Fibres
Transcription
Fibres
Chapter V : Composite materials Materials Selection Course J. Lecomte-Beckers 1 Content • Introduction • Particles reinforced composites • Structural composites • Fibre reinforced composites • Illustrative example: materials for skis J. Lecomte-Beckers 2 Origin of composite materials From Ancient Egypt thousand years ago: enhancement of mechanical properties of bricks with the addition of short straw yarns to wet clay Natural composite materials: – Wood: cellulose fibres in a lignin matrix – Bone: complex mixture of collagen and calcium phosphate J. Lecomte-Beckers 3 What is a composite material ? Solid state material made up of at least two species keeping their intrinsic properties and combining them to exhibit a material with improved global properties ≠ from a metallic alloy or a ceramic blend J. Lecomte-Beckers 4 Assets of composite materials • Lightness, improved mechanical and chemical resistance • Lowered maintenance, freedom of shapes • Increase life time of some equipments • Better toughness and • resistance to fire enhancement of safety • Better thermal, phonic and electric insulation Enhanced performance as a basis for innovative technological solutions J. Lecomte-Beckers 5 Composition of a composite Made up of 2 phases : – Matrix : continuous and envelops the other phase – Reinforcement, surrounded by the matrix Properties of a composite are depending on – Properties and fraction of both (or more) phases – Geometry of reinforcement J. Lecomte-Beckers 6 Classification of composites Composite Particles reinforced Coarse Dispersed Fibre reinforced Long fibres (aligned) Structural Short fibres Aligned Randomly oriented J. Lecomte-Beckers 7 Particles reinforced composites Dispersion reinforcement • Presence of small particles preventing dislocation motions (metallic matrix) • Enhancement of properties is depending on atomic or molecular interaction between the matrix and the reinforcement (also called load) Coarse particles • Increasing of mechanical properties depends on the binding strength between matrix and particles J. Lecomte-Beckers 8 Fibre reinforced composites Fibres = most efficient reinforcing materials = improved mechanical properties when junction with matrix is effective Generally ductile matrix spreading material applied stress to fibres Influence of position and fibres length between each other on composite properties J. Lecomte-Beckers 9 Structural composites Multi-layer composite • Made up of several layers of an anisotropic material • Superposition, intersection and sticking of layers isotropic material with load direction Sandwich composite • Made up of two layers with high mechanical properties separated by a core material (e.g.: Al/PP/Al) • High resistance and stiffness with low density J. Lecomte-Beckers 10 Current composites • 99% of composites are with an organic matrix • Composites with inorganic matrix (metallic or ceramic): low use J. Lecomte-Beckers 11 Content • Introduction • Particles reinforced composites • Structural composites • Fibre reinforced composites • Illustrative example: materials for skis J. Lecomte-Beckers 12 Coarse particles composites • Interactions between particles and matrix are not atomic nor molecular but are coming from mechanics • Reinforcement particles are harder and stiffer than matrix and prevent it to flow around them • Transfer of stress from matrix to particles • Reinforcement level is depending on binding force between particles and matrix • Made from metals, glasses, ceramics or polymers J. Lecomte-Beckers 13 Dispersion reinforced composites • Smaller particles (diameter from 0.01µm to 0.1µm) • Reinforcement by matrix-load interactions at the atomic or molecular level • Metallic Matrix bears applied load and particles are limiting the motion of dislocations of plastic deformation and of yield and tensile strength, and hardness J. Lecomte-Beckers 14 Dispersion reinforced composites • Varied particles geometry BUT same size (and behaviour) in the 3 main directions • Particularly improved properties with fine particles uniformly distributed in matrix • Mechanical properties are rising with an increase of volumic fraction of reinforcing phase J. Lecomte-Beckers 15 Dispersion reinforced composites sup Ec EmVm E pV p inf Ec E m .E p Vm E p V p E m Young’s Modulus (GPa) Dual phase composite: Upper limit Lower limit Tungsten particles fraction J. Lecomte-Beckers 16 Cermets • Coarse particles composites: metallic matrix with high fraction of ceramic particles • Most used cermets: cemented carbides • Very hard particles of refractory ceramics (WC or TiC) binded with a metallic matrix (Co or Ni) • Application of cermets : maching tools for hard steels • In certain cermets, fraction of particles can exceed 90 vol.