Dr. Jean-Baptiste Sortais Institut des Sciences Chimiques de
Transcription
Dr. Jean-Baptiste Sortais Institut des Sciences Chimiques de
Dr. Jean-Baptiste Sortais Institut des Sciences Chimiques de Rennes UMR 6226-CNRS-Université de Rennes1 Campus de Beaulieu 263 Avenue du Général Leclerc 35042 Rennes Cedex, France [email protected] Associate Professor, Université Rennes 1 Education 2013 2003-2007 2002-2003 2001-2002 2000-2001 1999-2000 1996-1999 Habilitation, Université de Rennes 1, Rennes, France, Defence December 2nd 2013 PhD diploma, Université Louis Pasteur, Strasbourg, France. Defence January 26th 2007, "Cycloruthenated complexes : from complexes to enantioselective catalysts", Laboratoire de Synthèses Métallo-induites, advisor: M. Pfeffer Diplôme d’Etudes Approfondies de Chimie Organique Moléculaire et Supramoléculaire (M. Sc., Organic Chemistry) Graduate with highest honors, Université Louis Pasteur, Strasbourg, France Magistère de Chimie-Physique (M. Sc., Physical Chemistry), Graduate with honors, Ecole Normale Supérieure (ENS) Lyon, France Agrégation de Sciences Physiques (high-level competitive examination for recruiting high-school teachers), Chemistry, ENS Lyon, France Maîtrise de Chimie-Physique (B.Sc.-M.Sc., Physical Chemistry), Graduate with honors, ENS Lyon, France Licence de Chimie-Physique (B. Sc.), Graduate with honors, ENS Lyon, France Preparatory courses for the national competitive exam for entry to French engineering schools, Lycée B. Pascal, Clermont-Ferrand, France Professional Experience (after the PhD) 09 2009-Present 05 2008-08-2009 03 2007- 04 2008 Associate Professor, Chaire CNRS-UR1 (2009-2014), Université de Rennes 1, UMR 6226, Institut des Sciences Chimiques de Rennes, Team « Organométalliques : Matériaux et Catalyse » “Metal-free activation of hydrogene”, postdoctoral associate with Pr. G. Erker, Organisch-Chemisches Institut, Münster, Germany “New catalysts for dynamic kinetic resolution for primary alcohols and primary amines” postdoctoral associate (Lavoisier fellowship) with Pr. J. E. Bäckvall, Organic Chemistry, Arrhenius Laboratory, Stockholm University, Stockholm, Sweden Teaching Experience 2009-Present 2006-2007 2003-2006 2003-2005 Associate Professor, Université de Rennes 1, Rennes Temporary teaching position at the University Louis Pasteur, Strasbourg (90 hours) Teaching assistant at the University Louis Pasteur, Strasbourg (about 64 hours per year) Trainer at the DEPULP (continuing education department), "Mechanisms in Organic Chemistry", (30 hours per year), Université Louis Pasteur, Strasbourg Scientific Production 47 publications, 2 Book Chapters 22 Oral communications (including 6 invited academic seminars) 29 Poster communications Fellowship and Awards 2009-2014 2007 2003-2006 2003 1999-2003 Chaire CNRS-Université Rennes 1 Lavoisier Post-doctoral Fellowship, French Ministry of Foreign Affairs PhD Fellowship (Allocataire Moniteur Normalien), French Ministry of Education, Research and Technology Laureate of the « Agrégation de Sciences Physiques », option Chimie. Student of the Ecole Normale Supérieure de Lyon Supervision and Funding • • • • Participation to the collaboration with Pr. P. Ghosh, Indian Institute of Technology Bombay, India, in the framework of the project CEFIPRA with the Ministère des Affaires Etrangères, « Studies of Iron Complexes of N/O−functionalized N−heterocyclic Carbenes in Homogeneous Catalysis », PhD fellowship to L. P. Bheeter. Active participation to the project ANR IRONHYC, with the team of Dr. S. Sabo-Etienne, LCC, Toulouse. 