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Conformément à la réglementation (UE) N° 1907/2006, Annexe II
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Nom du produit
FR-1206
8303
Id produit
17/03/2014
Date de révision
Révision 13
30/10/2012
Remplace
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1: Identification de la substance/du mélange de la société/l'entreprise
1.1 Identifiant du produit :
Bromure hexacyclodécane
Formule chimique
Enregistrement REACH N° :
C 12 H 18 Br 6
01-2119539454-36-0005
Poids moléculaire
641.5
Famille chimique
Cycloalcane halogéné
1.2. Usages identifiés pertinents Ingnifuge
de la substance ou du mélange
et usages déconseillés
1.3. Détails du fournisseur de la ICL-IP Terneuzen B.V.
P.O. Box 318, 4530 AH Terneuzen, Pays-Bas
fiche de données de sécurité
Tél. (00 31) 115 689000
e-mail:[email protected]
Téléphone en cas d'urgence :
- Pour l'Europe
- Pour le Royaume-Uni et
l'Irlande
( +31) 115 689000
+44 (0) 1270 502891 (24 Hours)
Section 2 : IDENTIFICATION DES DANGERS
2.1. Classification de la substance ou du mélange
Classification selon la
Réglementation (CE) N°
1272/2008 [CLP/GHS]
Informations supplémentaires
Lact. H362 Peut être nocif pour les bébés nourris au lait maternel.
Aquatique aigu 1, H400: Très toxique pour les organismes aquatiques
Aquatique chronique 1, H410 Très toxique pour les organismes aquatiques,
entraîne des effets néfastes à long terme
Aucun(e)
Classification selon la Directive
R64: Puede perjudicar a los niños alimentados con leche materna.
67/548/CEE, 1999/45/EC
Dangereux pour l'environnement ; R50/53:Très toxique pour les
organismesaquatiques, peut entraîner des effets néfastes à long terme pour
l'environnementaquatique
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Id produit
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Date de révision
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2.2. Eléments d'étiquette
Étiquetage conformément à la Réglementation CLP CE (N°) 1272/2008
Mention d'avertissement
ATTENTION
Mentions de danger
H361 - Susceptible de nuire à la fertilité ou au foetus
H362 - Peut être nocif pour les bébés nourris au lait maternel
H410 - Très toxique pour les organismes aquatiques, entraîne des effets néfastes
à long terme
Conseils de prudence
sécurité
P260 - Ne pas respirer les poussières/fumées/gaz/brouillards/vapeurs/aérosols
P263 - Éviter tout contact avec la substance au cours de la grossesse/pendant
P391 - Recueillir le produit répandu
P280 - Porter des gants de protection/des vêtements de protection/un équipement
de protection des yeux/du visage
chimiques conformément aux législations locales, régionales, nationales et
internationales
2.3. Autres dangers
Hexabromocyclododecane est une substance persistante, bioaccumulative et
toxique (PBT) conformément aux critères de l'Annexe XIII de la réglementation
REACH
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3. Composition / informations sur les composants
Composants
% en poids
Index no. :
Numéro EEC
Hexabromocyclododécane
3194-55-6
99.5
602-109-00-4
221-695-9
Classification de
l'UE
Repr. 2 H361
Lact. H362
Aquatic Acute 1,
H400
Aquatic Chronic 1,
H410
(In accordance with
CLP 1272/2008)
Repr.Cat. 3;R63
R64
N;R50/53
(In accordance with
DSD 67/548/EEC)
4. Premier Secours
4.1. Description des premiers soins
Contact oculaire
En maintenant les paupières ouvertes, immédiatement rincer abondammment
avec de l'eau courante pendant 20 minutes au moins. Consulter immédiatement
un médecin.
Contact cutané
Retirer tous vêtements contaminés. Rincer la peau soigneusement avec du savon
doux et de l'eau en abondance durant 15 minutes au moins. Nettoyer les
vêtements avant de les réutiliser. Consulter immédiatement un médecin.
Inhalation
En cas d'inhalation de poussières ou de vapeur provenant des matériaux
chauffés,
transporter la victime à l'air libre.
Veiller à ce que la victime reste calme et n'ait pas froid. Pratiquer la respiration
artificielle si nécessaire et consulter un médecin immédiatement.
Ingestion
En cas d'ingestion, laver soigneusement la bouche avec une grande quantité
d'eau. Consulter immédiatement un médecin.
------------------------------------------------------------------------------------IMPORTANT : Ne jamais faire boire une personne inconsciente
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4.2. Symptômes et effets les plus importants, à la fois immédiatement et ultérieurement
4.3. Indication de consultation Traiter en fonction des symptômes et des besoins.
immédiate d'un médecin et de Pas d'antidote spécifique.
traitement particulier nécessaire
5. Lutte contre l'Incendie
5.1. Supports d'extinction
Ce produit n'est pas inflammable. Adapter les moyens d'extinction aux conditions
d'incendie environnantes.
La poussière n'est pas sensible à l'allumage à partir de décharges statiques. La
5.2 Dangers particuliers
découlant de la substance ou du poussière risque de former avec l'air un mélange faiblement explosif (Catégorie
mélange
de HBr.
5.3. Conseils pour les pompiers Refroidir les conteneurs en vaporisant de l'eau. Dans les entrepôts fermés, fournir
un appareil respiratoire autonome aux pompiers en mode de pression positive.
6. Mesures en cas de dispersion accidentelle
6.1. Précautions personnelles,
équipements de protection et
procédures d'urgence
Porter un appareil de protection respiratoire, des lunettes de protection chimiques,
des gants et des bottes en caoutchouc.
6.2. Précautions
environnementales
Empêcher les émissions du produit dans l'environnement, y compris l'air, les sols
et tous les cours d'eau.
6.3. Méthodes et matériaux pour Ramasser à la pelle dans des emballages intacts et les jeter comme déchets
dangereux ou en vue d'une éventuelle réutilisation. Eviter de soulever de la
contenir et nettoyer
poussière. Aérer la zone et laver le site du déversement après ramassage complet
des matériaux.
6.4 Renvoi à d'autres sections
Aucune.
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7. Manipulation et Stockage
7.1. Précautions à prendre pour Eviter tout contact avec le corps. Veiller à ce que les conteneurs soient
une manipulation sans danger hermétiquement fermés.
7.2. Conditions de stockage en Entreposer dans un lieu sec et bien aéré à l'écart des matières incompatibles (cf.
section 10).
toute sécurité, y compris les
incompatibilités
7.3. Usage final spécifique
Pas d'exigences spécifiques
8. Contrôle d'exposition/Protection individuelle
8.1. Paramètres de contrôle
Composants
% en poids
Données ACGIH - TLV
Hexabromocyclododécane
3194-55-6
99.5
Non déterminé
Recommandation du fabricant
DONNÉES SELON RU
EH40 MEL (TABLE 1) TWA
Non déterminé
Valeurs limite du TRGS
data
Non déterminé
TWA- 1 mg/m³
Les DNEL (Niveaux sans effets dérivés) et PNEC (Concentrations sans effets prédits) pour les voies et les
compartiments sujets d'inquiétude sont présentés ci-dessous :
DNELS pour les travailleurs
Effets systémiques à long terme 2040 mg/kg bw/jour (dermique)
1.43 mg/m³ (inhalation)
DNEL pour la population générale
Effets systémiques à long terme 1020 mg/kg bw/jour (dermique)
0.719 mg/m³ (inhalation)
0.719 mg/kg bw/jour (oral)
PNEC eau
0.31 µg/l (eau potable)
0.062 µg/l (eau de mer)
PNEC sédiments
10 mg/kg sédiments dw (eau potable)
1 mg/kg sédiment dw (eau de mer)
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PNEC sol
12.8 mg/kg sol dw
PNEC centrale d'épuration des
eaux (STP)
0.15 mg/l
8.2. Contrôles d'exposition
Exigences d'aération
Equipements de protection
individuelle :
- Protection respiratoire
La ventilation doit suffire à maintenir une concentration atmosphérique
au-Dessous de la limite d'exposition recommandée.
Casque respiratoire homologué
- Protection des mains
- Protection des yeux
- Protection de la peau et du
corps
Gants de protection chimique
Lunettes de protection chimique
Combinaison et bottes
Mesures d'hygiène
Ne pas manger, fumer ou boire pendant la manipulation, le traitement ou le
stockage du produit. Se laver les mains completement apres toute manipulation et
avant de manger ou de fumer. Une douche de sécurité et un bain oculaire doivent
être fournis.
9. Propriétés physiques et chimiques
9.1. Informations sur les propriétés physiques et chimiques de base
Aspect
Point/intervalle de fonte
Point/intervalle d'ébullition
Point d'éclair
Taux d'évaporation (éther=1)
Pression de vapeur
Densité de vapeur
Solubilité :
- Solubilité dans l'eau
- Solubilité dans d'autres
solvants
Coefficient de répartition
octanol/eau
Température d'autoignition
Dangers d'explosion
Poudre cristalline de couleur blanc à blanc cassé s'écoulant librement
175-185°C
Non applicable (se décompose)
Sans objet
Non applicable aux conditions standards
6.45 x 10(-5) Pa (21°C)
Non applicable aux conditions standards
66 µg/l (20°C)
Styrène : 10 g/100g à 25°C
Acétone : 7g/100g à 25°C
Toluène : 6,5 g/100g à 25°C
Puissance enregistrée - 5.625 (25°C)
Sans objet
Pas explosif
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Propriétés comburantes
Température de décomposition
Limites
d'explosion/d'inflammation
Gravité spécifique
Pas d'oxydation
> 230°C
Non inflammable
2.18
10. Stabilité et Réactivité
10.1 Réactivité
Aucun à notre connaissance.
10.2 Stabilité chimique
Stable sous conditions normales.
10.4 Conditions à éviter
Chauffage au-dessus de 230 °C
10.5 Matières incompatibles
Agents oxydants
10.6 Produits de décomposition HBr
dangereux
11. Informations toxicologiques
11.1 Informations sur les effets toxicologiques
Toxicité aiguë :
- Rat, oral DL50
>5,000 mg/kg
- Lapin, cutané DL50
>8,000 mg/kg
- Rat, inhalation CL50
>200 mg/l/1 hour
Grave détérioration/irritation des Non irritant
yeux
Corrosion/irritation de la peau
Non irritant
Sensibilisation des voies
respiratoires ou de la peau
N'est pas un agent sensibilisant
Mutagénicité
Non mutagène selon le test d'Ames
Non clastogène au cours des tests réalisés sur les aberrations chromosomiques
des lymphocytes humains
Cancérogénicité
Non classé par l'IARC.
Pas inclus dans le Rapport des produits cancérigènes NTP 12
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Teratogénèse
Non tératogène, NOAEL=1000 mg/kg poids du corps (rat, gavage)
NOAEL 300 mg/kg/jour (4 semaines, oral, rat). NOAEL 1000 mg/kg/jour (13
Toxicité d'organes cibles
spécifiques (STOT) - exposition semaines, oral, rat).
répétée
12. Informations écologiques
12.1 Toxicité
Toxicité aquatique :
- 96 heures-LC50 - Poisson
>6.8 ug/L, nominal, (Rainbow trout)
72 heures - EC50 -- Algue marine52 ug/l (Skeletonema costatum)
>6.8 ug/L, 96 Hours, nominal (Selenastrum capricornutum)
- EC50, Algues d'eau douce
12.2 Persistance et dégradabilité Biodégradable inhérente Dans des sédiments, HBCD n'est pas persistant dans
des conditions aérobies ou anaérobies avec des valeurs de demi-vie de 11 à 32
jours et de 1,1 à 1,5 jours, respectivement.
Dans le sol, HBCD n'est pas persistant dans des conditions anaérobies mais est
persistant dans des conditions aérobies avec des valeurs de demi-vie de 6,9 jours
et 64 à 441 jours, respectivement.
12.3 Potentiel bioaccumulatif
HBCD est considéré comme bioaccumulatif. Une valeur BCF d'état constant de
8,974 a été obtenue dans un test de bioconcentration à flux traversant avec la
truite arc-en-ciel.
12.4 Mobilité dans le sol
L'adsorption/désorption de la substance a été démontrée comme étant élevée (log
Koc >5)
En raison de la solubilité dans l'eau et du coefficient d'adsorption/désorption de
HBCD, la distribution dans les sols n'est anticipée qu'à partir de particules en
suspension et au cours d'événements d'inondations.
12.5 Résultats d'évaluation PBT Critères PBT remplis
et vPvB
12.6 Autres effets négatifs
Aucun à notre connaissance
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13. Considerations relatives a l'elimination
13.1 Méthodes de traitement des
déchets
Traiter les déchets solides et les déchets d'emballage dans un incinérateur équipé
Elimination des déchets
d'un système adéquat de nettoyage de gaz ou les envoyer à une décharge
contrôlée. Eliminer soigneusement conformément aux réglementations
locales/nationales.