% excellent resistance to abrasion J. Lecomte-Beckers 17 Cemented carbide (WC-Co) Micrograph of WC-Co Mechanical properties of WC grains and Co matrix Co (10% vol.) in black J. Lecomte-Beckers 18 Elastomers and plastics • Frequently particulates reinforced (black carbon) • Black carbon: cheap, contains fine spheroïdal carbon particles • Tires are containing from 15 to 30 vol.% of black carbon increase of fracture toughness, tensile strength and resistance to abrasion and laceration Micrograph of a synthetic rubber J. Lecomte-Beckers Carbon particle diameter in the order of 20 to 50 nm 19 Concrete • Coarse particles composite • Matrix (cement) and reinforcement (sand and gravel granulates) = ceramic material • Concrete ≠ cement • Concrete = composite material made up of granulates linked with a binding agent (cement) used in the solid state J. Lecomte-Beckers 20 Metal and metallic alloys • Improvement of strength and hardness with uniform dispersion of very hard fine particles (few vol.%) • Dispersed phase = oxide (generally but not the best – low interaction) • Effective reinforcement is depending on matrix-load interactions for preventing motion of dislocations • Reinforcement is not subject to ageing because of its inert behaviour with increasing temperature J. Lecomte-Beckers 21 Content • Introduction • Particles reinforced composites • Structural composites • Fibre reinforced composites • Illustrative example: materials for skis J. Lecomte-Beckers 22 Main characteristics • Made of an homogenous and a composite material • Properties are depending of species, shape and size • Multi-layer composites and sandwich-like structures J. Lecomte-Beckers 23 Multi-layer composites • Made of weaves or panels with anisotropic properties • Stacked layers which are sticked together with alternating orientation of best resistance direction (e.g.: 0/45/90° or 0/90°) Représentation schématique d’un composite stratifié J. Lecomte-Beckers 24 Multi-layer composites • Case of plywood: fibres of a layer are oriented to 90° with previous layer • Manufacturing of composites from coton, paper or glass fibres in a polymeric matrix • High strength in lots of direction of the same plan (pretty low inter-layer resistance) J. Lecomte-Beckers 25 Laminate (Sandwich-like) structures • Made of two layer of a tough material with intercalated core material which is less dense and exhibit lower strength and stiffness (I profile principle) • External layers are bearing the majority of stress (higher stiffness in parallel system) - particularly interesting for bending forces • Aluminium based alloys, FRP, Ti based alloys or steels for external layers J. Lecomte-Beckers 26 Core • Two functions: – Bear perpendicular strains between the two external layers – Provide stiffness with profile shearing forces • Core made up of polymeric foams, synthetic rubbers, inorganic cements and balsa J. Lecomte-Beckers 27 Sandwich-like structure with alveolar core • Core = alveolar structure with foils including hexagonal cells • Cells are staying next to each other as in a hive J. Lecomte-Beckers 28 Sandwich-like structure with alveolar core • Now: realisation of very complex sandwich-like structures such as rotary lifting device of helicopter Unidirectional composite Unidirectional composite Unidirectional composite layers oriented at ±45° Aluminium honeycomb Helicopter rotor blade J. Lecomte-Beckers 29 Content • Introduction • Particles reinforced composites • Structural composites • Fibre reinforced composites • Illustrative example: materials