2012-2015. Active participation to the project Create Bioricat, Britanny Council, financial support of a two years postdoctoral grant 2011-2013. Active participation to the project which led to the attribution of a PhD fellowship to Jianxia Zheng by Axa Research Fund 2011-2014. Since 2009: 5 PhD Students, 3 Post-doctorates, 8 masters students, 6 undergraduate students Research Interests Organometallic chemistry, Earth abundant transition metals, Homogeneous Catalysis, Hydrosilylation, Hydroboration, C-H Activation, Reduction Academic Collaborations • • • • • • • • Dr. V. Ritleng, Pr. M. J. Chetcuti, Université de Strasbourg, France Dr. V. César, Dr. D. Valyaev, Dr. N. Lugan, Pr. G. Lavigne, LCC, Toulouse, France Dr. S. Demir, Pr. I. Ozdemir, Inönü University, Malatya, Turkey, Project TUBITAK 20112012, Project Bosphorus 2014-2015 (Coordinator) Pr. P. Ghosh, Indian Institute of Technology Bombay, India, project CEFIPRA Dr. S. Bontemps, Dr. S. Sabo-Etienne, LCC, Toulouse, France, ANR IRONHYC, 2012-2015 Pr. J. Chirinos, Universidad del Zulia, Maracaibo, Venezuela, Project ECOS-NORD (20132016) Dr. B. Royo, ITQB, Lisbon, Portugal, Project PESSOA 2014-2015 International associated Laboratory, LIA CHEMSUSCAT, Université Rennes 1/Leibniz Institut für katalyse, Univ. Rostock, Germany Collaboration with industrials BlueStar Silicons (2012-2013) 2 List of Publications 2015 2014 2013 47) “Iron-Catalyzed C−H Borylation of Arenes” T. Dombray, C. G. Werncke, S. Jiang, M. Grellier, L. Vendier, S. Bontemps, J.-B. Sortais, S. Sabo-Etienne, C. Darcel, J. Am. Chem. Soc., 2015, 137, 4062-4065. 46) “Nickel Complexes of 1,2,4-Triazole Derived Amido-functionalized N-heterocyclic Carbene Ligands: Synthesis, Theoretical Studies and Catalytic Application”, A. Kumar, L. P. Bheeter, M. K. Gangwar, J.-B. Sortais, C. Darcel, P. Ghosh, J. Organomet. Chem. 2015, doi:10.1016/j.jorganchem.2015.03.007. 45) “When iron met phosphines: a happy marriage for reduction catalysis”, L. C. Misal Castro, H. Li, J.-B. Sortais, C. Darcel, Green Chem., 2015, 17, 2283-2303. 44) “Methylation of secondary amines with dialkyl carbonates and hydrosilanes catalysed by iron complexes”, J. Zheng, C. Darcel, J.-B. Sortais, Chem. Commun., 2014, 50, 14229-14232. 43) “Iron-catalysed tandem isomerisation/hydrosilylation reaction of allylic alcohols with amines”, H. Li, M. Achard, C. Bruneau, J.-B. Sortais, C. Darcel, RSC Adv., 2014, 4, 2589225897. 42) “Imidazolidinium ferrate complexes: Synthesis and catalytic propreties”, S. Demier, Y. Gokce, T. Roisnel, J.-B. Sortais, C. Darcel, I. Ozdemir, C. R. Chimie, 2014, 17, 541-548. 41) “Cationic Iron(II) Complexes of the Mixed Cyclopentadienyl (Cp) and the N-heterocyclic Carbene (NHC) Ligands as Effective Precatalysts for the Hydrosilylation of Carbonyl Compounds”, D. Kumar, A. P. Prakasham, L. P. Bheeter, J.-B. Sortais, M. Gangwar, T. Roisnel, A. Kalita, C. Darcel, P. Ghosh, J. Organomet. Chem. 2014, 762, 81-87. 40) “Hydrosilylation of Aldehydes and Ketones Catalyzed by Half-Sandwich Manganese (I) N-Heterocyclic Carbene Complexes” J. Zheng, S. Elangovan, D. A. Valyaev, R. Brousses, V. César, J.-B. Sortais, C. Darcel, N. Lugan, G. Lavigne, Adv. Synth. Catal., 2014, 356, 10931097 39) “(NHC)Fe(CO)4 efficient pre-catalyst for selective hydroboration of functional alkenes under UV conditions” J. Zheng, J.-B. Sortais, C. Darcel, ChemCatChem, 2014, 6, 763-766 38) “Cobalt carbonyl based catalyst for hydrosilylation of carboxamides”, T. Dombray, C. Helleu, C. Darcel, J.-B. Sortais, Adv. Synth. Catal., 2013, 355, 3358-3362 37) “Cyclopentadienyl N-heterocyclic carbene-nickel complexes as efficient pre-catalysts for the hydrosilylation of imines” L. P. Bheeter, M. Henrion, M. J. Chetcuti, C. Darcel, V. Ritleng, J.-B. Sortais, Catal. Sci. Technol. 2013, 3, 3111-3116 36) “Selective reduction of carboxylic acids to aldehydes though manganese catalysed hydrosilylation” J. Zheng, S. Chevance, C. Darcel, J.-B. Sortais, Chem. Commun., 2013, 49, 10010-10012 35) “(Cyclopentadienyl)iron(II) Complexes of N-Heterocyclic Carbenes Bearing a Malonate or Imidate Backbone: Synthesis, Structure, and Catalytic Potential in Hydrosilylation” V. César, L. C. Misal Castro, T. Dombray, J.-B. Sortais, C. Darcel, S. Labat, K. Miqueu, J.-M. Sotiropoulos, R. Brousses, N. Lugan, G. Lavigne, Organometallics, 2013, 32, 4643-4655 34) “Nickel-Catalysed Reductive Amination with Hydrosilanes” J. Zheng, T. Roisnel, C. Darcel, J.