 19103
Information Telephone Numbers
Phone Number
Available Hrs
Product Safety Department
215-419-7704
8:00 AM to 5:00 PM
(Eastern)
Product Name
Product Synonym(s)
Siliporite(R) Molecular Sieves (Extrudates or Beads)
See Miscellaneous Section for all grades covered by this MSDS.
Chemical Family
Chemical Formula
Chemical Name
EPA Reg Num
Product Use
Synthetic Zeolites
NA
Sodium, Calcium, Barium, Lithium or Potassium Aluminosilicates
Adsorbent used for separation and purification such as the removal of water from air
and gases and separation of normal and iso-paraffins.
2 COMPOSITION / INFORMATION ON INGREDIENTS
Ingredient Name
CAS RegistryNumber
Typical %
OSHA
Zeolites
Kaolin
1318-02-1
1332-58-7
> 90% By Wt.
0-10% By Wt.
Y
Y
Bentonite clay
Clay, attapulgite
Sepiolite
1302-78-9
12174-11-7
63800-37-3
14464-46-1
0-10% By Wt.
0-10% By Wt.
0-10% By Wt.
< 0.2% By Wt.
Y
Y
Y
Y
15468-32-3
< 0.1% By Wt.
Y
Cristobalite
Tridymite
The substance(s) marked with a "Y" in the OSHA column, are identified as hazardous chemicals according to the
criteria of the OSHA Hazard Communication Standard (29 CFR 1910.1200)
This material is classified as hazardous under Federal OSHA regulation.
This product complies with TSCA inventory requirements. For chemical identity purposes, TSCA considers
Zeolites as crystalline aluminosilicates consisting of a mixture of silicon oxide (CAS# 7631-86-9) and aluminum
oxide (CAS# 1344-28-1) in various proportions with metallic oxides.
3 HAZARDS IDENTIFICATION
Emergency Overview
Off-white extrudate or beads with no odor.
CAUTION!
MAY CAUSE EYE IRRITATION.
CANCER HAZARD. CONTAINS CRYSTALLINE SILICA WHICH CAN CAUSE CANCER.
Repeated and prolonged inhalation of respirable particles can cause lung cancer and delayed lung damage (silicosis).
Potential Health Effects
MSDS #: 3323
Entered: 9/28/06
Product Code: 43000
Revision: 48
Issued: 19 JUN 2006
Page 1
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Siliporite(R) Molecular Sieves (Extrudates or Beads)
Material Safety Data Sheet
Arkema Inc.
EHS - MSDS
Received: 9/28/06
Inhalation and skin contact are expected to be the primary routes of occupational exposure to this material. Zeolites
will become hot as they absorb water. Prolonged contact can cause burns to moist body tissues. Repeated and
prolonged inhalation of crystalline silica may cause a disabling lung disease (commonly known as silicosis). Clinical
signs and symptoms of silicosis include cough, shortness of breath, wheezing and impairment of lung function.
Impairment of lung function may be progressive. In the usual case of silicosis, there is a slow deterioration of capacity
for physical effort, decreased chest expansion, and an increased susceptibility to tuberculosis and other respiratory
infections. Crystalline silica inhaled in the form of quartz is classified as carcinogenic to humans (Group 1) by the
International Agency for Research on Cancer (IARC) and respirable forms of crystalline silica are listed as substances
known to be a human carcinogen by the National Toxicology Program.
Short term, extremely heavy exposures to crystalline quartz dust (particularly small-sized particles) can result in acute
silicosis. This disease is rapidly progressive with diffuse pulmonary involvement, which may develop within months of
initial exposure. Individuals with acute silicosis may suffer an abrupt onset of violent coughing, labored breathing, and
weight loss; death has been known to occur within one to two years.
4
FIRST AID MEASURES
IF IN EYES, immediately flush with plenty of water. Get medical attention if irritation persists.
IF ON SKIN, flush the area with plenty of water. Remove contaminated clothing and shoes. Wash clothing
before reuse. Get medical attention if irritation develops and persists.
IF SWALLOWED, do NOT induce vomiting. Give water to drink. Get medical attention immediately. NEVER
GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
IF INHALED, remove to fresh air. If breathing is difficult, get medical attention.
5
FIRE FIGHTING MEASURES
Fire and Explosive Properties
Auto-Ignition Temperature
Flash Point
Flammable Limits- Upper
Lower
NA
NA
NA
NA
Flash Point Method
Extinguishing Media
Use extinguishing media appropriate to surrounding fire conditions.
