Anthony KERMAGORET - Institut de Chimie Radicalaire

Anthony KERMAGORET
Maitre de Conférences, Aix-Marseille Université
Date et lieu de naissance : 8 juin 1980 à Quimperlé (France)
Adresses électroniques : [email protected]
Téléphone professionnelle : 04 91 28 80 94
Institut de Chimie radicalaire UMR-7273, équipe CROPS, service 542, UFR-Science,
Faculté Etoile/St-Jérôme, Aix-Marseille Université, Av. Escadrille Normandie-Niemen,
13397 Marseille cedex 20.
Carrière scientifique
depuis
Sept-2015
Maitre de conférences (section 33) à L’Université Aix-Marseille
ICR-CROPS, UMR-CNRS 7273, Faculté St-Jérôme, AMU
Section CNU-33 chimie des matériaux
2015
Fev-sept
Chercheur post-doctorant CNRS, ICR-CROPS, UMR-CNRS 7273,
Université Aix-Marseille sous la direction de Dr. D. Gigmes.
Sujet : Synthèse de nanomachines par chimie supramoléculaire
2011-2015
Chercheur post-doctorant, CERM laboratory (University of Liège,
Belgium) sous la direction de Dr. C. Detrembleur.
Sujet : Synthèses de polymères par voie radicalaire contrôlée par
complexes organométalliques.
2009-2011
Chercheur post-doctorant CNRS, LCOMS (CPE Lyon, France) sous la
direction de Dr. C. Copéret.
Sujet : Catalyseurs supportés sur matériaux silice pour oligomérisation
2008-2009
Chercheur post-doctorant, CAT Catalytic Center (ITMC, RWTH-Aachen
University, Germany) sous la direction de Dr. T. E. Müller.
Sujet : synthèse catalytique de polymères polycarbonates et polyéthers par
copolymérisation CO2/époxydes.
2008-2007
Attaché temporaire enseignement et recherche, faculté de pharmacie de
l’université Paris XI (France). Enseignements en biostatistiques160 h TD.
Recherche au sein de BioCIS sous la direction de Dr. G. Morgant. Sujet :
Complexes de rhénium à chélates sélénium pour applications anticancer.
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Etudes et diplômes
2007-2003
Thèse de doctorat au laboratoire de chimie de coordination (Université de
Strasbourg, France) sous la direction de Dr P. Braunstein. Thèse MRT.
Sujet : synthèse de nouveaux complexes de fer et nickel pour
l’oligomérisation de l’éthylène.
2003-2001
DEA et Maitrise Chimie, Université de Brest (France).
Stage (DEA, 8 mois) au laboratoire CEMCA (Brest, France) sous la
direction de Pr. H. Desabbayes.
Sujet : complexes NHC du rhodium pour hydroformylation du styrène.
2001-2000
Licence Chimie, Université Rennes I (France).
2000-1998
DUT Chimie, Université Rennes I (France).
Stage (3 mois) au laboratoire CEMCA (Université de Brest, France) sous la
direction de Pr. H. Desabbayes.
Sujet : synthèse vecteurs ammonium-phosphonate pour thérapie génique.
Expertises :

Techniques de synthèse : synthèses organiques, inorganiques et organométalliques

Ingénierie macromoléculaire, synthèse et caractérisation de polymères.

Catalyse : oligomérisation et polymérisation d’oléfines sous très haute pression.