-B. Sortais, ChemCatChem, 2013, 5, 2861-2864 33) “Selective Reduction of Esters to Aldehydes under the Catalysis of Well-Defined NHC– Iron Complexes” H. Li, L. C. Misal Castro, J. Zheng, T. Roisnel, V. Dorcet, J.-B. Sortais, C. Darcel, Angew. Chem. Int. Ed., 2013, 52, 8045-8049 32) “Synthesis of new iron–NHC complexes as catalysts for hydrosilylation reactions” S. Demir, Y. Gökçe, N. Kaloğlu, J.-B. Sortais, C. Darcel, İ. Özdemir, Appl. Organometal. Chem., 2013, 28, 459-464 31) “Unexpected selectivity in ruthenium-catalyzed hydrosilylation of primary amides: synthesis of secondary amines”, B. Li, J.-B. Sortais, C. Darcel, Chem. Commun., 2013, 49, 3691-3693 3 2012 2011 2010 30) “Chiral cyclopentadienyl-type ligands: a new breakthrough for asymmetric C-H functionalisation” J.-B. Sortais, C. Darcel, ChemCatChem, 2013, 5, 1067-1068 29) “N-Heterocyclic Carbene Ligands and Iron: An Effective Association for Catalysis” D. Bézier, J.-B. Sortais, C. Darcel, Adv. Synth. Catal., 2013, 355, 19-33 28) “A Convenient Nickel-Catalyzed Hydrosilylation of Carbonyl Derivatives” J. Zheng, C. Darcel, J.-B. Sortais, Catal. Sci. Technol., 2013, 3, 81-84 27) “Selective Switchable Iron-Catalyzed Hydrosilylation of Carboxylic Acids” L. C. Misal Castro, H. Li, J.-B. Sortais, C. Darcel, Chem. Commun., 2012, 48, 10514-10516 26) “Hydrosilylation of Aldehydes and Ketones Catalyzed by an N-Heterocyclic Carbene– Nickel Hydride Complex under Mild Conditions” L. P. Bheeter, M. Henrion, L. Brelot, C. Darcel, M. J. Chetcuti, J.-B. Sortais, V. Ritleng, Adv. Synth. Catal., 2012, 354, 2619-2624 25)“Phosphane-Pyridine Iron Complexes: Synthesis, Characterization and Application in Reductive Amination through the Hydrosilylation Reaction” H. Jaafar, H. Li, L. C. Misal Castro, J. Zheng, T. Roisnel, V. Dorcet, J.-B. Sortais, C. Darcel, Eur. J. Inorg. Chem., 2012, 3546-3550 24) “Iron-Catalyzed Hydrosilylation of Esters,” D. Bézier, G.T. Venkanna, L. C. Misal Castro, J. Zheng, T. Roisnel, J.-B. Sortais, C. Darcel, Adv. Synth. Catal., 2012, 354, 18791884 23) “Synthesis, Characterization, and Fluxional Behavior of a 34 Electron Homochiral Dimetallic Complex with an Unsupported Hydride Bridge between Two Ru Atoms” J.-P. Djukic, J.-B. Sortais, L. Barloy, M. Pfeffer, Organometallics, 2012, 31, 2821-2828 22) “Amine Synthesis via Mild Catalytic PHMS Hydrosilylation of Imines with [RuCl2(p−cymene)]2 catalyst” B. Li, J.−B. Sortais, C. Darcel, P. H. Dixneuf, ChemSusChem, 2012, 5, 396-399 21) “NHC−carbene cyclopentadienyl iron based catalyst for a general and efficient hydrosilylation of imines” L. C. Misal Castro, J.−B. Sortais, C. Darcel, Chem. Commun., 2012, 48, 151-153 20) “Iron Piano−Stool Phosphine Complexes for Catalytic Hydrosilylation Reaction” J. Zheng, L. C. Misal Castro, T. Roisnel, C. Darcel, J.−B. Sortais, Inorg. Chim. Acta, 2012, 380, 301-307 19) “Cyclopentadienyl–NHC Iron Complexes for Solvent−Free Catalytic Hydrosilylation of Aldehydes and Ketones” D. Bézier, F. Jiang, T. Roisnel, J.-B. Sortais, C. Darcel, Eur. J. Inorg. Chem., 2012, 1333-1337 18) “Well−Defined Cyclopentadienyl NHC Iron Complex as the Catalyst for Efficient Hydrosilylation of Amides to Amines and Nitriles” D. Bézier, G. T. Venkanna, J.-B. Sortais, C. Darcel, ChemCatChem, 2011, 3, 1747-1750 17) “Alkene Addition of Frustrated P/B and N/B Lewis Pairs at the [3]Ferrocenophane Framework” T. Voss, J.−B. Sortais, R. Frohlich, G. Kehr, G. Erker, Organometallics, 2011, 30, 584-594 16) “Cyclometalated Complexes of Ruthenium, Rhodium and Iridium as Catalysts for Transfer Hydrogenation of Ketones and Imines” N. Pannetier, J.-B. Sortais, J.-T. Issenhuth, L. Barloy, C. Sirlin, A. Holuigue, L. Lefort, L. Panella, J. G. de Vries, M. Pfeffer, M., Adv. Synth. Catal., 2011, 353, 2844-2852 15) “Iron Dihydride Complex as the Pre−catalyst for Efficient Hydrosilylation of Aldehydes and Ketones Under Visible Light Activation” L. C. Misal Carlos, D. Bézier, J.-B. Sortais, C. Darcel, Adv. Synth. Catal., 2011, 353, 1279−1284 14) “N−Heterocyclic Carbene Piano−Stool Iron Complexes as Efficient Catalysts for Hydrosilylation of Carbonyl Derivatives” F. Jiang, D. Bézier, J.