safety data sheet - PH Vitres d`Autos

Transcription

SAFETY DATA SHEET
THE DOW CHEMICAL COMPANY
Product name: BETAPRIME™ 5201 Bare Metal Etch Primer
Issue Date: 04/09/2015
Print Date: 07/09/2015
THE DOW CHEMICAL COMPANY encourages and expects you to read and understand the entire
(M)SDS, as there is important information throughout the document. We expect you to follow the
precautions identified in this document unless your use conditions would necessitate other appropriate
methods or actions.
1. IDENTIFICATION
Recommended use of the chemical and restrictions on use
Identified uses: A primer - For use in automotive applications.
COMPANY IDENTIFICATION
THE DOW CHEMICAL COMPANY
2030 WILLARD H DOW CENTER
MIDLAND MI 48674-0000
UNITED STATES
Customer Information Number:
800-258-2436
[email protected]
EMERGENCY TELEPHONE NUMBER
24-Hour Emergency Contact: 800-424-9300
Local Emergency Contact: 800-424-9300
2. HAZARDS IDENTIFICATION
Hazard classification
This material is hazardous under the criteria of the Federal OSHA Hazard Communication Standard
29CFR 1910.1200.
Flammable liquids - Category 2
Eye irritation - Category 2A
Reproductive toxicity - Category 1B
Specific target organ toxicity - single exposure - Category 3
Specific target organ toxicity - repeated exposure - Category 2 - Inhalation
Label elements
Hazard pictograms
® ™ Trademark of The Dow Chemical Company ("Dow") or an affiliated
company of Dow
Page 1 of 24
Signal word: DANGER!
Hazards
Highly flammable liquid and vapour.
Causes serious eye irritation.
May cause drowsiness or dizziness.
May damage fertility or the unborn child.
May cause damage to organs through prolonged or repeated exposure if inhaled.
Precautionary statements
Prevention
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Keep container tightly closed.
Ground/bond container and receiving equipment.
Use explosion-proof electrical/ ventilating/ lighting/ equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
Wash skin thoroughly after handling.
Use only outdoors or in a well-ventilated area.
Wear protective gloves/ protective clothing/ eye protection/ face protection.
Response
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with
water/shower.
IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON
CENTER or doctor/ physician if you feel unwell.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
IF exposed or concerned: Get medical advice/ attention.
If eye irritation persists: Get medical advice/ attention.
In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.
Storage
Store in a well-ventilated place. Keep container tightly closed.
Store in a well-ventilated place. Keep cool.
Store locked up.
Disposal
Dispose of contents/ container to an approved waste disposal plant.
Other hazards
no data available
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3. COMPOSITION/INFORMATION ON INGREDIENTS
This product is a mixture.
Component
CASRN
Acetone
67-64-1
> 20.0 - < 30.0 %
n-Butyl acetate
123-86-4
> 15.0 - < 25.0 %
Concentration
2-PROPENOIC ACID, 2-METHYL-, 2-[(1,129354-73-2
DIMETHYLETHYL)AMINO]ETHYL ESTER,
POLYMER WITH ETHYL 2-PROPENOATE &
METHYL 2-METHYL-2-PROPENOATE
> 5.0 - < 15.0 %
Barium sulfate
7727-43-7
> 5.0 - < 15.0 %
Ethyl acetate
141-78-6
> 5.0 - < 15.0 %
Propylene glycol monomethyl ether acetate
108-65-6
> 5.0 - < 15.0 %
Talc
14807-96-6
> 5.0 - < 15.0 %
Zinc Oxide
1314-13-2
> 5.0 - < 15.0 %
Benzylbutyl Phthalate
85-68-7
< 10.0 %
isopropanol
67-63-0
< 10.0 %
PHOSPHORIC ACID, ZINC SALT (2:3) (8CI,
9CI) (CAINDEX NAME)
7779-90-0
< 10.0 %
Toluene
108-88-3
< 10.0 %
Titanium dioxide
13463-67-7
< 5.0 %
4. FIRST AID MEASURES
Description of first aid measures
General advice: First Aid responders should pay attention to self-protection and use the
recommended protective clothing (chemical resistant gloves, splash protection). If potential for
exposure exists refer to Section 8 for specific personal protective equipment.
Inhalation: Move person to fresh air. If not breathing, give artificial respiration; if by mouth to mouth
use rescuer protection (pocket mask, etc). If breathing is difficult, oxygen should be administered by
qualified personnel. Call a physician or transport to a medical facility.
Skin contact: Wash off with plenty of water.
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Eye contact: Immediately flush eyes with water; remove contact lenses, if present, after the first 5
minutes, then continue flushing eyes for at least 15 minutes. Obtain medical attention without delay,
preferably from an ophthalmologist. Suitable emergency eye wash facility should be immediately
available.
Ingestion: Do not induce vomiting. Call a physician and/or transport to emergency facility
immediately.
Most important symptoms and effects, both acute and delayed: Aside from the information found
under Description of first aid measures (above) and Indication of immediate medical attention and
special treatment needed (below), any additional important symptoms and effects are described in
Section 11: Toxicology Information.
