RESEARCH LABORATORIES_oct2011

RESEARCH LABORATORIES
LABORATORY OF SOLID STATE CHEMISTRY AND CATALYSIS
Head: Prof. Lionel Montagne, [email protected]
Team 1 : SOLID STATE CHEMISTRY
Team director :
Phone :
Address :
Prof. Rose-Noëlle VANNIER ([email protected])
+ 33 3 20 43 65 83
École Nationale Supérieure de Chimie de Lille
Avenue Mendeleïev
Bâtiment C7a
BP 108
59652 VILLENEUVE D’ASCQ CEDEX
Research Fields:
Solid State Chemistry
Ionic, electronic and mixed conductors, ferroelectric
Precursors and new routes for oxide synthesis
Solid Oxide Fuel Cell, Electrochemical separation of gas
Glasses
Materials for nuclear applications
Solid State NMR
Scientific equipment:
X-ray diffraction platform (powder diffractometers, Four circle and CCD X-ray single crystal
diffractometers, High temperature X-ray diffraction (up to 1200°C with controlled
atmospheres)
Thermal analysis
Impedance spectroscopy, Ionic transport number measurements
Solid State NMR
Electron microscopy
Key-words :
Ceramics
Fuel cells
Crystal structure determination
Electrical properties
Magnetic properties
Glasses
Solid State NMR
Main fields of applications:
Gas separation
Energy storage and savings
Electrochemical membranes
Refractory materials and glasses
Environment
Team 2 : HETEROGENEOUS CATALYSIS
Team director : Prof. Pascal GRANGER ([email protected] )
Phone :
+ 33 3 20 43 49 49
Addresses : Université des Sciences et Technologies de Lille Bâtiment C3
École Nationale Supérieure de Chimie de Lille Bâtiment C7
Ecole Centrale de Lille
Cité Scientifique
59650 VILLENEUVE D’ASCQ
Research Fields:
• Novel synthesis of ordered mesoporous functionalized catalysts with controlled nanosized metallic and oxidic particles.
• Advanced surface analysis and operando spectroscopic characterization
• Molecular modelling and reaction mechanisms
• Chemical engineering kinetics and reactor modelling, structured reactors, powder
technologies
All those competencies are profitably used in various practical applications dedicated to the
production of clean fuels (hydrotreating and Fischer-Tropsch reactions), biomass and light
alkanes conversion for the production of valuables intermediates and environmental catalysis
(deNOx, deN2O, COV)
Scientific equipment :
Surface analysis: XPS/LEIS/Tof-SIMS coupled to a catalytic cell working under controlled
atmosphere up to 800°C.
Raman and infrared spectrometers for in situ and operando investigations
Thermal analysis (Thermogravimetry, DSC TPR/TPO, adsorption of probe
molecules/therodesorpion)
Catalytic reactor (CSTR, plug flow slurry reactors running under atmospheric at high pressure
with online analytical systems.
Devices for the preparation and analysis of powder catalysts.
Key words :
Hydrocarbon activation, biomass conversion, Fischer-Tropsch, hydrotreating reaction
catalytic depollution, molecular modelling, surface analysis
Main fields of applications:
Petrochemistry, fine chemistry, energy production, atmospheric pollutant abatement
Team 3: Catalysis and Molecular Chemistry
Team director: Dr Francine AGBOSSOU-NIEDERCORN ([email protected] )
Phone:
+ 33 3 20 43 49 27
Address :
École Nationale Supérieure de Chimie de Lille
Avenue Mendeleïev
Bâtiment C7a
BP 90108
59652 VILLENEUVE D’ASCQ CEDEX
Research Fields:
• Synthesis and application of homogeneous organometallic catalysts
• Hydrogenation, carbonylation, hydroformylation, C-C, C-O and C-N bond formation,
oligomerization and polymerization
• Organic synthesis
• Surface organometallic complexes and catalysts
• Supramolecular catalysis
• Polymerization catalysis
These research fields aim at applying homogeneous catalysis to the production of fine
chemicals, clean processes, and polymeric materials.