-B. Sortais, C. Darcel, Adv. Synth. Catal., 2011, 353, 239-244 13) “Cyclen-catalyzed Henry reaction under neutral conditions” C. Vovard-Le Bray, F. Jiang, X.-F. Wu, J.-B. Sortais, C. Darcel, Tetrahedron Lett., 2010, 51, 4555-4557 12) “Cycloruthenated complexes as homogeneous catalysts for atom-transfer radical additions” K. Parkhomenko, L. Barloy, J.-B. Sortais, J.-P. Djukic, M. Pfeffer, Tetrahedron Lett., 2010, 51, 822-825 4 2009 2008 2007 2006 2005 2003 11) “1,2-Olefin addition of a frustrated amine-borane Lewis pair” J.-B. Sortais, T. Voss, G. Kehr, R. Frölich, G. Erker, Chem. Commun., 2009, 7417-7418 10) “A Chemoenzymatic Approach to Enantiomerically Pure Amines Using Dynamic Kinetic Resolution. Application to the Synthesis of NorSertraline” L. K. Thalén, D. Zhao, J.-B. Sortais, J. Paetzold, C. Hoben, J-E. Bäckvall, Chem. Eur. J., 2009, 15, 3403-3410 9) “Cycloruthenated Compounds, Synthesis and Applications” J.-P. Djukic, J.-B. Sortais, L. Barloy, M. Pfeffer, Eur. J. Inorg. Chem., 2009, 817-853 8) “Kinetics and Mechanism of Ruthenacycle-Catalysed Asymmetric Hydrogen Transfer” N. Pannetier, J.-B. Sortais, L. Barloy, C. Sirlin, M. Pfeffer, Organometallics, 2008, 27, 58525859 7) “µ 3-Carbonato-κ3O:O':O''-tris((η6-benzene) [(R)-1-(1amino-ethyl)naphthyl-κ2C2, N]ruthenium(II)) hexafluoridophosphate dichloromethane solvate” J.-B. Sortais, L. Brelot, M. Pfeffer, L. Barloy, Acta Cryst., 2008, E64, m483-m484 6) “Cyclometalation of Primary Benzyl Amines by Ruthenium(II), Rhodium(III), and Iridium(III) Complexes” J.-B. Sortais, N. Pannetier, A. Holuigue, L. Barloy, C. Sirlin, M. Pfeffer,N. Kyritsakas, Organometallics, 2007, 26, 1856-1867 5)“Cyclometalation of Secondary Benzyl Amines by Ruthenium(II) Complexes” J.-B. Sortais, N. Pannetier, N. Clément, L. Barloy, C. Sirlin, M. Pfeffer, N. Kyritsakas, Organometallics, 2007, 26, 1868-1874 4)“Nitrogen-containing xanthene-based chiral ligands: synthesis and catalytic applications of their palladium, silver and rhodium complexes” G. Malaisé, J.-B. Sortais, L. Barloy, M. Pfeffer, N. Kyritsakas, Polyhedron, 2006, 25, 3349-3365 3) “Cycloruthenated Compounds as Efficient Catalyst for Asymmetric Hydride Transfer Reaction” J.-B. Sortais, L. Barloy, C. Sirlin, A. H. M. de Vries, J. G. de Vries, M. Pfeffer, Pure Appl. Chem., 2006, 78, 457-462 2) “Cycloruthenated Primary and Secondary Amines as Efficient Catalyst Precursors for Asymmetric Transfer Hydrogenation” J.-B. Sortais, V. Ritleng, A. Voelklin, A. Holuigue, H. Smail, L. Barloy, C. Sirlin, G. K. M. Verzijl, J. A. F. Boogers, A. H. M. de Vries, J. G. de Vries, M. Pfeffer, Org. Lett., 2005, 7, 1247-1250 1) “Trifluoromethanesulfinic Acid Derivatives as Nucleophilic Trifluoromethylating Reagents” D. Inchauspe, J.-B. Sortais, T. Billard, B. R. Langlois, Synlett, 2003, 2, 233-235 List of oral communications 2004 2005 1) J.-B. Sortais, L. Barloy, C. Sirlin, M. Pfeffer DSM Scientific Meeting "Homogeneous Catalysis for Future Industrial Applications: New Carbon-Carbon Bond Forming and Asymmetric Catalysis", Vaals, Pays Bas, 15-16 November 2004 Cycloruthenated aromatic amine: Asymmetric transfer hydrogen catalysts 2) J.-B. Sortais, L. Barloy, M. Pfeffer Nanoparticules Métalliques en Catalyse (NANOMETCAT), Toulouse, France, 14-15 October 2004 Synthesis and characterization of rhodium (III) complexes with chiral ligands based on rigid xanthene backbone 3) J.-B. Sortais, L. Barloy, C. Sirlin, M. Pfeffer Symposium Synthèse et Catalyse, Strasbourg, France, 12 May 2004 Complexes cycloruthénés: synthèse et application en catalyse 4) J.-B. Sortais, L. Barloy , C. Sirlin, M. Pfeffer Séminaire Jeune Chercheur, Strasbourg, France, 22 November 2005 Cycloruthenated complexes: efficient catalysts in asymmetric hydrogen transfer 5) J.-B. Sortais, V. Ritleng, L. Barloy, C. Sirlin, J. G. de Vries, M. Pfeffer Gecom Concoord 2005, Autran, France, 5-10 June 2005 Complexes cycloruthénés d’amines primaires et secondaires : des catalyseurs efficaces en transfert énantiosélectif d’hydrogène 6) J.