Indication of any immediate medical attention and special treatment needed
Notes to physician: Maintain adequate ventilation and oxygenation of the patient. Hemodialysis may
be of benefit if substantial amounts have been ingested and the patient is showing signs of
intoxication. Consider hemodialysis for patients with persistent hypotension or coma unresponsive to
standard therapy (isopropanol levels >400 - 500 mg/dl). (Goldfrank 1998, King et al, 1970). Alcohol
consumed before or after exposure may increase adverse effects. No specific antidote. Treatment of
exposure should be directed at the control of symptoms and the clinical condition of the patient. Skin
contact may aggravate preexisting dermatitis.
5. FIREFIGHTING MEASURES
Suitable extinguishing media: Water fog or fine spray. Dry chemical fire extinguishers. Carbon
dioxide fire extinguishers. Foam. Alcohol resistant foams (ATC type) are preferred. General purpose
synthetic foams (including AFFF) or protein foams may function, but will be less effective.
Unsuitable extinguishing media: Do not use direct water stream. Straight or direct water streams
may not be effective to extinguish fire.
Special hazards arising from the substance or mixture
Hazardous combustion products: During a fire, smoke may contain the original material in addition
to combustion products of varying composition which may be toxic and/or irritating. Combustion
products may include and are not limited to: Carbon monoxide. Carbon dioxide.
Unusual Fire and Explosion Hazards: Container may vent and/or rupture due to fire. Electrically
ground and bond all equipment. Flammable mixtures of this product are readily ignited even by static
discharge. Vapors are heavier than air and may travel a long distance and accumulate in low lying
areas. Ignition and/or flash back may occur. Flammable mixtures may exist within the vapor space of
containers at room temperature. Flammable concentrations of vapor can accumulate at temperatures
above flash point; see Section 9.
Advice for firefighters
Fire Fighting Procedures: Keep people away. Isolate fire and deny unnecessary entry. Stay
upwind. Keep out of low areas where gases (fumes) can accumulate. Water may not be effective in
extinguishing fire. Use water spray to cool fire exposed containers and fire affected zone until fire is
out and danger of reignition has passed. Burning liquids may be extinguished by dilution with water.
Do not use direct water stream. May spread fire. Eliminate ignition sources. Move container from fire
area if this is possible without hazard. Burning liquids may be moved by flushing with water to protect
personnel and minimize property damage. Avoid accumulation of water. Product may be carried
across water surface spreading fire or contracting an ignition source.
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Special protective equipment for firefighters: Wear positive-pressure self-contained breathing
apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers,
boots, and gloves). If protective equipment is not available or not used, fight fire from a protected
location or safe distance.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures: Isolate area. Keep
unnecessary and unprotected personnel from entering the area. Keep personnel out of low areas.
Keep upwind of spill. Ventilate area of leak or spill. No smoking in area. Eliminate all sources of
ignition in vicinity of spill or released vapor to avoid fire or explosion. Vapor explosion hazard. Keep
out of sewers. For large spills, warn public of downwind explosion hazard. Check area with
combustible gas detector before reentering area. Ground and bond all containers and handling
equipment. Refer to section 7, Handling, for additional precautionary measures. Use appropriate
safety equipment. For additional information, refer to Section 8, Exposure Controls and Personal
Protection.
Environmental precautions: Prevent from entering into soil, ditches, sewers, waterways and/or
groundwater. See Section 12, Ecological Information.
Methods and materials for containment and cleaning up: Contain spilled material if possible.
Absorb with materials such as: Cat litter. Sand. Sawdust. Ground and bond all containers and
handling equipment. Pump with explosion-proof equipment. If available, use foam to smother or
supress. Collect in suitable and properly labeled containers. See Section 13, Disposal
Considerations, for additional information.
7. HANDLING AND STORAGE
Precautions for safe handling: Keep away from heat, sparks and flame. Avoid contact with eyes,
skin, and clothing. Avoid breathing vapor. Do not swallow. Wash thoroughly after handling. Keep
container closed. Use only with adequate ventilation. No smoking, open flames or sources of ignition
in handling and storage area. Ignition sources can include and are not limited to pilot lights, flames,
smoking, sparks, heaters, electrical equipment, and static discharges. Electrically bond and ground all
containers, personnel and equipment before transfer or use of material. Use of non-sparking or
explosion-proof equipment may be necessary, depending upon the type of operation. Containers,
even those that have been emptied, can contain vapors. Do not cut, drill, grind, weld, or perform
similar operations on or near empty containers. Vapors are heavier than air and may travel a long
distance and accumulate in low lying areas. Ignition and/or flash back may occur. Never use air
pressure for transferring product unless a risk assesment has been conducted that includes
consideration of the flammability of the product. See Section 8, EXPOSURE CONTROLS AND
PERSONAL PROTECTION.
Conditions for safe storage: Minimize sources of ignition, such as static build-up, heat, spark or
flame. Keep container closed. Flammable mixtures may exist within the vapor space of containers at
room temperature.