14. Informations relatives au transport
Numéro ONU
3077
ADR/RID
Appellation réglementaire d'expédition : Substance dangereuse pour
l'environnement, solide, sans autres précisions
(Bromure hexacyclodécane)
Catégorie : 9 - Substances et articles dangereux divers
Modèle d'étiquette de signalisation de danger n° : 9
Identification de risque N° 90
Groupe d'emballage : III
Code de classification : M74
Marquage : Substance dangereuse pour l'environnement
IMO
Catégorie : 9 - Substances et articles dangereux divers.
Etiquette : 9
Marquage : POLLUANT MARIN
ICAO/IATA
Catégorie : 9
Etiquette(s) de risque : Divers
Marquage : Substance dangereuse pour l'environnement
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15. Informations réglementaires
15.1 Réglementations et législations de sécurité, de santé et de protection de l'environnement pour la
substance ou le mélange
UE
HBCDD a été ajouté à ANNEXE XIV, Substances soumises à autorisation, selon
Administratif norvégien
Répertorié dans la liste d'observation des produits chimiques 2002 Substance
prioritaire pour la réduction des émissions d'ici 2010.
Etats-Unis
Répertorié dans l'inventaire EPA TSCA
Australie
Répertorié dans AICS
Canada
Répertorié dans DSL
Inventaire de Chine
Répertorié
Japon
ENCS n° 3-2254
ISHL n° 3-2254
Type III Contrôle des substances chimiques.
Corée
Répertorié dans l'ECL (KE-18398)
Nouvelle-Zélande
Répertorié dans NZIoC
Philippines
Répertorié dans PICCS
15.2 Évaluation de sécurité
chimique
Une évaluation de sécurité chimique a été effectuée conformément à la
réglementation REACH. Scénario d'exposition disponible.
16. Information complémentaire
Cette fiche de données de sécurité comporte des modifications par rapport à la version précédente dans la
(les) section(s)
8
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Politique de protection de la santé, de la sécurité et de l'environnement
Nous nous efforçons de nous assurer que nos opérations et nos produits répondent aux besoins de la communauté
internationale actuelle sans compromettre la capacité des générations futures à répondre à leurs besoins Nous
reconnaissons que le succès de notre entreprise dépend de la fourniture de produits et de services qui bénéficient à
la société tout en assurant la sécurité des êtres humains et la protection de l'environnement et des ressources
naturelles Dans le cadre de notre engagement en faveur du programme de responsabilité d'entreprise, nous
fournissons un environnement de travail protégeant la sécurité et la santé des employés et nous gérons en toute
responsabilité nos produits à tous les niveaux de leur cycle de vie pour protéger la santé des êtres humains et
l'environnement tout en maintenant des normes élevées de production et d'exploitation
POUR TENIR CET ENGAGEMENT NOUS : Nous respecterons ou irons au-delà des exigences réglementaires
nationales et internationales en vigueur et des autres exigences auxquelles nous adhérons communiquerons
ouvertement et encouragerons activement le dialogue avec les employés, les clients et la communauté en ce qui
promeuvent l'éthique de la responsabilité d'entreprise
développerons et fournirons des produits qui peuvent être fabriqués, transportés, utilisés et éliminés en toute sécurité
tout en répondant au mieux aux besoins de nos clients évalurons régulièrement, améliorerons continuellement et
gérerons de manière responsable les risques de santé, de sécurité et d'environnement associés aux produits et aux
processus à travers leur cycle de vie partagerons nos connaissances et notre expertise avec autrui et chercherons à
apprendre et à incorporer des pratiques améliorées dans nos propres opérations
éduquerons et formerons nos employés, nos sous-traitants et nos clients pour améliorer leurs performances en
matière de protection de la santé, de la sécurité et de l'environnement (HSE) communiquerons des informations à
jour pour permettre à nos employés, nos clients et aux autres parties intéressées de manipuler nos produits d'une
manière responsable sur le plan environnemental et en toute sécurité ferons tout ce qui est en notre pouvoir pour
travailler avec les clients, les fournisseurs, les distributeurs et les sous-traitants pour favoriser l'utilisation, le transport
et l'élimination de nos produits chimiques en toute sécurité Programmes de responsabilité sociale de l'entreprise en
matière de support de produits en coopération avec les clients, les distributeurs et les transporteurs
Bien que les informations et les recommandations stipulées dans les présentes (ci-Après désignées les «
informations ») soient présentées de bonne foi et considérées comme étant correctes à la date des présentes, ICL-IP
Terneuzen BV ne prend aucun engagement en ce qui concerne l'exhaustivité ou l'exactitude desdites informations.
Les informations sont fournies à la condition que les personnes les recevant feront usage de leurs propres
déterminations quand à la sûreté et quand à l`aptitude à leur propres objectifs, avant usage. ICL-IP Terneuzen BV
décline toute responsabilité quant à tout dommage découlant de la confiance en ces renseignements et de leur
utilisation.
AUCUNE ASSERTION NI GARANTIE, EXPRESSE OÙ TACITE, DE QUALITÉ MARCHANDE, DE CONVENANCE
UN USAGE PARTICULIER, OÙ DE TOUTE AUTRE NATURE, NE SONT FAITES PAR LES PRÉSENTES QUANT
AUX RENSEIGNEMENTS ET AU PRODUIT S`Y RAPPORTANT.
En cas de différence entre le contenu de cette MSDS et sa version anglaise, la version anglaise prévaut.
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Préparé par
Division HERA en ISRAEL
tel. : +/972-8-6297835
telefax : +/972-8-6297832 www.icl-Ip.com
e-mail:[email protected]
Fin de la Fiche de Données de Sécurité
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EC number:
247-148-4
Substance name:
Hexabromocyclododecane
CAS number:
25637-99-4
Annex
Index
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
Introduction
Overview of uses that were identified and assessed
ES2a – Manufacture of Expanded Polystyrene (EPS) and EPS articles
ES2b – Use of Expanded Polystyrene (EPS) articles
ES3a - Manufacture of Extruded polystyrene (XPS) and XPS articles
ES3b - Use of Extruded Polystyrene (XPS) articles
ES4a – Manufacture of high impact polystyrene (HIPS) and masterbatch and manufacture of HIPS
articles
ES4b – Use of high impact polystyrene (HIPS) articles
ES5a – Manufacture of polymer dispersion for textiles and textile articles
ES5b – Use of textile articles containing polymer dispersion
ES6a – Manufacture of flexible elastomeric foam (FEF) and FEF articles
ES6b – Use of flexible eslatomeric foam (FEF) articles
ES7 - Additional formulation use (no further information available)
Introduction
According to REACH Art. 37(5) downstream users of chemical substances shall identify, apply and
where suitable, recommend, appropriate measures to adequately control risks identified in the safety
data sheet supplied to them. This identification and application of the appropriate measures is often
called a compliance check.
In this Annex to the SDS we have gathered all relevant exposure scenarios for the substance
hexabromocyclododecane (HBCDD). In order for you to perform your compliance check an overview
table is given below (Table 1) of all uses of HBCDD that were identified and for which an exposure
scenario was generated. After you have localised your use in the table, you should check your
compliance with the conditions described in the corresponding exposure scenario further down in this
document.
All assessments were carried out using the modeling tools ECETOC TRA (for human exposure) and
EUSES (for environmental exposure). For human health, should you not be able to demonstrate
compliance with the conditions described in the exposure scnearios below, there is an option to
perform scaling running ECETOC TRA with your own data. Since scaling is not allowed with EUSES
for environmental health1, your options in case of non-compliance are either to contact your supplier or
to prepare your own Downstream User Chemical Safety Report.
1
The complexity of the EUSES model is of such a nature that it cannot be guaranteed that the Downstream User
has used the exact same parameter values as the registrant (besides the plant-specific data he has input), allowing a
correct scaling to be performed.
Version 04-03-2013
1 EC number:
247-148-4
Substance name:
CAS number:
25637-99-4
Table 1. Overview of uses that were identified and assessed
Resulting
life cycle
stage
ES2a – Manufacture of Expanded
Polystyrene (EPS) and EPS articles
x
ES6a – Manufacture of flexible
elastomeric foam (FEF) and FEF
articles
x
x
x
x
x
x
AC*
x
SU 3
SU 12
SU18
PC 32
AC 13
x
SU 19
SU 21
SU 22
SU 23
SU 12
n/a
PROC 3
PROC4
PROC 5
PROC 8b
PROC 9
PROC 14
PROC 21
PROC 21
AC 3
AC 13
SU 19
SU 21
SU 22
SU 23
SU 10
SU12
SU 16
n/a
PROC 5
PROC 12
PROC 14
PROC 21
AC 3
x
SU 19
n/a
PROC 3
PROC4
PROC 5
PROC 8b
PROC 9
PROC 14
PROC 21
x
SU 5
SU10
SU 18
PC 32
PC 34
AC 5
x
SU 21
SU 22
n/a
PROC 5
PROC 10
PROC 13
PROC 19
PROC 19
x
SU 10
SU11
PC 32
AC 10
x
SU 19
PC 32
PROC 2
PROC 3
PROC4
PROC 10
PROC 14
PROC 21
x
SU 3
SU 10
PC 19
Waste stage
PROC*
x
x
PC 32
PC 0
(B450
0)
PC 32
PROC 2
PROC 6
PROC 8a
PROC 8b
PROC 9
PROC 10
PROC 24c
*SU = Sector of use; PC = Product Category; PROC = Process Category; AC = Article Category
Version 04-03-2013
x
PC*
x
x
ES6b – Use of flexible eslatomeric
foam (FEF) articles
ES7 - Additional formulation use (no
further information available)
x
x
ES5b – Use of textile articles
containing polymer dispersion
SU*
x
x
ES4b – Use of high impact polystyrene
(HIPS) articles
ES5a – Manufacture of polymer
dispersion for textiles and textile
articles
x
x
ES3b - Use of Extruded Polystyrene
(XPS) articles
ES4a – Manufacture of high impact
polystyrene (HIPS) and masterbatch
and manufacture of HIPS articles
Consumer use
x
ES2b – Use of Expanded Polystyrene
(EPS) articles
ES3a - Manufacture of Extruded
polystyrene (XPS) and XPS articles
End use
Formulation
ES number
Service life (for
articles)
Identified
uses
AC 13
AC 3
AC 13
AC 3
AC 5
AC 10
AC 13
2 EC number:
247-148-4
Substance name:
CAS number:
25637-99-4
Exposure Scenario 2a: Manufacture of Expanded Polystyrene (EPS) and EPS articles. The flame retardant, expanded polystyrene (EPS) is manufactured by mixing the registered substance
(HBCDD) with styrene at low temperatures before charging into a reactor and polymerising at reaction
temperature. HBCDD is trapped within the polymer matrix during polymerisation. An expansion agent
is added to the reactor during the reaction and is absorbed by the polymer droplets (or beads).
Manufacture of EPS beads takes place within a closed system with little potential for exposure. EPS
beads can be used on-site to manufacture EPS articles, or can be stored, bagged/packaged and shipped
to an EPS article manufacturer.
Two different life cycle stages are distinguished in the Exposure Scenario: Manufacture of the
expanded polystyrene and manufacture of expanded polystyrene articles.
2a.1. Exposure Scenario: Manufacture of Expanded Polystyrene (EPS) and EPS articles. Title Manufacture of Expanded Polystyrene (EPS) and EPS articles. Sector of use SU 3, 12, 18 Process category Manufacture of EPS: PROC 3, 4 Manufacture of EPS articles: 5, 8b, 9, 14, 21
Product category PC 32 Article category AC 13 Environmental release category Manufacture of Expanded Polystyrene (EPS) -‐ ERC 2, 3 Manufacture of EPS Articles – ERC 5 Specific environmental release category Not available Processes, tasks, activities covered All activities involved in manufacturing EPS and EPS articles.