Enseignement universitaire et encadrement d’étudiants thésards et stagiaires Master
Liste de Publications (h indice de 15)
(1).
A. Al Mousawi, A. Kermagoret,* D.-L. Versace, J. Toufaily, T. Hamieh, B. Graff, F.
Dumur, D. Gigmes, J.-P. Fouassier, J. Lalevée. Polym. Chem., 2016, head of print. Copper
Photoredox Catalyts For Polymerization Upon Near UV or Visible Light:
Structure/Reactivity/Efficiency Relationships and Use in LED Projector 3D Printing Resins.
(2).
A. Kermagoret,* D. Gigmes. Tetrahedron, 2016, 72(48), 7672-7685. Combined
nitroxide mediated radical polymerization techniques for block copolymer synthesis.
(3).
N. Zivic, M. Bouzrati-Zerelli, A. Kermagoret,* F. Dumur, J.-P. Fouassier, D.
Gigmes, J. Lalevée. ChemCatChem, 2016, 8(9), 1617-1631. Photocatalysts in
Polymerization Reactions
(4).
A. Kermagoret, N. D. Q.Chau, B. Grignard, D. Cordella, A. Debuigne, C. Jérôme, C.
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Detrembleur. Macromol. Rapid Commun. 2016, 37(6), 539-544. Cobalt-Mediated Radical
Polymerization of Vinyl Acetate and Acrylonitrile in Supercritical Carbon Dioxide.
(5).
J. Demarteau, A. Kermagoret, I. German, D. Cordella, K. Robeyns, J. De Winter, P.
Gerbaux, C. Jerome, A. Debuigne, C. Detrembleur, Christophe. Chem. Commun., 2015,
51(76), 14334-14337. Halomethyl-cobalt(bis-acetylacetonate) for the controlled synthesis of
functional polymers.
(6).
D. Cordella, A. Kermagoret, A. Debuigne, C. Jérôme, D. Mecerreyes, M. Isik, D.
Taton, C. Detrembleur. Macromolecules, 2015, 48(15), 5230-5243. All poly(ionic liquid)based block copolymers by sequential controlled radical copolymerization of vinyl
imidazolium monomers.
(7).
A. Kermagoret, B. Wenn, A. Debuigne, C. Jérôme, T. Junkers, C. Detrembleur
Polymer Chem., 2015, 6, 3847-3857. Improved Photo-Induced Cobalt-Mediated Radical
Polymerization in Continuous Flow Photoreactors.
(8).
J.-M. Thomassin, K. Mathieu, A. Kermagoret, C.-A. Fustin, C. Detrembleur, C.
Jérôme, A. Debuigne, Polymer Chem., 2015, 6, 1856-1864. Double Thermo-Responsive
Hydrogels from Poly(vinylcaprolactam) Containing Di- and Triblock Copolymers.
(9).
P. Collery, A. Mohsen, A. Kermagoret, S. Corre, G. Bastian, A. Tomas, W. Ming, F.
Santoni, N. Guerra, D. Desmaele, J. D’angelo. Invest. New Drugs, 2015, 33, 848-860.
Antitumor activity of a rhenium (I)-diselenoether complex in experimental models of human
breast cancer.
(10). D. Cordella, A. Kermagoret, A. Debuigne, R. Riva, I. German, M. Isik, C. Jérôme, D.
Mecerreyes, D. Taton, C. Detrembleur, ACS Macroletters, 2014, 3, 1276-1280. Direct Route
to Well-Defined Poly(ionic liquid)s by Controlled Radical Polymerization in Water.
(11). A. Kermagoret, A. Debuigne, C. Jérôme, C. Detrembleur, Nature Chemistry, 2014,
6, 179-187. Precision design of ethylene/polar monomer-based copolymers by
organometallic-mediated radical polymerization.
(12). A. Kermagoret, K. Mathieu, J.-M. Thomassin, C.-A. Fustin, R. Duchêne, C. Jérôme,
C. Detrembleur, A. Debuigne, Polymer Chem. 2014, 5, 6534-6544. Double thermoresponsive
di- and triblock copolymers based on N-vinylcaprolactam and N-vinylpyrrolidone: synthesis
and comparative study of solution behavior.
(13). A. Kermagoret, C. Jérôme, C. Detrembleur, A. Debuigne, Eur. Polym. J. 2014, 62,
312-321. In situ bidentate to tetradentate ligand exchange reaction in cobalt-mediated radical
polymerization.
(14). A. Kermagoret, Y. Nakamura, M. Bourguignon, C. Detrembleur, C. Jérôme, S.
Yamago, A. Debuigne, ACS Macroletters, 2014, 114-118. Expanding the scope of controlled
radical polymerization via cobalt-tellurium radical exchange reaction.
(15). A. Kermagoret, R. Kerber, M. Conley, E. Callens, P. Florian, D. Massiot, C. Copéret,
F. Delbecq, X. Rozanska, P. Sautet, J. Catal. 2014, 313, 46-54. Chlorodiethylaluminum
supported on silica: a dinuclear Al surface species with bridging μ2–Cl–ligand and a highly
efficient co-catalyst for the Ni-catalyzed dimerization of ethene.
(16). A. Kermagoret, C.-A. Fustin, M. Bourguignon, C. Detrembleur, C. Jérôme, A.
Debuigne, Polymer Chem. 2013, 4, 2575-2583. One-pot controlled synthesis of double
thermoresponsive N-vinylcaprolactam-based copolymers with tunable LCSTs.
(17). A. Kermagoret, R.N. Kerber, M.P. Conley, E. Callens, P. Florian, D. Massiot, C.
Coperet, F. Delbecq, X. Rozanska, P. Sautet, Dalton Trans., 2013, 42, 12681-12687.
Triisobutylaluminum: bulkier and yet more reactive towards silica surfaces than triethyl or
trimethylaluminum.
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(18). R. Kerber, A. Kermagoret, E. Callens, P. Florian, D. Massiot, A. Lesage, C. Copéret,
