00000290 SAFETY DATA SHEET Page 1 PRODUCT

00000290
SAFETY DATA SHEET
Page 1
Pro Form Products Ltd.
604 McGeachie Drive
Milton, Ontario, L9T 3Y5
Canada
905-878-4990
PRODUCT: PF175-1 FIBERGLASS POLYESTER RESIN 3.78LTRS
Section 01: Chemical product and company identification
Product name................................................ PF175-1 FIBERGLASS POLYESTER RESIN 3.78LTRS
Manufactured for........................................... Pro Form Products Ltd.
604 McGeachie Drive
Milton, Ontario L9T3Y5
Tel (905) 878-4990 Fax (905) 878-1189
24 hour emergency number:......................... IN CANADA CALL CANUTEC (613) 996-6666-IN THE UNITED STATES CALL
CHEMTREC (800) 424-9300.
Material use................................................... Automotive. This product should not be used for any other purpose other than the ones
described in this section.
Chemical family............................................. Mixture.
Preparation date............................................ April 2, 2015.
Hazard rate
NFPA rating................................................... Health: 2 Fire: 3 Reactivity: 0.
HMIS............................................................. H: 2 F: 3 R: 0.
Section 02: Hazards identification
Signal Word................................................... DANGER.
Hazard Classification..................................... Flammable Liquid 3. Aspiration Toxicity 1. Skin Irritant 2. Eye Irritant 2. STOT SE 3. STOT
RE 1.
Hazard Description........................................ H226 Flammable liquid and vapour. H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause
respiratory irritation. H372 Causes damage to the liver and kidneys through prolonged or
repeated exposure.
Precautionary Statements............................. P210 Keep away from heat, sparks, open flames and hot surfaces. No smoking. P233
Keep container tightly closed. P240 Ground and bond container and receiving equipment.
P241 Use explosion proof equipment. P242 Use only non-sparking tools. P243 Take
precautionary measures against static discharge. P260 Do not breathe mist, vapours, or
spray. P264 Wash hands thoroughly after handling. P270 Do not eat drink or smoke while
using this product. P271 Use only outdoors or in a well ventilated area. P280 Wear
protective gloves and eye protection.
Response ..................................................... P301 + P310 If swallowed IMMEDIATELY CALL A POISON CONTROL CENTRE and
follow instructions provided by the centre. P302 + P352 - If on skin: wash with plenty of
water. . P303 + P361 + P353 If on skin or in hair: take off all contaminated clothing
immediately. Rinse thoroughly with water and use safety shower . P304 + P340 - If inhaled
remove person to fresh air and keep comfortable for breathing. P305 + P351 + P338 If in
eyes rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing until medical help arrives. P312 Call a POISON
CENTER/doctor if you feel unwell. P314 - Get medical advice/attention if you feel unwell.
P321 - Consult with a doctor or poison control centre if skin is itchy or a skin rash develops
or you feel unwell. P331 Do NOT induce vomiting. P332 + P313 - If skin irritation occurs
get medical attention or advice. P337 + P313 - If eye irritation persists get medical
attention. P362 + P364 - Take off contaminated clothing and wash before reuse. P370 +
P378 In case of fire - use dry chemical powder, CO2 or 6% foam.
Storage.......................................................... P403 + P235 Store in well ventilated area. Keep cool. P403 + P233 Store in a well
ventilated area. Keep container tightly closed. P405 Store locked up.
Disposal......................................................... P501 Dispose all unused, waste or empty containers in accordance with local regulations.
Section 03: COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous Ingredients
CAS #
Wt. %
STYRENE
100-42-5
30-60
00000290
SAFETY DATA SHEET
Page 2
PRODUCT: PF175-1 FIBERGLASS POLYESTER RESIN 3.78LTRS
Section 04: First aid measures
Eye contact.................................................... In case of contact, immediately flush eyes, keeping eyelids open, with plenty of water for at
least 15 minutes. Obtain medical attention.
Skin contact................................................... Remove all contaminated clothing and immediately wash the exposed areas with copious
amounts of water for a minimum of 30 minutes or up to 60 minutes for critical body areas. If
irritation persists, seek medical attention.
Inhalation....................................................... If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen, obtain medical attention.
Ingestion........................................................ If ingestion is suspected, contact physician or poison control center immediately. If
spontaneous vomiting occurs have victim lean forward with head down to prevent
aspiration of fluid into the lungs. Never give anything by mouth to an unconscious person.
Additional information.................................... Treat victims symptomatically. In the event of an incident involving this product ensure that
medical authorities are provided a copy of this safety data sheet.
Section 05: Fire fighting measures
Extinguishing media...................................... "Alcohol" foam, CO2, dry chemical.
Hazardous combustion products................... Oxides of carbon (CO, CO2).
Special fire fighting procedures..................... Firefighter should be equipped with self-contained breathing apparatus and full protective
clothing to protect against potentially toxic and irritating fumes. Solvent vapours may be
heavier than air and may build up and travel along the ground to an ignition source, which
may result in a flash back to the source of the vapours. Cool fire-exposed containers with
cold water spray. Heat will cause pressure buildup and may cause explosive rupture.
Section 06: Accidental release measures
Leak/spill.......................................................