Fire Fighting Instructions
Fire fighters and others who may be exposed to products of combustion should wear full fire fighting turn out
gear (full Bunker Gear) and self-contained breathing apparatus (pressure demand NIOSH approved or
equivalent). Fire fighting equipment should be thoroughly decontaminated after use.
Fire and Explosion Hazards
Material does not support combustion.
6
ACCIDENTAL RELEASE MEASURES
In Case of Spill or Leak
Contain spill. Sweep or scoop up and remove to suitable container. Consult a regulatory specialist to
determine appropriate state or local reporting requirements, for assistance in waste characterization and/or
hazardous waste disposal and other requirements listed in pertinent environmental permits.
MSDS #: 3323
Entered: 9/28/06
Product Code: 43000
Revision: 48
Issued: 19 JUN 2006
Page 2
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Siliporite(R) Molecular Sieves (Extrudates or Beads)
Material Safety Data Sheet
Arkema Inc.
7
EHS - MSDS
Received: 9/28/06
HANDLING AND STORAGE
Handling
Avoid breathing dust. Avoid contact with eyes, skin and clothing. Do not taste or swallow. Wash thoroughly
after handling. Use only with adequate ventilation. Keep container closed. Keep dry. Contact with water
releases heat.
Storage
Keep material dry; moisture may affect product quality. Moist air or chemical vapors will reduce the operating
life of this material. This material will release heat when absorbing water vapors. If a large quantity of this
material quickly absorbs an equal amount of water, the material can become hot enough to cause thermal
burns of the skin. Material recommended for re-packaging: high density polyethylene (HDPE), polypropylene
(PP), polytetrafluoroethylene (PTFE), fiberboard with moisture barrier.
8
EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering Controls
Investigate engineering techniques to reduce exposures below airborne exposure limits. Provide ventilation
if necessary to control exposure levels below airborne exposure limits (see below). If practical, use local
mechanical exhaust ventilation at sources of air contamination such as open process equipment.
Eye / Face Protection
Where there is potential for eye contact, wear chemical goggles and have eye flushing equipment available.
Skin Protection
Wear appropriate chemical resistant protective clothing and chemical resistant gloves to prevent skin
contact. Consult glove manufacturer to determine appropriate type glove material for given application.
Rinse contaminated skin promptly. Wash contaminated clothing and clean protective equipment before
reuse. Wash skin thoroughly after handling.
Respiratory Protection
Avoid breathing dust. When airborne exposure limits are exceeded (see below), use NIOSH approved
respiratory protection equipment appropriate to the material and/or its components. Consult respirator
manufacturer to determine appropriate type equipment for given application. Observe respirator use
limitations specified by NIOSH or the manufacturer. For emergency and other conditions where exposure
limit may be significantly exceeded, use an approved full face positive-pressure, self-contained breathing
apparatus or positive-pressure airline with auxiliary self-contained air supply. Respiratory protection
programs must comply with 29 CFR § 1910.134.
Other Exposure Limits - Ingredients
*OSHA and ACGIH have not established specific exposure limits for this material. However, OSHA and
ACGIH have established limits for nuisance dusts or Particles Not Otherwise Specified (PNOS) which are the
least stringent exposure limits applicable to dusts. The OSHA PEL/TWA for nuisance dusts is 15 mg/m3
total dust (TD), and 5 mg/m3 respirable dust (RD). The ACGIH TLV/TWA for Particles (insoluble or poorly
soluble) Not Otherwise Specified (PNOS) is 10 mg/m3 inhalable particulate and 3 mg/m3 respirable
particulate.
Airborne Exposure Guidelines for Ingredients
Exposure Limit
Kaolin
ACGIH TWA
OSHA TWA PEL
OSHA TWA PEL
Cristobalite
ACGIH TWA
Tridymite
Value
-Respirable fraction
-Total dust
-Respirable fraction
2 mg/m3
15 mg/m3
5 mg/m3
-Respirable fraction
0.025 mg/m3
MSDS #: 3323
Entered: 9/28/06
Product Code: 43000
Revision: 48
Issued: 19 JUN 2006
Page 3
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Siliporite(R) Molecular Sieves (Extrudates or Beads)
Material Safety Data Sheet
Arkema Inc.