Storage stability
Storage temperature:
Shelf life: Use within
> 5 - < 35 °C (> 41 - < 95
12 Month
°F)
Page 5 of 24
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure limits are listed below, if they exist.
Component
Acetone
n-Butyl acetate
Barium sulfate
Regulation
ACGIH
ACGIH
ACGIH
OSHA Z-1
ACGIH
STEL
TWA
STEL
TWA
TWA Inhalable
fraction
TWA total dust
TWA respirable
fraction
TWA Total
TWA Respirable
fraction
TWA
TWA
TWA
400 ppm
1,400 mg/m3 400 ppm
50 ppm
TWA
TWA
STEL
TWA
TWA
5 mg/m3
200 ppm
400 ppm
980 mg/m3 400 ppm
20 ppm
TWA
TWA
CEIL
Peak
BEI
200 ppm
300 ppm
500 ppm
OSHA P0
OSHA P0
Propylene glycol
monomethyl ether acetate
isopropanol
Toluene
Value/Notation
TWA
STEL
TWA
TWA
OSHA Z-1
OSHA Z-1
Ethyl acetate
Type of listing
ACGIH
ACGIH
ACGIH
OSHA Z-1
ACGIH
OSHA Z-1
US WEEL
Dow IHG
ACGIH
ACGIH
OSHA Z-1
ACGIH
OSHA Z-1
ACGIH
OSHA Z-2
OSHA Z-2
OSHA Z-2
250 ppm
500 ppm
BEI
2,400 mg/m3 1,000
ppm
BEI
150 ppm
200 ppm
710 mg/m3 150 ppm
5 mg/m3
15 mg/m3
5 mg/m3
10 mg/m3
5 mg/m3
Although some of the components of this product may have exposure guidelines, no exposure would
be expected under normal handling conditions due to the physical state of the material.
Exposure controls
Engineering controls: Use engineering controls to maintain airborne level below exposure limit
requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, use
only with adequate ventilation. Local exhaust ventilation may be necessary for some operations.
Individual protection measures
Eye/face protection: Use chemical goggles. If exposure causes eye discomfort, use a fullface respirator.
Skin protection
Hand protection: Use gloves chemically resistant to this material when prolonged or
frequently repeated contact could occur. Examples of preferred glove barrier
materials include: Butyl rubber. Polyethylene. Ethyl vinyl alcohol laminate (“EVAL”).
Examples of acceptable glove barrier materials include: Chlorinated polyethylene.
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Natural rubber (“latex”). Neoprene. Nitrile/butadiene rubber (“nitrile” or “NBR”).
Polyvinyl alcohol (“PVA”). Polyvinyl chloride (“PVC” or “vinyl”). Avoid gloves made of:
Viton. NOTICE: The selection of a specific glove for a particular application and
duration of use in a workplace should also take into account all relevant workplace
factors such as, but not limited to: Other chemicals which may be handled, physical
requirements (cut/puncture protection, dexterity, thermal protection), potential body
reactions to glove materials, as well as the instructions/specifications provided by the
glove supplier.
Other protection: When prolonged or frequently repeated contact could occur, use
protective clothing chemically resistant to this material. Selection of specific items
such as faceshield, boots, apron, or full-body suit will depend on the task.
Respiratory protection: Respiratory protection should be worn when there is a potential to
exceed the exposure limit requirements or guidelines. If there are no applicable exposure limit
requirements or guidelines, use an approved respirator. Selection of air-purifying or positivepressure supplied-air will depend on the specific operation and the potential airborne
concentration of the material. For emergency conditions, use an approved positive-pressure
self-contained breathing apparatus.
The following should be effective types of air-purifying respirators: Organic vapor cartridge
with a particulate pre-filter.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Physical state
Color
Liquid.
Gray
Odor
Solvent
Odor Threshold
No test data available
pH
Melting point/range
Freezing point
Boiling point (760 mmHg)
Flash point
closed cup -3.89 °C ( 25.00 °F) ASTM D3278
Evaporation Rate (Butyl Acetate
= 1)
Flammability (solid, gas)
Not applicable to liquids
Lower explosion limit
Upper explosion limit
Vapor Pressure
Relative Vapor Density (air = 1)
Relative Density (water = 1)
1.25 ASTM D1475
Water solubility
Partition coefficient: noctanol/water
no data available
Auto-ignition temperature
Page 7 of 24
Decomposition temperature
Kinematic Viscosity
Explosive properties
Oxidizing properties
Molecular weight
Volatile Organic Compounds
5.10 lb/gln EPA Method No. 24 (typical value)
NOTE: The physical data presented above are typical values and should not be construed as a
specification.
10. STABILITY AND REACTIVITY
Reactivity: No dangerous reaction known under conditions of normal use.
Chemical stability: Stable under recommended storage conditions. See Storage, Section 7.
Possibility of hazardous reactions: Polymerization will not occur.
Conditions to avoid: Exposure to elevated temperatures can cause product to decompose. Avoid
static discharge.
Incompatible materials: Avoid contact with: Acids. Bases. Oxidizers.