Ventilate. Eliminate all sources of ignition. Contain the spill. Avoid all personal contact.
Spilled material and water rinses are classified as chemical waste, and must be disposed
of in accordance with current local, provincial, state, and federal regulations. Evacuate all
non-essential personnel. Prevent runoff into drains, sewers, and other waterways. Absorb
with earth, sand, or another dry inert material. Shovel into suitable unsealed containers,
transport to well-ventilated area (outside) and treat with neutralizing solution: mixture of
water (80%) with non-ionic surfactant Tergitol TMN-10 (20%); or water (90%), concentrated
ammonia (3-8%) and detergent (2%).
Section 07: Handling and storage
Handling procedures.....................................
Avoid all skin contact and ventilate adequately, otherwise wear an appropriate breathing
apparatus. Always adopt precautionary measures against build-up of static which may
arise from appliances, handling and the containers in which product is packed. Avoid
breathing vapours or mist. Ground handling equipment. Handle and open container with
care. Employees should wash hands and face before eating or drinking. Keep away from
heat, sparks, and open flame.
Storage needs............................................... Keep away from heat, sparks, and open flames. Keep container closed when not in use.
Store away from oxidizing and reducing materials. Store away from sunlight.
Section 08: Exposure controls / personal protection
Ingredients
TWA
STYRENE
20 ppm
ACGIH TLV
STEL
No data
Protective equipment
Eye/type........................................................
Respiratory/type............................................
40 ppm
PEL
100 ppm
OSHA PEL
STEL
Not established
NIOSH
REL
100 ppm
Liquid chemical goggles.
Local exhaust ventilation is recommended. Wear an appropriate, properly fitted respirator
when contaminant levels exceed the recommended exposure limits.
Gloves/ type.................................................. Chemical resistant gloves.
Clothing/type................................................. Wear adequate protective clothes.
Footwear/type................................................ Safety boots per local regulations.
Other/type...................................................... Emergency showers and eye wash stations should be available.
Ventilation requirements................................ Provide natural or mechanical ventilation to control exposure levels below airborne
exposure limits. Local mechanical exhaust ventilation should be used at sources of air
contamination, such as open process equipment, or during purging operations, to capture
gases and fumes that may be emitted. Standard reference sources regarding industrial
ventilation (ie. ACGIH industrial ventilation) should be consulted for guidance about
adequate ventilation. .
Exposure limits
00000290
SAFETY DATA SHEET
Page 3
PRODUCT: PF175-1 FIBERGLASS POLYESTER RESIN 3.78LTRS
Section 09: Physical and chemical properties
Physical state................................................
Colour............................................................
Odour............................................................
Odour threshold (ppm)..................................
Vapour pressure (mm Hg).............................
Vapour density (air=1)...................................
pH..................................................................
Specific gravity..............................................
Freezing point (deg C)...................................
Solubility........................................................
Boiling point (deg C)......................................
Evaporation rate............................................
Flash point (deg C), method..........................
Auto ignition temperature (deg C).................
Upper flammable limit (% vol).......................
Lower flammable limit (% vol).......................
Coefficient of water\oil distribution.................
VOC...............................................................
Viscosity........................................................
Paste.
Clear, colourless to amber.
Hydrocarbon odour.
0.15-25 ppm (Styrene).
No data.
>1.
Not applicable.
9.45 lb/usg - 1.13 g/mL.
-30°C.
Slightly soluble in water.
145°C.
Moderate.
32°C Closed Cup.
490°C.
8.9.
1.1.
No data.
0.79 lb/usg - 94.66 g/L.
2520 cps Spindle #4.
Section 10: Stability and reactivity
Stability.......................................................... Stable at normal temperatures and pressures.
Reactivity conditions...................................... Avoid heat, sparks and flames. Explosive reactions can occur in the presence of strong
oxidizing agents.
Incompatibility................................................ Keep away from heat. Incompatible with strong oxidizers.
Hazardous products of decomposition.......... Oxides of carbon (CO,CO2).
Hazardous polymerization............................. Will not occur under normal temperature and pressure.
Section 11: Toxicological information
Ingredients
LC50
LD50
STYRENE
2770 ppm 4 hr rat
5000 mg/kg rat oral
Effects of acute exposure.............................. The aromatic hydrocarbon solvents in this product can be irritating to the eyes, nose and
throat. In high concentration, they may cause central nervous system depression and
narcosis characterized by nausea, lightheadedness and dizziness from overexposure by
inhalation.
Effects of chronic exposure........................... Breathing high concentrations of vapour may cause anesthetic effects and serious health
effects. Prolonged or repeated exposure may result in skin sensitization. Intentional misuse
by deliberately concentrating and inhaling this product may be harmful or fatal .
Route of entry ............................................... Eye contact. Skin contact. Inhalation.
Skin contact................................................... Can cause moderate irritation, defatting and dermatitis. May cause sensitization by skin
contact.
Skin absorption.............................................. Chronic skin exposure to solvents may cause effects similar to those identified under
chronic inhalation.
Eye contact.................................................... Can cause redness, irritation, tissue destruction.
Inhalation (acute)........................................... Solvent vapours may be irritating to the eyes, nose and throat, resulting in redness, burning
and itching of eyes, dryness of the throat and tightness in the chest. Breathing of high
vapour concentrations may cause anesthetic effects and serious health effects.