Tridymite
ACGIH TWA
ACGIH TWA
OSHA TWA PEL
OSHA TWA PEL
-As Respirable Particles (Insoluble or
Poorly Soluble) Not Otherwise
Specified
-As Inhalable Particles (Insoluble or
Poorly Soluble) Not Otherwise
Specified
-As Silica: Crystalline Tridymite
(Total Dust)
-As Silica: Crystalline Tridymite
(Respirable)
EHS - MSDS
Received: 9/28/06
3 mg/m3
10 mg/m3
0.15 mg/m3
0.5 mg/m3 (1.2 mppcf)
-Only those components with exposure limits are printed in this section.
-Skin contact limits designated with a "Y" above have skin contact effect. Air sampling alone is insufficient to accurately quantitate
exposure. Measures to prevent significant cutaneous absorption may be required.
-ACGIH Sensitizer designator with a value of "Y" above means that exposure to this material may cause allergic reactions.
-WEEL-AIHA Sensitizer designator with a value of "Y" above means that exposure to this material may cause allergic skin reactions.
9 PHYSICAL AND CHEMICAL PROPERTIES
Off-white extrudate or beads with no odor.
Appearance/Odor
pH
Specific Gravity
Vapor Pressure
Vapor Density
Melting Point
Freezing Point
Boiling Point
Solubility In Water
8-11
0.63-0.85
NA
NA
>1600 C
NA
NA
Insoluble
10 STABILITY AND REACTIVITY
Stability
This material is chemically stable under normal and anticipated storage and handling conditions.
Hazardous Polymerization
Does not occur.
Incompatibility
Reacts with HF and strong acids or alkalis.
Hazardous Decomposition Products
None
11 TOXICOLOGICAL INFORMATION
Toxicological Information
Data on this material and/or its components are summarized below.
Zeolites
Kidney effects were observed in rats and dogs administered high dose levels in their feed for one month, while
MSDS #: 3323
Entered: 9/28/06
Product Code: 43000
Revision: 48
Issued: 19 JUN 2006
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Siliporite(R) Molecular Sieves (Extrudates or Beads)
Material Safety Data Sheet
Arkema Inc.
EHS - MSDS
Received: 9/28/06
11 TOXICOLOGICAL INFORMATION
blood effects were also observed in dogs. Long-term inhalation by rats and dogs produced inflammation in the
lungs associated with accumulation of particulate. Chronic pneumonitis and acute bronchopneumonia were
also seen in rats. No adverse effects were noted in rats and rabbits or their offspring following administration in
the drinking water during pregnancy.
Quartz
Chronic inhalation of crystalline silica may cause a progressive pneumoconiosis (a disabling lung disease)
called silicosis. Data from animal studies on crystalline forms of silica confirm the capacity of free crystalline
silica to induce a fibrinogenic response in lungs. Studies on a variety of laboratory animals (rats, guinea pigs,
rabbits, and monkeys) using inhalation as well as intratracheal routes of exposure indicate the ability of
crystalline silica to produce silicosis similar to that seen in man. In addition, experiments in animals have
confirmed human experience that the presence of crystalline silica in the lung increased susceptibility to
tuberculosis and other lung infections. Crystalline silica inhaled in the form of quartz is classified as
carcinogenic to humans (Group 1) by the International Agency for Research on Cancer (IARC), and respirable
forms of crystalline silica are listed as substances known to be a human carcinogen by the National Toxicology
Program. Epidemiology studies cited by IARC give indications of increased risk for lung cancer from inhaled
crystalline silica (quartz) resulting from occupational exposure. Studies involving heavy industrial exposure to
silica in granite and foundry workers, brick factories and sandblasting produced increased levels of protein and
enzymes in urine, which is indicative of kidney damage.
12 ECOLOGICAL INFORMATION
Ecotoxicological Information
No data are available.
Chemical Fate Information
No data are available.
13 DISPOSAL CONSIDERATIONS
Waste Disposal
Recover, reclaim or recycle when practical. Dispose of in accordance with federal, state and local regulations.
Note: Chemical additions to, processing of, or otherwise altering this material may make this waste
management information incomplete, inaccurate, or otherwise inappropriate. Furthermore, state and local
waste disposal requirements may be more restrictive or otherwise different from federal laws and regulations.