for skis J. Lecomte-Beckers 30 Wished properties Strength and stiffness combined to lightness frequent characterisation of composites from their specific properties Specific strength = tensile strength / density Speficif stiffness= Young’s modulus / density Notice: low mechanical properties improvement with randomly oriented short fibres J. Lecomte-Beckers 31 Effect of fibre length • Mechanical properties are related to: – Properties of fibres – Importance of load transfer from matrix to fibres • Load transfer – Given by adhesion strength between fibres and matrix – Equal to zero at fibre ends matrix strain Matrix Fibre J. Lecomte-Beckers 32 Critical length of fibres Strength and rigidity are increased if fibre has a length higher than a certain critical size, lc *f d lc 2 c For GFRC or CFRC: lc ≈ 1mm (that is to say 20 to 150 times the diameter of fibre) If l >15 lc, continuous or long fibres good reinforcement of composite material Otherwise, discontinuous or short fibres If l < lc, deformation of matrix and low increase of properties J. Lecomte-Beckers 33 Effect of orientation and fraction of fibres • Properties are influenced by fibres disposal in matrix • Importance of orientation, fraction and distribution of fibres • 2 different fibre disposals: – Same direction: case of continuous and discontinuous fibres – Random orientation: case of discontinuous fibres • Uniform distribution of fibres optimal properties J. Lecomte-Beckers 34 Fibre hardening J. Lecomte-Beckers Disposition of fibres as reinforcement: (a) Aligned long fibres (b) Aligned short fibres (c) Random short fibres 35 Composites with continuous aligned fibres J. Lecomte-Beckers 36 Behaviour with tension – Longitudinal load • Response of composite to an external load is depending on: – Behaviour and fraction of both phases (matrix and fibres) – Direction of applied load – Anisotropy of composite J. Lecomte-Beckers 37 Behaviour with tension – Longitudinal load • Tensile behaviour of composite with brittle fibres and ductile matrix *f = ultimate strength fibre m* = ultimate strength matrix *f = fibres strain m* = matrix strain We admit *f < m* Related stress-strain curve J. Lecomte-Beckers 38 Behaviour with tension – Longitudinal load • Failure of composite when fibres are * cracking ( f ) • No brittle failure because: - Mechanical resistance of fibres is not equal (intrinsic differences + collapsing effect) no simultaneous failure – Matrix keeps its properties if *f < m* cracked fibres are shorter but continue to bear the load and promote strength Composite stress-strain curve J. Lecomte-Beckers 39 Elastic behaviour – Longitudinal load • Assumptions: – High adherence of fibres to matrix – Isodeformation ( c m f ) Fc Fm F f Then c S c m S m f S f With division by Sc (transversal cross section area) : Sf Sm c m f Sc Sc J. Lecomte-Beckers 40 Elastic behaviour – Longitudinal load • When composites, matrix and reinforcement have the S same length: m = Vm and Sc Sf Sc = Vf (volumic fractions) c mVm f V f With Isodeformation assumption, we can divide each term by it respective strain f c m Vm Vf c m f J. Lecomte-Beckers 41 Elastic behaviour – Longitudinal load • However, if elastic strain: f c , m , Ef Ec Em f c m Ecl EmVm E f V f Only 2 phases (matrix and reinforcement) Vm V f 1 Hence, J. Lecomte-Beckers Ecl Em (1 V f ) E f V f 42 Elastic behaviour – Transversal load Load ┴ to direction of fibres alignment iso-stress c m f c mVm f V f Strain of composite: However, Vm E Em cl E With division by σ, we get 1 Ecl So Ecl J. Lecomte-Beckers Em E f Vm E f V f E m Ef Vf 1 1 Vm Vf Em Ef Em E f (1 V f ) E f V f E m 43 Longitudinal tensile strength • We admit tensile strength = maximum stress • Maximum corresponds to rupture of fibres and start damaging of composite Material Glass-Polyester High modulus carbon-epoxide Kevlar-epoxide Tensile strength (MPa) 700 1000 1200 Longitudinal tensile strength of 3 common composites J. Lecomte-Beckers 44 Longitudinal tensile strength • Complex failuring phenomena; several modes are existing • Mode given by: – Properties of fibres and matrix – Nature and strength of matrix-fibres bonds • If *f < m* no cracking