Inhalation (chronic)........................................ Chronic exposure to organic solvent vapors have been associated with various neurotoxic
effects including permanent brain and/or nervous system damage, kidney, liver, blood
damage and reproductive effects among women. Symptoms may include nausea,
vomiting, abdominal pain, headache, impaired memory, loss of coordination, insomnia and
breathing difficulties. Excessive inhalation of vapours can cause respiratory irritation,
dizziness, headache, nausea and asphyxiation.
Ingestion........................................................ Aspiration of material into lungs can cause chemical pneumonitis which can be fatal. May
be harmful or fatal if swallowed.
Carcinogenicity of material............................ None known.
Reproductive effects...................................... None known.
Toxicological Data
Section 12: Ecological information
Environmental............................................... Do not allow to enter waters, waste water or soil.
Biodegradability............................................. No data.
00000290
SAFETY DATA SHEET
Page 4
PRODUCT: PF175-1 FIBERGLASS POLYESTER RESIN 3.78LTRS
Section 13: Disposal considerations
Waste disposal.............................................. This material and its container must be disposed of as hazardous waste. Avoid release to
the environment. Dispose of waste in accordance with all applicable Federal,
Provincial/State and local regulations.
Section 14: Transport information
TDG Classification......................................... UN3269 - Polyester Resin Kit - Class 3 - Packing Group III - This product meets the
criterial for Limited Quantity Exemptions when packaged in containers less than 5 litres .
DOT Classification (Road)............................. UN3269 - Polyester Resin Kit - Class 3 - Packing Group III - Ltd Qty (5 Liters/1.3 Gallons).
IATA Classification (Air)................................ UN3269 - Polyester Resin Kit - Class 3 - Packing Group III.
IMDG Classification (Marine)........................ UN3269 - Polyester Resin Kit - Class 3 - Packing Group III - EmS: F-E S-D.
Marine Pollutant............................................ Potential marine pollutant.
Proof of Classification.................................... In accordance with Part 2.2.1 of the Transportation of Dangerous Goods Regulations (July
2, 2014) - we certify that classification of this product is correct. .
Section 15: Regulatory information
CEPA status..................................................
OSHA............................................................
SARA Title III
Section 302 - extremely hazardous ..............
substances
Section 311/312 - hazard categories.............
Section 313...................................................
EPA hazardous air pollutants (HAPS) ..........
40CFR63
TSCA inventory status...................................
California Proposition 65...............................
On Domestic Substances List (DSL).
This product is considered hazardous under the OSHA Hazard Communication Standard.
None.
Immediate health, delayed health, fire hazard.
Styrene.
Styrene. Methanol.
All components are listed.
This product does not contain any chemical(s) known to the State of California to cause
cancer or reproductive toxicity.
Section 16: Other information
Prepared by: ................................................. REGULATORY AFFAIRS.
Telephone number:....................................... (800) 387-7981.
Disclaimer:..................................................... DISCLAIMER: All information appearing herein is based upon data obtained from
experience and recognized technical sources. To the best of our knowledge, it is believed
to be correct as of the date of issue but we make no representations as to its accuracy or
sufficiency and do not suggest or guarantee that any hazards listed herein are the only
ones which exist. The hazard information contained herein is offered solely for the
consideration of the user, subject to his own investigation and verification of compliance
with applicable regulations, including the safe use of the product under every foreseeable
condition. The information relates only to the product designated herein, and does not
relate to its use in combination with any other material or in any other process.
Preparation date: .......................................... Apr02/15
00000292
MATERIAL SAFETY DATA SHEET
Page 1
Pro Form Products Ltd.
604 McGeachie Drive
Milton; Ontario; L9T 3Y5
Canada
PRODUCT: LIQUID HARDENER
Section 01: Chemical product and company identification
Product name................................................ LIQUID HARDENER
Manufactured for........................................... Pro Form Products Ltd.
604 McGeachie Drive
Milton, Ontario L9T3Y5
Tel (905) 878-4990 Fax (905) 878-1189
24 hour emergency number:......................... In Canada call Canutec (613) 996-6666 - In the United States call Chemtrec (800)
424-9300.
Material use................................................... Accelerator and activator.
Chemical family............................................. Organic peroxide.
Preparation date............................................ January 21, 2014.
Hazard rate
NFPA rating................................................... Health: 3 Fire: 2 Reactivity: 2.
HMIS............................................................. H: 3 F: 2 R: 2.
Section 02: Hazards identification
Signal Word................................................... DANGER.
Hazard Classification..................................... Acute Toxicity 3. Eye Damage 1. Skin Irritant 2. Aspiration Toxicity 1. STOT RE 2. STOT
SE 2. Oxidizing Liquids 2. Flammable Liquid 4.
Hazard Description........................................ H318 Causes serious eye damage. H311 Toxic in contact with skin. H331 Toxic if inhaled.
H301 Toxic if swallowed. H304 May be fatal if swallowed and enters airways. H371 May
cause damage to the liver and kidneys. H373 May cause damage to the liver and kidneys
through prolonged or repeated contact. H227 Combustible liquid.
