Dr. Jean-Baptiste Sortais Institut des Sciences Chimiques de

Dr. Jean-Baptiste Sortais
Institut des Sciences Chimiques de Rennes
UMR 6226-CNRS-Université de Rennes1
Campus de Beaulieu
263 Avenue du Général Leclerc
35042 Rennes Cedex, France
[email protected]
Associate Professor, Université Rennes 1
Education
2013
2003-2007
2002-2003
2001-2002
2000-2001
1999-2000
1996-1999
Habilitation, Université de Rennes 1, Rennes, France, Defence December 2nd 2013
PhD diploma, Université Louis Pasteur, Strasbourg, France. Defence January 26th
2007, "Cycloruthenated complexes : from complexes to enantioselective catalysts",
Laboratoire de Synthèses Métallo-induites, advisor: M. Pfeffer
Diplôme d’Etudes Approfondies de Chimie Organique Moléculaire et
Supramoléculaire (M. Sc., Organic Chemistry) Graduate with highest honors,
Université Louis Pasteur, Strasbourg, France
Magistère de Chimie-Physique (M. Sc., Physical Chemistry), Graduate with honors,
Ecole Normale Supérieure (ENS) Lyon, France
Agrégation de Sciences Physiques (high-level competitive examination for recruiting
high-school teachers), Chemistry, ENS Lyon, France
Maîtrise de Chimie-Physique (B.Sc.-M.Sc., Physical Chemistry), Graduate with
honors, ENS Lyon, France
Licence de Chimie-Physique (B. Sc.), Graduate with honors, ENS Lyon, France
Preparatory courses for the national competitive exam for entry to French engineering
schools, Lycée B. Pascal, Clermont-Ferrand, France
Professional Experience (after the PhD)
09 2009-Present
05 2008-08-2009
03 2007- 04 2008
Associate Professor, Chaire CNRS-UR1 (2009-2014), Université de Rennes 1,
UMR 6226, Institut des Sciences Chimiques de Rennes, Team
« Organométalliques : Matériaux et Catalyse »
“Metal-free activation of hydrogene”, postdoctoral associate with Pr. G. Erker,
Organisch-Chemisches Institut, Münster, Germany
“New catalysts for dynamic kinetic resolution for primary alcohols and primary
amines” postdoctoral associate (Lavoisier fellowship) with Pr. J. E. Bäckvall,
Organic Chemistry, Arrhenius Laboratory, Stockholm University, Stockholm,
Sweden
Teaching Experience
2009-Present
2006-2007
2003-2006
2003-2005
Associate Professor, Université de Rennes 1, Rennes
Temporary teaching position at the University Louis Pasteur, Strasbourg (90 hours)
Teaching assistant at the University Louis Pasteur, Strasbourg (about 64 hours per
year)
Trainer at the DEPULP (continuing education department), "Mechanisms in Organic
Chemistry", (30 hours per year), Université Louis Pasteur, Strasbourg
Scientific Production
47 publications, 2 Book Chapters
22 Oral communications (including 6 invited academic seminars)
29 Poster communications
Fellowship and Awards
2009-2014
2007
2003-2006
2003
1999-2003
Chaire CNRS-Université Rennes 1
Lavoisier Post-doctoral Fellowship, French Ministry of Foreign Affairs
PhD Fellowship (Allocataire Moniteur Normalien), French Ministry of Education,
Research and Technology
Laureate of the « Agrégation de Sciences Physiques », option Chimie.
Student of the Ecole Normale Supérieure de Lyon
Supervision and Funding
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Participation to the collaboration with Pr. P. Ghosh, Indian Institute of Technology Bombay,
India, in the framework of the project CEFIPRA with the Ministère des Affaires Etrangères,
« Studies of Iron Complexes of N/O−functionalized N−heterocyclic Carbenes in
Homogeneous Catalysis », PhD fellowship to L. P. Bheeter.
Active participation to the project ANR IRONHYC, with the team of Dr. S. Sabo-Etienne,
LCC, Toulouse. 2012-2015.
Active participation to the project Create Bioricat, Britanny Council, financial support of a
two years postdoctoral grant 2011-2013.
Active participation to the project which led to the attribution of a PhD fellowship to Jianxia
Zheng by Axa Research Fund 2011-2014.
Since 2009: 5 PhD Students, 3 Post-doctorates, 8 masters students, 6 undergraduate students
Research Interests
Organometallic chemistry, Earth abundant transition metals, Homogeneous Catalysis, Hydrosilylation,
Hydroboration, C-H Activation, Reduction
Academic Collaborations
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Dr. V. Ritleng, Pr. M. J. Chetcuti, Université de Strasbourg, France
Dr. V. César, Dr. D. Valyaev, Dr. N. Lugan, Pr. G. Lavigne, LCC, Toulouse, France
Dr. S. Demir, Pr. I. Ozdemir, Inönü University, Malatya, Turkey, Project TUBITAK 20112012, Project Bosphorus 2014-2015 (Coordinator)
Pr. P. Ghosh, Indian Institute of Technology Bombay, India, project CEFIPRA
Dr. S. Bontemps, Dr. S. Sabo-Etienne, LCC, Toulouse, France, ANR IRONHYC, 2012-2015
Pr. J. Chirinos, Universidad del Zulia, Maracaibo, Venezuela, Project ECOS-NORD (20132016)
Dr. B. Royo, ITQB, Lisbon, Portugal, Project PESSOA 2014-2015
International associated Laboratory, LIA CHEMSUSCAT, Université Rennes 1/Leibniz
Institut für katalyse, Univ. Rostock, Germany
Collaboration with industrials BlueStar Silicons (2012-2013)
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List of Publications
2015
2014
2013
47) “Iron-Catalyzed C−H Borylation of Arenes” T. Dombray, C. G. Werncke, S. Jiang, M.