Hazardous decomposition products: Decomposition products depend upon temperature, air supply
and the presence of other materials.
11. TOXICOLOGICAL INFORMATION
Toxicological information on this product or its components appear in this section when such data is
available.
Acute toxicity
Acute oral toxicity
Low toxicity if swallowed. Small amounts swallowed incidentally as a result of normal
handling operations are not likely to cause injury; however, swallowing larger amounts may
cause injury. May cause central nervous system depression. May cause nausea and
vomiting. Signs and symptoms of excessive exposure may include: Facial flushing. Low
blood pressure. Irregular heartbeats.
As product: Single dose oral LD50 has not been determined.
Acute dermal toxicity
Prolonged skin contact is unlikely to result in absorption of harmful amounts.
As product: The dermal LD50 has not been determined.
Acute inhalation toxicity
Prolonged excessive exposure may cause adverse effects. May cause respiratory irritation
and central nervous system depression. Symptoms may include headache, dizziness and
drowsiness, progressing to incoordination and unconsciousness. Excessive exposure (400
Page 8 of 24
ppm) to isopropanol may cause eye, nose and throat irritation. Incoordination, confusion,
hypotension, hypothermia, circulatory collapse, respiratory arrest and death may follow a
longer duration or higher levels. Observations in animals include middle ear lining damage
upon exposure to vapors of isopropanol. However, the relevance of this to humans is
unknown In humans, symptoms may include: Nausea and/or vomiting. Alcohol consumption
and exertion may increase the adverse effects of toluene.
The LC50 has not been determined.
Skin corrosion/irritation
Prolonged contact may cause severe skin irritation with local redness and discomfort.
May cause drying and flaking of the skin.
Serious eye damage/eye irritation
May cause severe eye irritation.
May cause moderate corneal injury.
Vapor may cause eye irritation experienced as mild discomfort and redness.
Sensitization
For the component(s) tested:
Did not cause sensitisation on laboratory animals.
For respiratory sensitization:
No relevant data found.
Specific Target Organ Systemic Toxicity (Single Exposure)
May cause drowsiness or dizziness.
Specific Target Organ Systemic Toxicity (Repeated Exposure)
Contains component(s) which have been reported to cause effects on the following organs in animals:
Kidney.
Liver.
Pancreas.
Spleen.
Thymus.
Bladder.
Male reproductive organs.
Nasal tissue.
Blood.
Central nervous system.
Respiratory tract.
Toluene has caused hearing loss in laboratory animals upon exposure to high concentrations.
Intentional misuse by deliberately inhaling toluene may cause nervous system damage, hearing loss,
liver and kidney effects and death.
Development of cataracts has been reported in laboratory animals after prolonged repeated skin
exposure to acetone.
Carcinogenicity
Contains component(s) which have caused cancer in some laboratory animals.
Teratogenicity
Contains component(s) which caused birth defects in laboratory animals only at doses toxic to the
mother. In laboratory animals, toluene has been toxic to the fetus at doses toxic to the mother; it has
caused birth defects in mice when administered orally, but not by inhalation. Contains component(s)
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which did not cause birth defects in lab animals, but did produce other fetal effects at doses nontoxic
to the mother. Contains component(s) which, in laboratory animals, have been toxic to the fetus at
doses nontoxic to the mother. Isopropanol has been toxic to the fetus in laboratory animals at doses
toxic to the mother.
Reproductive toxicity
Contains component(s) which have interfered with fertility in animal studies. Contains component(s)
which have been shown to interfere with reproduction in animal studies.
Mutagenicity
Contains component(s) which were negative in some in vitro genetic toxicity studies and positive in
others. Contains component(s) which were negative in some animal genetic toxicity studies and
positive in others.
Aspiration Hazard
Based on available information, aspiration hazard could not be determined.
COMPONENTS INFLUENCING TOXICOLOGY:
Acetone
Acute oral toxicity
LD50, Rat, 5,800 mg/kg
LD50, Rabbit, > 20,000 mg/kg
LC50, Rat, 4 Hour, vapour, 76 mg/l
n-Butyl acetate
Acute oral toxicity
LD50, Rat, male, 12,789 mg/kg
LD50 Oral, Rat, female, 10,760 mg/kg
LD50, Rabbit, male and female, > 14,112 mg/kg
At room temperature, exposure to vapor is minimal due to low volatility; single exposure is not
likely to be hazardous. Excessive exposure may cause irritation to upper respiratory tract
(nose and throat) and lungs. Symptoms of excessive exposure may be anesthetic or narcotic
effects; dizziness and drowsiness may be observed.
As product: The LC50 has not been determined.
2-PROPENOIC ACID, 2-METHYL-, 2-[(1,1-DIMETHYLETHYL)AMINO]ETHYL ESTER, POLYMER
WITH ETHYL 2-PROPENOATE & METHYL 2-METHYL-2-PROPENOATE
Acute oral toxicity
Single dose oral LD50 has not been determined.
The dermal LD50 has not been determined.