Precautionary Statements............................. P243 Take precautionary measures against static discharge. P251 Do not pierce or burn
container, even after use. P261 Avoid breathing mists, vapours and sprays. P264 Wash
thoroughly after handling. P270 Do not eat drink or smoke while using this product. P271
Use only outdoors or in a well ventilated area. P273 Avoid release to the environment.
P280 Wear protective gloves and eye protection. P202 Do not handle this product until all
safety instructions have been read and understood. P284 In case of inadequate ventilation
wear respiratory protection. P210 Keep away from heat, sparks, open flames and hot
surfaces. No smoking. P211 Do not spray on an open flame or other ignition sources. P233
Keep container tightly closed. P235 Keep cool. P240 Ground and bond container and
receiving equipment. P241 Use explosion proof equipment. P242 Use only non-sparking
tools.
Note ............................................................. This product is an oxidizer.
Section 03: COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous Ingredients
CAS #
Wt. %
2,2,4-TRIMETHYL-1,3-PENTANEDIOL
DIISOBUTYRATE
6846-50-0
40-70
METHYL ETHYL KETONE PEROXIDE
HYDROGEN PEROXIDE
1338-23-4
7722-84-1
15-40
1-5
Section 04: First aid measures
Eye contact.................................................... In case of contact, immediately flush eyes, keeping eyelids open, with plenty of water for at
least 15 minutes. Obtain medical attention.
Skin contact................................................... Remove all contaminated clothing and immediately wash the exposed areas with copious
amounts of water for a minimum of 30 minutes or up to 60 minutes for critical body areas. If
irritation persists, seek medical attention.
Inhalation....................................................... If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen, obtain medical attention.
Ingestion........................................................ Do not induce vomiting. If ingestion is suspected, contact physician or poison control center
immediately. If spontaneous vomiting occurs have victim lean forward with head down to
prevent aspiration of fluid into the lungs. Never give anything by mouth to an unconscious
person.
00000292
MATERIAL SAFETY DATA SHEET
Page 2
PRODUCT: LIQUID HARDENER
Section 04: First aid measures
Additional information.................................... Treat victims symptomatically. The main hazard from ingestion is aspiration of the liquid
into the lungs. In the event of an incident involving this product ensure that medical
authorities are provided a copy of this safety data sheet.
Section 05: Fire fighting measures
Extinguishing media...................................... "Alcohol" foam, CO2, dry chemical.
Hazardous combustion products................... Oxides of carbon (CO,CO2). Ethane and Methane.
Special fire fighting procedures..................... Firefighter should be equipped with self-contained breathing apparatus and full protective
clothing to protect against potentially toxic and irritating fumes. Fight fire like a fuel oil fire.
Cool fire-exposed containers with cold water spray. Heat will cause pressure buildup and
may cause explosive rupture.
Unusual fire / explosion hazards................... During a fire, irritating and toxic gases and aerosols may be generated by thermal
decomposition and combustion.
Section 06: Accidental release measures
Leak/spill.......................................................
Ventilate. Eliminate all sources of ignition. Isolate area and keep unauthorized people
away. Do not walk through spilled material. Wear recommended protective equipment.
Ventilate. Open windows and doors to allow air circulation. Dike area to prevent spreading.
The use of absorbent socks or spill pillows may be required. Stop leak if safe to do so.
Prevent runoff into drains, sewers, and other waterways. Contain the spill. Absorb with
earth, sand, or another dry inert material. Scrape or shovel into containers. Spilled material
and water rinses are classified as chemical waste, and must be disposed of in accordance
with current local, provincial, state, and federal regulations.
Section 07: Handling and storage
Handling procedures.....................................
Keep away from heat, sparks, and open flame. Avoid all skin contact and ventilate
adequately, otherwise wear an appropriate breathing apparatus. Always adopt
precautionary measures against build-up of static which may arise from appliances,
handling and the containers in which product is packed. Avoid breathing vapours or mist.
Ground handling equipment. Handle and open container with care. Employees should
wash hands and face before eating or drinking.
Storage needs............................................... Keep away from heat, sparks, and open flames. Keep container closed when not in use.
Store in a cool dry place away from organic materials.
Section 08: Exposure controls / personal protection
Protective equipment
Eye/type........................................................
Liquid chemical goggles. Chemical safety goggles and full faceshield if a splash hazard
exists.
Respiratory/type............................................ Local exhaust ventilation is recommended. Wear an appropriate, properly fitted respirator
when contaminant levels exceed the recomended exposure limits.
Gloves/ type.................................................. Chemical resistant gloves.
Clothing/type................................................. Wear adequate protective clothes. Wear long sleeves and trousers to prevent dermal
exposure.
Footwear/type................................................ Safety boots per local regulations.
Other/type...................................................... Emergency shower should be in close proximity. Eye wash facility should be close in
proximity.
Ventilation requirements................................ Local exhaust at points of emission. Use local exhaust or general room ventilation sufficient
to prevent overexposure.