Grellier, L. Vendier, S. Bontemps, J.-B. Sortais, S. Sabo-Etienne, C. Darcel, J. Am. Chem.
Soc., 2015, 137, 4062-4065.
46) “Nickel Complexes of 1,2,4-Triazole Derived Amido-functionalized N-heterocyclic
Carbene Ligands: Synthesis, Theoretical Studies and Catalytic Application”, A. Kumar, L. P.
Bheeter, M. K. Gangwar, J.-B. Sortais, C. Darcel, P. Ghosh, J. Organomet. Chem. 2015,
doi:10.1016/j.jorganchem.2015.03.007.
45) “When iron met phosphines: a happy marriage for reduction catalysis”, L. C. Misal
Castro, H. Li, J.-B. Sortais, C. Darcel, Green Chem., 2015, 17, 2283-2303.
44) “Methylation of secondary amines with dialkyl carbonates and hydrosilanes catalysed by
iron complexes”, J. Zheng, C. Darcel, J.-B. Sortais, Chem. Commun., 2014, 50, 14229-14232.
43) “Iron-catalysed tandem isomerisation/hydrosilylation reaction of allylic alcohols with
amines”, H. Li, M. Achard, C. Bruneau, J.-B. Sortais, C. Darcel, RSC Adv., 2014, 4, 2589225897.
42) “Imidazolidinium ferrate complexes: Synthesis and catalytic propreties”, S. Demier, Y.
Gokce, T. Roisnel, J.-B. Sortais, C. Darcel, I. Ozdemir, C. R. Chimie, 2014, 17, 541-548.
41) “Cationic Iron(II) Complexes of the Mixed Cyclopentadienyl (Cp) and the N-heterocyclic
Carbene (NHC) Ligands as Effective Precatalysts for the Hydrosilylation of Carbonyl
Compounds”, D. Kumar, A. P. Prakasham, L. P. Bheeter, J.-B. Sortais, M. Gangwar, T.
Roisnel, A. Kalita, C. Darcel, P. Ghosh, J. Organomet. Chem. 2014, 762, 81-87.
40) “Hydrosilylation of Aldehydes and Ketones Catalyzed by Half-Sandwich Manganese (I)
N-Heterocyclic Carbene Complexes” J. Zheng, S. Elangovan, D. A. Valyaev, R. Brousses, V.
César, J.-B. Sortais, C. Darcel, N. Lugan, G. Lavigne, Adv. Synth. Catal., 2014, 356, 10931097
39) “(NHC)Fe(CO)4 efficient pre-catalyst for selective hydroboration of functional alkenes
under UV conditions” J. Zheng, J.-B. Sortais, C. Darcel, ChemCatChem, 2014, 6, 763-766
38) “Cobalt carbonyl based catalyst for hydrosilylation of carboxamides”, T. Dombray, C.
Helleu, C. Darcel, J.-B. Sortais, Adv. Synth. Catal., 2013, 355, 3358-3362
37) “Cyclopentadienyl N-heterocyclic carbene-nickel complexes as efficient pre-catalysts for
the hydrosilylation of imines” L. P. Bheeter, M. Henrion, M. J. Chetcuti, C. Darcel, V.
Ritleng, J.-B. Sortais, Catal. Sci. Technol. 2013, 3, 3111-3116
36) “Selective reduction of carboxylic acids to aldehydes though manganese catalysed
hydrosilylation” J. Zheng, S. Chevance, C. Darcel, J.-B. Sortais, Chem. Commun., 2013, 49,
10010-10012
35) “(Cyclopentadienyl)iron(II) Complexes of N-Heterocyclic Carbenes Bearing a Malonate
or Imidate Backbone: Synthesis, Structure, and Catalytic Potential in Hydrosilylation” V.
César, L. C. Misal Castro, T. Dombray, J.-B. Sortais, C. Darcel, S. Labat, K. Miqueu, J.-M.
Sotiropoulos, R. Brousses, N. Lugan, G. Lavigne, Organometallics, 2013, 32, 4643-4655
34) “Nickel-Catalysed Reductive Amination with Hydrosilanes” J. Zheng, T. Roisnel, C.
Darcel, J.-B. Sortais, ChemCatChem, 2013, 5, 2861-2864
33) “Selective Reduction of Esters to Aldehydes under the Catalysis of Well-Defined NHC–
Iron Complexes” H. Li, L. C. Misal Castro, J. Zheng, T. Roisnel, V. Dorcet, J.-B. Sortais, C.