Page 10 of 24
Barium sulfate
Acute oral toxicity
LD50, Rat, male, > 5,000 mg/kg
No adverse effects are anticipated from single exposure to dust. For respiratory irritation and
narcotic effects: No relevant data found.
Ethyl acetate
Acute oral toxicity
LD50, Rabbit, 4,934 mg/kg
LC50, Rat, 4 Hour, vapour, > 28.6 mg/l
Acute oral toxicity
LD50, Rat, > 5,000 mg/kg
LC50, Rat, 6 Hour, > 10.8 mg/l No deaths occurred at this concentration.
Talc
Acute oral toxicity
Single dose oral LD50 has not been determined.
Zinc Oxide
Acute oral toxicity
LD50, Rat, > 5,000 mg/kg
Page 11 of 24
LC50, Rat, 4 Hour, dust/mist, > 5 mg/l No deaths occurred at this concentration.
Acute oral toxicity
LD50, Rat, > 2,000 - 20,400 mg/kg
LC50, Rat, 4 Hour, > 6.7 mg/l
isopropanol
Acute oral toxicity
May cause central nervous system depression. May cause nausea and vomiting. Signs and
symptoms of excessive exposure may include: Facial flushing. Low blood pressure. Irregular
heartbeats.
LD50, Rat, 5,840 mg/kg OECD 401 or equivalent
Lethal Dose, Humans, 100 ml Estimated.
Observations in animals include middle ear lining damage upon exposure to vapors of
isopropanol. However, the relevance of this to humans is unknown Excessive exposure (400
ppm) to isopropanol may cause eye, nose and throat irritation. Incoordination, confusion,
hypotension, hypothermia, circulatory collapse, respiratory arrest and death may follow a
longer duration or higher levels.
LC50, Rat, male and female, 6 Hour, vapour, > 10000 ppm
PHOSPHORIC ACID, ZINC SALT (2:3) (8CI, 9CI) (CAINDEX NAME)
Acute oral toxicity
LD50, Rat, > 5,000 mg/kg
LC50, Rat, 4 Hour, dust/mist, 5.4 mg/l
Toluene
Acute oral toxicity
LD50, Rat, 5,580 mg/kg
LC50, Rat, male and female, 4 Hour, vapour, > 20 mg/l
Page 12 of 24
Titanium dioxide
Acute oral toxicity
LD50, Rat, > 10,000 mg/kg
LC50, Rat, male, 4 Hour, Dust, > 6.82 mg/l No deaths occurred at this concentration.
12. ECOLOGICAL INFORMATION
Ecotoxicological information on this product or its components appear in this section when such data
is available.
Toxicity
Acetone
Acute toxicity to fish
Material is practically non-toxic to aquatic organisms on an acute basis
(LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).
LC50, Oncorhynchus mykiss (rainbow trout), 96 Hour, 5,500 - 6,100 mg/l
Acute toxicity to aquatic invertebrates
EC50, Daphnia magna (Water flea), 48 Hour, 6,084 mg/l, Method Not Specified.
LC50, Ceriodaphnia dubia (water flea), 48 Hour, 8,098 mg/l
Acute toxicity to algae/aquatic plants
EC50, Skeletonema costatum, 5 d, Biomass, 11,800 - 14,400 mg/l
Toxicity to bacteria
IC50, activated sludge, 3 Hour, > 1,000 mg/l, OECD 209 Test
Toxicity to Above Ground Organisms
Material is practically non-toxic to birds on a dietary basis (LC50 > 5000 ppm).
dietary LC50, Coturnix japonica (Japanese quail), > 20,000 ppm
n-Butyl acetate
Material is slightly toxic to aquatic organisms on an acute basis (LC50/EC50 between 10 and
100 mg/L in the most sensitive species tested).
LC50, Pimephales promelas (fathead minnow), flow-through test, 96 Hour, 18 mg/l
LC50, Daphnia magna (Water flea), 48 Hour, 44 mg/l, Method Not Specified.
ErC50, Desmodesmus subspicatus (green algae), 72 Hour, Growth rate inhibition, 648 mg/l
EC50, Bacteria, 16 Hour, > 1,000 mg/l
Page 13 of 24
Chronic toxicity to aquatic invertebrates
NOEC, Daphnia magna (Water flea), 21 d, 23 mg/l
Barium sulfate
Based on information for a similar material:
Ethyl acetate
LC50, Pimephales promelas (fathead minnow), 96 Hour, 230 mg/l
EC50, Daphnia magna (Water flea), 24 Hour, 3,090 mg/l, DIN 38412
NOEC, Pseudokirchneriella subcapitata (green algae), 72 Hour, > 100 mg/l, OECD Test
Guideline 201
EbC50, alga Scenedesmus sp., static test, 48 Hour, Biomass, 3,300 mg/l
Chronic toxicity to fish
NOEC, Pimephales promelas (fathead minnow), 32 d, < 9.65 mg/l
NOEC, Daphnia magna (Water flea), semi-static test, 21 d, number of offspring, 2.4 mg/l
LC50, Oncorhynchus mykiss (rainbow trout), 96 Hour, 134 mg/l, Method Not Specified.