of matrix before fibres • When fibres are cracked load is transfered to matrix J. Lecomte-Beckers 45 Transverse tensile strength • Materials are designed to bear load aligned with fibres otherwise rupture hazard • If very low mechanical resistance even lower than matrix, reinforcement lowers mechanical properties! Material Transverse tensile strength (MPa) Glass-Polyester 20 High modulus carbon-epoxide 35 Kevlar-epoxide 20 Transverse tensile strength of 3 common composites J. Lecomte-Beckers 46 Transverse tensile strength • Transverse tensile strength influence factors: – Properties of fibres and matrix – Bonding energy between fibres and matrix – Defect (e.g. presence of air bubbles, inclusions…) • Improvement of transverse mechanical properties with modification of matrix properties J. Lecomte-Beckers 47 Composites with aligned discontinuous fibres J. Lecomte-Beckers 48 Longitudinal tensile strength • Reinforcement with discontinuous fibres lower than with continuous fibres BUT commercial interest of glass, C and aramid short fibres • If l > lc, cd* *f V f 1 • If l < lc, cd* ' J. Lecomte-Beckers lc m' (1 V f ) 2l l c V f m' (1 V f ) d 49 Composites with randomly oriented discontinuous fibres J. Lecomte-Beckers 50 Characteristics • Young’s modulus: Ecd KE f V f EmVm K = efficience coefficient of fibres, depends on Vf and comprised between 0.1 and 0.6 E Ef Em , with Vf BUT with random orientation of fibres, E proportionally to K Property (g.cm-3) No reinforcement Density Tensile strength (MPa) Young’s modulus (GPa) Ductility (%) Toughness, Izod test (J) 1.19-1.22 59-62 2.24-2.345 90-115 1.3-1.8 20 1.35 110 5.93 4-6 0.23 With reinforcement (vol.%) 30 40 1.43 1.52 131 159 8.62 11.6 3-5 3-5 0.23 0.28 Properties of polycarbonate polymer with and without unoriented glass fibres J. Lecomte-Beckers 51 Summary • Composites with aligned fibres: – Generally anistropic – Optimal properties in the fibres direction – In transverse direction, reinforcement is nearly inefficient and tensile strength is low – If stress is oriented in another direction strength is comprised between the two extremes behaviour J. Lecomte-Beckers 52 Reinforcement fibres: general information • Characteristics of brittle materials: lower strength in the block form than in the low diameter fibre form • Elimination of most surface defects during manufacturing of fibres Probability of fibre failure is dropping when its diameter is diminished asset for manufacturing J. Lecomte-Beckers 53 Types of reinforcement fibres • 3 types: whiskers, fibres and wires Whiskers: • Rod-like monocrystals with very high length/diameter ratio • Nearly perfect crystalline structure • Exceptional and best tensile strength ever • Very high cost and difficulties (or impossibility) to add them to a matrix nearly not used as reinforcement fibres • Made up of carbides, silicon nitride or aluminium oxide. J. Lecomte-Beckers 54 Types of reinforcement fibres Fibres : • Polycristallyne or amorphous • Low diameter • Made from a polymer or a ceramic: aramid, glass, C, B, Al oxide, Si carbide… Wires: • Fine but with large diameter • Made up of steels, Mo or W • Applications: tyres with radial carcass, external spacecraft wraps… J. Lecomte-Beckers 55 Examples of reinforcement fibres Material Density (g.cm-3) Ultimate strength (GPa) Graphite Silicon Nitride Aluminium Oxide Silicon Carbide 2.2 3.2 4.0 3.2 20 5-7 10-20 20 Aluminium Oxide Aramide (Kevlar 49) Carbon* Glass E Boron Silicon carbide UHMWPE (Spectra 900) 3.95 1.44 1.78-2.15 2.58 2.57 3.0 0.97 1.38 3.6-4.1 1.5-4.8 3.45 3.6 3.9 2.6 Specific strength (GPa) Whiskers 9.1 1.56-2.2 2.5-5.0 6.25 Fibres 0.35 2.5-2.85 0.7-2.7 1.34 1.40 1.30 2.68 Young’s modulus (GPa) Specific modulus (GPa) 700 350-380 700-1500 480 318 109-118 175-375 150 379 131 228-724 72.5 400 400 117 96 91 106-407 28.1 156 133 121 Metallic Wires High strength steel 7.9 2.39 0.30 210 26.6 Molybdenum 10.2 2.2 0.22 324 31.8 Tungsten 19.3 2.89 0.15 407 21.1 * Carbon term is used (in opposition to graphite) to consider theses fibres because they contain crystalline graphite areas, non crystalline materials and unaligned crystalline areas J. Lecomte-Beckers 