Darcel, Angew. Chem. Int. Ed., 2013, 52, 8045-8049
32) “Synthesis of new iron–NHC complexes as catalysts for hydrosilylation reactions” S.
Demir, Y. Gökçe, N. Kaloğlu, J.-B. Sortais, C. Darcel, İ. Özdemir, Appl. Organometal.
Chem., 2013, 28, 459-464
31) “Unexpected selectivity in ruthenium-catalyzed hydrosilylation of primary amides:
synthesis of secondary amines”, B. Li, J.-B. Sortais, C. Darcel, Chem. Commun., 2013, 49,
3691-3693
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2012
2011
2010
30) “Chiral cyclopentadienyl-type ligands: a new breakthrough for asymmetric C-H
functionalisation” J.-B. Sortais, C. Darcel, ChemCatChem, 2013, 5, 1067-1068
29) “N-Heterocyclic Carbene Ligands and Iron: An Effective Association for Catalysis” D.
Bézier, J.-B. Sortais, C. Darcel, Adv. Synth. Catal., 2013, 355, 19-33
28) “A Convenient Nickel-Catalyzed Hydrosilylation of Carbonyl Derivatives” J. Zheng, C.
Darcel, J.-B. Sortais, Catal. Sci. Technol., 2013, 3, 81-84
27) “Selective Switchable Iron-Catalyzed Hydrosilylation of Carboxylic Acids” L. C. Misal
Castro, H. Li, J.-B. Sortais, C. Darcel, Chem. Commun., 2012, 48, 10514-10516
26) “Hydrosilylation of Aldehydes and Ketones Catalyzed by an N-Heterocyclic Carbene–
Nickel Hydride Complex under Mild Conditions” L. P. Bheeter, M. Henrion, L. Brelot, C.
Darcel, M. J. Chetcuti, J.-B. Sortais, V. Ritleng, Adv. Synth. Catal., 2012, 354, 2619-2624
25)“Phosphane-Pyridine Iron Complexes: Synthesis, Characterization and Application in
Reductive Amination through the Hydrosilylation Reaction” H. Jaafar, H. Li, L. C. Misal
Castro, J. Zheng, T. Roisnel, V. Dorcet, J.-B. Sortais, C. Darcel, Eur. J. Inorg. Chem., 2012,
3546-3550
24) “Iron-Catalyzed Hydrosilylation of Esters,” D. Bézier, G.T. Venkanna, L. C. Misal
Castro, J. Zheng, T. Roisnel, J.-B. Sortais, C. Darcel, Adv. Synth. Catal., 2012, 354, 18791884
23) “Synthesis, Characterization, and Fluxional Behavior of a 34 Electron Homochiral
Dimetallic Complex with an Unsupported Hydride Bridge between Two Ru Atoms” J.-P.
Djukic, J.-B. Sortais, L. Barloy, M. Pfeffer, Organometallics, 2012, 31, 2821-2828
22) “Amine Synthesis via Mild Catalytic PHMS Hydrosilylation of Imines with
[RuCl2(p−cymene)]2 catalyst” B. Li, J.−B. Sortais, C. Darcel, P. H. Dixneuf, ChemSusChem,
2012, 5, 396-399
21) “NHC−carbene cyclopentadienyl iron based catalyst for a general and efficient
hydrosilylation of imines” L. C. Misal Castro, J.−B. Sortais, C. Darcel, Chem. Commun.,
2012, 48, 151-153
20) “Iron Piano−Stool Phosphine Complexes for Catalytic Hydrosilylation Reaction” J.
Zheng, L. C. Misal Castro, T. Roisnel, C. Darcel, J.−B. Sortais, Inorg. Chim. Acta, 2012, 380,
301-307
19) “Cyclopentadienyl–NHC Iron Complexes for Solvent−Free Catalytic Hydrosilylation of
Aldehydes and Ketones” D. Bézier, F. Jiang, T. Roisnel, J.-B. Sortais, C. Darcel, Eur. J.
Inorg. Chem., 2012, 1333-1337
18) “Well−Defined Cyclopentadienyl NHC Iron Complex as the Catalyst for Efficient
Hydrosilylation of Amides to Amines and Nitriles” D. Bézier, G. T. Venkanna, J.-B. Sortais,
C. Darcel, ChemCatChem, 2011, 3, 1747-1750
17) “Alkene Addition of Frustrated P/B and N/B Lewis Pairs at the [3]Ferrocenophane
Framework” T. Voss, J.−B. Sortais, R. Frohlich, G. Kehr, G. Erker, Organometallics, 2011,
30, 584-594
16) “Cyclometalated Complexes of Ruthenium, Rhodium and Iridium as Catalysts for
Transfer Hydrogenation of Ketones and Imines” N. Pannetier, J.-B. Sortais, J.-T. Issenhuth, L.
Barloy, C. Sirlin, A. Holuigue, L. Lefort, L. Panella, J. G. de Vries, M. Pfeffer, M., Adv.
Synth. Catal., 2011, 353, 2844-2852
15) “Iron Dihydride Complex as the Pre−catalyst for Efficient Hydrosilylation of Aldehydes
and Ketones Under Visible Light Activation” L. C. Misal Carlos, D. Bézier, J.-B. Sortais, C.
