Programme cours chimie du recycle - V10.12.2013

COURS Master 3/Doctoral - ED459 (2013-2014)
PHYSICAL CHEMISTRY: FROM SPECIATION TO RECYCLING
Scientific basis for the transfer between phases:
Jeudis:
13h30-14h15
14h30-15h15
7 novembre
Chemical potential (J.F Dufrêche)
Chemical isotopic separation (S. Pellet-Rostaing)
14 novembre
Speciation in solution: Initiation to
complexation chemistry (J.F Dufrêche)
Osmotic pressure (Th. Zemb)
21 novembre
Conférence n°1
Le verre : de l‘Antiquité au confinement des
déchets nucléaires. 1/2 (E. Vernaz)
Conférence n°2
Le verre : de l‘Antiquité au confinement des déchets
nucléaires. 2/2 (E. Vernaz)
(28novembre)
Pas de cours (AERES ICSM)
5 décembre
Entropy and temperature (J.F Dufrêche)
Liquid-vapour separation (Th. Zemb)
12 décembre
Liquid-vapor in fluids (Th. Zemb)
Conférence n ° 3
De l’extraction sans solvant : un exemple de lqiudievapeur? 1/2 (Th. Zemb)1/2
19 décembre
Energetics of fluid interfaces (J.F Dufrêche)
Conférence n° 4
…à l’extraction sans extractant : des légendes
urbaines ou une opportunité pour les énergies
renouvelables du futur ? 2/2 (Th. Zemb)
9 janvier
Aggregation and micellisation (Th. Zemb)
Phase diagrams and separation processes (Th.
Zemb)
16 janvier
Conférence n° 5
Conférence n° 6
Separation by pores in self-assembled biomimetic
bilayers (M. Barboiu, Labex Chemisyst)
Self-assembly
Montpellier)
23 janvier
The chemical potential of the oxygen pO2
(J.F Dufrêche)
Wetting and pre-wwetting (Th. Zemb)
30 janvier
The chemical potential of the electron (J.F
Dufrêche)
Equation of state (J.F Dufrêche)
6 février
Small angle scattering: form and structure P11
Chemical reactions in trace
factors (Guillaume. Tocquer)
ultratrace amount (Nicolas Dacheux)
13 février
Conférence n° 7
Biological effects of radiation: cell and organism
(MH Hengé)
in
ionic
liquids
(André
Vioux,
and
Conférence n° 8
Extraction from living body: decorporation (Eric
Ansoborlo)
20 février
Dynamic of bulk complex fluids and fluids
interfaces: optical determination (O. Diat)
Surface
decontamination
Cambedouzou)
(Julien.
Dynamical methods and kinetics
27 février
Molecular modelling:
equilibrium and P13
Hydration of ions: chaotropy and
dynamical methods (J.F Dufrêche)
cosmotropy (Daniel Meyer)
6 mars
Pas de cours: vacances semestrielles UM2
13 mars
Conférence n° 9
Acoustophoresis and electro-acoustic effects
(Pierre Bauduin)
Conférence n° 10
Extraction by micro-wave heating
Avignon)
20 mars
Diffusion phenomena (J.F Dufrêche)
Characterisation of aggregates by light (Luc
Girard)
27 mars
Leçon terminale session 2013/14 :
Open problems in ienaics (Pr Jean-François Dufrêche)
Eco-design (Pr Yves Brechet)
(Farid Chemat
COURS Master 3/Doctoral - ED459 2014-2015
PHYSICAL CHEMISTRY: FROM SPECIATION TO RECYCLING
Weak interactions beyond the nearest neighbour
Jeudis:
13h30-14h15
14h30-15h15
6 novembre
Colloidal forces : van der Waals and
dispersion forces (Th. Zemb)
Separation by physisoprtion (A. Grandjean)
13 novembre
Electrostatic forces and DLVO stability at
primitive level (J.F Dufrêche)
Ion specific effects: usage in flotation
tanning (Th. Zemb)
20 novembre
Conference n° 1
Conference n° 2
(27novembre)
Pas de cours : conseil scientifique ICSM
4 décembre
Colloidal forces : solvation and depletion Primary and secondary hydration forces (Th.