56 Matrix: general aspects • Metal, polymer or ceramic • For ductile matrix: metal or polymer • Reinforcement increases fracture toughness of ceramic matrix composites • ≠ roles of matrix: – Binding of fibres, distribution of stress and transfer to fibres – Protection of fibres against abrasion and chemical reactions – Isolation of fibres between each other and et blocking of cracks J. Lecomte-Beckers 57 Matrix: general aspects • Resistance of composite until cracked fibres is lower than a critical value • Strong enough fibre-matrix bonds in order to avoid unjoining of fibres • Ultimate strength of composite is linked to the strength of this bond • Optimal joining maximises load transfer between matrix (weak) and fibres (strong) J. Lecomte-Beckers 58 Plan • Introduction • Particles reinforced composites • Structural composites • Fibre reinforced composites • Illustrative example: materials for skis J. Lecomte-Beckers 59 Materials for skis • Materials for 2000 year ski are similar to the one of 80’s • Difference : evolution of ski shape modification of behaviour on snow • Fundamental form parameter of ski: y-axis geometry J. Lecomte-Beckers 60 Ligne de cote du ski • Curve including the most drawn Traditional ski aside points of spatula and heel and the most centred point of y-axis line Trajectory shoe along the edge • Control the ability of ski to Parabolic ski promote turning • Higher curvature on y-axis line, heel y-axis line lower turn radius easier skiing J. Lecomte-Beckers shoe spatula Trajectory y 61 Contact with track • Important function of ski • Good contact better trajectory control • Ski must be: • Flexible with bending • Stiff with torsion J. Lecomte-Beckers Contradictory abilities 62 Shape of skis • Evolution since 10 years • Made possible with breakthrough of CAM and numeric use in machining (manufacturing of very complex moulds) • Progress of CAD Optimisation of ski J. Lecomte-Beckers 63 Used materials External VDD Protection layer GFR epoxy multi-layer Aluminium alloy GFR epoxy multi-layer Polyurethane foam core Insert Aluminium alloy Internal VDD Kevlar FR epoxy multi-layer GFR epoxy multi-layer Sole (sintered PE) Side J. Lecomte-Beckers Edge (steel) Cut of a Rossignol Dualtec ski 64 Used materials Material Density (g.cm-3) Ultimate strength (GPa) Graphite Silicon Nitride Aluminium Oxide Silicon Carbide 2.2 3.2 4.0 3.2 20 5-7 10-20 20 Aluminium Oxide Aramide (Kevlar 49) Carbon* Glass E Boron Silicon carbide UHMWPE (Spectra 900) 3.95 1.44 1.78-2.15 2.58 2.57 3.0 0.97 1.38 3.6-4.1 1.5-4.8 3.45 3.6 3.9 2.6 Specific strength (GPa) Whiskers 9.1 1.56-2.2 2.5-5.0 6.25 Fibres 0.35 2.5-2.85 0.7-2.7 1.34 1.40 1.30 2.68 Young’s modulus (GPa) Specific modulus (GPa) 700 350-380 700-1500 480 318 109-118 175-375 150 379 131 228-724 72.5 400 400 117 96 91 106-407 28.1 156 133 121 Metallic Wires High strength steel 7.9 2.39 0.30 210 26.6 Molybdenum 10.2 2.2 0.22 324 31.8 Tungsten 19.3 2.89 0.15 407 21.1 * Carbon term is used (in opposition to graphite) to consider theses fibres because they contain crystalline graphite areas, non crystalline materials and unaligned crystalline areas J. Lecomte-Beckers 65 Characteristics of skis • Criterion for materials selection: lightness use of a foam for the ski core • Ski has to bear a bending moment • Reinforcing materials are located aroung the core and are loaded with tension in the lower part and with compression in the upper part. J. Lecomte-Beckers 66 Fibre reinforcement • High strain level required with no torsion nor failure reinforced materials with high yield strength • Main reinforcing specy: Glass fibres (GF) • Interesting Performance / Cost ratio; • For pretty high lenghtening with high deformation ratio; • Used in the form of fibre weaves bent on a polyester layer. J. Lecomte-Beckers 67 Fibre reinforcement • Longitudinal aromatic polyamid fibres (Kevlar K49) in the ribbon form in the lower part of ski (low compressive strength) • Carbon fibres are rarely used because of frequent rupture and high cost J. Lecomte-Beckers 68 Other reinforcement • Aeronautic aluminium alloy sheet (7000 serie, Zicral) Typical composition (wt.