Darcel, Adv. Synth. Catal., 2011, 353, 1279−1284
14) “N−Heterocyclic Carbene Piano−Stool Iron Complexes as Efficient Catalysts for
Hydrosilylation of Carbonyl Derivatives” F. Jiang, D. Bézier, J.-B. Sortais, C. Darcel, Adv.
Synth. Catal., 2011, 353, 239-244
13) “Cyclen-catalyzed Henry reaction under neutral conditions” C. Vovard-Le Bray, F. Jiang,
X.-F. Wu, J.-B. Sortais, C. Darcel, Tetrahedron Lett., 2010, 51, 4555-4557
12) “Cycloruthenated complexes as homogeneous catalysts for atom-transfer radical
additions” K. Parkhomenko, L. Barloy, J.-B. Sortais, J.-P. Djukic, M. Pfeffer, Tetrahedron
Lett., 2010, 51, 822-825
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2008
2007
2006
2005
2003
11) “1,2-Olefin addition of a frustrated amine-borane Lewis pair” J.-B. Sortais, T. Voss, G.
Kehr, R. Frölich, G. Erker, Chem. Commun., 2009, 7417-7418
10) “A Chemoenzymatic Approach to Enantiomerically Pure Amines Using Dynamic Kinetic
Resolution. Application to the Synthesis of NorSertraline” L. K. Thalén, D. Zhao, J.-B.
Sortais, J. Paetzold, C. Hoben, J-E. Bäckvall, Chem. Eur. J., 2009, 15, 3403-3410
9) “Cycloruthenated Compounds, Synthesis and Applications” J.-P. Djukic, J.-B. Sortais, L.
Barloy, M. Pfeffer, Eur. J. Inorg. Chem., 2009, 817-853
8) “Kinetics and Mechanism of Ruthenacycle-Catalysed Asymmetric Hydrogen Transfer” N.
Pannetier, J.-B. Sortais, L. Barloy, C. Sirlin, M. Pfeffer, Organometallics, 2008, 27, 58525859
7)
“µ 3-Carbonato-κ3O:O':O''-tris((η6-benzene)
[(R)-1-(1amino-ethyl)naphthyl-κ2C2,
N]ruthenium(II)) hexafluoridophosphate dichloromethane solvate” J.-B. Sortais, L. Brelot, M.
Pfeffer, L. Barloy, Acta Cryst., 2008, E64, m483-m484
6) “Cyclometalation of Primary Benzyl Amines by Ruthenium(II), Rhodium(III), and
Iridium(III) Complexes” J.-B. Sortais, N. Pannetier, A. Holuigue, L. Barloy, C. Sirlin, M.
Pfeffer,N. Kyritsakas, Organometallics, 2007, 26, 1856-1867
5)“Cyclometalation of Secondary Benzyl Amines by Ruthenium(II) Complexes” J.-B. Sortais,
N. Pannetier, N. Clément, L. Barloy, C. Sirlin, M. Pfeffer, N. Kyritsakas, Organometallics,
2007, 26, 1868-1874
4)“Nitrogen-containing xanthene-based chiral ligands: synthesis and catalytic applications of
their palladium, silver and rhodium complexes” G. Malaisé, J.-B. Sortais, L. Barloy, M.
Pfeffer, N. Kyritsakas, Polyhedron, 2006, 25, 3349-3365
3) “Cycloruthenated Compounds as Efficient Catalyst for Asymmetric Hydride Transfer
Reaction” J.-B. Sortais, L. Barloy, C. Sirlin, A. H. M. de Vries, J. G. de Vries, M. Pfeffer,
Pure Appl. Chem., 2006, 78, 457-462
2) “Cycloruthenated Primary and Secondary Amines as Efficient Catalyst Precursors for
Asymmetric Transfer Hydrogenation” J.-B. Sortais, V. Ritleng, A. Voelklin, A. Holuigue, H.