Exposure limits
Ingredients
TWA
ACGIH TLV
STEL
PEL
OSHA PEL
STEL
NIOSH
REL
2,2,4-TRIMETHYL-1,3-PE No data
NTANEDIOL
DIISOBUTYRATE
No data
No data
No data
No data
METHYL ETHYL
No data
KETONE PEROXIDE
HYDROGEN PEROXIDE 1 ppm
No data
No data
No data
No data
No data
1 ppm TWA; 1.4
mg/m3 TWA
No data
1 ppm TWA; 1.4
mg/m3 TWA; 75
ppm IDLH
00000292
MATERIAL SAFETY DATA SHEET
Page 3
PRODUCT: LIQUID HARDENER
Section 09: Physical and chemical properties
Physical state................................................
Colour............................................................
Odour............................................................
Odour threshold (ppm)..................................
Vapour pressure (mm Hg).............................
Vapour density (air=1)...................................
pH..................................................................
Specific gravity..............................................
Freezing point (deg C)...................................
Solubility........................................................
Boiling point (deg C)......................................
Evaporation rate............................................
Flash point (deg C), method..........................
Auto ignition temperature (deg C).................
Upper flammable limit (% vol).......................
Lower flammable limit (% vol).......................
Coefficient of water\oil distribution.................
% Volatile by weight......................................
VOC...............................................................
Viscosity........................................................
Liquid.
Clear, red or orange.
Ketone odour.
No data.
No data.
>1. Heavier than air.
No data.
1.17 @ 25C.
No data.
Insoluble in water.
Decomposes at temperatures above 55C.
Slower than ether.
82 Seta Flash Closed Cup.
398.
No data.
No data.
No data.
Negligible.
None.
No data.
Section 10: Stability and reactivity
Stability.......................................................... Unstable. Hazardous and uncontrollable decomposition may occur above 55C. The
self-accelerating decomposition temperature is 60C.
Reactivity conditions...................................... Avoid open flames, sparks, heat, electrical and static discharge, storage at high
temperatures.
Incompatibility................................................ Strong acids. Strong alkalis. Strong oxidizers.
Hazardous products of decomposition.......... See hazardous combustion products.
Hazardous polymerization............................. Hazardous polymerization will not occur.
Section 11: Toxicological information
Route of entry ............................................... Eye contact. Skin contact. Inhalation. Ingestion.
Effects of acute exposure.............................. Corrosive to eyes. Contact with eyes can cause severe irritation. May cause eye damage.
Contact with skin can cause severe irritation. Inhalation of vapours can cause nasal and
respiratory irritation, dizziness, weakness, fatigue, nausea, headache, possible
unconsciousness, and asphyxiation. If ingested, this product may be absorbed and result in
gastrointestinal irritation, nausea, vomiting, and diarrhea. May cause burns of the mouth,
throat, esophagus, and stomach. Aspiration of material into the lungs can cause chemical
pneumonitis which can be fatal.
Effects of chronic exposure........................... Prolonged or repeated overexposure can cause damage to eyes, skin, and mucous
membranes. May aggravate pre-existing skin and eye disorders. May cause respiratory
damage. Extended exposure to MEKP can cause liver and kidney damage.
Carcinogenicity of material............................ The components of this product are not listed by IARC, NTP or regulated as a carcinogen
by OSHA.
Toxicological Data
Ingredients
LC50-inh, rat
LD50-Oral,rat
2,2,4-TRIMETHYL-1,3-PENTANEDIOL
DIISOBUTYRATE
No data
6,800 mg/kg Rat Oral; 4,400 uL/kg Rabbit
Dermal
METHYL ETHYL KETONE PEROXIDE
HYDROGEN PEROXIDE
200 ppm 4 Hr Rat
No data
484 mg/kg Rat Oral; 500 mg/kg Rabbit Dermal
No data
Section 12: Ecological information
Environmental............................................... Do not allow to enter waters, waste water or soil.
Biodegradability............................................. No data.
Section 13: Disposal considerations
Waste disposal.............................................. Empty containers must be handled with care due to product residue. Dispose of as an
industrial waste in a manner acceptable to good waste management practice and in
accordance with applicable local, provincial/State or federal regulations.
00000292
MATERIAL SAFETY DATA SHEET
Page 4
PRODUCT: LIQUID HARDENER
Section 14: Transport information
TDG Classification (Road)............................. This product meets the Limited Quantity exemption when packaged in containers that are
equal or less than 0.125 litre. When shipping this product in a package greater than 0.125
litre, the classification is "Organic Peroxide, Type D, Liquid (Methyl Ethyl Ketone Peroxide)
- Class 5.2 - UN3105 - PGII".
IATA Classification (Air)................................ Organic Peroxide Type D, Liquid (Methyl Ethyl Ketone Peroxide) - Class 5.2 - UN3105 PGII.
IMDG Classification (Marine)........................ Organic Peroxide Type D, Liquid (Methyl Ethyl Ketone Peroxide) - Class 5.2 - UN3105 PGII.
Marine Pollutant............................................ No.
Section 15: Regulatory information
WHMIS classification.....................................
CEPA status..................................................
Section 313...................................................
OSHA............................................................
SARA Title III
Section 302 - extremely hazardous ..............
substances
Section 311/312 - hazard categories.............
EPA hazardous air pollutants (HAPS) ..........
40CFR63
TSCA inventory status...................................
California Proposition 65...............................
B3. C. D2B. F.
On Domestic Substances List (DSL).
Methyl ethyl ketone.
