Contact : - Equipe Chimie Moléculaire et Organisation du Solide

Contact : - Equipe Chimie Moléculaire et Organisation du Solide

LARIONOVA JOULIA
Professor, Université Montpellier 2, Faculté des
Sciences,
Département de Chimie, HDR
Contact :
ICGM - UMR5253- Equipe CMOS
Université Montpellier II
2 Place Eugène Bataillon - CC 1502
34095 Montpellier CEDEX 5
Tel: +33 (0)4 67 14 4805
Fax: +33 (0)4 67 14 33 35
Email : [email protected]
University Diploma:
1993 : Engineer of Radiochemistry and nuclear physics, mention: Excellent, Department of physics –
chemistry, Technological Institute of St. Petersburg, , St. Petersburg, Russia.
1995 : Diploma of Master 2 (DEA) in Inorganic Chemistry and Materials, mention B, Université Paris Sud,
Orsay, Director of Master 2: Pr. O. Kahn. Title: Bi-functional Molecular Materials.
1998 : PhD, Université Bordeaux I, Director of PhD: Pr. O. Kahn. Title : Molecular process and magnetic
transitions. Date of PhD: 16/11/1998.
2004 : Habilitation Diploma, Université Montpellier II. Title : Organization and Dimensionality of Magnetic
Materials. Date: 04/05/2004.
Post-doctoral Positions:
1998 : Director Prof. C. Floriani, University of Lausanne, Switzerland. Title : Molecular approach for extended
structures.
1999 : Director Prof. S. Decurtins, University of Bern, Switzerland. Title: Synthesis and study of magnetic
clusters.
Research Activity :
♦ Fields :
• Coordination Chemistry – Coordination Polymer Networks;
• Molecular Materials – Molecular magnets; molecular engineering, structure – properties relationship.
• Nanoparticles et nanomaterials (metal and metal oxide, coordination polymer nanoparticles);
• Magnetic properties and luminescence.
♦ Principal research themes:
Crystalline engineering and molecular materials: 1994 - 2002
1994 –1996: Coordination chemistry of Rh, Ru, Os and Pt complexes (Key words : coordination chemistry,
ruthenium, rhodium, osmium, platinum complexes).
1997-1998: Molecular magnets based on oxamato , oxamido and oxalate bridging ligands: synthesis, structures
and magnetic properties (Key words : molecular magnets, coordination polymers, magnetic properties,
coordination chemistry, transition metals).
Above 1998: Molecular engineering in the cyanométallates based systems M2+/[M’(CN)n] 4- (M and M’ =
transition metals, n = 4-8). Synthesis, structures, magnetic properties, intercalation; structure – properties
relationship. (Key words: coordination chemistry, cyanometallates, magnetic properties, host-guest systems,
magnetic clusters, coordination polymers).
Nanoparticles and nanomaterials with tailored properties: 2002 - …
- Coordination Polymer Nanoparticles (cyanometalates’ type) synthesized as colloids (organic, aqueous and
ionic liquids) and confined into the inorganic matrixes (functionalized mesostructured silica, porous glasses),
organic matrices (polymers) (Key words : nanoparticles, coordination polymers, cyanometallates,
multifunctional materials, colloidal solutions, gadolinium, superparamagnets, Magnetic Resonance Imaging,
relaxivity, chitosan, PEG, confinement, inorganic – organic matrixes, mesostructured silica, ionic liquids,
organization, magnetic properties, luminescence).
- Metallic, Alloy and Metal Oxide Nanoparticles into colloids (ionic liquids, organic solutions) or confined into
the inorganic matrices (functionalized mesostructured silica) (Key words : nanoparticles, confinement,
magnetic properties, mesostructured silica, matrixes, hybrid materials);
- Grafting of biomolecules (sugars) on the surface of magnetic nanoparticles for therapeutic treatment and
diagnosis. (Key words: nanoparticles, superparamagnets, MRI, hyperthermia, therapeutic treatment, sugars);
♦ Publications into the scientific journals: 71
♦ Patent : 1
♦ Conferences et Communications : 69
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Selection of recent articles:
Synthesis and behaviour of size controlled cyano-bridged coordination polymer nanoparticles within
hybrid mesoporous silica, B. Folch, Y. Guari, J. Larionova, C. Luna, C. Sangregorio, C. Innocenti, A.
Caneschi, Ch. Guérin, New J. Chem., 2008, (Advance Article, cover), 32, 273-282.
Soluble
Ligand-Stabilized
Cyano-Bridged
Coordination
Polymer
Nanoparticles
E.
Chelebaeva,
Y.
Guari,
J.
Larionova,
A.
Trifonov,
Ch.
Guérin,
Chem. Mater. 2008; 20(4); 1367-1375.
Towards the ultimate size limit of the memory effect in spin crossover solids, J. Larionova, L. Salmon,
Y. Guari, A. Tokarev, K. Molvinger, G. Molnar, A. Bousseksou, Angew. Chem. Int. Ed. 2008, 47,
8236-8240.
The
Canted
Antiferromagnetic
Approach
to
Single-Chain
Magnets
K. Bernot, J. Luzon, R. Sessoli, A. Vindigni, J. Thion, S. Richeter, D. Leclercq, J. Larionova, A. van der
Lee, J. Am. Chem. Soc. (Article); 2008; 130(5); 1619-1627.
Toward 2D Organization of Metallic Cyano-Bridged Coordination Polymer Nanoparticles at the NanoLevel within Ionic Liquid Crystal, J. Larionova, Y. Guari, C. Blanc, P. Dieudonné, A. Tokarev, C.
Guérin, Langmuir 2009, 25, 1138-1147.
Bifunctional Cyano-Bridged Coordination Polymers: toward Multifunctional Materials.
E. Chelebaeva, J. Larionova, Y. Guari, R. A. Sa Ferreira, L. D. Carlos, F. A. Almeida A. Trifonov, Ch.
Guérin, C. Inorg. Chem. 2009, 48, 5983-5995.
Water-Soluble Rhamnose-Coated Fe3O4 Nanoparticles, L. Lartigue,K. Oumzil, Y. Guari, J. Larionova,
Ch. Guérin, J.-L. G. Montero , V. Barragan-Montero, C. Sangregorio, A. Caneschi, C. Innocenti, T.
Kalaivani, P. Arosio, A. Lascialfari, Organic Letters, 2009, 11, 2992-2995.
Nanoscale coordination polymers exhibiting luminescence properties and NMR relaxivity, E.
Chelebaeva, J. Larionova, Y. Guari, Y, R. A. S. Ferreira, L. D. Carlos, A. A. Trifonov, T. Kalaivani, A.
Lascialfari, Ch. Guérin, K. Molvinger, L. Datas, M. Maynadier, M. Gary-Bobo, M. Garcia, Nanoscale,
2011, 3, 1200-1210.
Water-Dispersible Sugar-Coated Iron Oxide Nanoparticles. An Evaluation of their Relaxometric and
MagneticHyperthermia Properties, L. Lartigue, C. Innocenti, T. Kalaivani, A. Awwad, M. del Mar
Sanchez, Y. Guari, J. Larionova, Ch. Guerin, J.-L. Montero, V. Barragan-Montero, P. Arosio, A.
Lascialfari, D. Gatteschi, C. Sangregorio, J. Am. Chem. Soc., 2011.