Smail, L. Barloy, C. Sirlin, G. K. M. Verzijl, J. A. F. Boogers, A. H. M. de Vries, J. G. de
Vries, M. Pfeffer, Org. Lett., 2005, 7, 1247-1250
1) “Trifluoromethanesulfinic Acid Derivatives as Nucleophilic Trifluoromethylating
Reagents” D. Inchauspe, J.-B. Sortais, T. Billard, B. R. Langlois, Synlett, 2003, 2, 233-235
List of oral communications
2004
2005
1) J.-B. Sortais, L. Barloy, C. Sirlin, M. Pfeffer
DSM Scientific Meeting "Homogeneous Catalysis for Future Industrial Applications:
New Carbon-Carbon Bond Forming and Asymmetric Catalysis", Vaals, Pays Bas, 15-16
November 2004
Cycloruthenated aromatic amine: Asymmetric transfer hydrogen catalysts
2) J.-B. Sortais, L. Barloy, M. Pfeffer
Nanoparticules Métalliques en Catalyse (NANOMETCAT), Toulouse, France, 14-15
October 2004
Synthesis and characterization of rhodium (III) complexes with chiral ligands based on rigid
xanthene backbone
3) J.-B. Sortais, L. Barloy, C. Sirlin, M. Pfeffer
Symposium Synthèse et Catalyse, Strasbourg, France, 12 May 2004
Complexes cycloruthénés: synthèse et application en catalyse
4) J.-B. Sortais, L. Barloy , C. Sirlin, M. Pfeffer
Séminaire Jeune Chercheur, Strasbourg, France, 22 November 2005
Cycloruthenated complexes: efficient catalysts in asymmetric hydrogen transfer
5) J.-B. Sortais, V. Ritleng, L. Barloy, C. Sirlin, J. G. de Vries, M. Pfeffer
Gecom Concoord 2005, Autran, France, 5-10 June 2005
Complexes cycloruthénés d’amines primaires et secondaires : des catalyseurs efficaces en
transfert énantiosélectif d’hydrogène
6) J.-B. Sortais, L. Barloy, C. Sirlin, M. Pfeffer
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2006
2009
2011
2012
2013
2014
2015
Symposium Synthèse et Catalyse, Strasbourg, France, 11 May 2005
Complexes cycloruthénés : des catalyseurs efficaces en transfert énantiosélectif d’hydrogène
7) J.-B. Sortais
Institut Charles Sadron, Strasbourg, France, 21 November 2006
Catalyse asymétrique de transfert d'hydrogène
8) J.-B. Sortais, C. Darcel
Joint Florence-Rennes IDECAT Meeting, Florence, 19-20 October 2009
Iron-catalyzed transformations towards C-C, C-O and C-N bond formations
9) L. C. Misal Castro, D. Bézier, J.-B. Sortais, C. Darcel,
Gecom-Concord, Merlinont, France, May 2011
Well-Defined Iron Complexes for Efficient Catalytic Hydrosilylation of Carbon-Heteroatom
Double Bonds Under Visible Light Activation
10) J.-B. Sortais, D. Bézier, L. C. Misal Castro, F. Jiang, J. Zheng, C. Darcel
EuCOMC 19, July 2011, Toulouse, France
Well Defined Iron Complexes as Catalysts for Hydrosilylation Reaction
11) C. Darcel, J.-B. Sortais, D. Bézier, L. C. Misal Castro, F. Jiang, J. Zheng,
OMCOS 16, July 2011, Shanghai, China
Well Defined Iron Complexes as Efficient Catalysts for Hydrosilylation Reactions
12) C. Darcel, J.-B. Sortais, D. Bézier, L. C. Misal Castro, J. Zheng, F. Jiang, H. Jaafar, G.T.
Venkanna,
International Green Catalysis Symposium, 7-9 March 2012, Rennes, France
Iron complexes and their applications in catalytic reductions
13) L. C. Misal Castro, J.-B. Sortais, C. Darcel,
Journée des Doctorants de l’UMR 6226, 7 June 2012, Rennes, France
Well Defined Iron Complexes as Efficient Catalysts for Hydrosilylation Reactions of CarbonHeteroatom Double Bonds
14) C. Darcel, J.-B. Sortais, D. Bézier, L. C. Misal Castro, F. Jiang, J. Zheng, L. P. Bheeter
ICOMC 2012, 2-7 September 2012, Lisbon, Portugal
Well defined iron complexes as efficient catalysts for hydrosilylation reactions of carbonyl
and carboxylic derivatives
15) C. Darcel, J.-B. Sortais, D. Bézier, L. C. Misal Castro, H. Li, J. Zheng,
8th IFCOS Meeting On Organic Synthesis, 1-3 April, 2013, Goa, India
Well defined iron complexes as efficient catalysts for hydrosilylation reactions of carboxylic
derivatives.