This product is considered hazardous under the OSHA Hazard Communication Standard.
None.
Immediate health, delayed health.
None.
All components are listed.
This product does not contain any chemical(s) known to the State of California to cause
cancer or reproductive toxicity.
Section 16: Other information
Prepared by: ................................................. Regulatory Affairs.
Telephone number:....................................... (800) 387-7981.
Disclaimer:..................................................... DISCLAIMER: All information appearing herein is based upon data obtained from
experience and recognized technical sources. To the best of our knowledge, it is believed
to be correct as of the date of issue but we make no representations as to its accuracy or
sufficiency and do not suggest or guarantee that any hazards listed herein are the only
ones which exist. The hazard information contained herein is offered solely for the
consideration of the user, subject to his own investigation and verification of compliance
with applicable regulations, including the safe use of the product under every foreseeable
condition. The information relates only to the product designated herein, and does not
relate to its use in combination with any other material or in any other process.
00000286
FICHES DE DONNÉES DE SÉCURITÉ
Page 1
Pro Form Products Ltd.
604 McGeachie Drive
Milton, Ontario, L9T 3Y5
Canada
905-878-4990
PRODUIT: PF 141 DURCISSEUR EN CREME BLEU
SECTION 01: Identification du produit et de la société chimique
Nom du produit.............................................. PF 141 DURCISSEUR EN CREME BLEU
Fabriqué pour................................................ Pro Form Products Ltd.
604 McGeachie Drive
Milton, Ontario L9T3Y5
Tel (905) 878-4990 Fax (905) 878-1189
numéro d'urgence 24 heures :....................... AU CANADA, APPELER CANUTEC (613) 996-6666-IN ÉTATS-UNIS ÉTATS APPELLENT
CHEMTREC (800) 424-9300.
Utilisation des matériaux............................... Accélérateur et activateur. Usage industriel seulement - tenir hors de portée des enfants.
Ce produit ne doit pas être utilisé à d'autres usages que celles décrites dans cette section.
Famille chimique........................................... Mélange.
Date de préparation....................................... 14 juillet 2015.
Taux de risque
Classification de NFPA.................................. Santé: 2 Feu: 0 Réactivité: 0.
IHM................................................................ S: 2 F: 2 R: 0.
SECTION 02: Identification des dangers
Mention d'avertissement................................
Classification de danger................................
Description du danger...................................
Conseils de prudence....................................
DANGER.
2 solides comburants. Peroxyde organique du Type C.
H242 chauffage peut provoquer un incendie. H272 Peut aggraver un incendie ; oxydant.
P210 éloigner de la chaleur, les étincelles, les flammes nues et les surfaces chaudes. Ne
pas fumer. P220 éloigner de vêtements et d'autres matériaux combustibles. P234
conserver uniquement dans l'emballage d'origine. P235 Garder froid. P240 Les récipients
et les équipements de réception doivent être mis à terre. P280 Porter des gants et des
lunettes de protection.
Intervention.................................................... P370 P378 en cas d'incendie - utiliser sec mousse chimique en poudre, CO2 ou 6 %.
Stockage....................................................... P403 Entreposer dans un endroit bien aéré. P410 protéger des rayons du soleil. P411
conserver à des températures ne dépassant ne pas 60° C/140° F. P420 stocker
séparément.
Élimination..................................................... P501 disposer tous le produit non utilisées, déchets ou les contenants vides conformément
aux règlements locaux.
SECTION 03: COMPOSITION/INFORMATION SUR LES INGRÉDIENTS
INGREDIENTS DANGEREUX
# CAS
Wt. %
PEROXYDE DE BENZOYLE
STÉARATE DE ZINC
96-36-0
557-05-1
50-60
5-10
SECTION 04: Mesures de premiers soins
Contact avec les yeux...................................
En cas de contact, rincer immédiatement les yeux à grande eau pendant au moins 15
minutes, tout en gardant les paupières ouvertes. Obtenir des soins médicaux.
Contact avec la peau..................................... Enlever les vêtements contaminés et immédiatement laver les surfaces exposées avec
une grande quantité d'eau pendant au moins 30 minutes ou 60 minutes pour les surfaces
du corps critiques. Si l'irritation persiste, consulter un médecin.
Inhalation....................................................... En cas d'inhalation, enlever à l'air frais. Si la victime ne respire pas, pratiquer la respiration
artificielle. Si la respiration est difficile, donner de l'oxygène, obtenir des soins médicaux.
Ingestion........................................................ Ne pas tenter de faire vomir. Si l'ingestion est suspectée, contacter immédiatement un
médecin ou un centre antipoison. Si des vomissements spontanés surviennent, faire
pencher la victim vers l'avant avec la tête vers le bas afin d'éviter l'aspiration du liquide
dans les poumons. Ne jamais rien donner par la bouche à une personne inconsciente.
Plus d'informations........................................ Traitement symptomatique des victimes. Le principal danger de l'ingestion est l'aspiration
du liquide dans les poumons. Dans le cas d'un incident concernant ce produit, s'assurer
que les autorités médicales reçoivent une copie de cette fiche de données de sécurité.
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PRODUIT: PF 141 DURCISSEUR EN CREME BLEU
SECTION 05: Mesures anti-incendie
Moyens d'extinction....................................... Mousse "Alcool", CO2, poudre chimique.