EC50, Daphnia magna (Water flea), 48 Hour, 408 mg/l, Method Not Specified.
ErC50, Pseudokirchneriella subcapitata (microalgae), static test, 96 Hour, > 1,000 mg/l, OECD
Test Guideline 201 or Equivalent
Talc
Material is practically non-toxic to fish on an acute basis (LC50 > 100 mg/L).
LC50, Danio rerio (zebra fish), 24 Hour, > 100,000 mg/l, Method Not Specified.
Zinc Oxide
Page 14 of 24
Material is very highly toxic to aquatic organisms on an acute basis (LC50/EC50 <0.1 mg/L in
the most sensitive species).
LC50, Oncorhynchus mykiss (rainbow trout), static test, 96 Hour, 0.14 - 1.1 mg/l, Method Not
Specified.
EC50, Daphnia magna (Water flea), static test, 48 Hour, 0.07 mg/l, Method Not Specified.
Material is highly toxic to aquatic organisms on an acute basis (LC50/EC50 bet ween 0.1 and 1
mg/L in the most sensitive species tested).
LC50, Fish., 96 Hour, 0.51 mg/l
LC50, Pimephales promelas (fathead minnow), flow-through test, 96 Hour, 2.32 mg/l, Method
Not Specified.
LC50, Pimephales promelas (fathead minnow), 96 Hour, 2.1 - 5.3 mg/l, OECD Test Guideline
203 or Equivalent
LC50, Lepomis macrochirus (Bluegill sunfish), 96 Hour, 1.7 mg/l, OECD Test Guideline 203 or
Equivalent
LC50, Oncorhynchus mykiss (rainbow trout), 96 Hour, 3.3 mg/l, OECD Test Guideline 203 or
Equivalent
LC50, Cyprinodon variegatus (sheepshead minnow), 96 Hour, 3.0 mg/l, Method Not Specified.
EC50, Daphnia magna, 48 Hour, 0.97 mg/l, OECD Test Guideline 202 or Equivalent
LC50, Daphnia magna (Water flea), 48 Hour, 1.8 mg/l, OECD Test Guideline 202 or
Equivalent
EC50, Daphnia magna (Water flea), 48 Hour, 3.7 mg/l, OECD Test Guideline 202 or
Equivalent
ErC50, diatom Navicula sp., 72 Hour, 0.66 mg/l, OECD Test Guideline 201 or Equivalent
NOEC, diatom Navicula sp., 72 Hour, 0.17 mg/l, OECD Test Guideline 201 or Equivalent
NOEC, Pimephales promelas (fathead minnow), 30 d, 0.14 - 0.36 mg/l
NOEC, saltwater mysid Mysidopsis bahia, 28 d, 0.075 mg/l
NOEC, Daphnia magna (Water flea), 21 d, number of offspring, 0.52 mg/l
isopropanol
LC50, Pimephales promelas (fathead minnow), flow-through test, 96 Hour, 9,640 mg/l, OECD
Test Guideline 203 or Equivalent
LC50, Daphnia magna (Water flea), static test, 24 Hour, > 1,000 mg/l, OECD Test Guideline
202 or Equivalent
Page 15 of 24
NOEC, alga Scenedesmus sp., static test, 7 d, Growth inhibition (cell density reduction), 1,800
mg/l
ErC50, alga Scenedesmus sp., static test, 72 Hour, Growth rate inhibition, > 1,000 mg/l
EC50, activated sludge, > 1,000 mg/l
NOEC, Daphnia magna (Water flea), semi-static test, 21 d, 30 mg/l
Material is very highly toxic to aquatic organisms on an acute basis (LC50/EC50 <0.1 mg/L in
the most sensitive species).
LC50, Rainbow trout (Oncorhynchus mykiss), 96 Hour, 0.09 mg/l, Method Not Specified.
EC50, Daphnia magna (Water flea), static test, 48 Hour, > 1.08 mg/l, OECD Test Guideline
202
Toluene
Material is moderately toxic to aquatic organisms on an acute basis (LC50/EC50 between 1
and 10 mg/L in the most sensitive species tested).
LC50, Oncorhynchus mykiss (rainbow trout), semi-static test, 96 Hour, 5.8 mg/l
LC50, Fish., flow-through test, 96 Hour, 5.5 mg/l
EC50, Daphnia magna (Water flea), static test, 24 Hour, 7 mg/l, OECD Test Guideline 202
LC50, water flea Ceriodaphnia dubia, semi-static test, 48 Hour, 3.78 mg/l
EbC50, Pseudokirchneriella subcapitata (green algae), 72 Hour, Biomass, 12.5 mg/l, OECD
Test Guideline 201
IC50, Bacteria, 16 Hour, 29 mg/l
NOEC, Fish., flow-through test, 40 d, growth, 1.4 mg/l
NOEC, Ceriodaphnia dubia (water flea), 7 d, number of offspring, 0.74 mg/l
NOEC, Daphnia magna (Water flea), 21 d, number of offspring, 2 mg/l
Toxicity to soil-dwelling organisms
LC50, Eisenia fetida (earthworms), 150 - 280 mg/kg
Titanium dioxide
NOEC mortality, Leuciscus idus (Golden orfe), static test, 48 Hour, > 1,000 mg/l
Page 16 of 24
EC50, Daphnia magna (Water flea), static test, 48 Hour, > 1,000 mg/l
Persistence and degradability
Acetone
Biodegradability: Material is readily biodegradable. Passes OECD test(s) for ready
biodegradability.