-B. Sortais, L. Barloy, C. Sirlin, M. Pfeffer 5 2006 2009 2011 2012 2013 2014 2015 Symposium Synthèse et Catalyse, Strasbourg, France, 11 May 2005 Complexes cycloruthénés : des catalyseurs efficaces en transfert énantiosélectif d’hydrogène 7) J.-B. Sortais Institut Charles Sadron, Strasbourg, France, 21 November 2006 Catalyse asymétrique de transfert d'hydrogène 8) J.-B. Sortais, C. Darcel Joint Florence-Rennes IDECAT Meeting, Florence, 19-20 October 2009 Iron-catalyzed transformations towards C-C, C-O and C-N bond formations 9) L. C. Misal Castro, D. Bézier, J.-B. Sortais, C. Darcel, Gecom-Concord, Merlinont, France, May 2011 Well-Defined Iron Complexes for Efficient Catalytic Hydrosilylation of Carbon-Heteroatom Double Bonds Under Visible Light Activation 10) J.-B. Sortais, D. Bézier, L. C. Misal Castro, F. Jiang, J. Zheng, C. Darcel EuCOMC 19, July 2011, Toulouse, France Well Defined Iron Complexes as Catalysts for Hydrosilylation Reaction 11) C. Darcel, J.-B. Sortais, D. Bézier, L. C. Misal Castro, F. Jiang, J. Zheng, OMCOS 16, July 2011, Shanghai, China Well Defined Iron Complexes as Efficient Catalysts for Hydrosilylation Reactions 12) C. Darcel, J.-B. Sortais, D. Bézier, L. C. Misal Castro, J. Zheng, F. Jiang, H. Jaafar, G.T. Venkanna, International Green Catalysis Symposium, 7-9 March 2012, Rennes, France Iron complexes and their applications in catalytic reductions 13) L. C. Misal Castro, J.-B. Sortais, C. Darcel, Journée des Doctorants de l’UMR 6226, 7 June 2012, Rennes, France Well Defined Iron Complexes as Efficient Catalysts for Hydrosilylation Reactions of CarbonHeteroatom Double Bonds 14) C. Darcel, J.-B. Sortais, D. Bézier, L. C. Misal Castro, F. Jiang, J. Zheng, L. P. Bheeter ICOMC 2012, 2-7 September 2012, Lisbon, Portugal Well defined iron complexes as efficient catalysts for hydrosilylation reactions of carbonyl and carboxylic derivatives 15) C. Darcel, J.-B. Sortais, D. Bézier, L. C. Misal Castro, H. Li, J. Zheng, 8th IFCOS Meeting On Organic Synthesis, 1-3 April, 2013, Goa, India Well defined iron complexes as efficient catalysts for hydrosilylation reactions of carboxylic derivatives. 16) T. Dombray, C. Helleu, C. Darcel, J.-B. Sortais Journée Chimie Organique 2013, 24-26 September, 2013, Ecole Polytechnique Palaiseau, France Cobalt Carbonyl Catalyzed Hydrosilylation of Amides 17) J.-B. Sortais Institut des Sciences Moléculaires de Marseille, Equipe ChiroSciences, 4 April 2014, Marseille, France Earth abundant metalds in hydrosilylation reactions 18) J.-B. Sortais, D. Darcel, J. Zheng, L. C. Misal Castro, H. Li 5th EuCheMS, 31 August-4 September 2014, Istanbul, Turkey Selective reduction of carboxylic acids derivatives catalyzed by iron and manganese complexes 19) J.-B. Sortais Laboratoire de Chimie de Coordination, 18 December 2014, Toulouse, France Iron catalysis with hydrosilanes and hydroboranes 20) J.-B. Sortais Instituto de Tecnologia Quimica a Biologica (ITQB), Oeiras, 24 February 2015, Portugal Iron catalysis with hydrosilanes and hydroboranes 21) J.-B. Sortais 6 Instituto Superior Tecnico (IST), Lisbon, 26 February 2015, Portugal Iron catalysis with hydrosilanes and hydroboranes 22) J.-B. Sortais Institut des Sciences Moléculaires, Université de Bordeaux, 26 March 2015 Iron catalysis with hydrosilanes and hydroboranes List of poster communications 2005 2010 2011 2012 1) J.-B. Sortais, N. Pannetier, L. Barloy, V. Ritleng, C. Sirlin, J. G. de Vries, M. Pfeffer OMCOS 13, Geneva, Suisse, 17-21 July 2005 Cycloruthenation of Chiral at Carbon, Primary and Secondary Amines. An Easy Reaction, that leads to Efficient Catalysts 2) J.-B. Sortais, L. Barloy, C. Sirlin, A. H. M. de Vries, J. G. de Vries, M. Pfeffer OMCOS 13, Genève, Suisse, 17-21 July 2005 Cycloruthenated Compounds as Efficient Catalysts For Asymmetric Transfer Hydrogenation 3) J.-B. Sortais, N. Pannetier, M. Pfeffer, C. Sirlin Advances in Supramolecular Chemistry Symposium - Jean-Marie Lehn’s Lab 40th Anniversary, Strasbourg, France, 27-30 July 2005 Supramolecular catalysis: asymmetric hydrogen transfer mediated by a cycloruthenated complex 4) J.