2a.2. Operational conditions and risk management measures 2a.2.1. Contributing scenario controlling ENVIRONMENTAL EXPOSURE Operational conditions Amounts used Tonnage used at a local scale (tonnes/year)2 Annual site use: 188.88 tonnes, both for manufacturing EPS and EPS articles. Based upon a total annual EU tonnage for this use of 3400 tonnes, 18 use sites and 300 use days per annum Frequency and duration of use Type of release Continuous Emission days (days/year) 300 Site specific monitoring data Environmental release data are available, indicating that release of HBCDD to the environment through manufacture of EPS beads and EPS articles will be very low Other Operational Conditions of use affecting environmental exposure Local freshwater dilution factor
10
2 This is the maximum tonnage that is allowed to be used by the Downsteam User on his site Version 04-03-2013
3 EC number:
247-148-4
Substance name:
CAS number:
25637-99-4
Flow rate of the receiving surface
water (m3/day)
18,000
Indoor/outdoor use of the substance
Indoor
Emission factor water
Manufacture of EPS: 0.02 (ERC 2)
Manufacture of EPS articles: 0.5 (ERC 5)
Emission factor air
Manufacture of EPS: 0.30 (ERC 3)
Emission factor soil
Manufacture of EPS: 0.001 (ERC3)
Risk Management Measures Technical on-‐site conditions and measures to limit or reduce discharges, air emissions and releases to soil EPS manufacture: All manufacturing facilities use an on-‐site STP to clean up waste-‐water. Releases via dust to air must be reduced, by filtering exhaust gases. Manufacture of EPS articles: The main release to soil is through disposal of contaminated packaging to landfill. This release can be reduced or eliminated by sending contaminated packaging to incineration. Emissions to air are minimal, however can be regulated by scrubbing and filtering emission gases (not required) Conditions and measures related to waste water treatment Size of STP (m3/day)
2,000 Degradation potential of the substance Inherently biodegradable
Conditions and measures related to external treatment of waste for disposal EPS manufacture:
Waste water (daily emission: 4.4g/day for both manufacture of EPS and manufacture of EPS articles) can be treated by
on-site or municipal STP. The registered substance is not harmful to sewage micro-organisms and is rapidly degraded in
anaerobic conditions.
Solid waste such as contaminated packaging is expected to be sent to incineration.
Manufacture of EPS articles:
A STP connection rate of 80% is assumed for the total, regional and continental release estimation.
Conditions and measures related to external recovery of waste
Not available, recovery of the registered substance from aqueous and solid wastes is not commercially feasible at the
present time due to the low concentration of the registered substance in waste streams.
2a.2.2. Contributing scenario controlling WORKER EXPOSURE Product characteristics Substance name: HBCDD
TRA dustiness: particle size distribution: 99% < 280µm
Physical property: solid Amounts used Covers percentage substance in the product up to:
EPS manufacture: Substance used as supplied in powder or granule form (i.e. 100%)
Manufacture of EPS articles: 0.7 % Frequency and duration of use/exposure Covers daily exposures up to 8 hours (both scenarios) Other given operational conditions affecting workers exposure Indoor use, both uses Technical conditions and measures at process level (source) to prevent release EPS manufacture:
Substance is loaded into an intermediate storage bin then drawn into a closed formulation process. Water used for
preparation of EPS beads is reused in order to conserve the substance, which maybe present and reduce the amount
released to the environment.
Exposure during tabletting/compression/ extrusion/pellettisation is unlikely due to the low volatility of the substance and
Version 04-03-2013
4 EC number:
247-148-4
Substance name:
CAS number:
25637-99-4
the closed nature of the processes. Any exposure would be negligible during low-energy manipulation of the polymer
article as the substance will be held within the polymer matrix under normal working conditions.
Processing takes place in a closed system; although the preparation is heated, the substance is unlikely to be released to air
due to the low vapour pressure of the substance.
Technical conditions and measures to control dispersion from source towards the worker
EPS manufacture:
Indoors with Local Exhaust Ventilation 90% efficiency (default ecetoc TRA)
Indoors with Local Exhaust Ventilation 90% efficiency (default ecetoc TRA)
Conditions and measures related to personal protection, hygiene and health evaluation
EPS manufacture:
Respiratory protection (90% effectiveness), used continuously wherever exposure is possible.
Additional good practice advice beyond REACH Chemical Safety Assessment
Not available
2a.3. Exposure estimation and reference to its source 2a.3.1. Exposure estimations contributing scenario for ENVIRONMENT Tool used for evaluation EUSES General parameter set State of the substance Solid Biodegradability Inherently biodegradable Exposure estimations Indirect exposure of humans via the environment (calculated with ECETOC TRA) Value unit Local total daily intake for humans, total 7.21E-‐01 [mg.kg-‐1.day-‐1] Local PECs Unit AIR Annual average local PEC in air (total) 8.62E-‐07 [mg.m-‐3] WATER, SEDIMENT Local PEC in surface water during emission episode (dissolved) 4.26E-‐05 [mg.l-‐1] Annual average local PEC in surface water (dissolved) 3.51E-‐05 [mg.l-‐1] Local PEC in fresh-‐water sediment during emission episode 4.21E-‐02 [mg.kgwwt-‐1] Local PEC in seawater during emission episode (dissolved) 2.06E-‐05 [mg.l-‐1] Annual average local PEC in seawater (dissolved) 1.69E-‐05 [mg.l-‐1] Local PEC in marine sediment during emission episode 2.03E-‐02 [mg.kgwwt-‐1] SOIL, GROUNDWATER Local PEC in agric. soil (total) averaged over 30 days 6.39E-‐02 [mg.kgwwt-‐1] Local PEC in agric. soil (total) averaged over 180 days 6.39E-‐02 [mg.kgwwt-‐1] Local PEC in grassland (total) averaged over 180 days 2.52E-‐02 [mg.kgwwt-‐1] Local PEC in groundwater under agricultural soil 7.98E-‐05 [mg.l-‐1] STP PEC for micro-‐organisms in the STP 2.50E-‐01 [mg.l-‐1] Conc in fish for secondary poisoning (freshwater) n.a. [mg.kgwwt-‐1] Conc in earthworms from agricultural soil n.a. [mg.kg-‐1] Conc in fish for secondary poisoning (marine) n.a. [mg.kgwwt-‐1] Conc in fish-‐eating marine top-‐predators n.a. [mg.kgwwt-‐1] Secondary poisoning 2a.3.2. Exposure estimations contributing scenario for WORKERS Tool used for evaluation Version 04-03-2013
ECETOC TRA v2 5 EC number:
247-148-4
Substance name:
CAS number:
25637-99-4
General parameter set Type of setting: Industrial Duration of exposure: > 4hr/day Use of ventilation: Local Exhaust Ventilation 90% efficiency (default ECETOC TRA) Use of respiratory protection: Respiratory protection (90% effectiveness), used continuously wherever possible Use of dermal protection: none Concentration in preparation: > 25% (manufacture of EPS); 0.7% (manufacture of EPS articles) Exposure Estimations PROC
3 4 5 8b 9 14 21 Contributing scenarios Use in closed batch process (synthesis or formulation) Use in batch and other process (synthesis) where opportunity for exposure arises Mixing or blending in batch processes for formulation of preparations and articles (multistage and/or significant contact) Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities Transfer of substance or preparation into small containers (dedicated filling line, including weighing) Production of preparations or articles by tabletting, compression, extrusion, palletisation Low energy manipulation of substances bound in materials and/or articles Predicted Inhalative
Exposure - (mg/m3)
Predicted Dermal
exposure (mg/kg/d)
RMMs, in addition
to those mentioned
in 2a.2.2.
1.00E-‐02 3.43E-‐02 2.50E-‐02 6.86E-‐01 2.50E-‐01 6.86E-‐02 LEV Respiratory protection (90%) LEV Respiratory protection (90%) LEV Respiratory protection (90%) 1.25E-‐01 6.86E-‐01 LEV Respiratory protection (90%) 2.00E-‐01 6.86E-‐01 1.00E-‐01 3.43E-‐01 1.00E-‐01 2.83E-‐01 LEV Respiratory protection (90%) LEV Respiratory protection (90%) LEV Respiratory protection (90%) 2a.4. Guidance to DU to evaluate whether he works inside the boundaries set by the ES 2a.4.1. Guidance to DU to evaluate whether he works inside the boundaries set by contributing scenario for ENVIRONMENTAL EXPOSURE Environmental exposure has been evaluated using the EUSES model. Within the conditions described above, there are no further limitations on the use of the substance in manufacturing of Expanded Polystyrene (EPS) and EPS articles. 2a.4.2. Guidance to DU to evaluate whether he works inside the boundaries set by contributing scenario for WORKER EXPOSURE The workers exposure has been evaluated using ECETOC TRA integrated tool version 2. Evaluate whether you work within the boundaries of the operational conditions and risk management measures described in the tables above. Within those conditions safe use was shown. Should you however not be able to demonstrate compliance with the conditions described above, scaling of the results is possible using the ECETOC TRA model that was run to generate the above assessment. Version 04-03-2013
6 EC number:
247-148-4
Substance name:
CAS number:
25637-99-4
Exposure Scenario 2b: Use of Expanded Polystyrene (EPS) articles. 2b.1. Exposure Scenario: Use of Expanded Polystyrene (EPS) articles. Title Use of Expanded Polystyrene (EPS) articles. Sector of use SU 19, 21, 22, 23 Process category PROC 21
Product category Not available Article category AC 13 Environmental release category ERC 11a, 12a Specific environmental release category Emission factor to air: 3.5E-‐07 Emission factor to soil: 1E-‐04 Emission factors are based on the EU Risk Assessment. Processes, tasks, activities covered All activities involved in the use of expanded Polystyrene (EPS) articles.
2b.2. Operational conditions and risk management measures 2b.2.1. Contributing scenario controlling ENVIRONMENTAL EXPOSURE Operational conditions Amounts used Tonnage used at a local scale (tonnes/year)3 A worst case value of 1 tonne of EPS insulation board is estimated for a single site. The worst case value for the HBCDD concentration in EPS is 0.7% (w/w), therefore a worst case annual use amount per site is 7 kg. Due to the highly disperse use of the compound the environmental assessment was carried out on a regional scale. Frequency and duration of use Type of release Continuous Emission days (days/year) 300 Site specific monitoring data Not available Other Operational Conditions of use affecting environmental exposure Local freshwater dilution factor
10
water (m3/day)
2,000
Indoor and outdoor use
Emission Factor Water
Not applicable
Emission Factor Air
3.5E-07
Emission Factor Soil
1E-04
Risk Management Measures Technical on-‐site conditions and measures to limit or reduce discharges, air emissions and releases to soil Not available 3 This is the maximum tonnage that is allowed to be used by the Downsteam User on his site Version 04-03-2013
7 EC number:
247-148-4
Substance name:
CAS number:
25637-99-4
Conditions and measures related to waste water treatment Size of STP (m3/day)
Conditions and measures related to external treatment of waste for disposal at the end of service life 100% of the EPS insulation board is discarded at the end of the life cycle (~20-50 years). 30-50% of the EPS in insulation
boards is expected to be recycled while 50-70% is expected to go to landfill.
An unknown amount of EPS insulation board is incinerated, either in unregulated burning (example: bonfires at
households or at construction/demolition sites).
Approximately 30-50% of the EPS insulation board is expected to be recycled. No labelling for recovered EPS material is
currently available. Polymer waste streams are expected to be contaminated with HBCDD in low concentrations.
2b.2.2. Contributing scenario controlling WORKER EXPOSURE Product characteristics Substance name: hexabromocyclododecane
TRA dustiness: low
Physical property: solid (encapsulated in articles) Amounts used Covers percentage substance in the product up to 0.7 % Frequency and duration of use/exposure Covers daily exposures up to 8 hours Other given operational conditions affecting workers exposure Indoor and outdoor use Technical conditions and measures at process level (source) to prevent release during service life The substance is bound within the polymer matrix reducing the amount of substance released to the environment.
Conditions and measures at level of article production to prevent release during service life
EPS insulation boards are ‘cured’ for approximately 1 week prior to supply for use. The HBCDD contained within the
EPS insulation board is bound within the polymer matrix and is not expected to be bio-available. The EPS beads make the
EPS insulation board friable during sawing and abrasive cutting, particles produced are not expected to be of an inhalable
size. Any amount of the registered substance within the particles created would be held within the polymer matrix of the
particles and would not be available for exposure.
Human factors not influenced by risk management
Exposure to the registered substance is negligible during installation of EPS articles as the substance will be held within
the polymer matrix. Any residual or settled amount of the registered substance on the surface of the EPS article or any
release during cutting of the EPS article is expected to be negligible as the substance is present at a maximum
concentration of 0.7 % in the EPS beads.
Not available
Due to the size and weight of the EPS particulates formed during cutting and installation of the EPS board (>10μm)
dermal exposure is considered to be the only significant route of exposure from particulates.
Sweep up any particles/beads of EPS created during cutting and dispose of to incineration or landfill.