forces (J.F Dufrêche)
Zemb)
11 décembre
Molecules with selective complexation
(D. Meyer or S. Pellet-Rostaing)
Emulsification and phase separation (Th. Zemb)
19 décembre
Conference n ° 3
Conference n° 4
8 janvier
Solvent cohesion, evaporation (J F Dufrêche) Advanced methods:
pertraction (Th. Zemb)
15 janvier
Conference n° 5
Conference n° 6
22 janvier
Adsorption isotherm on fluid interfaces
(J.F Dufrêche)
Ion distribution between fluid phases and the
the pseudo-phase approach (Th. Zemb)
centrifugation
and
and
Surface decontamination(Julien. Cambedouzou)
Dynamical methods and kinetics
29 janvier
Molecular modelling : equilibrium and Hydration of ions: chaotropy and cosmotropy
dynamical methods (J.F Dufrêche)
(E. Leontidis Uni Chypre)
5 février
Conference n° 7
Conference n°8
12 février
Diffusion phenomena (J.F Dufrêche)
Characterisation of aggregates by light (Luc
Girard)
19 février
Transport: viscosity and
frequency Transport of heat : conductivity and Fourier
dependant shear moduli ( J F Dufrêche)
equation ( J F Dufrêche)
26 février
Smoluchovski kinetics of aggregation: DLA Separation
and RLA (J F Dufrêche)
Dacheux)
5 mars
Pas de cours: vacances semestrielles UM2
12 mars
Conference n°9
19 mars
Brownian motion : self
diffusion (J.F Dufrêche)
26 mars
Electrokinetic transport and hydrodynamics Gas and liquid chromatography
(J.F Dufrêche)
Toquer)
5 avril
Leçon terminale de la session 2014/2015 :
The key of control of viscosity in the solvent phase for extraction :
-Colloidal scale (Th. Zemb, Marcoule)
-Chemical engineering scale (NN. , Nancy)
by
co-precipitation
(Nicolas
Conference n° 10
and
collective Characterisation of aggregates by light (Luc
Girard)
(Guillaume
CONFERENCES ASSOCIEES AU COURS DE CHIMIE DU RECYCLAGE 2013/14 et 2014/2015
----------------------------------------------------------------------------------------------------------------------------Les conférences 2013/2014 ainsi que les conférences 2014-2015 seront choisies dans la liste (non
exhaustive ) suivante, en fonction des disponibilités des conférenciers (contact M. Lecomte Mar/Dir):
C1- Introduction to chemistry of f-elements (Daniel. Meyer)
C2- Introduction to physical chemistry of f-elements ( Daniel Meyer)
C3- Cristallisation and controlled glass formation (Agnès Grandjean),
C4- Acoustophoresis and electro-acoustic effects ( Pierre Bauduin ),
C5-Ultracentrifugation for speciation of inorganic polyelectrolytes (Helmuth Coelfen ),
C6- Self-organisation in Ionic liquids (Werner Kunz)
C7- Water and solvent miscibility of organized ionic liquids ( Werner Kunz),
C8- Osmolytes (Werner Kunz)
C9-Pyrochemical purification and separation of aluminium : open problems (NN.)
C10- Control of oxidation and homogeneity in glass formation ( resp. Labo commun CEA/AREVA)
C11- General principles of eco-extraction f plant materials ( Farid Chemat)
C12- Extraction by micro-wave heating ( Farid Chemat)
C12- Separation by pores in self-assembled biomimetic bilayers (M. Barboiu, Labex Chemisyst)
C13- Self-assembly in ionic liquids (André Vioux, Montpellier)
C14- Heterogeneity in calcium silicates, ageing and geopolymer formulation (NN.)
C15- Fundamentals of radiotoxicity and chemotoxicity (MH Hengé)
C16- Biological effects of radiation : cell and organism (MH Hengé)
C17- Biological effects : risks and thresholds (MH Hengé)
C18- Extraction from living body : old an modern methods of decorporation (Eric Ansoborlo)
C19- Evaporation and encapsulation in pre-ouzo regime (Thomas Zemb)
C20- Flotation methods for separation in mining: new methods and open problems (Fréderic Villiéras,
Nancy )
C21/C22 – “Le verre de l’Antiquité à nos jours” ( Etienne Vernaz)
C23- High technology filters from risk husk for renewable production of irrigation water ( Pradip, Tata
research and IIT Mumbai)
C24- Kinetics of self-assembled systems ( Michael Gradzielski, TU Berlin)
C25- Material reformation: using freezing surface potential for precursors of ceramics ( NN St Gobain
CREE Centre )
C26- between complex ions and dense material ( Denis Gebauer, TU Konstanz)
C27- Separation chemistry in sub-critical water (NN.)
C28- Silica as micro-cages for unicellular organisms producing high value molecules (J. Bartlett, USC,
Australia)
C29 et plus - sur proposition…..
PS/ NN désigne des experts non encore détecté nominativement, mais sur un sujet identifié.
Merci d’avance de toute suggestion.
AIM of Recycling chemistry Lectures of Marcoule
Aim : Understand and master in practice the three basic steps of recycling :
Dissolution, separation and material reformation
The lectures will be in French, with slides in (English ),
slides available in the morning before on the web site of ICSM
Core : separation chemistry involving one fluid state : liquid-liquid , liquid-solid or liquidinterface (flotation, chromatography…)
Side aspects concern fragmentation in divided state, dissolution and reforming material
5 scientific disciplines are involved :
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chemical engineering (and processes)
physical chemistry
analytical chemistry
statistical thermodynamics
safety and environmental issues
The physical chemistry lectures consist in three modules, delivered over two years (ON Thursdays
after Lunch November-March, ie when winter time applies) :
En route to ienaics
Weak interactions beyond the nearest neighbour
Kinetics and Dynamical methods
The lectures will be associated to invited conferences 45 minutes including discussion
The lectures will be held in Salle Balard at INSTN/Marcoule via video-link in Montpellier.
Lectures hold in French with slides in Frenglish, unless otherwise stated.