-B. Sortais, T. Voss, G. Kehr, R. Fröhlich, G. Erker Journées de Chimie de Coordination, 28-29 January 2010, Palaiseau, France 1,2-Olefin Addition of a Frustrated Amine/Borane Lewis Pair 5) D. Bézier, F. Jiang, J-B Sortais, C. Darcel EuCOMC 19, July 2011, Toulouse, France N-Heterocyclic Carbene Piano-Stool Iron Complexes as Efficient Catalysts for Hydrosilylation of Carbonyl Derivatives 6) L. C. Misal Castro, D. Bézier, J.-B. Sortais, C. Darcel Gecom-Concord, Merlinont, France, May 2011 Iron-Hydride Complex as pre-Catalyst for Efficient Hydrosilylation of Carbonyl Derivatives under Visible Light Activation 7) H. Jaafar, H. Li, Luis C. Misal Castro, J.-B. Sortais, C. Darcel International Green Catalysis Symposium, 7-9 March 2012, Rennes, France Phosphino-Pyridine Iron Complexes and Application on Hydrosilylation Catalysed Reactions 8) F. Jiang, D. Bézier, J.-B. Sortais, C. Darcel International Green Catalysis Symposium, 7-9 March 2012, Rennes, France N-Hetrocyclic Carbene Piano-Stool Iron Complexes as Efficient Catalysts for Hydrosilylation of Carbonyl Derivatives 9) L. P. Bheeter, M. Henrion, M. Rocquin, V. Ritleng, M. J. Chetcuti, J.-B. Sortais, C. Darcel International Green Catalysis Symposium, 7-9 March 2012, Rennes, France Half-sandwich NHC nickel complexes as efficient catalysts in hydrosilylation reactions 10) L. C. Misal Castro, J.-B. Sortais, C. Darcel International Green Catalysis Symposium, 7-9 March 2012, Rennes, France Iron-Catalyzed Hydrosilylation of imines 11) J. Zheng, L. C. Misal Castro, J.-B. Sortais, C. Darcel International Green Catalysis Symposium, 7-9 March 2012, Rennes, France Iron Piano-Stool Phosphine Complexes for catalytic hydrosilylation reactions 12) J.-B. Sortais, L. C. Misal Castro, J. Zheng, D. Bézier, F. Jiang, C. Darcel 18th International Symposium on Homogenous Catalysis, 9-13 July 2012, Toulouse, France Iron catalyzed hydrosilylation: from carbonyls to carboxylic acid derivatives 13) L .C. Misal Castro, D. Bézier, J. Zheng, J.-B. Sortais, C. Darcel 7 2013 2014 International Conference Catalysis in Organic Synthesis, 15-20 September 2012, Moscow, Russia Well defined iron complexes as efficient catalysts for hydrosilylation reactions of carbonheteroatom double bonds 14) J. Zheng, L. C. Misal Castro, J.-B. Sortais, C. Darcel ICOMC 2012, 2-7 September 2012, Lisbon, Portugal Iron piano-stool phosphine complexes for catalytic hydrosilylation reactions 15) J.-B. Sortais, Luis C. Misal Castro, H. Li, J. Zheng, C. Darcel ESOC 18th 2013, 7-12 July 2013, Marseille, France Iron catalysed reduction of carboxylic acids with hydrosilanes 16) J. Zheng, C. Darcel, J.-B. Sortais EuCOMC XX, 30 June-4 July 2013, St Andrews, Scotland Nickel catalysed reductive amination with silanes 17) L. P. Bheeter, M. J. Chetcuti, V. Ritleng, C. Darcel, J.-B. Sortais EuCOMC XX, 30 June-4 July 2013, St Andrews, Scotland Hydrosilylation of imines catalyzed by an N-Heterocyclic carbene nickel complex 18) T. Dombray, C. Helleu, C. Darcel, J.-B. Sortais Journée Chimie de Coordination 2014, January 30-31, 2014, Université de Rennes, France Cobalt Carbonyl Catalyzed Hydrosilylation of Amides 19) J. Zheng, C. Darcel, J.-B. Sortais Journée Chimie de Coordination 2014, January 30-31, 2014, Université de Rennes, France Iron catalyzed hydroboration 20) S. Elangovan, J. Zheng, C. Darcel, J.-B. Sortais Journée Chimie de Coordination 2014, January 30-31, 2014, Université de Rennes, France Manganese catalyzed hydrosilylation reaction 21) S. Quintero Duque, C. Darcel, J.-B. Sortais Journée Chimie de Coordination 2014, January 30-31, 2014, Université de Rennes, France Well defined iron complexes bearing N-Heterocyclic Carbenes and pentamethylcyclopentadienyl (Cp*) ligands as catalysts for hydrosilylation reactions 22) L. P. Bheeter, M. Henrion, M. Rocquin, V. Ritleng, M. J. Chetcuti, J.