14 TRANSPORT INFORMATION
DOT Name
DOT Technical Name
DOT Hazard Class
UN Number
DOT Packing Group
RQ
Not Regulated by DOT
PG
15 REGULATORY INFORMATION
MSDS #: 3323
Entered: 9/28/06
Product Code: 43000
Revision: 48
Issued: 19 JUN 2006
Page 5
of 7
Siliporite(R) Molecular Sieves (Extrudates or Beads)
Material Safety Data Sheet
EHS - MSDS
Received: 9/28/06
Arkema Inc.
Hazard Categories Under Criteria of SARA Title III Rules (40 CFR Part 370)
Immediate (Acute) Health Y
Delayed (Chronic) Health Y
Fire
Reactive
Sudden Release of Pressure
N
N
N
TSCA Memo for Product
Clay, attapulgite cas# 12174-11-7 is a naturally occuring component, it is TSCA exempt.
Crystaline silica has the following CAS#’s:
Cristobalite: 14464-46-1; Quartz: 14808-60-7; Tripoli: 1317-95-9; Tridymite: 15468-32-3
This product complies with TSCA inventory requirements. For chemical identity purposes, TSCA considers
Zeolites as crystalline aluminosilicates consisting of a mixture of silicon oxide (CAS# 7631-86-9) and aluminum
oxide (CAS# 1344-28-1) in various proportions with metallic oxides.
Ingredient Related Regulatory Information:
SARA Reportable Quantities
CERCLA RQ
SARA TPQ
Kaolin
Cristobalite
Clay, attapulgite
Zeolites
Sepiolite
Tridymite
NE
NE
NE
NE
NE
NE
NE
NE
California Prop 65 - Carcinogen
This product does contain the following chemical(s), as indicated below, currently on the California list of Known Carcinogens.
Cristobalite
Tridymite
Massachusetts Right to Know
This product does contain the following chemicals(s), as indicated below, currently on the Massachusetts Right to Know Substance
List.
Cristobalite
Kaolin
Tridymite
New Jersey Right to Know
This product does contain the following chemical(s), as indicated below, currently on the New Jersey Right-to-Know Substances List.
Cristobalite
Tridymite
Zeolites
Pennsylvania Right to Know
This product does contain the following chemical(s), as indicated below, currently on the Pennsylvania Hazardous Substance List.
Cristobalite
Kaolin
Tridymite
16 OTHER INFORMATION
MSDS #: 3323
Entered: 9/28/06
Product Code: 43000
Revision: 48
Issued: 19 JUN 2006
Page 6
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Siliporite(R) Molecular Sieves (Extrudates or Beads)
Material Safety Data Sheet
Arkema Inc.
EHS - MSDS
Received: 9/28/06
Revision Information
Revision Date
Supercedes Revision Dated
Revision Number 48
19 JUN 2006
01-JUN-2006
Revision Summary
Added grade name
Key
NE= Not Established
NA= Not Applicable
(R) = Registered Trademark
Miscellaneous
WHMIS D2A Carcinogen
WHMIS D2B Eye Irritant
Applicable grades covered by this MSDS:
82B, AGD F, DT 300/ B, EPX, G5, G502/B, G5CO2M/B/MLZ B, G5F, G5L, G5CO2MLZ, G5000/LZ/B/LZ B,
G5085/B, G5B, G5P, G5C F, G5085LZ, G5C, G5 86, G5 86 B, G5L 86, H3R/Ri/RI B, NK10/F/10B/10R,
NK20/20B/20C/20CF/20P, NK30/COS/COS B/COS F/B, NK31B, NPG 50, NPG50F, NPL50, OPX/F, OPX/P,
PG3001B, PHYG1, PHYG3/B, RA, S82/B, SCR30/B, SCR31, SRA/F, SRC.
Arkema Inc. believes that the information and recommendations contained herein (including data and
statements) are accurate as of the date hereof. NO WARRANTY OF FITNESS FOR ANY PARTICULAR
PURPOSE, WARRANTY OF MERCHANTABILITY, OR ANY OTHER WARRANTY, EXPRESSED OR
IMPLIED, IS MADE CONCERNING THE INFORMATION PROVIDED HEREIN. The information provided
herein relates only to the specific product designated and may not be valid where such product is used in
combination with any other materials or in any process. Further, since the conditions and methods of use are
beyond the control of Arkema Inc., Arkema Inc. expressly disclaims any and all liability as to any results
obtained or arising from any use of the product or reliance on such information.
MSDS #: 3323
Entered: 9/28/06
Product Code: 43000
Revision: 48
Issued: 19 JUN 2006
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