16) T. Dombray, C. Helleu, C. Darcel, J.-B. Sortais
Journée Chimie Organique 2013, 24-26 September, 2013, Ecole Polytechnique Palaiseau,
France
Cobalt Carbonyl Catalyzed Hydrosilylation of Amides
17) J.-B. Sortais
Institut des Sciences Moléculaires de Marseille, Equipe ChiroSciences, 4 April 2014,
Marseille, France
Earth abundant metalds in hydrosilylation reactions
18) J.-B. Sortais, D. Darcel, J. Zheng, L. C. Misal Castro, H. Li
5th EuCheMS, 31 August-4 September 2014, Istanbul, Turkey
Selective reduction of carboxylic acids derivatives catalyzed by iron and manganese
complexes
19) J.-B. Sortais
Laboratoire de Chimie de Coordination, 18 December 2014, Toulouse, France
Iron catalysis with hydrosilanes and hydroboranes
20) J.-B. Sortais
Instituto de Tecnologia Quimica a Biologica (ITQB), Oeiras, 24 February 2015,
Portugal
Iron catalysis with hydrosilanes and hydroboranes
21) J.-B. Sortais
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Instituto Superior Tecnico (IST), Lisbon, 26 February 2015, Portugal
Iron catalysis with hydrosilanes and hydroboranes
22) J.-B. Sortais
Institut des Sciences Moléculaires, Université de Bordeaux, 26 March 2015
Iron catalysis with hydrosilanes and hydroboranes
List of poster communications
2005
2010
2011
2012
1) J.-B. Sortais, N. Pannetier, L. Barloy, V. Ritleng, C. Sirlin, J. G. de Vries, M. Pfeffer
OMCOS 13, Geneva, Suisse, 17-21 July 2005
Cycloruthenation of Chiral at Carbon, Primary and Secondary Amines. An Easy Reaction,
that leads to Efficient Catalysts
2) J.-B. Sortais, L. Barloy, C. Sirlin, A. H. M. de Vries, J. G. de Vries, M. Pfeffer
OMCOS 13, Genève, Suisse, 17-21 July 2005
Cycloruthenated Compounds as Efficient Catalysts For Asymmetric Transfer Hydrogenation
3) J.-B. Sortais, N. Pannetier, M. Pfeffer, C. Sirlin
Advances in Supramolecular Chemistry Symposium - Jean-Marie Lehn’s Lab 40th
Anniversary, Strasbourg, France, 27-30 July 2005
Supramolecular catalysis: asymmetric hydrogen transfer mediated by a cycloruthenated
complex
4) J.-B. Sortais, T. Voss, G. Kehr, R. Fröhlich, G. Erker
Journées de Chimie de Coordination, 28-29 January 2010, Palaiseau, France
1,2-Olefin Addition of a Frustrated Amine/Borane Lewis Pair
5) D. Bézier, F. Jiang, J-B Sortais, C. Darcel
EuCOMC 19, July 2011, Toulouse, France
N-Heterocyclic Carbene Piano-Stool Iron Complexes as Efficient Catalysts for
Hydrosilylation of Carbonyl Derivatives
6) L. C. Misal Castro, D. Bézier, J.-B. Sortais, C. Darcel
Gecom-Concord, Merlinont, France, May 2011
Iron-Hydride Complex as pre-Catalyst for Efficient Hydrosilylation of Carbonyl Derivatives
under Visible Light Activation
7) H. Jaafar, H. Li, Luis C. Misal Castro, J.-B. Sortais, C. Darcel
International Green Catalysis Symposium, 7-9 March 2012, Rennes, France
Phosphino-Pyridine Iron Complexes and Application on Hydrosilylation Catalysed Reactions
8) F. Jiang, D. Bézier, J.-B. Sortais, C. Darcel
International Green Catalysis Symposium, 7-9 March 2012, Rennes, France
N-Hetrocyclic Carbene Piano-Stool Iron Complexes as Efficient Catalysts for Hydrosilylation
of Carbonyl Derivatives
9) L. P. Bheeter, M. Henrion, M. Rocquin, V. Ritleng, M. J. Chetcuti, J.-B. Sortais, C. Darcel
International Green Catalysis Symposium, 7-9 March 2012, Rennes, France
Half-sandwich NHC nickel complexes as efficient catalysts in hydrosilylation reactions
10) L. C. Misal Castro, J.-B. Sortais, C. Darcel
International Green Catalysis Symposium, 7-9 March 2012, Rennes, France
Iron-Catalyzed Hydrosilylation of imines
11) J. Zheng, L. C. Misal Castro, J.-B. Sortais, C. Darcel
International Green Catalysis Symposium, 7-9 March 2012, Rennes, France
Iron Piano-Stool Phosphine Complexes for catalytic hydrosilylation reactions
12) J.-B. Sortais, L. C. Misal Castro, J. Zheng, D. Bézier, F. Jiang, C. Darcel
18th International Symposium on Homogenous Catalysis, 9-13 July 2012, Toulouse,
France
Iron catalyzed hydrosilylation: from carbonyls to carboxylic acid derivatives
13) L .C. Misal Castro, D. Bézier, J. Zheng, J.-B. Sortais, C. Darcel
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2013
2014
International Conference Catalysis in Organic Synthesis, 15-20 September 2012,
Moscow, Russia
Well defined iron complexes as efficient catalysts for hydrosilylation reactions of carbonheteroatom double bonds
14) J. Zheng, L. C. Misal Castro, J.-B. Sortais, C. Darcel
ICOMC 2012, 2-7 September 2012, Lisbon, Portugal
Iron piano-stool phosphine complexes for catalytic hydrosilylation reactions
15) J.-B. Sortais, Luis C. Misal Castro, H. Li, J. Zheng, C. Darcel
ESOC 18th 2013, 7-12 July 2013, Marseille, France