-B. Sortais, C. Darcel Journée Chimie de Coordination 2014, January 30-31, 2014, Université de Rennes, France Half-sandwich NHC-nickel complexes as efficient catalysts for hydrosilylation of aldehydes and ketones 23) T. Dombray, C. Helleu, C. Darcel, J.-B. Sortais 2nd International Green Catalysis Symposium, April 2-4, 2014, Université de Rennes, France Cobalt Carbonyl Catalyzed Hydrosilylation of Amides 24) J. Zheng, C. Darcel, J.-B. Sortais 2nd International Green Catalysis Symposium, April 2-4, 2014, Université de Rennes, France Iron catalyzed hydroboration 25) S. Elangovan, J. Zheng, C. Darcel, J.-B. Sortais 2nd International Green Catalysis Symposium, April 2-4, 2014, Université de Rennes, France Manganese catalyzed hydrosilylation reaction 26) S. Quintero Duque, C. Darcel, J.-B. Sortais 2nd International Green Catalysis Symposium, April 2-4, 2014, Université de Rennes, France Well defined iron complexes bearing N-Heterocyclic Carbenes and pentamethylcyclopentadienyl (Cp*) ligands as catalysts for hydrosilylation reactions 8 27) L. P. Bheeter, M. Henrion, M. Rocquin, V. Ritleng, M. J. Chetcuti, J.-B. Sortais, C. Darcel 2nd International Green Catalysis Symposium, April 2-4, 2014, Université de Rennes, France Half-sandwich NHC-nickel complexes as efficient catalysts for hydrosilylation of aldehydes and ketones 28) T. Dombray, C. Helleu, C. Darcel, J.-B. Sortais 5th EuCheMS, August 31-September 4, 2014, Istanbul, Turkey. Cobalt Carbonyl Catalyzed Hydrosilylation of Amides 29) J. Zheng, C. Darcel, J.-B. Sortais 5th EuCheMS, August 31-September 4, 2014, Istanbul, Turkey. Iron catalyzed hydroboration Supervision PhD students Saravanakumar Elangovan (10/2013-) co-tutelle with C. Darcel/J.-B. Sortais (UR1) and M. Beller (LIKAT, Rostock) Jianxia Zheng (10/2011-10/2014) co-direction with C. Darcel, « Hydroelementation reactions catalyzed by earth abundant metals », defended in Rennes, 07/10/2014 funded by Axa Research Funds. Linus Pauling Bheeter (10/2011-12/2014) co-direction with C. Darcel, « Nickel catalyzed hydrosilylation and borylation », defended in Rennes, 11/12/2014, funded by CEFIPRA. Luis C. Misal Castro (10/2009-11/2012) co-direction with C. Darcel “Molecular defined iron complexes for catalytic hydrosilylation reactions”, defended in Rennes, 23/11/2012. Currently, postdoc fellow in the group of N. Chatani, Osaka, Japan, since January 2013. David Bézier (2008-2011) co-direction with C. Darcel (2009-2011) “Réactions d’hydratation et d’hydrosilylation catalysées par le fer”, defended in Rennes, 18/11/2011. Currently, post-doc fellow in the group of M. Brookhart, Chapel Hill, USA, since January 2012. Post-doctoral researchers Dr. Thomas Dombray (10/2012-) co-direction with C. Darcel, funded by “la Région Bretagne”, via the project Create “Bioricat” and the ANR “IRONHYC” Dr. Venkanna Gopaladasu T. (October 2010- October 2011) co-direction with C. Darcel, funded by the « Université de Rennes 1 » Dr. Hassen Jaafar (April 2011-September 2012) co-direction with C. Darcel, funded by “la région Bretagne”, via the project Create « Bioricat » Masters students Fan Jiang (2009-2011), International Master in Molecular Catalysis and Green Chemistry, Rennes Jianxia Zheng (2010-2011), International Master in Molecular Catalysis and Green Chemistry, Rennes. Haoquan Li (2011-2013) International Master in Molecular Catalysis and Green Chemistry, Rennes, currently PhD student with Pr. M. Beller, LIKAT, Rostock, Germany Saravanakumar Elangovan (2012-2013) International Master in Molecular Catalysis and Green Chemistry, Rennes, currently PhD student with Pr. C. Darcel/Dr. J-B. Sortais and Pr. M. Beller Laurentine Nziraguseswa (2012-2013) Master 2 Chimie Moléculaire, Rennes Samuel Quintero Duque (2012-2014) International Master in Molecular Catalysis and Green Chemistry, Rennes She Jiang (2013-2015) International Master in Molecular Catalysis and Green Chemistry, Rennes Duo Wei (2014-2016) International Master in Molecular Catalysis and Green Chemistry, Rennes 9 Undergraduated students Florian Chotard (Spring 2011) Fanny Herbert (Spring 2012) Antoine Bruneau-Voisin (Spring 2013) Camille Helleu (June 2013) Anatole Clerc-Cathala (Spring 2014) Hiwote Mebrate (June 2014) Teaching activities • As Teaching Assistant at the University Louis Pasteur, Strasbourg (about 64 hours per year) 2003-2006 2003-2005 - Chimie des éléments, Deug 1ère année, Chimie-Physique (15h TD) - Chimie expérimentale, DEUG 1ère année, Chimie-Physique (30h TP) Les thèmes abordés vont de la structure de l’atome à la chiralité. - Synthèse Organique et Minérale DEUG 2ème année, Chimie-Physique (40h TP) Travaux pratiques de chimie organique et inorganique incluant les réactions et les techniques classiques de la chimie (distillation, recristallisation, chromatographies, réduction d’une cétone, synthèse et réactivité d’un Grignard, dosage pHmétrique…) 2003-2004 - Correction de leçons à l’agrégation de chimie Préparation à l’agrégation de Sciences Physiques, option Chimie (6h TD) 2005-2006 - Chimie expérimentale Licence Chimie-Physique, S2 (12h TD, 32h TP) - TP de Chimie Organique Licence Physique-Chimie S3 (7h TD, 21h TP) • As Temporary Teaching position at the University Louis Pasteur, Strasbourg (90 hours) 20062007 - TD de Spectroscopie Master 1 Chimie et Sciences du vivant (16h TD) - TD de Chimie Organique Licence de Chimie S5 (15h TD) - Méthodologie du Travail Universitaire Licence de Chimie S1 (12h CI+12h TD) Cette unité d’enseignement a pour objectif d’accompagner l’étudiant, entrant à l’université, à acquérir l’autonomie et l’organisation dont dépend son succès futur. Pour cela, l’ensemble des outils pédagogiques disponibles à l’université lui sont présentés (bibliothèque, ressources en ligne…), une attention toute particulière est portée sur la prise de note. - Chimie Organique Expérimentale Licence de Chimie S3 (19h TD + 9h TP) • Trainer at the DEPULP (continuing education department), "Mechanisms in Organic Chemistry" (30 hours per year), Université Louis Pasteur, Strasbourg (June 2004 and June 2005) Cours de formation permanente en Chimie Organique intitulé « Chimie organique : mécanismes réactionnels et implications synthétiques ». Public : un groupe de 5 à 15 personnes ayant des parcours allant du DUT au Doctorat ou Diplôme d’ingénieur en Chimie, animé par deux formateurs. La formation couvre le programme de Licence en chimie organique. L’intensité de la formation (6 h par jour) nécessite d’alterner cours, exercices, et discussions portant sur les préoccupations et les attentes de chacun des participants. • As assistant professor at the University Rennes 1 10 - Introduction à la chimie de coordination, M1 Biochimie, (cours 6h, TD 6h, TP 12h) Introduction aux notions de complexes, ligands, formalisme de Green et catalyse - Cours de Chimie Organique, Leçon de Chimie, Préparation de l'Agrégation de Sciences Physiques. (40h) Préparation à l’épreuve écrite de Chimie Organique, révision du programme de chimie organique de licence ou des classes préparatoires aux grandes écoles. - TP de Chimie Organométallique, M1 Chimie (14h) Synthèse des complexes de ruthénium et de palladium sous atmosphère inerte, caractérisation et application en catalyse. -TD de Réactivité et Stéréochimie en Chimie Organique, L3 Biochimie (8h) - Introduction à la catalyse organométallique et la chimie verte, M1-M2 MEF (cours 8h) - Cours-TD d’atomistique, L1 Chimie (20h) - TP de chimie générale, L1 Chimie (18h) - TD de thermochimie, L1 Chimie (10h) Conference organization Participation to the local organization committee of five international conferences and symposium • • • • • ISOM 19, (International Symposium on Olefin Methathesis) Rennes, France, 10-15 july 2011. Symposium "International Green catalysis Symposium and Advanced spring School on Green Catalysis", Rennes, 7−9 March 2012. International Symposium of Metal-Mediated Chemistry, Strasbourg, France, November 22th 2013 Symposium "2nd International Green catalysis Symposium and Advanced spring School on Green Catalysis", Rennes, 2-4 April 2014. "2nd International Symposium on C-H activation", Rennes, 30 June-3 July 2014. 11