Produits de combustion dangereux............... Oxydes de carbone (CO, CO2). Acide benzoïque. Hydrocarbures.
Procédures anti-incendie spéciaux............... Les pompiers devraientt être équipé avec un appareil respiratoire autonome et un
vêtement de protection complet pour se protéger contre les vapeurs potentiellement
toxiques et irritantes. Lutte contre le feu comme un feu de mazout.
Fire inhabituel/risques d'explosion................ Risque d'incendie augmente quand le matériel devienne sec. Vapeurs peuvent être plus
lourdes que l'air. Elles peuvent parcourir de longues distances le long du sol avant
d'allumer et de provoquer un retour de flammes à la source de la vapeur.
SECTION 06: Mesures de rejet accidentel
Cas de fuite ou de déversement...................
Ventiler. Éliminer toutes sources d'ignition. Isoler la région contaminée et interdire l'accès à
toute personne non autorisée. Éviter de marcher dans le produit répandu. Contenir le
déversement. Prévenir l'évacuation dans les tuyaux, les égouts et d'autres voies d'eau.
Absorber avec de la terre, du sable ou avec une autre matière inerte sèche. Les produits
de rinçage et de l'eau déversés sont classés comme déchets chimiques et doivent être
éliminés conformément aux règlements locales, des provinces, d'États et fédéraux.
SECTION 07: Manutention et stockage
Procédures de manutention..........................
Tenir à l'écart de la chaleur, des étincelles et des flammes nues. Ne pas respirer les
vapeurs, les brouillards ou les poussières. Éviter tout contact de la peau et ventiler
adéquatement, sinon porter un appareil de protection respiratoire approprié. Faire la
manutention selon de bonnes pratiques en matière d'hygiène et de sûreté industrielle.
Toujours adopter des mesures de précaution contre l'accumulation d'électricité statique qui
peut découler des appareils, de la manipulation et des contenants dans lesquels le produit
est emballé. Mettre à terre l'équipement de manutention. Manipuler et ouvrir le récipient
avec précaution. Les employés devraient se laver les mains et le visage avant de manger
ou de boire.
Conditions d'entreposage.............................. Tenir à l'écart de la chaleur, des étincelles et des flammes nues. Garder le récipient fermé
lorsque le produit n'est pas utilisé. Stocker dans un endroit frais et sec à l'écart de matières
organiques.
SECTION 08: Contrôles d'exposition/personal protection
INGREDIENTS
TWA
PEROXYDE DE
BENZOYLE
5 mg/m3
ACGIH TLV
STEL
Pas établi
PEL
5 mg/m3
OSHA PEL
STEL
Pas établi
STÉARATE DE ZINC
10 mg/m3
Yeux/type......................................................
Respiratoire/type...........................................
NIOSH
REL
5 mg/m3 TWA
Pas établi
10 mg/m3
Pas établi
10 mg/m3 TWA
Lunettes de protection contre les produits chimiques liquides.
La ventilation locale est recommandée. Porter un respirateur approprié, bien ajusté lorsque
les niveaux de contaminants dépassent les limites d'exposition recommandées.
Gants/type..................................................... Gants résistants aux produits chimiques.
Vêtements/type............................................. Porter des vêtements protecteurs adéquats.
Chaussures/type........................................... Bottes de sécurité selon les réglementations locaux.
Autres/type.................................................... Les douches d'urgence et les stations de lavage oculaire devraient être disponibles.
Exigences de ventilation................................ Ventilation locale aux points d'émission.
SECTION 09: Propriétés physiques et chimiques
État physique
Couleur..........................................................
Odeur............................................................
Seuil de l'odeur (ppm)...................................
Point d'ébullition (deg C)...............................
Taux d'évaporation........................................
Point d'éclair (OC), méthode
Point de congélation (deg C).........................
Point de fusion (deg c)..................................
pH..................................................................
Température d'auto-inflammation (deg C).....
Limite inférieure d'inflammabilité (% vol.)......
Limite supérieure d'inflammabilité (% vol.)....
Solubilité........................................................
Gravité spécifique..........................................
Densité de vapeur (air = 1)............................
Pression de vapeur (mm Hg)........................
Viscosité........................................................
Bleu.
Odeur légère, benzaldéhyde-like.
Aucune donnée.
100.5°C (212.9°F).
3.1.
Aucune donnée.
145°C (293°F).
5.2 - 6.5.
Aucune donnée.
Aucune donnée.
Aucune donnée.
53 mg/L @ 5°C.
1.2.
Aucune donnée.
0.0002 hPa . Estimée.
Aucune donnée.
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PRODUIT: PF 141 DURCISSEUR EN CREME BLEU
SECTION 09: Propriétés physiques et chimiques
COV...............................................................
% Volatile par poids.......................................
Température de décomposition.....................
Densité..........................................................
0 lb/usg - 0 g/mL.
Environ 20 %.
50°C (122°F) SADT.
9.98 lb/gal.
SECTION 10: Stabilité et réactivité
Stabilité.......................................................... Stable à des températures et à des pressions normales.
Conditions de réactivité................................. Éviter la chaleur, des étincelles et des flammes. Décomposition possible si exposé à des
températures élevées.