2b.3. Exposure estimation and reference to its source 2b.3.1. Exposure estimations contributing scenario for ENVIRONMENT Tool used for evaluation EUSES General parameter set State of the substance Solid (encapsulated in articles) Biodegradability Inherently biodegradable Exposure estimations Indirect exposure of humans via the environment (ECETOC TRA) Value Unit total daily intake for humans, total 2.39E-‐4 [mg.kg-‐1.day-‐1] Regional PECs Unit AIR Version 04-03-2013
8 EC number:
247-148-4
Substance name:
CAS number:
25637-99-4
Annual average PEC in air (total) 2.17E-‐11 [mg.m-‐3] WATER, SEDIMENT PEC in surface water during emission episode (dissolved) 1.91E-‐09 [mg.l-‐1] PEC in fresh-‐water sediment during emission episode 3.44E-‐06 [mg.kgwwt-‐1] PEC in seawater during emission episode (dissolved) 2.02E-‐10 [mg.l-‐1] PEC in marine sediment during emission episode 3.70E-‐07 [mg.kgwwt-‐1] SOIL, GROUNDWATER PEC in agric. soil (total) 2.48E-‐07 [mg.kgwwt-‐1] PEC in grassland (total) averaged over 180 days 2.59E-‐07 [mg.kgwwt-‐1] PEC in groundwater under agricultural soil n.a. [mg.l-‐1] STP PEC for micro-‐organisms in the STP (ECETOC TRA ERC 12a) 1690 [mg.l-‐1] Conc in fish for secondary poisoning (freshwater) n.a. [mg.kgwwt-‐1] Conc in earthworms from agricultural soil n.a. [mg.kg-‐1] Conc in fish for secondary poisoning (marine) n.a. [mg.kgwwt-‐1] Conc in fish-‐eating marine top-‐predators n.a. [mg.kgwwt-‐1] Secondary poisoning 2b.3.2. Exposure estimations contributing scenario for WORKERS Tool used for evaluation ECETOC TRA v2 General parameter set Type of setting: Industrial Dustiness: Low Duration of exposure: > 4hr/day Use of ventilation: no Use of respiratory protection: no Use of dermal protection: no Concentration in preparation: 0.7 % Exposure Estimations PROC
21 Contributing scenarios Low energy manipulation of substances bound in materials and/or articles Predicted Inhalative
Exposure - (mg/m3)
Predicted Dermal
exposure (mg/kg/d)
RMMs, in addition
to those mentioned
in section 2b.2.2.
3.00 2.83 None 2b.4. Guidance to DU to evaluate whether he works inside the boundaries set by the ES 2b.4.1. Guidance to DU to evaluate whether he works inside the boundaries set by contributing scenario for ENVIRONMENTAL EXPOSURE Environmental exposure has been evaluated using the EUSES model. Within the conditions described above, there are no further limitations on the use of the substance in Expanded Polystyrene (EPS) articles. 2b.4.2. Guidance to DU to evaluate whether he works inside the boundaries set by contributing scenario for WORKER EXPOSURE The workers exposure has been evaluated using ECETOC TRA integrated tool version 2. Evaluate whether you work within the boundaries of the operational conditions and risk management measures described in the tables above. Within those conditions safe use was shown. Should you however not be able to demonstrate compliance with the conditions described above, scaling of the results is possible using the ECETOC TRA model that was run to generate the above assessment. Version 04-03-2013
9 EC number:
247-148-4
Substance name:
CAS number:
25637-99-4
Exposure Scenario 3a: Manufacture of Extruded Polystyrene (XPS) and XPS articles. HBCDD in powder or granules is mixed into the polymer in a semi-closed or open system, foaming
agents are added and the preparation extruded and cut into granules and packaged for shipping to
article manufacturers. The manufacture of XPS articles involves the foaming of the polymer
preparations in semi-closed or open systems, followed by extrusion, cutting and shaping of the
resulting polymer foam to the desired shape. XPS articles (mainly in the form of boards) are packed
onto pallets and cured for 1 week prior to shipping. This exposure scenario covers both the
manufacturing of the extruded polystyrene and manufacturing the articles.
3a.1. Exposure Scenario: Manufacture of Extruded Polystyrene (XPS) and XPS articles. Title Manufacture of Extruded Polystyrene (XPS) and XPS articles. Sector of use SU 12 Process category Manufacture XPS: PROC 5,14
Manufacture XPS articles: PROC 12, 14
Product category PC 32 Article category AC 3, 13 Environmental release category Manufacturing XPS: ERC 2, 3 Manufacturing XPS articles: ERC 5 Specific environmental release category Not available Processes, tasks, activities covered All activities involved in manufacturing XPS and XPS articles.
3a.2. Operational conditions and risk management measures 3a.2.1. Contributing scenario controlling ENVIRONMENTAL EXPOSURE Operational conditions Amounts used Tonnage used at a local scale (tonnes/year)4 Annual use per site: 123.6 tonnes, based on a total annual EU tonnage use 1730 / number of use sites (14). Both for manufacturing XPS and manufacturing XPS articles Frequency and duration of use Type of release Continuous Emission days (days/year) 300 Site specific monitoring data Not available Other Operational Conditions of use affecting environmental exposure Local freshwater dilution factor
10
water (m3/day)
18,000
Indoor use of substance in partially open system (open during loading and
extrusion).
10 EC number:
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Substance name:
CAS number:
25637-99-4
Manufacturing XPS: 0.02 (ERC 2)
Manufacturing XPS articles: 0.50 (ERC 5)
Emission Factor Air
Risk Management Measures Technical on-‐site conditions and measures to limit or reduce discharges, air emissions and releases to soil XPS manufacture: Not available Manufacture of XPS articles: Waste generated by the foaming and trimming processes is recycled back into the process. Conditions and measures related to waste water treatment Size of STP (m3/day)
Conditions and measures related to external treatment of waste for disposal A waste water must be directed to a municipal waste water treatment plant.
Not available
3a.2.2. Contributing scenario controlling WORKER EXPOSURE Product characteristics Substance name: hexabromocyclododecane
Physical property: solid Amounts used XPS manufacture:
Covers percentage substance in the product up to 100 %
Manufacture of XPS articles:
Frequency and duration of use/exposure Covers daily exposures up to 8 hours Other given operational conditions affecting workers exposure Indoor use Technical conditions and measures at process level (source) to prevent release XPS manufacture:
Bags or supersacks are loaded into hopper designed to minimise dust emissions. The substance is then drawn into a closed
system for mixing with polystyrene and extruded.
XPS containing HBCDD or mixed with HBCDD during the melting and mixing process is further mixed with foaming or
blowing agents to form a foam which can be extruded and cut to its final shape. The XPS board is cured for approximately
1 week prior to shipping and use.
XPS manufacture:
Local Exhaust Ventilation 90% efficiency (default ECETOC TRA)
Local Exhaust Ventilation 90% efficiency (default ECETOC TRA)
XPS manufacture:
Version 04-03-2013
11 EC number:
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Substance name:
CAS number:
25637-99-4
Not available
3a.3. Exposure estimation and reference to its source 3a.3.1. Exposure estimations contributing scenario for ENVIRONMENT Tool used for evaluation EUSES General parameter set State of the substance Solid Biodegradability Inherently biodegradable Exposure estimations Indirect exposure of humans via the environment Value unit Local total daily intake for humans, total 1.06E-‐04 [mg.kg-‐1.day-‐1] Local PECs Unit AIR Annual average local PEC in air (total) 5.65E-‐07 [mg.m-‐3] WATER, SEDIMENT Local PEC in surface water during emission episode (dissolved) 2.79E-‐05 [mg.l-‐1] Annual average local PEC in surface water (dissolved) 2.29E-‐05 [mg.l-‐1] Local PEC in fresh-‐water sediment during emission episode 2.75E-‐02 [mg.kgwwt-‐1] Local PEC in seawater during emission episode (dissolved) 1.35E-‐05 [mg.l-‐1] Annual average local PEC in seawater (dissolved) 1.11E-‐05 [mg.l-‐1] Local PEC in marine sediment during emission episode 1.33E-‐02 [mg.kgwwt-‐1] SOIL, GROUNDWATER Local PEC in agric. soil (total) averaged over 30 days 4.18E-‐02 [mg.kgwwt-‐1] Local PEC in agric. soil (total) averaged over 180 days 4.18E-‐02 [mg.kgwwt-‐1] Local PEC in grassland (total) averaged over 180 days 1.65E-‐02 [mg.kgwwt-‐1] Local PEC in groundwater under agricultural soil 5.22E-‐05 [mg.l-‐1] STP PEC for micro-‐organisms in the STP 2.98E-‐04 [mg.l-‐1] Conc in fish for secondary poisoning (freshwater) n.a. [mg.kgwwt-‐1] Conc in earthworms from agricultural soil n.a. [mg.kg-‐1] Conc in fish for secondary poisoning (marine) n.a. [mg.kgwwt-‐1] Conc in fish-‐eating marine top-‐predators n.a. [mg.kgwwt-‐1] Secondary poisoning 3.2. Exposure estimations contributing scenario for WORKERS Tool used for evaluation ECETOC TRA v2 General parameter set Type of setting: Industrial Duration of exposure: > 4hr/day Use of ventilation: Local Exhaust Ventilation 90% efficiency (default ECETOC TRA) Use of individual respiratory protection: Respiratory protection (90% effectiveness), used wherever exposure is possible Use of dermal protection: none Concentration in preparation: > 25% Exposure Estimations PROC
5 Contributing scenarios Mixing or blending in batch processes for formulation of preparations and articles (multistage and/or significant contact) Version 04-03-2013
Predicted Inhalative
Exposure - (mg/m3)
Predicted Dermal
exposure (mg/kg/d)
RMMs, in addition
to those listed in
section 3a.2.2.
5.00E-‐03 6.86E-‐02 LEV Respiratory protection 12 EC number:
247-148-4
Substance name:
CAS number:
25637-99-4
12 Use of blowing agents in manufacture of foam 14 Production of preparations or articles by tabletting, compression, extrusion, palletisation 3.21E-‐02 3.43E-‐02 1.00E-‐03 3.41E-‐01 LEV Respiratory protection LEV Respiratory protection 3a.4. Guidance to DU to evaluate whether he works inside the boundaries set by the ES 3a.4.1. Guidance to DU to evaluate whether he works inside the boundaries set by contributing scenario for ENVIRONMENTAL EXPOSURE Environmental exposure has been evaluated using the EUSES model. Within the conditions described above, there are no further limitations on the use of the substance in the manufacture of Extruded Polystyrene (XPS) and XPS articles. 3a.4.2. Guidance to DU to evaluate whether he works inside the boundaries set by contributing scenario for WORKER EXPOSURE The workers exposure has been evaluated using ECETOC TRA integrated tool version 2. Evaluate whether you work within the boundaries of the operational conditions and risk management measures described in the tables above. Within those conditions safe use was shown. Should you however not be able to demonstrate compliance with the conditions described above, scaling of the results is possible using the ECETOC TRA model that was run to generate the above assessment. Version 04-03-2013
13 EC number:
247-148-4
Substance name:
CAS number:
25637-99-4
Exposure Scenario 3b: Use of Extruded Polystyrene (XPS) articles. 3b.1. Exposure Scenario: Use of Extruded Polystyrene (XPS) articles. Title Use of Extruded Polystyrene (XPS) articles. Sector of use SU 19, 21, 22, 23 Process category PROC 21
Product category Not available Article category Not available Environmental release category ERC 11a, 12a Specific environmental release category Not available Processes, tasks, activities covered All activities involved in the use of Extruded Polystyrene (XPS) articles.
3b.2. Operational conditions and risk management measures 3b.2.1. Contributing scenario controlling ENVIRONMENTAL EXPOSURE Operational conditions Amounts used Tonnage used at a local scale (tonnes/year)5 A worst case value of 1 tonne of XPS is expected to be cut by workers per site per day (300 tonnes/year). The worst-‐case concentration of the registered substance in XPS is 3% therefore a worst-‐case daily site use of 30 kg/day (or 900 kg/year) is expected. Since the use is widely dispersive in nature, the environmental assessment is based on regional concentrations Frequency and duration of use Type of release Continuous Emission days (days/year) 300 Site specific monitoring data Not available Other Operational Conditions of use affecting environmental exposure Local freshwater dilution factor
10
water (m3/day)
18,000
Indoor and outdoor
0.025
Emission Factor Air
0.025
0.025
Risk Management Measures Technical measures at the production level to limit or reduce discharges during service life Many of the construction articles that are made of XPS do not require any trimming or cutting during installation, 5 This is the tonnage that is maximally allowed to be used by the Downsteam User on his site Version 04-03-2013
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Substance name:
CAS number:
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and so reduce overall waste and emissions to the environment. Conditions and measures related to waste water treatment Size of STP (m3/day)
Conditions and measures related to external treatment of waste for disposal A sewage treatment plant is considered to be in place
Not available
TRA dustiness: low
Physical property: solid Amounts used Covers percentage substance in the product up to 3 % (realistic worst case) Frequency and duration of use/exposure Covers daily exposures up to 8 hours Other given operational conditions affecting workers exposure Indoor and outdoor use Technical conditions and measures at article production level (source) to prevent release during service life The substance is bound within the polymer matrix and will not be released. The XPS boards are cured for approximately 1
week prior to shipping and use.