Iron catalysed reduction of carboxylic acids with hydrosilanes
16) J. Zheng, C. Darcel, J.-B. Sortais
EuCOMC XX, 30 June-4 July 2013, St Andrews, Scotland
Nickel catalysed reductive amination with silanes
17) L. P. Bheeter, M. J. Chetcuti, V. Ritleng, C. Darcel, J.-B. Sortais
EuCOMC XX, 30 June-4 July 2013, St Andrews, Scotland
Hydrosilylation of imines catalyzed by an N-Heterocyclic carbene nickel complex
18) T. Dombray, C. Helleu, C. Darcel, J.-B. Sortais
Journée Chimie de Coordination 2014, January 30-31, 2014, Université de Rennes,
France
Cobalt Carbonyl Catalyzed Hydrosilylation of Amides
19) J. Zheng, C. Darcel, J.-B. Sortais
Journée Chimie de Coordination 2014, January 30-31, 2014, Université de Rennes,
France
Iron catalyzed hydroboration
20) S. Elangovan, J. Zheng, C. Darcel, J.-B. Sortais
Journée Chimie de Coordination 2014, January 30-31, 2014, Université de Rennes,
France
Manganese catalyzed hydrosilylation reaction
21) S. Quintero Duque, C. Darcel, J.-B. Sortais
Journée Chimie de Coordination 2014, January 30-31, 2014, Université de Rennes,
France
Well defined iron complexes bearing N-Heterocyclic Carbenes and pentamethylcyclopentadienyl (Cp*) ligands as catalysts for hydrosilylation reactions
22) L. P. Bheeter, M. Henrion, M. Rocquin, V. Ritleng, M. J. Chetcuti, J.-B. Sortais, C. Darcel
Journée Chimie de Coordination 2014, January 30-31, 2014, Université de Rennes,
France
Half-sandwich NHC-nickel complexes as efficient catalysts for hydrosilylation of aldehydes
and ketones
23) T. Dombray, C. Helleu, C. Darcel, J.-B. Sortais
2nd International Green Catalysis Symposium, April 2-4, 2014, Université de Rennes,
France
Cobalt Carbonyl Catalyzed Hydrosilylation of Amides
24) J. Zheng, C. Darcel, J.-B. Sortais
2nd International Green Catalysis Symposium, April 2-4, 2014, Université de Rennes,
France
Iron catalyzed hydroboration
25) S. Elangovan, J. Zheng, C. Darcel, J.-B. Sortais
2nd International Green Catalysis Symposium, April 2-4, 2014, Université de Rennes,
France
Manganese catalyzed hydrosilylation reaction
26) S. Quintero Duque, C. Darcel, J.-B. Sortais
2nd International Green Catalysis Symposium, April 2-4, 2014, Université de Rennes,
France
Well defined iron complexes bearing N-Heterocyclic Carbenes and pentamethylcyclopentadienyl (Cp*) ligands as catalysts for hydrosilylation reactions
8
27) L. P. Bheeter, M. Henrion, M. Rocquin, V. Ritleng, M. J. Chetcuti, J.-B. Sortais, C. Darcel
2nd International Green Catalysis Symposium, April 2-4, 2014, Université de Rennes,
France
Half-sandwich NHC-nickel complexes as efficient catalysts for hydrosilylation of aldehydes
and ketones
28) T. Dombray, C. Helleu, C. Darcel, J.-B. Sortais
5th EuCheMS, August 31-September 4, 2014, Istanbul, Turkey.
Cobalt Carbonyl Catalyzed Hydrosilylation of Amides
29) J. Zheng, C. Darcel, J.-B. Sortais
5th EuCheMS, August 31-September 4, 2014, Istanbul, Turkey.
Iron catalyzed hydroboration
Supervision
PhD students
Saravanakumar Elangovan (10/2013-) co-tutelle with C. Darcel/J.-B. Sortais (UR1) and M. Beller
(LIKAT, Rostock)
Jianxia Zheng (10/2011-10/2014) co-direction with C. Darcel, « Hydroelementation reactions
catalyzed by earth abundant metals », defended in Rennes, 07/10/2014 funded by Axa Research
Funds.
Linus Pauling Bheeter (10/2011-12/2014) co-direction with C. Darcel, « Nickel catalyzed
hydrosilylation and borylation », defended in Rennes, 11/12/2014, funded by CEFIPRA.
Luis C. Misal Castro (10/2009-11/2012) co-direction with C. Darcel “Molecular defined iron
complexes for catalytic hydrosilylation reactions”, defended in Rennes, 23/11/2012. Currently, postdoc fellow in the group of N. Chatani, Osaka, Japan, since January 2013.
David Bézier (2008-2011) co-direction with C. Darcel (2009-2011) “Réactions d’hydratation et
d’hydrosilylation catalysées par le fer”, defended in Rennes, 18/11/2011. Currently, post-doc fellow in
the group of M. Brookhart, Chapel Hill, USA, since January 2012.
Post-doctoral researchers
Dr. Thomas Dombray (10/2012-) co-direction with C. Darcel, funded by “la Région Bretagne”, via
the project Create “Bioricat” and the ANR “IRONHYC”
Dr. Venkanna Gopaladasu T. (October 2010- October 2011) co-direction with C. Darcel, funded by
the « Université de Rennes 1 »
Dr. Hassen Jaafar (April 2011-September 2012) co-direction with C. Darcel, funded by “la région
Bretagne”, via the project Create « Bioricat »
Masters students
Fan Jiang (2009-2011), International Master in Molecular Catalysis and Green Chemistry, Rennes
Jianxia Zheng (2010-2011), International Master in Molecular Catalysis and Green Chemistry,
Rennes.