Incompatibilité............................................... Éviter tout contact dans des conditions non contrôlées avec:. Produits chimiques
organiques. Acides inorganiques. Oxydants forts. Accélérateurs. Agents réducteurs.
Alcools. Amines. Bases fortes.
Produits de décomposition dangereux.......... Voir les produits de combustion dangereux.
Polymérisation dangereuse........................... La polymérisation dangereuse ne se produira pas.
SECTION 11: Renseignements toxicologiques
INGREDIENTS
LC50
LD50
PEROXYDE DE BENZOYLE
STÉARATE DE ZINC
Aucune données
Aucune données
7710 mg/kg rat orale
Aucune données
Voie d'entrée ................................................ Contact avec les yeux. Contact avec la peau. Ingestion. Inhalation.
Effets d'une exposition aiguë......................... Contact avec la pâte peut entraîner irritation, rougeur, larmoiement et une vision floue.
Peut causer l'irritation de la peau. En cas d'ingestion, ce produit peut être absorbé et
provoquer une irritation gastro-intestinale, nausées, vomissements et diarrhée. L'aspiration
du produit dans les poumons peut causer une pneumonie chimique qui peut être mortelle.
Effets d'une exposition chronique.................. Contact cutané prolongé ou répété peut causer de séchage ou gerçures de la peau.
Cancérogénicité de la matière....................... Ce produit n'est pas répertorié par le NTP, le CIRC ou réglementé comme cancérogène
par l'OSHA.
Effets sur la reproduction.............................. Aucune donnée.
SECTION 12: Informations écologiques
Environnement.............................................. Prévenir l'entrée dans les eaux, les eaux usées ou le sol.
Biodégradabilité............................................. Aucune donnée.
SECTION 13: Considérations relatives
Élimination des déchets................................
Conteneurs vides doivent être manipulés avec soin en raison des résidus de produits.
Éliminer comme un déchet industriel d'une manière acceptable à la pratique de la bonne
gestion des déchets et conformément aux règlements locaux, des provinces/États ou
fédéraux pertinents.
SECTION 14: Informations relatives au transport
TMD............................................................... Le produit est conforme à l'exemption de quantité limitée lorsqu'il est emballé dans des
récipients moins de 0,5 kg. Pour les colis supérieurs à 0,5 kg, le classement est - Peroxide
organique, Type E, solide (peroxyde de benzoyle) - classe 5,2 - UN3108 - GE II.
Classification du DOT (route)........................ Peroxyde organique, Type E, solide (peroxyde de benzoyle) - UN3108 - classe 5.2 - PG II.
Classification de l'IATA (Air).......................... Peroxyde organique, Type E, solide (peroxyde de benzoyle) - classe 5,2 - UN3108 - PG II.
Classification de l'IMDG (maritime)............... Peroxyde organique, Type E, solide (peroxyde de benzoyle) - classe 5,2 - UN3108 - PG II.
Polluant marin............................................... Potentiel polluant marin.
Preuve de la Classification............................ Conformément à la partie 2.2.1 du règlement sur le transport de marchandises
dangereuses (2 juillet 2014) - nous confirme que la classification de ce produit est exacte. .
SECTION 15: Renseignements sur la réglementation
Statut de la LCPE..........................................
OSHA............................................................
SARA Title III
Section 302 - substances extrêmement .......
dangereuses
Section 311/312 - catégories de danger.......
Section 313...................................................
40CFR63 de polluants atmosphériques .......
dangereux EPA
Statut de l'Inventaire TSCA...........................
Ce produit est répertorié sur la Liste intérieure de substances (LIS).
Ce produit est considéré comme dangereux par l'OSHA Hazard Communication Standard.
Aucun.
Risque d'incendie. Réactif.
Peroxyde de benzoyle.
Aucun.
Tous les composants sont répertoriés.
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PRODUIT: PF 141 DURCISSEUR EN CREME BLEU
SECTION 15: Renseignements sur la réglementation
Proposition 65 de la Californie......................
Ce produit ne contient pas de produits chimiques reconnus par l'Etat de Californie pour
causer le cancer ou la toxicité pour la reproduction.
SECTION 16: Autres informations
Préparé par: ................................................. AFFAIRES RÉGLEMENTAIRES.
Numéro de téléphone :.................................. (800) 387-7981.
Avertissement:............................................... AVERTISSEMENT : Toutes les informations figurant dans les présentes sont issues des
données obtenues par l'expérience et des sources techniques reconnues. Au meilleur de
nos connaissances, il est considéré comme correct à partir de la date de délivrance, mais
nous ne faisons aucune représentation quant à leur exactitude ou le caractère suffisant et
ne suggèrent ni garantir que tous les risques énumérés ici sont les seuls qui existent.
Informations sur les dangers qu'il contient sont offert uniquement pour le compte de
l'utilisateur, sous réserve de sa propre enquête et la vérification de la conformité avec les
règlements applicables, y compris l'utilisation sécuritaire du produit dans toutes les
conditions prévisibles. L'information ne concerne que le produit désigné dans les présentes
et ne se rapporte pas à son utilisation en combinaison avec tout autre matériel ou tout
autre procédé.
Date de préparation : .................................... JUI14/15