Not available
Not available
Not available
3b.3. Exposure estimation and reference to its source 3b.3.1. Exposure estimations contributing scenario for ENVIRONMENT Tool used for evaluation EUSES General parameter set State of the substance solid Biodegradability Inherently biodegradable Exposure estimations Indirect exposure of humans via the environment Value unit Total daily intake for humans (ECETOC TRA) 1.22E-‐04 [mg.kg-‐1.day-‐1] Regional PECs Unit AIR Annual average PEC in air (total) 1.22E-‐12 [mg.m-‐3] WATER, SEDIMENT PEC in surface water during emission episode (dissolved) 1.36E-‐10 [mg.l-‐1] PEC in fresh-‐water sediment during emission episode 2.46E-‐07 [mg.kgwwt-‐1] PEC in seawater during emission episode (dissolved) 1.31E-‐11 [mg.l-‐1] PEC in marine sediment during emission episode 2.59E-‐08 [mg.kgwwt-‐1] SOIL, GROUNDWATER PEC in agric. soil (total) 1.39E-‐08 [mg.kgwwt-‐1] PEC in grassland (total) averaged over 180 days 1.46E-‐08 [mg.kgwwt-‐1] PEC in groundwater under agricultural soil n.a. [mg.l-‐1] Version 04-03-2013
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STP PEC for micro-‐organisms in the STP (ECETOC TRA, ERC 11a) 859 [mg.l-‐1] Conc in fish for secondary poisoning (freshwater) n.a. [mg.kgwwt-‐1] Conc in earthworms from agricultural soil n.a. [mg.kg-‐1] Conc in fish for secondary poisoning (marine) n.a. [mg.kgwwt-‐1] Conc in fish-‐eating marine top-‐predators n.a. [mg.kgwwt-‐1] Secondary poisoning 3b.3.2. Exposure estimations contributing scenario for WORKERS Tool used for evaluation ECETOC TRA v2 General parameter set Type of setting: Industrial Dustiness: Low (exposure is to cut off waste, which high particle sizes) Duration of exposure: > 4hr/day Use of ventilation: no Use of respiratory protection: no Use of dermal protection: no Concentration in preparation: 3 % Exposure Estimations PROC
Exposure - (mg/m3)
Predicted Dermal
exposure (mg/kg/d)
RMMs
3.00E-‐03 2.83E-‐03 none 3b.4. Guidance to DU to evaluate whether he works inside the boundaries set by the ES 3b.4.1. Guidance to DU to evaluate whether he works inside the boundaries set by contributing scenario for ENVIRONMENTAL EXPOSURE Environmental exposure has been evaluated using the EUSES model. Within the conditions described above, there are no further limitations on the use of the substance in Extruded Polystyrene (XPS) articles. 3b.4.2. Guidance to DU to evaluate whether he works inside the boundaries set by contributing scenario for WORKER EXPOSURE The workers exposure has been evaluated using ECETOC TRA integrated tool version 2. Evaluate whether you work within the boundaries of the operational conditions and risk management measures described in the tables above. Within those conditions safe use was shown. Should you however not be able to demonstrate compliance with the conditions described above, scaling of the results is possible using the ECETOC TRA model that was run to generate the above assessment. Version 04-03-2013
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Substance name:
CAS number:
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Exposure Scenario 4a: Manufacture of High Impact Polystyrene (HIPS) and masterbatch and manufacture of HIPS articles High Impact Polystyrene (HIPS) can be manufactured either by the mixing of HBCDD into the
polystyrene at the desired formulation or in higher concentrations to create a “masterbatch” which can
then be blended with ‘virgin’ polystyrene to create HIPS with the desired concentration of the
registered substance.
HIPS articles are manufactured by extrusion, moulding and/or cutting/shaping to form the desired
shape.
This exposure scenario covers both the actual manufacturing of HIPS and the manufacturing of HIPS
articles.
4a.1. Exposure Scenario: Manufacture of High Impact Polystyrene (HIPS) and masterbatch and manufacture of HIPS articles Title Manufacture of High Impact Polystyrene (HIPS) and masterbatch and manufacture of HIPS articles Sector of use SU 10, 12, 16 Process category HIPS manufacture and masterbatch
PROC 3, 4, 5, 8b, 9
Manufacture of HIPS articles
PROC 5, 8b, 14
Product category PC 32 Article category AC 3 Environmental release category HIPS manufacture and masterbatch ERC 2, 3 Manufacture of HIPS articles ERC 5 Specific environmental release category Not available Processes, tasks, activities covered All activities involved in manufacturing High Impact Polystyrene (HIPS) and
masterbatch and HIPS articles
4a.2. Operational conditions and risk management measures 4a.2.1. Contributing scenario controlling ENVIRONMENTAL EXPOSURE Operational conditions Amounts used Tonnage used at a local scale (tonnes/year)6 Annual use per site = 250 tonnes/year Frequency and duration of use Type of release Continuous Emission days (days/year) 300 Site specific monitoring data 6 This is the maximum tonnage that is allowed to be used by the Downsteam User on his site Version 04-03-2013
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Substance name:
CAS number:
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Measured data for environmental exposure is available which shows that emissions from all uses of the registered substance across the entire EU area are very low (VECAP, 2010). Other Operational Conditions of use affecting environmental exposure Local freshwater dilution factor
10
water (m3/day)
18,000
Indoor. Where applicable mixing of HIPS with masterbatch takes place in a closed
system. Manufacture of HIPS articles takes place in closed systems.
HIPS manufacture and masterbatch: 0.02 (ERC 2)
Manufacture of HIPS articles: 0.50 (ERC 5)
Emission Factor Air
Risk Management Measures Technical on-‐site conditions and measures to limit or reduce discharges, air emissions and releases to soil HIPS manufacture: An on-‐site STP is indicated by some users, if an on-‐site STP is not in use a municipal STP must be used. Releases via dust to air are reduced by filtering exhaust gases (Size and effectiveness of filter not determined). Manufacture of HIPS articles: HIPS articles are designed specifically not to be drilled, cut or otherwise modified. Conditions and measures related to waste water treatment Size of STP (m3/day)
Conditions and measures related to external treatment of waste for disposal Not available
Not available
Physical property: solid Amounts used Substance contained at ca. 7% (w/w) in HIPS and at higher yet unspecified concentrations in masterbatch. Frequency and duration of use/exposure Covers daily exposures up to 8 hours Other given operational conditions affecting workers exposure Indoor use Technical conditions and measures at process level (source) to prevent release HIPS manufacture and masterbatch:
Formulation of preparations and blending operations are expected to be carried out in semi-‐closed or open systems.
Closed process for metering and compounding at high temperature.
Manufacture of HIPS articles:
Reformulation and manufacture (heating, mixing and moulding) takes place in closed systems.
HIPS manufacture and masterbatch:
Local Exhaust Ventilation (LEV) 90% efficiency (default ECETOC TRA)
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Local Exhaust Ventilation (LEV) 90% efficiency (default ECETOC TRA)
HIPS manufacture and masterbatch:
Not available
4a.3. Exposure estimation and reference to its source 4a.3.1. Exposure estimations contributing scenario for ENVIRONMENT Tool used for evaluation EUSES General parameter set State of the substance Solid Biodegradability Inherently biodegradable Exposure estimations Indirect exposure of humans via the environment Value unit Local total daily intake for humans, total (ECETOC TRA) 6.10E-‐05 [mg.kg-‐1.day-‐1] Local PECs Unit AIR Annual average local PEC in air (total) 3.27E-‐07 [mg.m-‐3] WATER, SEDIMENT Local PEC in surface water during emission episode (dissolved) 1.65E-‐05 [mg.l-‐1] Annual average local PEC in surface water (dissolved) 1.35E-‐05 [mg.l-‐1] Local PEC in fresh-‐water sediment during emission episode 1.62E-‐02 [mg.kgwwt-‐1] Local PEC in seawater during emission episode (dissolved) 7.96E-‐06 [mg.l-‐1] Annual average local PEC in seawater (dissolved) 6.54E-‐06 [mg.l-‐1] Local PEC in marine sediment during emission episode 7.86E-‐03 [mg.kgwwt-‐1] SOIL, GROUNDWATER Local PEC in agric. soil (total) averaged over 30 days 2.47E-‐02 [mg.kgwwt-‐1] Local PEC in agric. soil (total) averaged over 180 days 2.47E-‐02 [mg.kgwwt-‐1] Local PEC in grassland (total) averaged over 180 days 9.74E-‐03 [mg.kgwwt-‐1] Local PEC in groundwater under agricultural soil 3.08E-‐05 [mg.l-‐1] STP PEC for micro-‐organisms in the STP 1.76E-‐04 [mg.l-‐1] Conc in fish for secondary poisoning (freshwater) n.a. [mg.kgwwt-‐1] Conc in earthworms from agricultural soil n.a. [mg.kg-‐1] Conc in fish for secondary poisoning (marine) n.a. [mg.kgwwt-‐1] Conc in fish-‐eating marine top-‐predators n.a. [mg.kgwwt-‐1] Secondary poisoning 4a.3.2. Exposure estimations contributing scenario for WORKERS Tool used for evaluation ECETOC TRA v2 General parameter set Type of setting: Industrial Duration of exposure: > 4hr/day Use of ventilation: Local Exhaust Ventilation (90% efficiency, default ECETOC TRA) Use of respiratory protection: Respiratory protection (90% effectiveness), used wherever exposure is possible Use of dermal protection: no Concentration in preparation: < 25% Version 04-03-2013
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Exposure Estimations PROC
3 4 5 8b 9 14 Contributing scenarios Use in closed batch process (synthesis or formulation) Use in batch and other process (synthesis) where opportunity for exposure arises Mixing or blending in batch processes for formulation of preparations and articles (multistage and/or significant contact) Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities Transfer of substance or preparation into small containers (dedicated filling line, including weighing) Production of preparations or articles by tabletting, compression, extrusion, palletisation Predicted Inhalative
Exposure - (mg/m3)
Predicted Dermal
exposure (mg/kg/d)
RMMs, in addition
to those listed in
section 4a.2.2.
1.00E-‐02 3.43E-‐02 2.50E-‐01 6.86E-‐01 2.50E-‐01 6.86E-‐02 LEV Respiratory protection LEV Respiratory protection LEV Respiratory protection 1.25E-‐01 6.86E-‐01 LEV Respiratory protection 2.00E-‐01 6.86E-‐01 1.00E-‐01 3.43E-‐01 LEV Respiratory protection LEV Respiratory protection 4a.4. Guidance to DU to evaluate whether he works inside the boundaries set by the ES 4a.4.1. Guidance to DU to evaluate whether he works inside the boundaries set by contributing scenario for ENVIRONMENTAL EXPOSURE Environmental exposure has been evaluated using the EUSES model. Within the conditions described above, there are no further limitations on the use of the substance in manufacturing High Impact Polystyrene (HIPS) and masterbatch and manufacture of HIPS articles 4a.4.2. Guidance to DU to evaluate whether he works inside the boundaries set by contributing scenario for WORKER EXPOSURE The workers exposure has been evaluated using ECETOC TRA integrated tool version 2. Evaluate whether you work within the boundaries of the operational conditions and risk management measures described in the tables above. Within those conditions safe use was shown. Should you however not be able to demonstrate compliance with the conditions described above, scaling of the results is possible using the ECETOC TRA model that was run to generate the above assessment. Version 04-03-2013
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Substance name:
CAS number:
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Exposure Scenario 4b: Use of High Impact Polystyrene (HIPS) articles. 4b.1. Exposure Scenario: Use of High Impact Polystyrene (HIPS) articles. Title Use of High Impact Polystyrene (HIPS) articles. Sector of use SU 19 Process category PROC 21
Product category Not available Article category AC 3 Environmental release category ERC 11a, 12a Specific environmental release category Not available Processes, tasks, activities covered Use of High Impact Polystyrene (HIPS) articles.
