Material Safety Data Sheet

Material Safety Data Sheet
According to regulation (EC) No. 1907/2006 (REACH)
79550 - Zapon Lacquer
Revised edition: 23.02.2008
Printed: 15.12.2009
1. Identification of the Substance/Preparation and of the Company/Undertaking
Identification of the Product
Product Name:
Article No.:
Use of the Substance/Preparation:
Zapon Lacquer
79550
Artists´ and Restoration Material
Company
Company:
Address:
Tel/Fax:
Internet:
Emergency No.:
Kremer Pigmente GmbH & Co. KG
Hauptstrasse 41-47, D 88317 Aichstetten
Tel +49 7565 914480, Fax +49 7565 1606
www.kremer-pigmente.de, [email protected]
+49 7565 914480, Mon-Fri 8:00 - 17:00
2. Hazard Identification
Hazard designation:
Xn Harmful
F Flammable
Risk Phrases:
R11 Highly flammable.
R66 Repeated exposure may cause skin dryness or cracking.
R21 Harmful in contact with skin.
R22 Harmful if swallowed.
R20 Harmful by inhalation.
3. Composition/Information on Ingredients
Hazardous Ingredients:
Methyl ethyl ketone (MEK) (2-Butanone; Xi, F; R11,36,66,67) < 1%
CAS-Nr: 78-93-3 EINECS-Nr: 201-159-0 EC-Nr: 606-002-00-3
Butylglycol (Xn; R20/21/22, 36/38) < 5 %
CAS-Nr: 111-76-2 EINECS-Nr: 203-905-0 EC-Nr: 603-014-00-0
Ethanol (F; R11) 50%
CAS-Nr: 64-17-5 EINECS-Nr: 200-578-6 EC-Nr:
n-Butylacetate (R10,66,67) 10-15%
CAS-Nr: 123-86-4 EINECS-Nr: 204-658-1 EC-Nr:
n-Butanol (Xi; R10-22-37/38-41-67) 15-20%
CAS-Nr: 71-36-3 EINECS-Nr:
EC-Nr: 603-004-00-6
4. First Aid Measures
After inhalation:
Remove to fresh air, if necessary give artificial respiration. Keep
affected person warm.
Give artificial respiration in case breathing is not regular or if it has
stopped.
In case of unconsciousness, store, respectively transport in stable
side position.
If breathing is difficult call a physician.
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Material Safety Data Sheet
According to regulation (EC) No. 1907/2006 (REACH)
79550 - Zapon Lacquer
Revised edition: 23.02.2008
After skin contact:
After eye contact:
After ingestion:
Printed: 15.12.2009
Remove contaminated clothing. Wash off immediately with plenty
of water and soap.
In case of complaints consult physician.
Rinse open eyes with plenty of water for at least 15 minutes. Consult
physician.
Rinse mouth with water and drink plenty of water.
Do not induce vomiting. Consult physician immediately.
5. Fire-Fighting Measures
Suitable extinguishing media:
Unsuitable extinguishing media:
Protective equipment:
Further information:
CO2, extinguishing powder, water jet.
Fight larger fire with water jet or alcohol resistant foam.
Never apply a strong water jet.
Use self-contained breathing apparatus and full protective gear.
Cool exposed containers with water spray.
6. Accidental Release Measures
Personal precautions:
Environmental precautions:
Methods of cleaning/absorption:
Wear appropriate protective equipment. Keep spectators away.
Provide adequate ventilation. Keep away from sources of ignition.
Avoid contact with skin and eyes. Do not ingest or inhale.
Do not discharge into drains, surface or ground water in
concentrated form.
Contact local authorities if product pollutes soil or vegetation.
Contain with absorbent material (sand, diatomaceous earth, universal
absorbent, Oil Dri) and dispose accordingly.
7. Handling and Storage
Handling
Instructions on safe handling:
Information on fire and explosion
protection:
Storage
Storage conditions:
Storage class (VCI):
Keep containers tightly closed.
Provide adequate ventilation, also in floor area (vapors are heavier
than air).
Keep away from sources of ignition - do not smoke. Take
precautionary measures against static discharges.
Combustible liquids.
Vapors in combination with air can form an explosive compound.
Cool exposed containers with water.
Use only in explosion protective area. Extinguish any naked flames.
No not smoke. Remove ignition sources. Avoid sparks. Ensure
electrical continuity by bonding and grounding (earthing) all
equipment.
Keep containers tightly closed. Protect against heat and direct
sunlight. Store cool and dry. Heat can lead to a pressure increase and
risk of bursting.
Store product in a well ventilated area.
Floor must be solvent resistant and leakproof.
3A
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Material Safety Data Sheet
According to regulation (EC) No. 1907/2006 (REACH)
79550 - Zapon Lacquer
Revised edition: 23.02.2008
Storage safety regulation
(BetrSichV):
Printed: 15.12.2009
Highly flammable.
8. Exposure Controls/Personal Protection
Additional information about
design of technical systems:
Components with workplace
control parameters (Germany):
Value:
Components with workplace
control parameters (EC):
Value:
Personal protective equipment
General protective measures:
Respiratory protection:
Hand protection::
Protective glove material:
Eye protection:
Body protection:
Adequate ventilation to control airborne concentrations below the
exposure limits.