%) : Al + 6Zn + Mg, (Cu, Mn at lower %) obtaining stiffness for torsion and flexibility for bending ability to turn with accuracy J. Lecomte-Beckers 69 Damping devices • Presence of vibration damping devices (VDD) • One is external (sticked on ski) • Other one is internal (in the core) • Internal VDD is made up of rubber with high damping capacity and surrounded by twisted steel wires • External VDD is composed of Zicral and an viscoelastic material • Role of VDD: Damp vibration of ski which are detriment during the slide J. Lecomte-Beckers 70 Noyau central • Mousse de polyuréthane semi-rigide • Obtenue par injection dans un moule de constituants liquides réactifs (diisocyanates et polyols) mélangé avant l’injection J. Lecomte-Beckers 71 Sole • Protective material on the lower face of ski • Main role: ensure sliding of ski • Used material: HDPE (low abrasion resistance but behaviour suitable for all types of snow) with very high molecular weight (2 000 000) and formed by sintering • Microporous material J. Lecomte-Beckers 72 Last components of ski • Edges: made from a chromium steel with 0.6 wt.% C (Rockwell Hardness: 49-51) • Protective layer: • Modified styrene-acrylonitrile copolymer reinforced with short glass fibres • Or multi-layer laminate with impregnated paper with thermoset phenolic or melamine resin J. Lecomte-Beckers 73 Assembling of ski • Components are assembled with an adhesive (thermohardened epoxy resin) • High pressure joining: from 8 to 10 kg cm-2 and T° from 100 to 120°C during 15 min • Then pressurised cooling up to glass transition of adhesive • Joining • Distribution of shear stress • Obtaining a structure with good fatigue behaviour J. Lecomte-Beckers 74 Manufacturing of ski • Other technology: • Addition of ski components in the mould • Injection of liquid species to form directly a polyurethane foam in the mould • Expanding, hardening • Foam: Core of the ski and adhesive binding agent for the ski components J. Lecomte-Beckers 75 Wood • Core material for more than 50% of skis • Natural, low density, pretty cheap and microporous material • Good resistance to hot crushing (compressive stress) hardening of adhesives • Main defect: moisturisation J. Lecomte-Beckers 76 Friction of ski • Function of ski : ensure sliding lowest friction between sole and snow • Friction mecanism is complex because snow is an heterogenous material with ice crystals • For T°>-10°C : friction is lubricated by a water film (friction T° water film) • Water film: lubricant with low friction coefficient (µ=0.02) J. Lecomte-Beckers 77 Friction of ski • For T°< -10°C, -15°C : induced friction heat is evacuated Waxed wood Ice asperities are sticking to the sole and µ for wood and steel • For PTFE and PE it is not the cas and µ remains low under -10°C J. Lecomte-Beckers Friction coefficient µ lubricating film Temperature 78 Sandwich-like structure • Ski = nice example of sandwich-like structure combining several materials • Each material has its function • Quality of a ski depends on the choice of an optimal structure and shape • Changes in length, width, size and camber modulation of flexibility distribution J. Lecomte-Beckers 79 Cut of a high performance ski Bidirectional layers. Glass fibres (±45° with ski axis). Provides torsion stiffness. Unidirectional layers. Glass fibres (mainly 0° but also 90°). Provides longitudinal stiffness. Core wrap. Bidirectional layers of glass fibres. Acts as torsion bar and joing external part of core. Bidirectional layer. Glass fibres (±45°). Provides torsion stiffness. Edge. Hardened steel. Eases in turns allowing ski to grip in snow. J. Lecomte-Beckers Upper part. ABS with low vitrous transition temperature. External wrap and appearance Side. ABS with low vitrous transition temperature. External wrap and appearance Core. Polyurethane. Improve Filling material. Damping layer. Polyurethane. Improve resistance to chattering. Unidirectional layers. Glass fibres (mainly 0° but also 90°). Provides longitudinal stiffness. Bidirectional layer. Glass fibres (±45°). Provides torsion stiffness. Sole. Compressed carbon (carbon fibres in a polymer matrix). Sliding surface is hard and abrasion resistant 80