4b.2. Operational conditions and risk management measures 4b.2.1. Contributing scenario controlling ENVIRONMENTAL EXPOSURE Operational conditions Amounts used Tonnage used at a local scale (tonnes/year)7 Annual tonnage 1000 tonnes/year is used as realistic worst-‐case value. The article is not expected to be processed at the site apart from assembly of moulded parts and installation. HIPS articles are expected to be small and contain HBCDD at a maximum concentration of 7%. As the use is wide dispersive the environmental assessment is based on a regional scale. Fraction of main local source 0.15 Frequency and duration of use Type of release Continuous Emission days (days/year) 300 Site specific monitoring data Not available Other Operational Conditions of use affecting environmental exposure Local freshwater dilution factor
10
water (m3/day)
18,000
Indoor use
0.025
Emission Factor Air
0.025
0.025
Risk Management Measures Technical on-‐site conditions and measures to limit or reduce discharges, air emissions and releases to soil 7 This is the maximum tonnage that is allowed to be used by the Downsteam User on his site Version 04-03-2013
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Substance name:
CAS number:
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Not available Conditions and measures related to waste water treatment Size of STP (m3/day)
Conditions and measures related to external treatment of waste for disposal All waste water must be directed to an STP
Not available
TRA dustiness: low
Physical property: solid Amounts used Covers percentage substance in the product up to 7 % Frequency and duration of use/exposure Covers daily exposures up to 8 hours Other given operational conditions affecting workers exposure Indoor use Technical measures at the article production level (source) to prevent release during service life HIPS articles are designed for use without, drilling, cutting or other modification. The substance is bound within the polymer matrix and is not released. No containment is necessary to limit exposure as the substance cannot be released from the polymer matrix under normal
working conditions.
No engineering controls required as there is no exposure from use of the article under normal working conditions.
No personal protective equipment PPE required as there is no expected exposure from use of the article under normal
working conditions.
Not available
4b.3. Exposure estimation and reference to its source 4b.3.1. Exposure estimations contributing scenario for ENVIRONMENT Tool used for evaluation EUSES General parameter set State of the substance Solid (encapsulated in articles) Biodegradability Inherently biodegradable Exposure estimations Indirect exposure of humans via the environment Value unit Local total daily intake for humans, total (ECETOC TRA) 7.02E-‐05 [mg.kg-‐1.day-‐1] Regional PECs Unit AIR Annual average PEC in air (total) 2.5E-‐15 [mg.m-‐3] WATER, SEDIMENT PEC in surface water during emission episode (dissolved) 1.35E-‐14 [mg.l-‐1] PEC in fresh-‐water sediment during emission episode 2.63E-‐11 [mg.kgwwt-‐1] PEC in seawater during emission episode (dissolved) 3.49E-‐15 [mg.l-‐1] PEC in marine sediment during emission episode 6.62E-‐12 [mg.kgwwt-‐1] SOIL, GROUNDWATER PEC in agric. soil (total) 2.88E-‐11 [mg.kgwwt-‐1] Version 04-03-2013
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Substance name:
CAS number:
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PEC in grassland (total) averaged over 180 days 3.01E-‐11 [mg.kgwwt-‐1] PEC in groundwater under agricultural soil n.a. [mg.l-‐1] STP PEC for micro-‐organisms in the STP (ECETOC TRA, ERC 12a) 497 [mg.l-‐1] Conc in fish for secondary poisoning (freshwater) n.a. [mg.kgwwt-‐1] Conc in earthworms from agricultural soil n.a. [mg.kg-‐1] Conc in fish for secondary poisoning (marine) n.a. [mg.kgwwt-‐1] Conc in fish-‐eating marine top-‐predators n.a. [mg.kgwwt-‐1] Secondary poisoning 4b.3.2. Exposure estimations contributing scenario for WORKERS Tool used for evaluation ECETOC TRA v2 General parameter set Type of setting: Industrial Dustiness: Low Duration of exposure: > 4hr/day Use of ventilation: no Use of respiratory protection: no Use of dermal protection: no Concentration in preparation: < 25 % Exposure Estimations PROC
Exposure - (mg/m3)
Predicted Dermal
exposure (mg/kg/d)
RMMs
3.00 2.83 No 4b.4. Guidance to DU to evaluate whether he works inside the boundaries set by the ES 4b.4.1. Guidance to DU to evaluate whether he works inside the boundaries set by contributing scenario for ENVIRONMENTAL EXPOSURE Environmental exposure has been evaluated using the EUSES model. Within the conditions described above, there are no further limitations on the use of the substance in High Impact Polystyrene (HIPS) articles. 4b.4.2. Guidance to DU to evaluate whether he works inside the boundaries set by contributing scenario for WORKER EXPOSURE The workers exposure has been evaluated using ECETOC TRA integrated tool version 2. Evaluate whether you work within the boundaries of the operational conditions and risk management measures described in the tables above. Within those conditions safe use was shown. Should you however not be able to demonstrate compliance with the conditions described above, scaling of the results is possible using the ECETOC TRA model that was run to generate the above assessment. Version 04-03-2013
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Substance name:
CAS number:
25637-99-4
Exposure Scenario 5a: Manufacture of Polymer dispersion for textiles and textile articles. The polymer based back coating is formulated in the polymer industry for supply to textiles and
furniture manufacturers. HBCDD is formulated in an open batch system by mixing the fine powder of
the registered substance into a dispersion of the polymer in water (commonly synthetic latex, acrylates
or PVC) together with thickeners and dispersion agents. The polymer dispersion is then supplied to
textile or furniture manufacturers for use as a back coating.
This scenario covers both the manufacturing of polymer dispersion for textiles and the manufacturing
of textile articles.
5a.1. Exposure Scenario: Manufacture of Polymer dispersion for textiles and textile articles. Title Manufacture of Polymer dispersion for textiles and textile articles. Sector of use SU 5, 10, 18 Process category Manufacture of polymer dispersion for textiles
PROC 5
Manufacture of textile articles
PROC 10, 13, 19
Product category PC 32, 34 Article category AC 5 Environmental release category Manufacture of polymer dispersion for textiles
ERC 2
Manufacture of textile articles
ERC 5 Specific environmental release category Not available Processes, tasks, activities covered All activities involved in the manufacturing of polymer dispersion for textiles and
textile articles.
5a.2. Operational conditions and risk management measures 5a.2.1. Contributing scenario controlling ENVIRONMENTAL EXPOSURE Operational conditions Amounts used Tonnage used at a local scale (tonnes/year)8 65.6 tonnes/year Frequency and duration of use Type of release Continuous Emission days (days/year) 300 Site specific monitoring data Not available Other Operational Conditions of use affecting environmental exposure Local freshwater dilution factor
10
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CAS number:
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water (m3/day)
18,000
Indoor
Manufacture of polymer dispersion for textiles, 0.02 (ERC 2)
Manufacture of textile articles: 0.50 (ERC 5)
Emission Factor Air
Manufacture of polymer dispersion for textiles: 0.025 (ERC 2)
Manufacture of polymer dispersion for textiles: 0.0001 (ERC 2)
Risk Management Measures Technical on-‐site conditions and measures to limit or reduce discharges, air emissions and releases to soil Manufacture of polymer dispersion for textiles Not available Manufacture of textiles Solid waste including sludge from on-‐site STPs at textile backcoaters is either incinerated or put on controlled landfills, due to the potential of heavy metal contamination. Conditions and measures related to waste water treatment Size of STP (m3/day)
Not available
5a.2.2. Contributing scenario controlling WORKER EXPOSURE Product characteristics Substance name: Hexabromocyclododecane
TRA dustiness: high
Physical property: solid Amounts used Manufacture of polymer dispersion for textiles:
Manufacture of textile articles:
Covers percentage substance in the product up to 25 % Frequency and duration of use/exposure Covers daily exposures up to 8 hours Other given operational conditions affecting workers exposure Indoor use Technical conditions and measures at process level (source) to prevent release Not available
Manufacture of polymer dispersion for textiles:
Local Exhaust Ventilation (LEV), 90% efficiency (default ECETOC TRA)
Manufacture of polymer dispersion for textiles:
respiratory protection (90% effectiveness)
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respiratory protection (90% effectiveness)
Not available
5a.3. Exposure estimation and reference to its source 5a.3.1. Exposure estimations contributing scenario for ENVIRONMENT Tool used for evaluation EUSES General parameter set State of the substance solid Biodegradability Inherently biodegradable Exposure estimations Indirect exposure of humans via the environment Value unit Local total daily intake for humans, total (ECETOC TRA) 5.2E-‐05 [mg.kg-‐1.day-‐1] Local PECs Unit AIR Annual average local PEC in air (total) 3.02E-‐07 [mg.m-‐3] WATER, SEDIMENT Local PEC in surface water during emission episode (dissolved) 1.48E-‐05 [mg.l-‐1] Annual average local PEC in surface water (dissolved) 1.22E-‐05 [mg.l-‐1] Local PEC in fresh-‐water sediment during emission episode 1.46E-‐02 [mg.kgwwt-‐1] Local PEC in seawater during emission episode (dissolved) 7.16E-‐06 [mg.l-‐1] Annual average local PEC in seawater (dissolved) 5.89E-‐06 [mg.l-‐1] Local PEC in marine sediment during emission episode 7.07E-‐03 [mg.kgwwt-‐1] SOIL, GROUNDWATER Local PEC in agric. soil (total) averaged over 30 days 2.22E-‐02 [mg.kgwwt-‐1] Local PEC in agric. soil (total) averaged over 180 days 2.22E-‐02 [mg.kgwwt-‐1] Local PEC in grassland (total) averaged over 180 days 8.77E-‐03 [mg.kgwwt-‐1] Local PEC in groundwater under agricultural soil 2.77E-‐05 [mg.l-‐1] STP PEC for micro-‐organisms in the STP 1.58E-‐04 [mg.l-‐1] Conc in fish for secondary poisoning (freshwater) n.a. [mg.kgwwt-‐1] Conc in earthworms from agricultural soil n.a. [mg.kg-‐1] Conc in fish for secondary poisoning (marine) n.a. [mg.kgwwt-‐1] Conc in fish-‐eating marine top-‐predators n.a. [mg.kgwwt-‐1] Secondary poisoning 5a.3.2. Exposure estimations contributing scenario for WORKERS Tool used for evaluation ECETOC TRA v2 General parameter set Type of setting: Industrial Dustiness: high Duration of exposure: > 4hr/day Use of ventilation: yes, local exhaust ventilation (90% efficiency default ECETOC TRA) Use of respiratory protection: yes, 90 % effectiveness Use of dermal protection: no Concentration in preparation: > 25% manufacturing polymer, < 25% manufacture textiles Exposure Estimations Version 04-03-2013
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Substance name:
CAS number:
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PROC
Contributing scenarios 5 Mixing or blending in batch processes for formulation of preparations and articles (multistage and/or significant contact) 10 Roller application or brushing 13 Treatment of articles by dipping and pouring 19 Hand-‐mixing with intimate contact and only PPE available Predicted Inhalative
Exposure - (mg/m3)
Predicted Dermal
exposure (mg/kg/d)
RMMs, in addition
to those listed in
section 5a.2.2.
2.50E-‐01 6.86E-‐02 LEV Respiratory protection 1.00E-‐01 1.37 1.60E-‐02 6.86E-‐01 2.50E-‐01 1.41E+01 LEV Respiratory protection LEV Respiratory protection LEV Respiratory protection 5a.4. Guidance to DU to evaluate whether he works inside the boundaries set by the ES 5a.4.1. Guidance to DU to evaluate whether he works inside the boundaries set by contributing scenario for ENVIRONMENTAL EXPOSURE Environmental exposure has been evaluated using the EUSES model. Within the conditions described above, there are no further limitations on the use of the substance in the manufacturing of Polymer dispersion for textiles and textile articles. 5a.4.2. Guidance to DU to evaluate whether he works inside the boundaries set by contributing scenario for WORKER EXPOSURE The workers exposure has been evaluated using ECETOC TRA integrated tool version 2. Evaluate whether you work within the boundaries of the operational conditions and risk management measures described in the tables above. Within those conditions safe use was shown. Should you however not be able to demonstrate compliance with the conditions described above, scaling of the results is possible using the ECETOC TRA model that was run to generate the above assessment. Version 04-03-2013
27 EC number:
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Substance name:
CAS number:
25637-99-4
Exposure Scenario 5b: Use of textile articles containing polymer dispersion. 5b.1. Exposure Scenario: Use of textile articles containing polymer dispersion. Title Use of textile articles containing polymer dispersion. Sector of use SU 21, 22 Process category PROC 19
Product category Not available Article category AC 5 Environmental release category ERC 11, 12 Specific environmental release category Not available Processes, tasks, activities covered Use of textile articles containing polymer dispersion.