F. Delbecq, X. Rozanska, P. Sautet, J. Am. Chem. Soc. 2012, 134, 6767-6775.
Nature and structure of aluminum surface sites grafted on silica from a combination of high
field aluminum-27 solid-state NMR spectroscopy and first principle calculations.
(19). A. Debuigne, A. Morin, A. Kermagoret, Y. Piette, C. Detrembleur, C. Jérôme, R. Poli
Chem. Eur. J., 2012, 18, 12834-12844. Key Role of Intramolecular Metal Chelation and
Hydrogen Bonding in the Cobalt-Mediated Radical Polymerization of N-Vinyl amides
(20). P. Collery, A. Mohsen, A. Kermagoret, J. D’Angelo, G. Morgant, D. Desmaele, A.
Tomas, T. Collery, M. Wei, A. Badawi, Anticancer Research 2012, 32, 2769-2781.
Combination of three metals for the treatment of cancer: gallium, rhenium and platinum. 1Determination of the optimal schedule of treatment.
(21). A. Kermagoret , G. Morgant, J. d’Angelo, A. Tomas, P. Roussel, G. Bastian, P.
Collery, D. Desmaële, Polyhedron, 2011, 30, 347-353. Synthesis, structural characterization
and biological activity against several human tumor cell lines of four rhenium(I) diselenoethers complexes.
(22). J. Zhang, P. Teo, R. Pattacini, A. Kermagoret, R. Welter, T.S.A. Hor, P. Braunstein,
Angew. Chem. Int. Ed., 2010, 49, 4443-4446. Templating effect of sodium cations in the
synthesis of polynuclear, multicubane-type mixed Na-Ni complexes.
(23). P. Chavez, I. G. Rios, A. Kermagoret, R. Pattacini, A. Meli, C. Bianchini, G.
Giambastiani, P. Braunstein, Organometallics, 2009, 28, 1776-1784
Nickel Complexes with Phosphinito-Oxazoline Ligands: Temperature-Controlled of Mono- or
dinuclear Complexes and Catalytic Oligomerization of Ethylene and Propylene.
(24). A. Kermagoret and P. Braunstein, Dalton Trans., 2008, 585-587
Contrasting bonding modes of a tridentate bis(oxazoline)phosphine ligand in cobalt and iron
vs. palladium complexes: unprecedented N,N-coordination for a N,P,N ligand.
(25). A. Kermagoret, F. Tomicki, P. Braunstein, Dalton Trans., 2008, 2945-2955. Nickel
and iron complexes with N,P,N-type ligands: synthesis, structure and catalytic
oligomerization of ethylene.
(26). A. Kermagoret and P. Braunstein, Organometallics, 2008, 27, 88-99
Mono- and Dinuclear Ni Complexes with Phosphino-, Phosphinito-, and Phosphonitopyridine
Ligands: Synthesis, Structures, and Catalytic Oligomerization of Ethylene.
(27). A. Kermagoret and P. Braunstein, Dalton Trans., 2008, 822-831. SHOP-type nickel
complexes with alkyl substituents on phosphorus, synthesis and catalytic ethylene
oligomerization.
(28). A. Kermagoret and P. Braunstein, Dalton Trans., 2008, 1564-1573
Synthesis of nickel complexes with bidentate N,O-type ligands and application in the catalytic
oligomerization of ethylene.
(29). S. Jie, M. Agostinho, A. Kermagoret, C. S. J. Cazin, P. Braunstein, Dalton Trans.,
2007, 4472-4482. Mono- and dinuclear Co complexes with chelating or bridging bidentate
P,N phosphino- and phosphinito-oxazoline ligands: synthesis, structures and catalytic
ethylene oligomerisation.
(30). A. Kermagoret, R. Pattacini, P. C. Vasquez, G. Rogez, R. Welter, P. Braunstein,
Angew. Chem. Int. Ed., 2007, 46, 6438-6441. Unprecedented Tetranuclear Complexes with
20-Electron NiII Centers: The Role of Pressure and Temperature on Their Solid-State and
Solution Fragmentation.
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(31). Q.-Z. Yang, A. Kermagoret, M. Agostinho, O. Siri, P. Braunstein, Organometallics,
2006, 25, 5518-5527. Nickel Complexes with Functional Zwitterionic N,OBenzoquinonemonoimine-Type Ligands: Syntheses, Structures, and Catalytic Oligomerization
of Ethylene.
Brevets
Müller T. E., Gürtler C., Kermagoret A., Dienes Y., Busygin I., Köhler , Leitner W.
PCT Int. Appl. (2012), WO 2012059550; Ger. Offen. (2012), DE 102010043409 A1
Method for producing aliphatic polycarbonate polyols by living polymerization of cyclic
carbonates
Müller T. E., Gürtler C., Kermagoret A., Dienes Y., Barruet J., Wolf A., Grasser S.
PCT Int. Appl. (2013), WO 2013087582 A2; Eur. Pat. Appl. (2013), EP 2604641 A1
method for producing polyetherester carbonate polyols
Chapitre de livre
“Controlled Synthesis of EVA-Based Copolymers by Organometallic Mediated Radical
Polymerization” Jérémy Demarteau, Anthony Kermagoret, Christine Jérôme, Christophe
Detrembleur, Antoine Debuigne, ACS Symposium Series (2015), 1188 (Controlled Radical
Polymerization), 47-61.
Communication CNRS
(http://www.cnrs.fr/inc/communication/direct_labos/sautet.htm)
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