10-day Window: Pass
Biodegradation: 91 %
Exposure time: 28 d
Method: OECD Test Guideline 301B or Equivalent
Theoretical Oxygen Demand: 2.20 mg/mg Estimated.
Biological oxygen demand (BOD)
Incubation
BOD
Time
5d
69.1 %
10 d
72.7 %
20 d
73.6 %
Photodegradation
Test Type: Half-life (indirect photolysis)
Sensitizer: OH radicals
Atmospheric half-life: 52 d
Method: Estimated.
n-Butyl acetate
biodegradability.
10-day Window: Pass
Exposure time: 28 d
Method: OECD Test Guideline 301D or Equivalent
Photodegradation
Atmospheric half-life: 2.32 d
Method: Estimated.
Biodegradability: No relevant data found.
Barium sulfate
Biodegradability: Biodegradation is not applicable.
Ethyl acetate
Page 17 of 24
biodegradability.
10-day Window: Pass
Exposure time: 28 d
Method: OECD Test Guideline 301D or Equivalent
Theoretical Oxygen Demand: 1.82 mg/mg
biodegradability. Material is ultimately biodegradable (reaches > 70% mineralization in OECD
test(s) for inherent biodegradability).
10-day Window: Pass
Exposure time: 28 d
Method: OECD Test Guideline 301F or Equivalent
10-day Window: Not applicable
Exposure time: 28 d
Method: OECD Test Guideline 302B or Equivalent
Talc
Zinc Oxide
biodegradability. Material is ultimately biodegradable (reaches > 70% mineralization in OECD
test(s) for inherent biodegradability).
Exposure time: 14 d
Method: OECD Test Guideline 301C or Equivalent
Biodegradation: > 99 %
Exposure time: 24 Hour
Method: OECD Test Guideline 302A or Equivalent
Photodegradation
Atmospheric half-life: 11.6 Hour
Method: Estimated.
isopropanol
Page 18 of 24
biodegradability.
10-day Window: Pass
Exposure time: 21 d
Method: OECD Test Guideline 301E or Equivalent
10-day Window: Pass
Exposure time: 5 d
Method: Other guidelines
Chemical Oxygen Demand: 2.09 mg/mg Estimated.
Biological oxygen demand (BOD)
Incubation
BOD
Time
5d
20 - 72 %
20 d
78 - 86 %
Photodegradation
Atmospheric half-life: 1.472 d
Method: Estimated.
Toluene
biodegradability.
Exposure time: 14 d
Method: OECD Test Guideline 301C or Equivalent
Theoretical Oxygen Demand: 3.13 mg/mg Calculated.
Photodegradation
Atmospheric half-life: 2 d
Method: Estimated.
Titanium dioxide
Bioaccumulative potential
Bioaccumulation: No test data available
Page 19 of 24
Mobility in soil
Acetone
Potential for mobility in soil is very high (Koc between 0 and 50).
Partition coefficient(Koc): 0.37 - 2.0 Estimated.
n-Butyl acetate
Partition coefficient(Koc): 19 - 70 Estimated.
Barium sulfate
Ethyl acetate
Partition coefficient(Koc): 3 Estimated.
Partition coefficient(Koc): 1.7 Estimated.
Talc
No data available.
Zinc Oxide
No data available.
Potential for mobility in soil is high (Koc between 50 and 150).
isopropanol
Partition coefficient(Koc): 1.1 Estimated.
Toluene
Titanium dioxide
No data available.
Page 20 of 24
13. DISPOSAL CONSIDERATIONS
Disposal methods: DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY
OF WATER. All disposal practices must be in compliance with all Federal, State/Provincial and local
laws and regulations. Regulations may vary in different locations. Waste characterizations and
compliance with applicable laws are the responsibility solely of the waste generator. AS YOUR
SUPPLIER, WE HAVE NO CONTROL OVER THE MANAGEMENT PRACTICES OR
MANUFACTURING PROCESSES OF PARTIES HANDLING OR USING THIS MATERIAL. THE
INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED IN ITS
INTENDED CONDITION AS DESCRIBED IN MSDS SECTION: Composition Information. FOR
UNUSED & UNCONTAMINATED PRODUCT, the preferred options include sending to a licensed,
permitted: Incinerator or other thermal destruction device.
Treatment and disposal methods of used packaging: Empty containers should be recycled or
otherwise disposed of by an approved waste management facility. Waste characterizations and
compliance with applicable laws are the responsibility solely of the waste generator. Do not re-use
containers for any purpose.