5b.2. Operational conditions and risk management measures 5b.2.1. Contributing scenario controlling ENVIRONMENTAL EXPOSURE Operational conditions Amounts used Tonnage used at a local scale (tonnes/year)9 0.268 tonnes/year (EU risk assessment) Frequency and duration of use Type of release Continuous Environmental exposure may be possible through both particulate releases and through washing. The registered substance will be bound within the polymer matrix which is coated to the back of the textiles and incorporated into the inside of the textile articles. Emission days (days/year) 365 Site specific monitoring data Not available Other Operational Conditions of use affecting environmental exposure Local freshwater dilution factor
10
water (m3/day)
18,000
Indoor use
5E-06 (environmental exposure is dominated by emissions through washing)
Emission Factor Air
Negligible
Negligible
Risk Management Measures 9 This is the maximum tonnage that is allowed to be used by the Downsteam User on his site Version 04-03-2013
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Substance name:
CAS number:
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Technical on-‐site conditions and measures to limit or reduce discharges, air emissions and releases to soil Not available Conditions and measures related to waste water treatment Size of STP (m3/day)
Conditions and measures related to external treatment of waste for disposal It is assumed that during service life 80% of emissions to waste water will be directed to an STP. During washing all
waste water is directed to an STP.
Solid waste after service life will be sent to a landfill.
Not available
5b.2.2. Contributing scenario controlling HUMAN EXPOSURE Product characteristics Substance name: hexabromocyclododecane
TRA dustiness: low
Physical property: solid Amounts used Covers percentage substance in the product up to 7.7 % (As the primary use of the textiles treated with the back coating is
upholstery for furniture and automotive seats the 7.7 w.t-% concentration is considered to represent a worst case value for
fabrics). Frequency and duration of use/exposure Covers daily exposures up to 8 hours for workers Covers daily exposures up to 8 hours for consumers Other given operational conditions affecting human exposure Indoor use, human exposure is expected only through textile particulates released during abrasive wear, such exposure is expected to be negligible Technical measures at the article production level (source) to prevent release during service life Not available
Not available
No personal protective equipment (PPE) required.
Not available
5b.3. Exposure estimation and reference to its source 5b.3.1. Exposure estimations contributing scenario for ENVIRONMENT Tool used for evaluation EUSES General parameter set State of the substance Solid (encapsulated in articles) Biodegradability Inherently biodegradable Exposure estimations Indirect exposure of humans via the environment Value unit Local total daily intake for humans, total (ECETOC TRA) 7.4E-‐05 [mg.kg-‐1.day-‐1] Local PECs Unit AIR Annual average PEC in air (total) 1.09E-‐09 [mg.m-‐3] WATER, SEDIMENT PEC in surface water during emission episode (dissolved) 3.34E-‐07 [mg.l-‐1] PEC in fresh-‐water sediment during emission episode 3.30E-‐04 [mg.kgwwt-‐1] PEC in seawater during emission episode (dissolved) 3.45E-‐08 [mg.l-‐1] Version 04-03-2013
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CAS number:
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PEC in marine sediment during emission episode 3.34E-‐04 [mg.kgwwt-‐1] SOIL, GROUNDWATER PEC in agric. soil (total) 1.54E-‐05 [mg.kgwwt-‐1] PEC in grassland (total) averaged over 180 days 1.54E-‐05 [mg.kgwwt-‐1] PEC in groundwater under agricultural soil 1.92E-‐08 [mg.l-‐1] STP PEC for micro-‐organisms in the STP (ECETOC TRA, ERC 12a) 1.66E-‐08 [mg.l-‐1] Conc in fish for secondary poisoning (freshwater) n.a. [mg.kgwwt-‐1] Conc in earthworms from agricultural soil n.a. [mg.kg-‐1] Conc in fish for secondary poisoning (marine) n.a. [mg.kgwwt-‐1] Conc in fish-‐eating marine top-‐predators n.a. [mg.kgwwt-‐1] Secondary poisoning 5b.3.2. Exposure estimations contributing scenario for WORKERS/CONSUMERS Tool used for evaluation ECETOC TRA v2 General parameter set Type of setting: Industrial/Consumer Dustiness: Low Duration of exposure: > 4hr/day Use of ventilation: no Use of respiratory protection: no Use of dermal protection: no Concentration in preparation: < 25 % Exposure Estimations PROC
14 14 14 14 Contributing scenarios Production of preparations or articles by tabletting, compression, extrusion, palletisation Worker exposure Production of preparations or articles by tabletting, compression, extrusion, palletisation Consumer exposure, clothing Production of preparations or articles by tabletting, compression, extrusion, palletisation Consumer exposure, bedding matresses Production of preparations or articles by tabletting, compression, extrusion, palletisation Consumer exposure, seats, flooring Predicted Inhalative
Exposure - (mg/m3)
Predicted Dermal
exposure (mg/kg/d)
RMMs, in addition
to those listed in
section 5b.2.2.
5E-‐01 1.41E+2 No 1.96 1.03E+03 No 22.8 23.9 No 14.6 1.46E+02 No 5b.4. Guidance to DU to evaluate whether he works inside the boundaries set by the ES 5b.4.1. Guidance to DU to evaluate whether he works inside the boundaries set by contributing scenario for ENVIRONMENTAL EXPOSURE Environmental exposure has been evaluated using the EUSES model. Within the conditions described above, there are no further limitations on the use of the substance in the use of textile articles containing polymer dispersion.. 5b.4.2. Guidance to DU to evaluate whether he works inside the boundaries set by contributing scenario for WORKER and CONSUMER EXPOSURE The worker and consumer exposure have been evaluated using ECETOC TRA integrated tool version 2. Evaluate whether you work within the boundaries of the operational conditions and risk management measures described in the tables above. Within those conditions safe use was shown. Version 04-03-2013
30 EC number:
247-148-4
Substance name:
CAS number:
25637-99-4
Should you however not be able to demonstrate compliance with the conditions described above, scaling of the results is possible using the ECETOC TRA model that was run to generate the above assessment. Version 04-03-2013
31 EC number:
247-148-4
Substance name:
CAS number:
25637-99-4
Exposure Scenario 6a: Manufacture of Flexible Elastomeric Foam (FEF) and FEF articles. This exposure scenario covers both the actual manufacturing of Flexible Elastomeric Foam (FEF) and
the manufacturing of FEF articles. The manufacture of FEF and FEF articles takes place in closed and
partially-open systems. Although opportunity for exposure arises in some systems, such exposure is
limited and can be reduced by correct use of personal protective equipment (PPE) and other risk
management measures. The formulated FEF is either applied to surfaces by low energy techniques
such as rolling or extruded and shaped to form finished articles.
As with the manufacture of Expanded Polystyrene (EPS) and Extruded Polystyrene (XPS) articles any
exposure to workers is expected through the dermal route during the cutting and handling of the
extruded FEF articles. Environmental emission data has been based upon the measured known
emission data for the total emission of HBCDD for all uses for the whole EU area and the estimated
tonnage for this use.
6a.1. Exposure Scenario: Manufacture of Flexible Elastomeric Foam (FEF) and FEF articles. Title Manufacture of Flexible Elastomeric Foam (FEF) and FEF articles. Sector of use SU 10, 11 Process category Manufacture of FEF PROC 2, 3, 4
Manufacturing of FEF articles 10, 14
Product category PC 32 Article category AC 10 Environmental release category Manufacturing FEF ERC 2, 3 Manufacturing of FEF articles ERC 5 Specific environmental release category Environmental releases are based on the VECAP survey Processes, tasks, activities covered All activities involved in the manufacture of FEF and FEF articles
6a.2. Operational conditions and risk management measures 6a.2.1. Contributing scenario controlling ENVIRONMENTAL EXPOSURE Operational conditions Amounts used Tonnage used at a local scale (tonnes/year)10 400 tonnes/year The annual use per site is based upon a representative total EU tonnage / the fraction of main local source 0.4 (standard EUSES default value). Frequency and duration of use Type of release Continuous Emission days (days/year) 300 Site specific monitoring data Measured data are available in the VECAP survey Other Operational Conditions of use affecting environmental exposure 10 This is the maximum tonnage that is allowed to be used by the Downsteam User on his site Version 04-03-2013
32 EC number:
247-148-4
Substance name:
CAS number:
25637-99-4
Local freshwater dilution factor
10
water (m3/day)
18,000
Indoor
7E-06 (VECAP Survey)
Emission Factor Air
Risk Management Measures Technical on-‐site conditions and measures to limit or reduce discharges, air emissions and releases to soil Not available Conditions and measures related to waste water treatment Size of STP (m3/day)
Not available
Physical property: solid Amounts used Covers percentage substance in the product > 25 % Frequency and duration of use/exposure Both manufacture of FEF and FEF articles: Covers daily exposures up to 8 hours Other given operational conditions affecting workers exposure Both manufacture of FEF and FEF articles: Indoor use Technical conditions and measures at process level (source) to prevent release Manufacture of FEF:
Used in closed systems with limited release to air
Manufacture of FEF articles:
Not available
Manufacture of FEF:
Local exhaust ventilation (LEV), 90% efficiency (default ECETOC TRA)
Manufacture of FEF:
Not available
6a.3. Exposure estimation and reference to its source 6a.3.1. Exposure estimations contributing scenario for ENVIRONMENT Tool used for evaluation EUSES General parameter set State of the substance Solid Biodegradability Inherently biodegradable Version 04-03-2013
33 EC number:
247-148-4
Substance name:
CAS number:
25637-99-4
Exposure estimations Indirect exposure of humans via the environment Value unit Local total daily intake for humans, total 6.10E-‐05 [mg.kg-‐1.day-‐1] Local PECs Unit AIR Annual average local PEC in air (total) 1.83E-‐06 [mg.m-‐3] WATER, SEDIMENT Local PEC in surface water during emission episode (dissolved) 9.03E-‐05 [mg.l-‐1] Annual average local PEC in surface water (dissolved) 7.42E-‐05 [mg.l-‐1] Local PEC in fresh-‐water sediment during emission episode 8.91E-‐02 [mg.kgwwt-‐1] Local PEC in seawater during emission episode (dissolved) 4.37E-‐05 [mg.l-‐1] Annual average local PEC in seawater (dissolved) 3.59E-‐05 [mg.l-‐1] Local PEC in marine sediment during emission episode 4.31E-‐02 [mg.kgwwt-‐1] SOIL, GROUNDWATER Local PEC in agric. soil (total) averaged over 30 days 1.35E-‐01 [mg.kgwwt-‐1] Local PEC in agric. soil (total) averaged over 180 days 1.35E-‐01 [mg.kgwwt-‐1] Local PEC in grassland (total) averaged over 180 days 5.34E-‐02 [mg.kgwwt-‐1] Local PEC in groundwater under agricultural soil 1.69E-‐04 [mg.l-‐1] STP PEC for micro-‐organisms in the STP 9.64E-‐04 [mg.l-‐1] Conc in fish for secondary poisoning (freshwater) n.a. [mg.kgwwt-‐1] Conc in earthworms from agricultural soil n.a. [mg.kg-‐1] Conc in fish for secondary poisoning (marine) n.a. [mg.kgwwt-‐1] Conc in fish-‐eating marine top-‐predators n.a. [mg.kgwwt-‐1] Secondary poisoning 6a.3.2. Exposure estimations contributing scenario for WORKERS Tool used for evaluation ECETOC TRA v2 General parameter set Type of setting: Industrial Duration of exposure: > 4hr/day Use of ventilation: Local Exhaust Ventilation, 90% efficiency (default ECETOC TRA) Use of respiratory protection: Respiratory protection (90% effectiveness), used continuously wherever possible Use of dermal protection: none Concentration in preparation: > 25% Exposure Estimations PROC
Contributing scenarios 2 Use in closed, continuous process with occasional controlled exposure 3 Use in closed batch process (synthesis or formulation) 4 Use in batch and other process (synthesis) where opportunity for exposure arises 10 Roller application or brushing Version 04-03-2013
Predicted Inhalative
Exposure - (mg/m3)
Predicted Dermal
exposure (mg/kg/d)
RMMs, in addition
to those listed in
section 6a.2.2
1.00E-‐02 1.37E-‐01 1.00E-‐02 3.43E-‐02 2.50E-‐01 6.86E-‐01 1.60E-‐02 1.37E00 LEV Respiratory protection LEV Respiratory protection LEV Respiratory protection LEV Respiratory protection 34 EC number:
247-148-4
Substance name:
CAS number:
25637-99-4
14 Production of preparations or articles by tabletting, compression, extrusion, pelletisation 1.00E-‐01 3.43E-‐01 LEV Respiratory protection 6a.4. Guidance to DU to evaluate whether he works inside the boundaries set by the ES 6a.4.1. Guidance to DU to evaluate whether he works inside the boundaries set by contributing scenario for ENVIRONMENTAL EXPOSURE Environmental exposure has been evaluated using the EUSES model, with emissions based on measurements, carried out within the framework of the VECAP survey. Within the conditions described above, there are no further limitations on the use of the substance in the manufacture of Flexible Elastomeric Foam (FEF) and FEF articles. 6a.4.2. Guidance to DU to evaluate whether he works inside the boundaries set by contributing scenario for WORKER EXPOSURE The workers exposure has been evaluated using ECETOC TRA integrated tool version 2. Evaluate whether you work within the boundaries of the operational conditions and risk management measures described in the tables above. Within those conditions safe use was shown. Should you however not be able to demonstrate compliance with the conditions described above, scaling of the results is possible using the ECETOC TRA model that was run to generate the above assessment. Version 04-03-2013
35 EC number:
247-148-4
Substance name:
CAS number:
25637-99-4
Exposure Scenario 6b: Use of Flexible Elastomeric Foam (FEF) articles 6b.1. Exposure Scenario: Use of Flexible Elastomeric Foam (FEF) articles Title Use of Flexible Elastomeric Foam (FEF) articles Sector of use SU 19 Process category PROC 21
Product category PC 32 Article category AC 10 Environmental release category ERC 11 Specific environmental release category Not available Processes, tasks, activities covered All activities involved in the use of FEF articles
6b.2. Operational conditions and risk management measures 6b.2.1. Contributing scenario controlling ENVIRONMENTAL EXPOSURE Operational conditions Amounts used Tonnage used at a local scale (tonnes/year)11 100 kg/site (worst case estimate) Frequency and duration of use Type of release Continuous Emission days (days/year) 365 Site specific monitoring data Not available Other Operational Conditions of use affecting environmental exposure Local freshwater dilution factor
10
water (m3/day)
18,000
Indoor
5E-04
Emission Factor Air
5E-04
0
2,000 11 This is the maximum tonnage that is allowed to be used by the Downsteam User on his site Version 04-03-2013
36 EC number:
247-148-4
Substance name:
CAS number:
25637-99-4
Degradation potential of the substance Inherently biodegradable
Conditions and measures related to external treatment of waste for disposal Environmental exposure from use and installation of the FEF articles is expected to be negligible as minimal quantities of
waste will be produced due to cost considerations. Any wastes are likely to be sent to landfill, leachates are unlikely to be
formed due to the highly insoluble nature of the registered substance in water.