Scientific equipment :
Catalytic reactors (high pressure autoclaves, multiclaves, polymerisation reactors)
Glove-boxes and synthesis under controlled atmosphere equipments
GC and HPLC chromatographs,
FTIR, elemental analysis
Key words :
Homogeneous catalysis, fine chemistry, organometallic complexes, polymerization, organic
synthesis
Main fields of applications:
Fine chemistry, polymeric materials, pharmaceutical industry
UNITE MATERIAUX ET TRANSFORMATIONS
UMR CNRS 8207
Director : Prof. Alexandre LEGRIS ([email protected])
Phone : +33 320 43 49 67
Fax : +33 320 43 65 91
Université des Sciences et Technologies de Lille
Bâtiment C6 - 59655 Villeneuve d’Ascq
Team 1 : « ENGINEERING POLYMERS »
Director: Prof. Jean-Marc LEFEBVRE ([email protected])
Phone : +33 (0) 320 43 49 67
Fax : +33 (0) 320 43 65 91
Thematics
• Engineering of flame retardancy of materials (Prof. S. Bourbigot)
Engineering and processing of filled polymers and nanocomposites:
– Intumescent systems, ceramization, synergy, synthesis of FRs
– Polymer nanocomposites (organomodified clays, LDH, carbon
nanotubes, POSS, metal oxides…)
– Reactive extrusion
Modeling and simulation of flame retarded materials:
– Development of experimental protocol at the small scale
– Kinetic analysis
– Modeling (burning polymer, heat barrier)
Sustainable materials
– Recycling
– Biopolymer, bionanocomposite
•
Engineering of surface treatment (Prof. M. Traisnel)
– Biomaterials
– Surface modification/Coating by chemical way (sol-gel +
chemisorption of corrosion inhibitors)
– Surface modification /Coating by physical way (cold plasma + flaming)
– Adhesion
Equipment
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•
Processing
– Twin screw extruder
– Single screw extruder
– Mixers (350 cc, 50cc) equipped with ‘N2 chamber’
– Micro extruder equipped for making film and monofilament (Film, Micro melt
spinning machine)
Fire testing
– Limiting oxygen index
– UL-94
– Mass loss calorimeter
– Small furnace
– Heat radiator test
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Thermal analyses
– DSC and MDSC (including k = f(T))
– TGA at high temperature (1550°C)
– Very high heating rate TGA (up to 500°C/min)
– Simultaneous TGA/DSC
– TC probe (thermal effusivity)
Surface treatment
– Cold plasma (radiofrequency and microwave) equipped with different
chambers
– Spraying machine
– Coating machine
– Padding machine
– Contact angle meter
Microscopies
– Optical microscopes
– Electronic microprobe
– SEM with EDX
– TEM
– AFM
Spectroscopy
– Liquid/solid state NMR (100, 300, 400, 800 MHz)
– XRD
– XPS
– ESR
– FTIR
To summarize
Modification and
functionalisation of surfaces
Reaction and resistance to fire
Anti-corrosion
Biocompatibility
Adhesion
Surface treatment
Properties
Field of
expertise
Materials
Characterization
Spectroscopy:
NMR, FTIR, ESR, XPS….
Microscopy: Optical, SEM, TEM, AFM, microprobe
Thermal analyses: TGA, DTA, DSC, DMA…
Fire testing
Modeling and simulation
Processing of polymers
(including reactive extrusion)
Material (bulk and surface)
chemistry
Team 2: PHYSICAL METALLURGY AND MATERIALS ENGINEERING
Team director:
Phone :
Address :
Prof. Alexandre LEGRIS ([email protected])
+ 33 3 20 43 49 75
Université des Sciences et Technologies de Lille
Bâtiment C6
59655 VILLENEUVE D’ASCQ CEDEX
Erasmus contact : Prof. Jean-Bernard VOGT ([email protected])
Research Fields :
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•
Physical mechanisms of phase transformations in metallic alloys, near or far from
thermodynamical equilibrium, with or without presence of external solicitations
(impact, irradiation, mechanical stress).
Reliability of metallic alloys with or without presence of corrosive environment
(fatigue, liquid metal embrittlement, environmentally assisted damage).
Simulation and Modelling of radiation damage
Processing and characterization of ceramics through non stand procedures :
1. composite coating by sol-gel process on metals and ceramics
2. structural and thermo mechanical characterisations of ceramics obtained by
Spark Plasma Sintering (SPS)
Scientific equipment :
X Ray diffractometer
Transmission and reflection Mössbauer Spectrometer
Scanning electron microscope equipped with EDX and EBSD detectors
Atomic Force Microscopes
Optical microscope and image collection system
Dilatometer
Electrochemical equipment
Micro- and macro-indentation
Tensile and fatigue machines equipped with extensometers, furnaces and environmental cells
Experimental set-up for testing metallic alloys in liquid metals (lead, sodium...)
Nitriding facilities and galvanisation unit
High energy mill, cold roller
Heat treatment furnaces
Keys-words :
Mechanical tests and fracture analysis
Microscopies -metallography
Mössbauer spectroscopy
Corrosion
Microstructure-galvanisation
Structural alloys
Main fields of applications :
Metallurgy – Steel making
Nuclear industry
Energy
Transportation industry
Battery
Laboratory of Organic and Macromolecular Chemistry
Director and Erasmus contact : Prof. Jean-Marie AUBRY ([email protected])
Phone : +33 3 20 43 49 64
Fax : +33 3 20 43 43 45
Address :
Equipe d’Accueil Chimie Moléculaire et Formulation
BP 90108
Bâtiment C7, Cité Scientifique
59652 Villeneuve d’Ascq cedex, France
Research Fields :
Pro and anti oxidant molecules
Organic synthesis, reactivity, functionnalization
Water soluble polymers with complexing properties
Photo and radiochemistry on polymers
Studies of photochemical reactions by NMR
Singlet Oxygen
Free radicals
Formulation
Polyphenols
Scientific equipment :
UV, Visible, IR and IRTF spectrophotometers
Spectrofluorimetry
Phosphorimeter
Photoreactive cells
Chromatographic devices
Potentiostat. Galvanostat
Electron beam (175kV)
UV sources
Dynamometers
Goniometry
Specific area measurements
Treatments of textile
EPR
NMR
Key-words :
Alcaloïds – Macromolecules – Antioxidant molecules – Singlet oygen
Pro-oxidant complexes - Photochemistry – Water soluble polymers – Free radicals
Main fields of applications :
Polymeric materials
Pharmaceutical industry
Surfactants
Cosmetics
Paints and varnishes