Butanol-n, CAS 71-36-3; TRGS 900: 100 ppm / 310 mg/m3 (Y)
Ethanol (CAS 64-17-5)
AGW: 960 mg/m3, 500 ml/m3; 2(II); DFG, Y
Methylethyl ketone (MEK; CAS 78-93-3)
Butylglykol, CAS 111-76-2, AGW: 98 mg/m3; 20 ppm
Butylacetate, CAS 123-86-4; MAK: 480 mg/m3 (8h); 480 mg/m3
(15 min)
AGW: 600 mg/m3, 200 ml/m3; 1(I); DFG, H,Y
Methylethyl ketone (MEK; 78-93-3)
IOELV (EU): Short term value: 900 mg/m3, 300 ml/m3; Long term
value: 600 mg/m3, 200 ml/m3
Remove contaminated clothing immediately.
Avoid contact with skin and avoid inhalation of vapour. Do not eat,
drink or smoke while working.
Required in case of insufficient ventilation.
Shortterm: gas filter A2.
Solvent resistant protective gloves.
The manufacturer´s directions for use should be observed because of
the great diversity of types.
Butyl rubber (480 min; 0.5 mm).
Fluoro carbon rubber -FKM (480 min; 0.4 mm).
Suitability and durability of a glove is dependent on usage, e.g.
frequency and duration of contact, chemical resistance of glove
material and dexterity. Always seek advice from glove suppliers.
Tightly fitting safety goggles.
Protective clothing, chemical resistant.
9. Physical and Chemical Properties
Form:
Color:
Odor:
Melting temperature:
Boiling temperature:
Flash point:
Ignition temperature:
Explosion risk:
liquid
colorless
alcohol-like
-121°C
78.3°C
12°C (DIN 51755 T1)
425°C
Product is not explosive; however, an explosive vapor/air mixture
can be formed.
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Material Safety Data Sheet
According to regulation (EC) No. 1907/2006 (REACH)
79550 - Zapon Lacquer
Revised edition: 23.02.2008
Lower explosion limit:
Upper explosion limit:
Vapor pressure:
Density:
Solubility in water:
Viscosity dynamic:
Coefficient of variation (nOctanol/Water):
Further information:
Printed: 15.12.2009
3.5 Vol.%
15 Vol.%
59 hPa (20°C)
0.79 g/cm3 (20°C)
miscible
1.2 mPas
-0.31 logPOW
The data is based on those of ethyl alcohol.
10. Stability and Reactivity
Thermal
decomposition/Conditions to be
avoided:
Substances to be avoided:
Hazardous decomposition
products:
No decomposition if used according to specifications.
Can be distilled at normal pressure without undergoing
decomposition.
Oxidizing agents.
Sulfuric acid, nitric acid.
Carbon monoxide and dioxide.
11. Toxicological Information
Irritant effect on eyes:
Sensitization:
Irritating
No sensitizing effect (guinea pig).
Further toxicological effects:
The main component is ethyl alcohol.
Depending on the absorbed concentrations different states of
intoxication is reached after an euphoric stage. Further symptoms are
loss of self-control, dizziness, vomiting.
12. Ecological Information
Elimination (Persistency and
Degradability):
Ecological effects
Aquatic toxicity:
- Fish toxicity:
Further information
Water hazard class:
Ethanol: readily biodegradable (84 %, 20d).
:
LC50: 8150 mg/l (48h, Leuciscus idus)
1
Do not let product contaminate ground water, waterways or sewage
system.
13. Disposal Considerations
Product:
Waste Code No.:
In accordance with current regulations, product may be taken to an
incineration plant.
If possible reuse product.
The waste code is determined according to the code of the European
Waste Catalog.
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Material Safety Data Sheet
According to regulation (EC) No. 1907/2006 (REACH)
79550 - Zapon Lacquer
Revised edition: 23.02.2008
Uncleaned packaging:
Printed: 15.12.2009
Dispose of according to official local regulations.
Dispose according to product.
14. Transport Information
Road Transportation ADR/RID
Class:
Packaging group:
UN No.:
Classification code:
Tunnel No.:
Hazard No.:
Correct technical name:
3
II
1993
F1
D/E
3
FLAMMABLE LIQUID, N.O.S. (Ethanol, 2-Ethoxyethanol)
Sea transportation
IMDG/GGVSee Class:
Packaging group:
UN No.:
EmS No.:
Hazard No.:
Correct technical name:
3
II
1993
F-E,S-E
3
FLAMMABLE LIQUID, N.O.S. (Ethanol, 2-Ethoxyethanol)
Air transportation
ICAO/IATA Class:
Packaging group:
UN No.:
Hazard No.:
Correct technical name:
3
II
1993
3
FLAMMABLE LIQUID, N.O.S. (Ethanol, 2-Ethoxyethanol)
15. Regulatory Information
Designation according to EC
guidelines:
Hazard designation:
The material is subject to classification according to EC lists.
F Flammable
Xn Harmful
Risk Phrases:
Safety Phrases:
R21 Harmful in contact with skin.
R20 Harmful by inhalation.
R22 Harmful if swallowed.
R66 Repeated exposure may cause skin dryness or cracking.
R11 Highly flammable.
S16 Keep away from sources of ignition - No smoking.
S46 If swallowed, seek medical advice immediately and show this
container or label.
S37 Wear suitable gloves.
S33 Take precautionary measures against static discharges.
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Material Safety Data Sheet
According to regulation (EC) No. 1907/2006 (REACH)
79550 - Zapon Lacquer
Revised edition: 23.02.2008
Printed: 15.12.2009
Safety Phrases:
S09 Keep container in a well-ventilated place.
S07 Keep container tightly closed.
S02 Keep out of reach of children.
S36 Wear suitable protective clothing.
Water hazard class:
1, slightly hazardous for water
16. Other Information
This product should be stored, handled and used in accordance with good hygiene practices and in
conformity with any legal regulations.
This information contained herein is based on the present state of knowledge and is intended to describe
our product from the point of view of safety requirements. It should be therefore not be construed as
guaranteeing specific properties.
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