Haoquan Li (2011-2013) International Master in Molecular Catalysis and Green Chemistry, Rennes,
currently PhD student with Pr. M. Beller, LIKAT, Rostock, Germany
Saravanakumar Elangovan (2012-2013) International Master in Molecular Catalysis and Green
Chemistry, Rennes, currently PhD student with Pr. C. Darcel/Dr. J-B. Sortais and Pr. M. Beller
Laurentine Nziraguseswa (2012-2013) Master 2 Chimie Moléculaire, Rennes
Samuel Quintero Duque (2012-2014) International Master in Molecular Catalysis and Green
Chemistry, Rennes
She Jiang (2013-2015) International Master in Molecular Catalysis and Green Chemistry, Rennes
Duo Wei (2014-2016) International Master in Molecular Catalysis and Green Chemistry, Rennes
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Undergraduated students
Florian Chotard (Spring 2011)
Fanny Herbert (Spring 2012)
Antoine Bruneau-Voisin (Spring 2013)
Camille Helleu (June 2013)
Anatole Clerc-Cathala (Spring 2014)
Hiwote Mebrate (June 2014)
Teaching activities
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As Teaching Assistant at the University Louis Pasteur, Strasbourg (about 64 hours per year)
2003-2006
2003-2005
- Chimie des éléments, Deug 1ère année, Chimie-Physique (15h TD)
- Chimie expérimentale, DEUG 1ère année, Chimie-Physique (30h TP)
Les thèmes abordés vont de la structure de l’atome à la chiralité.
- Synthèse Organique et Minérale DEUG 2ème année, Chimie-Physique (40h TP)
Travaux pratiques de chimie organique et inorganique incluant les réactions et les techniques
classiques de la chimie (distillation, recristallisation, chromatographies, réduction d’une cétone,
synthèse et réactivité d’un Grignard, dosage pHmétrique…)
2003-2004
- Correction de leçons à l’agrégation de chimie Préparation à l’agrégation de Sciences Physiques,
option Chimie (6h TD)
2005-2006
- Chimie expérimentale Licence Chimie-Physique, S2 (12h TD, 32h TP)
- TP de Chimie Organique Licence Physique-Chimie S3 (7h TD, 21h TP)
•
As Temporary Teaching position at the University Louis Pasteur, Strasbourg (90 hours) 20062007
- TD de Spectroscopie Master 1 Chimie et Sciences du vivant (16h TD)
- TD de Chimie Organique Licence de Chimie S5 (15h TD)
- Méthodologie du Travail Universitaire Licence de Chimie S1 (12h CI+12h TD)
Cette unité d’enseignement a pour objectif d’accompagner l’étudiant, entrant à l’université, à acquérir
l’autonomie et l’organisation dont dépend son succès futur. Pour cela, l’ensemble des outils
pédagogiques disponibles à l’université lui sont présentés (bibliothèque, ressources en ligne…), une
attention toute particulière est portée sur la prise de note.
- Chimie Organique Expérimentale Licence de Chimie S3 (19h TD + 9h TP)
•
Trainer at the DEPULP (continuing education department), "Mechanisms in Organic
Chemistry" (30 hours per year), Université Louis Pasteur, Strasbourg (June 2004 and June
2005)
Cours de formation permanente en Chimie Organique intitulé « Chimie organique : mécanismes
réactionnels et implications synthétiques ».
Public : un groupe de 5 à 15 personnes ayant des parcours allant du DUT au Doctorat ou Diplôme
d’ingénieur en Chimie, animé par deux formateurs.
La formation couvre le programme de Licence en chimie organique. L’intensité de la formation (6 h
par jour) nécessite d’alterner cours, exercices, et discussions portant sur les préoccupations et les
attentes de chacun des participants.
•
As assistant professor at the University Rennes 1
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- Introduction à la chimie de coordination, M1 Biochimie, (cours 6h, TD 6h, TP 12h)
Introduction aux notions de complexes, ligands, formalisme de Green et catalyse
- Cours de Chimie Organique, Leçon de Chimie, Préparation de l'Agrégation de Sciences Physiques.
(40h)
Préparation à l’épreuve écrite de Chimie Organique, révision du programme de chimie organique de
licence ou des classes préparatoires aux grandes écoles.
- TP de Chimie Organométallique, M1 Chimie (14h)
Synthèse des complexes de ruthénium et de palladium sous atmosphère inerte, caractérisation et
application en catalyse.
-TD de Réactivité et Stéréochimie en Chimie Organique, L3 Biochimie (8h)
- Introduction à la catalyse organométallique et la chimie verte, M1-M2 MEF (cours 8h)
- Cours-TD d’atomistique, L1 Chimie (20h)
- TP de chimie générale, L1 Chimie (18h)
- TD de thermochimie, L1 Chimie (10h)
Conference organization
Participation to the local organization committee of five international conferences and symposium
•
•
•
•
•
ISOM 19, (International Symposium on Olefin Methathesis) Rennes, France, 10-15 july
2011.
Symposium "International Green catalysis Symposium and Advanced spring School on
Green Catalysis", Rennes, 7−9 March 2012.
International Symposium of Metal-Mediated Chemistry, Strasbourg, France, November
22th 2013
Symposium "2nd International Green catalysis Symposium and Advanced spring School
on Green Catalysis", Rennes, 2-4 April 2014.
"2nd International Symposium on C-H activation", Rennes, 30 June-3 July 2014.
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