Not available
Physical property: solid Amounts used Covers percentage substance in the product up to 10 % (worst case estimate) Frequency and duration of use/exposure Covers daily exposures up to 8 hours Other given operational conditions affecting workers exposure Indoor use Technical conditions and measures at process level (source) to prevent release Not available
Not available
Not available
6b.3. Exposure estimation and reference to its source 6b.3.1. Exposure estimations contributing scenario for ENVIRONMENT Tool used for evaluation Expert judgement Considerations The soft rubber which FEF is made from ensures that the registered substance will be contained within the polymer matrix during installation and use. In addition to this no particulate emissions will be generated from the cutting of FEF articles during installation or removal. There is therefore no anticipated release of HBCDD during the use or life-‐
cycle of FEF articles. Wastes generated from cutting and installation of the FEF articles and at the end of the service-‐life are likely to be sent to landfill. The substance has a high molecular weight and is therefore expected to remain trapped within the polymer matrix. Should any of the HBCDD be released through degradation of the polymer matrix leachates are unlikely to be formed, based upon the highly insoluble nature of the substance in water. Exposure estimations Indirect exposure of humans via the environment Value Unit Local total daily intake for humans, total (ECETOC TRA, ERC 11) 1.01E-‐05 [mg.kg-‐1.day-‐1] Local PECs Unit AIR Annual average local PEC in air (total) 0 [mg.m-‐3] WATER, SEDIMENT Local PEC in surface water during emission episode (dissolved) 0 [mg.l-‐1] Annual average local PEC in surface water (dissolved) 0 [mg.l-‐1] Version 04-03-2013
37 EC number:
247-148-4
Substance name:
CAS number:
25637-99-4
Local PEC in fresh-‐water sediment during emission episode 0 [mg.kgwwt-‐1] Local PEC in seawater during emission episode (dissolved) 0 [mg.l-‐1] Annual average local PEC in seawater (dissolved) 0 [mg.l-‐1] Local PEC in marine sediment during emission episode 0 [mg.kgwwt-‐1] SOIL, GROUNDWATER Local PEC in agric. soil (total) averaged over 30 days 0 [mg.kgwwt-‐1] Local PEC in agric. soil (total) averaged over 180 days 0 [mg.kgwwt-‐1] Local PEC in grassland (total) averaged over 180 days 0 [mg.kgwwt-‐1] Local PEC in groundwater under agricultural soil 0 [mg.l-‐1] STP PEC for micro-‐organisms in the STP 0 [mg.l-‐1] Conc in fish for secondary poisoning (freshwater) 0 [mg.kgwwt-‐1] Conc in earthworms from agricultural soil 0 [mg.kg-‐1] Conc in fish for secondary poisoning (marine) 0 [mg.kgwwt-‐1] Conc in fish-‐eating marine top-‐predators 0 [mg.kgwwt-‐1] Secondary poisoning 6b.3.2. Exposure estimations contributing scenario for WORKERS Tool used for evaluation ECETOC TRA v2 General parameter set Type of setting: Industrial Duration of exposure: > 4hr/day Use of ventilation: Local Exhaust Ventilation, 90% efficiency (default ECETOC TRA) Use of respiratory protection: none Use of dermal protection: none Concentration in preparation: < 10% Exposure Estimations PROC
Exposure - (mg/m3)
Predicted Dermal
exposure (mg/kg/d)
RMMs
3.00 2.83 LEV 6b.4. Guidance to DU to evaluate whether he works inside the boundaries set by the ES 6b.4.1. Guidance to DU to evaluate whether he works inside the boundaries set by contributing scenario for ENVIRONMENTAL EXPOSURE Environmental exposure has been evaluated using expert judgement. Within the conditions described above, there are no further limitations on the use of the substance in Flexible Elastomeric Foam articles 6b.4.2. Guidance to DU to evaluate whether he works inside the boundaries set by contributing scenario for WORKER EXPOSURE The workers exposure has been evaluated using ECETOC TRA integrated tool version 2. Evaluate whether you work within the boundaries of the operational conditions and risk management measures described in the tables above. Within those conditions safe use was shown. Should you however not be able to demonstrate compliance with the conditions described above, scaling of the results is possible using the ECETOC TRA model that was run to generate the above assessment. Version 04-03-2013
38 EC number:
247-148-4
Substance name:
CAS number:
25637-99-4
Exposure Scenario 7: Additional formulation use 7.1. Exposure Scenario: Additional formulation use Title Additional formulation use. Sector of use SU 3, 10 Process category PROC 2, 6, 8a, 8b, 9, 10
Product category PC 19 Article category AC 13 Environmental release category ERC 2, 3, 10 a, 11a Specific environmental release category Emission factors are based on the VECAP survey Processes, tasks, activities covered This scenario covers the formulation of HBCDD into polymer preparations in
closed and partially open systems that are not covered by the previous exposure
scenarios.
7.2. Operational conditions and risk management measures 7.2.1. Contributing scenario controlling ENVIRONMENTAL EXPOSURE Operational conditions Amounts used Tonnage used at a local scale (tonnes/year)12 400 tonnes/year (based upon a total EU tonnage of 1000 tpa and a fraction of main local source of 0.4 (standard EUSES) Frequency and duration of use Type of release Continuous Emission days (days/year) 300 Site specific monitoring data Measured data are available in the VECAP Survey Other Operational Conditions of use affecting environmental exposure Local freshwater dilution factor
10
water (m3/day)
18,000
Indoor
7E-06
Emission Factor Air
6E-06
22E-06
2,000 12 This is the maximum tonnage that is allowed to be used by the Downsteam User on his site Version 04-03-2013
39 EC number:
247-148-4
Substance name:
CAS number:
25637-99-4
Degradation potential of the substance Inherently biodegradable
Not available
7.2.2. Contributing scenario controlling WORKER EXPOSURE Product characteristics Substance name: hexabromocyclododecane
Physical property: solid Amounts used Not available Frequency and duration of use/exposure Covers daily exposures up to 8 hours Other given operational conditions affecting workers exposure Indoor use Technical conditions and measures at process level (source) to prevent release Not available
Respiratory protection (90 % effectiveness), to be used wherever exposure is possible
Not available
7.3. Exposure estimation and reference to its source 7.3.1. Exposure estimations contributing scenario for ENVIRONMENT Tool used for evaluation EUSES vs 2.1 General parameter set State of the substance Solid Biodegradability Inherently biodegradable Exposure estimations Indirect exposure of humans via the environment Value Unit Local total daily intake for humans, total (ECETOC TRA) 1.24E-‐04 [mg.kg-‐1.day-‐1] Local PECs Unit AIR Annual average local PEC in air (total) 1.83E-‐06 [mg.m-‐3] WATER, SEDIMENT Local PEC in surface water during emission episode (dissolved) 9.03E-‐05 [mg.l-‐1] Annual average local PEC in surface water (dissolved) 7.42E-‐05 [mg.l-‐1] Local PEC in fresh-‐water sediment during emission episode 8.91E-‐02 [mg.kgwwt-‐1] Local PEC in seawater during emission episode (dissolved) 4.37E-‐05 [mg.l-‐1] Annual average local PEC in seawater (dissolved) 3.59E-‐05 [mg.l-‐1] Local PEC in marine sediment during emission episode 4.31E-‐02 [mg.kgwwt-‐1] SOIL, GROUNDWATER Local PEC in agric. soil (total) averaged over 30 days 1.35E-‐01 [mg.kgwwt-‐1] Local PEC in agric. soil (total) averaged over 180 days 1.35E-‐01 [mg.kgwwt-‐1] Local PEC in grassland (total) averaged over 180 days 5.34E-‐02 [mg.kgwwt-‐1] Local PEC in groundwater under agricultural soil 1.69E-‐04 [mg.l-‐1] STP PEC for micro-‐organisms in the STP 9.64E-‐04 [mg.l-‐1] Version 04-03-2013
40 EC number:
247-148-4
Substance name:
CAS number:
25637-99-4
Secondary poisoning Conc in fish for secondary poisoning (freshwater) n.a. [mg.kgwwt-‐1] Conc in earthworms from agricultural soil n.a. [mg.kg-‐1] Conc in fish for secondary poisoning (marine) n.a. [mg.kgwwt-‐1] Conc in fish-‐eating marine top-‐predators n.a. [mg.kgwwt-‐1] 7.3.2. Exposure estimations contributing scenario for WORKERS Tool used for evaluation ECETOC TRA vs 2 Exposure to workers is not expected to occur during formulation of polymer preparations due to the low vapour pressure of the registered substance. General parameter set Type of setting: Industrial Duration of exposure: > 4hr/day Use of ventilation: Local Exhaust Ventilation, 90% efficiency (default ECETOC TRA) Use of respiratory protection: Respiratory protection , 90% efficiency Use of dermal protection: none Exposure Estimations PROC
Contributing scenarios 2 Use in closed, continuous process with occasional controlled exposure 6 Calendering operations 8a 8b 9 Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-‐
dedicated facilities Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities Transfer of substance or preparation into small containers (dedicated filling line, including weighing) 10 Roller application or brushing 24c High (mechanical) energy work-‐up of substances bound in materials and/or articles Predicted Inhalative
Exposure - (mg/m3)
Predicted Dermal
exposure (mg/kg/d)
RMMs, in addition
to those listed in
section 7.2.2
1.00E-‐02 1.37E-‐01 2.50E-‐01 1.37 5.00E-‐01 1.37E-‐01 LEV Respiratory protection LEV Respiratory protection LEV Respiratory protection 1.25E-‐01 6.86E-‐01 LEV Respiratory protection 2.00E-‐01 6.86E-‐01 1.60E-‐02 1.37 2.00E-‐01 2.83E-‐01 LEV Respiratory protection LEV Respiratory protection LEV Respiratory protection 7.4. Guidance to DU to evaluate whether he works inside the boundaries set by the ES 7.4.1. Guidance to DU to evaluate whether he works inside the boundaries set by contributing scenario for ENVIRONMENTAL EXPOSURE Environmental exposure has been evaluated using the EUSES model. Within the conditions described above, there are no further limitations on the use of the substance in additional formulation use. 7.4.2. Guidance to DU to evaluate whether he works inside the boundaries set by contributing scenario for WORKER EXPOSURE The workers exposure has been evaluated using ECETOC TRA integrated tool version 2. Evaluate whether you work within the boundaries of the operational conditions and risk management measures described in the tables above. Within those conditions safe use was shown. Should you however not be able to demonstrate compliance with the conditions described above, scaling of the results is possible using the ECETOC TRA model that was run to generate the above assessment. Version 04-03-2013
41

FICHE DE DONNEES DE SECURITE

Transcription

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