14. TRANSPORT INFORMATION
DOT
Proper shipping name
UN number
Class
Packing group
Reportable Quantity
Coating solution
UN 1139
3
II
Benzyl butyl phthalate, Toluene
Classification for SEA transport (IMO-IMDG):
COATING SOLUTION
UN number
UN 1139
Class
3
Packing group
II
Marine pollutant
Zinc Oxide
Transport in bulk
Consult IMO regulations before transporting ocean bulk
according to Annex I or II
of MARPOL 73/78 and the
IBC or IGC Code
Classification for AIR transport (IATA/ICAO):
Coating solution
UN number
UN 1139
Class
3
Packing group
II
This information is not intended to convey all specific regulatory or operational
requirements/information relating to this product. Transportation classifications may vary by container
volume and may be influenced by regional or country variations in regulations. Additional
transportation system information can be obtained through an authorized sales or customer service
Page 21 of 24
representative. It is the responsibility of the transporting organization to follow all applicable laws,
regulations and rules relating to the transportation of the material.
15. REGULATORY INFORMATION
OSHA Hazard Communication Standard
This product is a “Hazardous Chemical” as defined by the OSHA Hazard Communication Standard,
29 CFR 1910.1200.
Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and
Community Right-to-Know Act of 1986) Sections 311 and 312
Fire Hazard
Acute Health Hazard
Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and
Community Right-to-Know Act of 1986) Section 313
Components
CASRN
PHOSPHORIC ACID, ZINC SALT (2:3) (8CI, 9CI) (CAINDEX NAME) 7779-90-0
isopropanol
67-63-0
Toluene
108-88-3
Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA)
Section 103
Components
CASRN
RQ
85-68-7
100 lbs RQ
Toluene
108-88-3
1000 lbs RQ
Acetone
67-64-1
5000 lbs RQ
n-Butyl acetate
123-86-4
5000 lbs RQ
Ethyl acetate
141-78-6
5000 lbs RQ
California Proposition 65 (Safe Drinking Water and Toxic Enforcement Act of 1986)
WARNING: This product contains a chemical(s) known to the State of California to cause birth defects
or other reproductive harm.
Pennsylvania Worker and Community Right-To-Know Act:
The following product components are cited in the Pennsylvania Hazardous Substance List and/or the
Pennsylvania Environmental Substance List, and are present at levels which require reporting.
Components
CASRN
Acetone
67-64-1
n-Butyl acetate
123-86-4
Barium sulfate
7727-43-7
Ethyl acetate
141-78-6
Talc
14807-96-6
Zinc Oxide
1314-13-2
85-68-7
isopropanol
67-63-0
Toluene
108-88-3
Page 22 of 24
Titanium dioxide
13463-67-7
United States TSCA Inventory (TSCA)
All components of this product are in compliance with the inventory listing requirements of the U.S.
Toxic Substances Control Act (TSCA) Chemical Substance Inventory.
:
16. OTHER INFORMATION
Hazard Rating System
NFPA
Health
2
Fire
3
Reactivity
0
Revision
Identification Number: 101215298 / A001 / Issue Date: 04/09/2015 / Version: 5.0
Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this
document.
Legend
ACGIH
BEI
CEIL
Dow IHG
OSHA P0
OSHA Z-1
OSHA Z-2
Peak
STEL
TWA
US WEEL
USA. ACGIH Threshold Limit Values (TLV)
Biological Exposure Indices
Acceptable ceiling concentration
Dow Industrial Hygiene Guideline
USA. OSHA - TABLE Z-1 Limits for Air Contaminants - 1910.1000
USA. Occupational Exposure Limits (OSHA) - Table Z-1 Limits for Air
Contaminants
USA. Occupational Exposure Limits (OSHA) - Table Z-2
Acceptable maximum peak above the acceptable ceiling concentration for an 8-hr
shift
Short-term exposure limit
8-hour, time-weighted average
USA. Workplace Environmental Exposure Levels (WEEL)
Information Source and References
This SDS is prepared by Product Regulatory Services and Hazard Communications Groups from
information supplied by internal references within our company.
THE DOW CHEMICAL COMPANY urges each customer or recipient of this (M)SDS to study it
carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and
understand the data contained in this (M)SDS and any hazards associated with the product. The
information herein is provided in good faith and believed to be accurate as of the effective date shown
above. However, no warranty, express or implied, is given. Regulatory requirements are subject to
change and may differ between various locations. It is the buyer’s/user’s responsibility to ensure that
his activities comply with all federal, state, provincial or local laws. The information presented here
pertains only to the product as shipped. Since conditions for use of the product are not under the
control of the manufacturer, it is the buyer’s/user’s duty to determine the conditions necessary for the
Page 23 of 24
safe use of this product. Due to the proliferation of sources for information such as manufacturerspecific (M)SDSs, we are not and cannot be responsible for (M)SDSs obtained from any source other
than ourselves. If you have obtained an (M)SDS from another source or if you are not sure that the
(M)SDS you have is current, please contact us for the most current version.
Page 24 of 24

safety data sheet - PH Vitres d`Autos

Transcription

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